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Upscaling to modules 升级到模块
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-17 DOI: 10.1038/s41560-025-01886-7
Stela Canulescu
The development of kesterite photovoltaic modules has long been hindered by low efficiencies and poor reproducibility. Researchers have now developed a solution-processing approach to achieve uniform and phase-pure kesterite films, enabling the fabrication of large-area modules with 10.1% efficiency.
长期以来,kesterite光伏组件的发展一直受到效率低和可重复性差的阻碍。研究人员现在已经开发出一种溶液处理方法来获得均匀且相纯的kesterite薄膜,从而能够以10.1%的效率制造大面积模块。
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引用次数: 0
Recoverable operation strategy for selective and stable electrochemical carbon dioxide reduction to methane 选择性稳定电化学二氧化碳还原为甲烷的可回收操作策略
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-16 DOI: 10.1038/s41560-025-01883-w
Guorui Gao, Behnam Nourmohammadi Khiarak, Hengzhou Liu, Thành Trần-Phú, Cornelius A. Obasanjo, Jackson Crane, Hung D. T. Lai, Gelson T. S. T. da Silva, Viktoria Golovanova, Jiantao Li, Huajie Ze, John Weiss, Zedong Zhang, Sungsik Lee, Rosalie K. Hocking, F. Pelayo García de Arquer, Edward H. Sargent, Cao-Thang Dinh
In the carbon dioxide (CO2) electroreduction reaction, catalysts determine, to a large extent, the system’s product selectivity, energy efficiency and stability. Conventionally, catalysts are prepared and optimized ex situ before the reaction, but they often suffer from low stability due to intrinsic structural changes during the reaction. Here we demonstrate a recoverable operation strategy for selective and stable electroreduction of CO2 to methane. In this approach, active catalysts are formed and fully reset in situ during CO2 electroreduction reaction. By stabilizing catalyst precursors and controlling the formation and removal of the catalysts, we demonstrate an over 500-hour CO2-to-methane conversion with a Faradaic efficiency of over 60% at the reduction current density of above 0.2 A cm−2 and full-cell voltage of below 4.0 V. We further showcase benefits of the recoverable operation for potential integration with intermittent renewable power supply, contributing to more than 100 days with day-on and night-off operation. Electrocatalysts for CO2 reduction are typically prepared and optimized ex situ before the reaction begins, but during reactions they may undergo changes that lower their performance. Here the authors show that active Cu catalysts can be formed on a recoverable basis and removed in situ during the CO2 reduction reaction, improving the stability of the system.
在二氧化碳(CO2)电还原反应中,催化剂在很大程度上决定了体系的产物选择性、能效和稳定性。传统上,催化剂是在反应前原位制备和优化的,但由于反应过程中固有结构的变化,催化剂的稳定性往往较低。在这里,我们展示了一种选择性和稳定的CO2电还原成甲烷的可回收操作策略。在这种方法中,活性催化剂在CO2电还原反应中形成并在原位完全复位。通过稳定催化剂前驱体并控制催化剂的形成和去除,我们证明了在还原电流密度高于0.2 a cm - 2和满电池电压低于4.0 V的情况下,co2到甲烷的转化时间超过500小时,法拉第效率超过60%。我们进一步展示了可恢复运行与间歇性可再生能源供应的潜在整合的好处,贡献了超过100天的昼夜交替运行。用于二氧化碳还原的电催化剂通常在反应开始前制备和优化,但在反应过程中,它们可能会发生变化,从而降低其性能。在CO2还原反应中,活性Cu催化剂可以在可回收的基础上形成并在原位去除,从而提高了体系的稳定性。
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引用次数: 0
Additives for thermal stability 热稳定性添加剂
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-10 DOI: 10.1038/s41560-025-01879-6
Hui-Seon Kim
In perovskite solar cells, the conventional n–i–p structure employing spiro-MeOTAD as a p-type hole transport layer suffers from poor thermal stability. Now, a non-volatile solid-state additive, 4-(N-carbazolyl)pyridine, is introduced to improve the thermal stability of spiro-MeOTAD and enable solar cells to perform more reliably under harsh conditions.
在钙钛矿太阳能电池中,采用spro - meotad作为p型空穴传输层的传统n-i-p结构热稳定性差。现在,一种非挥发性固态添加剂4-(n-咔唑基)吡啶被引入,以提高spiro-MeOTAD的热稳定性,并使太阳能电池在恶劣条件下更可靠地工作。
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引用次数: 0
Binding and release in balance 平衡地束缚和释放
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-10 DOI: 10.1038/s41560-025-01884-9
Federico Dattila
Integrating CO2 capture and electrochemical conversion may lower energy consumption relative to the separated processes, but scale-up is limited by low carbon conversion and energy-intensive solvent regeneration. Now, research shows that piperazine, alongside a Ni single-atom catalyst, allows effective, stable CO2 capture, and conversion to CO in a low-energy process.
与分离过程相比,将二氧化碳捕获和电化学转化相结合可以降低能耗,但扩大规模受到低碳转化和能源密集型溶剂再生的限制。现在,研究表明,哌嗪与Ni单原子催化剂一起,可以有效、稳定地捕获二氧化碳,并在低能量的过程中转化为CO。
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引用次数: 0
Isotropic armour for high-voltage operation 高压操作用各向同性护甲
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-10 DOI: 10.1038/s41560-025-01878-7
Shengjun Xu, Francesco Ciucci
High-voltage solid-state sodium batteries often fail at the cathode–electrolyte interface due to side reactions. An isotropic metal–organic framework epilayer that conformally coats the cathode particles helps prevent side reactions, enabling stable cycling at an unusually high cutoff voltage of 4.2 V (vs Na/Na+), exceeding the typical ~3.9 V (vs Na/Na+) limit for polyethylene oxide-based sodium cells.
高压固态钠电池在阴极-电解质界面由于副反应而失效。一种各向同性的金属-有机框架脱壳层以保形涂层覆盖在阴极颗粒上,有助于防止副反应,在4.2 V (vs Na/Na+)的异常高截止电压下实现稳定循环,超过了聚乙烯氧化物基钠电池的典型~3.9 V (vs Na/Na+)极限。
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引用次数: 0
Aromatic interaction-driven out-of-plane orientation for inverted perovskite solar cells with improved efficiency 芳香相互作用驱动的倒置钙钛矿太阳能电池的面外取向提高了效率
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-10 DOI: 10.1038/s41560-025-01882-x
Qisen Zhou, Guoyu Huang, Jianan Wang, Tianyin Miao, Rui Chen, Xia Lei, Erxiang Xu, Sanwan Liu, He Zhu, Zhengtian Tan, Chenyang Shi, Xiaoxuan Liu, Qianqian Wang, Jingbai Li, Yihua Chen, Qi Chen, Yang Shen, Manling Sui, Yue Lu, Zonghao Liu, Wei Chen
Formamidinium and caesium metal halide perovskites enable high efficiency in inverted perovskite solar cells, but uncontrolled crystallization limits their performance. Here we regulate the nucleation and growth of the perovskite through aromatic interactions between naphthalene ammonium salts and naphthalenesulfonates. The ammonium groups of the naphthalene ammonium salts occupy the formamidinium site, while the sulfonate groups of the naphthalenesulfonates coordinate with lead ions. Their naphthalene moieties form tight aromatic stacking adjacent to the [PbI6]4− octahedra. These interactions promote ordered out-of-plane crystallization along the (100) plane, enhancing defect passivation and carrier transport. We achieve a power conversion efficiency of 27.02% (certified 26.88%) for inverted solar cells. Encapsulated devices retain 98.2% of their initial efficiency after 2,000 h of maximum power point tracking under continuous illumination in ambient air. Furthermore, we demonstrate a certified steady-state efficiency of 23.18% for inverted mini-modules with an aperture area of 11.09 cm2 and a certified efficiency of 29.07% for all-perovskite tandem solar cells. Uncontrolled crystallization of perovskite limits the performance of solar cells. Zhou et al. address this through aromatic interactions between naphthalene ammonium salts and naphthalenesulfonates, achieving improved efficiency in cells and modules.
甲脒钙钛矿和金属卤化铯钙钛矿在倒置钙钛矿太阳能电池中具有很高的效率,但不受控制的结晶限制了它们的性能。在这里,我们通过萘铵盐和萘磺酸盐之间的芳香相互作用调节钙钛矿的成核和生长。萘铵盐的铵基占据甲脒位,而萘磺酸盐的磺酸基与铅离子配位。它们的萘部分在[PbI6]4 -八面体附近形成紧密的芳香层。这些相互作用促进沿(100)平面有序的面外结晶,增强缺陷钝化和载流子输运。我们实现了27.02%(认证26.88%)的反向太阳能电池的功率转换效率。封装设备在环境空气中连续照明下,在最大功率点跟踪2000小时后,其初始效率仍保持98.2%。此外,我们证明了孔径面积为11.09 cm2的倒置微型组件的认证稳态效率为23.18%,全钙钛矿串联太阳能电池的认证效率为29.07%。不受控制的钙钛矿结晶限制了太阳能电池的性能。Zhou等人通过萘铵盐和萘磺酸盐之间的芳香相互作用来解决这个问题,从而提高了电池和组件的效率。
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引用次数: 0
Sulfonated polybenzimidazole for low-alkalinity ion solvating membrane water electrolysis 磺化聚苯并咪唑用于低碱度离子溶剂化膜电解
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-10 DOI: 10.1038/s41560-025-01876-9
Muhammad Mara Ikhsan, Chaeyeon Yang, Kamal Ghotia, Franz Egert, Syed-Asif Ansar, Olga Żurowska, Maria Rózga, Artur Michalak, Mikkel Rykær Kraglund, David Aili, Hyun S. Park, Fatemeh Razmjooei, Dirk Henkensmeier
Ion solvating membranes based on polybenzimidazole (PBI) are alternatives to diaphragms in alkaline water electrolysers but can typically only operate with electrolyte concentrations of 15–30 wt% KOH. Sulfonation of the membrane broadens the operational range to 0.1 wt%–30 wt%; however, the swelling of sulfonated para-PBI means that crosslinkers are needed, complicating membrane fabrication and decreasing alkaline stability. Here we report a non-crosslinked PBI membrane with a 50% degree of sulfonation that shows a high room temperature conductivity in 1 M KOH of 135 mS cm−1. We did not observe degradation in a 6-month alkaline stability test at 80 °C. Using this membrane in an anion-exchange membrane water electrolyser, we report a current density of 4.8 A cm−2 at 2 V (3 M KOH at 80 °C; Pt and NiFe electrode catalysts); the H2 crossover to the O2 side remained <2%. Using non-platinum group metal electrodes and a polyphenylene sulfide-reinforced membrane, a cell operated for >1,000 h without failure. KOH-doped membranes, so-called ion-solvating membranes (ISMs), have been used in alkaline water electrolysers but face challenges with stability and narrow operational windows. Here a non-crosslinked, partially sulfonated polybenzimidazole ISM with enhanced conductivity and stability is reported, achieving high current densities and prolonged operation.
基于聚苯并咪唑(PBI)的离子溶剂化膜是碱水电解槽隔膜的替代品,但通常只能在电解质浓度为15-30 wt% KOH的情况下工作。膜的磺化将操作范围扩大到0.1 wt% -30 wt%;然而,磺化的para-PBI膨胀意味着需要交联剂,使膜制作复杂化,降低了碱性稳定性。在这里,我们报道了一种磺化度为50%的非交联PBI膜,在1 M KOH下,其室温电导率为135 mS cm−1。在80°C下进行的为期6个月的碱性稳定性试验中,我们没有观察到降解。在阴离子交换膜中使用该膜,我们报道了在2 V (3 M KOH, 80°C, Pt和NiFe电极催化剂)下电流密度为4.8 a cm−2;H2向O2侧的交叉保持了2%。使用非铂族金属电极和聚苯硫醚增强膜,电池运行1000小时无故障。氢氧化钾掺杂膜,即所谓的离子溶剂化膜(ISMs),已被用于碱性水电解槽,但面临稳定性和窄操作窗口的挑战。本文报道了一种非交联、部分磺化的多苯并咪唑ISM,具有增强的电导率和稳定性,实现了高电流密度和长时间的操作。
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引用次数: 0
Bringing deformability to lithium metal 为锂金属带来可变形性
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-03 DOI: 10.1038/s41560-025-01877-8
Nohjoon Lee, Insu Hwang, Jang Wook Choi
Void formation between the solid electrolyte layer and electrode is a critical barrier to the long-term operation of solid-state batteries. Now, an electrochemically inactive yet mechanically soft metallic phase is integrated into the lithium metal anode, which preserves the electrical contact and enables reliable operation in practical cell settings.
固体电解质层与电极之间的空隙形成是固态电池长期工作的关键障碍。现在,一种电化学上不活跃但机械上柔软的金属相被集成到锂金属阳极中,从而保持了电接触,并在实际电池设置中实现了可靠的操作。
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引用次数: 0
Overcoming high-voltage limits in all-solid-state batteries with a fluoride-based shielding layer 用氟基屏蔽层克服全固态电池的高电压限制
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-03 DOI: 10.1038/s41560-025-01866-x
Voltage instability of battery materials has hindered the realization of high-voltage all-solid-state batteries (ASSBs). Now, 5 V-class ASSBs are enabled by a fluoride-based shielding layer, LiCl–4Li2TiF6, that combines high oxidative stability and Li+ conductivity. Applied to high-voltage cathodes, the shielding layer mitigates interfacial degradation and enables stable cycling at >5 V, including under high-capacity conditions.
电池材料的电压不稳定性阻碍了高压全固态电池(assb)的实现。现在,5个v级assb由基于氟化物的屏蔽层LiCl-4Li2TiF6实现,该屏蔽层结合了高氧化稳定性和Li+导电性。应用于高压阴极,屏蔽层减轻了界面退化,并在>; 5v下实现稳定循环,包括在高容量条件下。
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引用次数: 0
Swapping membranes for separators 用隔膜交换隔膜
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-03 DOI: 10.1038/s41560-025-01833-6
Charles E. Creissen
Carbon monoxide electrolysis has the potential to defossilize the production of chemicals and fuels, but its widespread adoption requires costs to be reduced. Now, an electrolysis device using a separator instead of a membrane achieves high-rate ethylene production with a low electricity input.
一氧化碳电解法有可能使化学制品和燃料的生产脱除化石,但它的广泛采用需要降低成本。现在,一种使用分离器代替膜的电解装置以低电力输入实现了高速率乙烯生产。
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引用次数: 0
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Nature Energy
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