首页 > 最新文献

SPIE Advanced Lithography最新文献

英文 中文
Influence of template fill in graphoepitaxy DSA 模板填充对石墨外延DSA的影响
Pub Date : 2016-03-25 DOI: 10.1117/12.2219580
J. Doise, J. Bekaert, B. T. Chan, Sungeun Hong, Guanyang Lin, R. Gronheid
Directed self-assembly (DSA) of block copolymers (BCP) is considered a promising patterning approach for the 7 nm node and beyond. Specifically, a grapho-epitaxy process using a cylindrical phase BCP may offer an efficient solution for patterning randomly distributed contact holes with sub-resolution pitches, such as found in via and cut mask levels. In any grapho-epitaxy process, the pattern density impacts the template fill (local BCP thickness inside the template) and may cause defects due to respectively over- or underfilling of the template. In order to tackle this issue thoroughly, the parameters that determine template fill and the influence of template fill on the resulting pattern should be investigated. In this work, using three process flow variations (with different template surface energy), template fill is experimentally characterized as a function of pattern density and film thickness. The impact of these parameters on template fill is highly dependent on the process flow, and thus pre-pattern surface energy. Template fill has a considerable effect on the pattern transfer of the DSA contact holes into the underlying layer. Higher fill levels give rise to smaller contact holes and worse critical dimension uniformity. These results are important towards DSA-aware design and show that fill is a crucial parameter in grapho-epitaxy DSA.
嵌段共聚物(BCP)的定向自组装(DSA)被认为是一种很有前途的7纳米节点及以上的模式方法。具体来说,使用圆柱形相BCP的石墨外延工艺可以为具有亚分辨率螺距的随机分布的接触孔提供有效的解决方案,例如在过孔和剪切掩膜层中发现。在任何石墨外延过程中,图案密度都会影响模板填充(模板内部的局部BCP厚度),并可能由于模板的过填充或欠填充而导致缺陷。为了彻底解决这一问题,应该研究确定模板填充的参数以及模板填充对最终图案的影响。在这项工作中,使用三种工艺流程变化(具有不同的模板表面能),模板填充被实验表征为图案密度和薄膜厚度的函数。这些参数对模板填充的影响高度依赖于工艺流程,因此预模表面能。模板填充对DSA接触孔向下层的图案传递有相当大的影响。较高的填充水平会导致接触孔变小,临界尺寸均匀性变差。这些结果对DSA感知设计具有重要意义,并表明填充是石墨外延DSA的关键参数。
{"title":"Influence of template fill in graphoepitaxy DSA","authors":"J. Doise, J. Bekaert, B. T. Chan, Sungeun Hong, Guanyang Lin, R. Gronheid","doi":"10.1117/12.2219580","DOIUrl":"https://doi.org/10.1117/12.2219580","url":null,"abstract":"Directed self-assembly (DSA) of block copolymers (BCP) is considered a promising patterning approach for the 7 nm node and beyond. Specifically, a grapho-epitaxy process using a cylindrical phase BCP may offer an efficient solution for patterning randomly distributed contact holes with sub-resolution pitches, such as found in via and cut mask levels. In any grapho-epitaxy process, the pattern density impacts the template fill (local BCP thickness inside the template) and may cause defects due to respectively over- or underfilling of the template. In order to tackle this issue thoroughly, the parameters that determine template fill and the influence of template fill on the resulting pattern should be investigated. In this work, using three process flow variations (with different template surface energy), template fill is experimentally characterized as a function of pattern density and film thickness. The impact of these parameters on template fill is highly dependent on the process flow, and thus pre-pattern surface energy. Template fill has a considerable effect on the pattern transfer of the DSA contact holes into the underlying layer. Higher fill levels give rise to smaller contact holes and worse critical dimension uniformity. These results are important towards DSA-aware design and show that fill is a crucial parameter in grapho-epitaxy DSA.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"16 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128871898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Net tracing and classification analysis on E-beam die-to-database inspection 电子束模对库检测的网络溯源与分类分析
Pub Date : 2016-03-25 DOI: 10.1117/12.2235347
Weihong Gao, Xuefeng Zeng, Peter Lin, Yan Pan, Ho Young Song, Hoang Nguyen, Na Cai, Zhijin Chen, Khurram Zafar
A novel classification methodology is constructed for Electron Beam (E-Beam) die-to-database (D2DB) inspection results on contact and via layers. It is a design guided defects classification flow that helps to pin-point true defects from a large amount of false alarm defects. Die-to-database E-beam inspection has remarkable features that can help find systematic defects such as Damaged Via and Missing Via; which will be reported as DVC (Dark Voltage Contrast) defects. However, the D2DB result usually reports millions of defects that lie on both ‘active via’ and ‘floating via’, the former being defects-of-interest (DOI), and the latter being of little significance. The indiscriminant mixture of DOI (on active vias) and nuisance (on floating vias) is a challenge in the use of D2DB for finding systematic via defects. We overcome this challenge by overlaying the E-beam defect location onto the design layout file (GDS or OASIS) and tracing the path of the via to determine whether or not it connects to the active or diffusion layer. Our proposed flow uses Net Tracing Classification (NTC) feature in Anchor Hotspot Solution (AHS) to classify all the reported DVC defects into different groups, according to the electrical connectivity of the contact. This classification involves multiple interconnected process layers. All the reported DVC defects will be classified into three groups: (1) Real DVC defects, in which the net traces down to active layer; (2) False DVC type 1, in which the net traces down to gate (which is always dark); (3) False DVC type 2, in which the net traces down to floating metal (which is always dark as well). This enhanced defect classification is greatly helpful in separating real DVC contact/via defects from false alarms. It has a secondary benefit of reducing the total number of defects, which is helpful for subsequent in-depth data analysis. In addition, the verified real DVC locations can be used to generate care areas for E-Beam die-to-die (D2D) inspection, which can effectively improve throughput and reduce the turn-around-time (TAT). In this paper, we will discuss a use case at the Vx layer.
建立了一种新的电子束(E-Beam)模对库(D2DB)接触层和通孔层检测结果的分类方法。它是一种设计引导的缺陷分类流程,有助于从大量的假警报缺陷中精确地指出真正的缺陷。模具到数据库电子束检测具有显著的特点,可以帮助发现系统缺陷,如破损的通孔和缺失的通孔;这将被报告为DVC(暗电压对比)缺陷。然而,D2DB结果通常报告数百万个位于“活动通道”和“浮动通道”上的缺陷,前者是兴趣缺陷(DOI),后者没有什么意义。DOI(在活动通孔上)和滋扰(在浮动通孔上)的混杂是使用D2DB查找系统通孔缺陷的挑战。我们将电子束缺陷位置叠加到设计布局文件(GDS或OASIS)上,并跟踪通孔的路径,以确定它是否连接到有源层或扩散层,从而克服了这一挑战。我们提出的流程使用锚点热点解决方案(AHS)中的网络跟踪分类(NTC)功能,根据触点的电连通性将所有报告的DVC缺陷分类为不同的组。这种分类涉及多个相互连接的流程层。所有报告的DVC缺陷将被分为三组:(1)真实的DVC缺陷,其中网络追踪到活动层;(2)假DVC 1型,网络一直追踪到门(门总是暗的);(3)假DVC类型2,其中网络追溯到浮动金属(也总是黑色的)。这种增强的缺陷分类非常有助于将真正的DVC接触/通道缺陷与错误警报分开。它的第二个好处是减少缺陷的总数,这对后续深入的数据分析很有帮助。此外,经过验证的真实DVC位置可用于生成E-Beam模对模(D2D)检查的护理区域,从而有效提高吞吐量并减少周转时间(TAT)。在本文中,我们将讨论Vx层的一个用例。
{"title":"Net tracing and classification analysis on E-beam die-to-database inspection","authors":"Weihong Gao, Xuefeng Zeng, Peter Lin, Yan Pan, Ho Young Song, Hoang Nguyen, Na Cai, Zhijin Chen, Khurram Zafar","doi":"10.1117/12.2235347","DOIUrl":"https://doi.org/10.1117/12.2235347","url":null,"abstract":"A novel classification methodology is constructed for Electron Beam (E-Beam) die-to-database (D2DB) inspection results on contact and via layers. It is a design guided defects classification flow that helps to pin-point true defects from a large amount of false alarm defects. Die-to-database E-beam inspection has remarkable features that can help find systematic defects such as Damaged Via and Missing Via; which will be reported as DVC (Dark Voltage Contrast) defects. However, the D2DB result usually reports millions of defects that lie on both ‘active via’ and ‘floating via’, the former being defects-of-interest (DOI), and the latter being of little significance. The indiscriminant mixture of DOI (on active vias) and nuisance (on floating vias) is a challenge in the use of D2DB for finding systematic via defects. We overcome this challenge by overlaying the E-beam defect location onto the design layout file (GDS or OASIS) and tracing the path of the via to determine whether or not it connects to the active or diffusion layer. Our proposed flow uses Net Tracing Classification (NTC) feature in Anchor Hotspot Solution (AHS) to classify all the reported DVC defects into different groups, according to the electrical connectivity of the contact. This classification involves multiple interconnected process layers. All the reported DVC defects will be classified into three groups: (1) Real DVC defects, in which the net traces down to active layer; (2) False DVC type 1, in which the net traces down to gate (which is always dark); (3) False DVC type 2, in which the net traces down to floating metal (which is always dark as well). This enhanced defect classification is greatly helpful in separating real DVC contact/via defects from false alarms. It has a secondary benefit of reducing the total number of defects, which is helpful for subsequent in-depth data analysis. In addition, the verified real DVC locations can be used to generate care areas for E-Beam die-to-die (D2D) inspection, which can effectively improve throughput and reduce the turn-around-time (TAT). In this paper, we will discuss a use case at the Vx layer.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122629759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Acid generation efficiency: EUV photons versus photoelectrons 产酸效率:EUV光子与光电子
Pub Date : 2016-03-25 DOI: 10.1117/12.2218457
D. Goldfarb, A. Afzali-Ardakani, M. Glodde
EUV photoacid generation efficiency has been described primarily in terms of the EUV photon absorption by the PAG or the resist matrix and the production of low energy photoelectrons, which are reported as being ultimately responsible for the high quantum efficiencies reported in EUV resists (<1). Such observation led to a number of recent studies on PAGs with variable electron affinity (EA) and reduction potential (Ered) presumably conducive to a differential EUV photoelectron harvesting efficiency. However, such studies either did not disclose the PAG chemical structures, replaced the EUV source with an e-beam source, or lacked a fundamental discussion of the underlying physical mechanisms behind EUV PAG decomposition. In this work, we report the EUV photospeed of a methacrylatebased resist formulated with a battery of openly disclosed isostructural sulfonium PAGs covering a wide range of EA’s and Ered’s, to unveil any preferential photoelectron scavenging effect. In parallel, several iodonium PAGs are also tested in order to compare the direct EUV photon absorption route to the photoelectron-based decomposition path. Contrarily to what has been widely reported, we have found no direct correlation whatsoever between photospeed and the calculated EA’s or experimental Ered’s for the isostructural sulfonium PAGs studied. Instead, we found that iodonium PAGs make more efficient use of the available EUV power due to their higher photoabsorption cross-section. Additionally, we determined a cation size effect for both PAG groups, which is able to further modulate the acid generation efficiency. Finally, we present a formal explanation for the unselective response towards photoelectron harvesting based on the stabilization of the PAG cation by bulky substituent groups, the spatial and temporal range of the transient photoelectron and the differences in electron transfer processes for the different systems studied.
EUV光酸的产生效率主要是根据PAG或抗蚀剂基质吸收EUV光子和产生低能光电子来描述的,据报道,这是EUV抗蚀剂中报道的高量子效率的最终原因(<1)。这种观察导致了最近对具有可变电子亲和力(EA)和还原电位(Ered)的pag的许多研究,这些研究可能有助于差分EUV光电子收集效率。然而,这些研究要么没有揭示PAG的化学结构,要么用电子束源代替EUV源,要么缺乏对EUV PAG分解背后潜在物理机制的基本讨论。在这项工作中,我们报告了一种甲基丙烯酸酯基抗蚀剂的EUV光速,该抗蚀剂由公开公开的等结构磺化膜组成,覆盖了广泛的EA和ed,以揭示任何优先的光电子清除作用。同时,为了比较直接的EUV光子吸收路径和基于光电子的分解路径,还测试了几种碘离子pag。与广泛报道的结果相反,我们发现,对于所研究的等结构磺胺pag,在计算EA和实验ed之间没有直接的相关性。相反,我们发现碘pag由于其更高的光吸收截面,可以更有效地利用可用的EUV功率。此外,我们确定了两个PAG组的阳离子尺寸效应,这能够进一步调节酸的产生效率。最后,我们根据大体积取代基对PAG阳离子的稳定性、瞬态光电子的时空范围以及不同系统中电子转移过程的差异,对光电子捕获的非选择性响应提出了正式的解释。
{"title":"Acid generation efficiency: EUV photons versus photoelectrons","authors":"D. Goldfarb, A. Afzali-Ardakani, M. Glodde","doi":"10.1117/12.2218457","DOIUrl":"https://doi.org/10.1117/12.2218457","url":null,"abstract":"EUV photoacid generation efficiency has been described primarily in terms of the EUV photon absorption by the PAG or the resist matrix and the production of low energy photoelectrons, which are reported as being ultimately responsible for the high quantum efficiencies reported in EUV resists (<1). Such observation led to a number of recent studies on PAGs with variable electron affinity (EA) and reduction potential (Ered) presumably conducive to a differential EUV photoelectron harvesting efficiency. However, such studies either did not disclose the PAG chemical structures, replaced the EUV source with an e-beam source, or lacked a fundamental discussion of the underlying physical mechanisms behind EUV PAG decomposition. In this work, we report the EUV photospeed of a methacrylatebased resist formulated with a battery of openly disclosed isostructural sulfonium PAGs covering a wide range of EA’s and Ered’s, to unveil any preferential photoelectron scavenging effect. In parallel, several iodonium PAGs are also tested in order to compare the direct EUV photon absorption route to the photoelectron-based decomposition path. Contrarily to what has been widely reported, we have found no direct correlation whatsoever between photospeed and the calculated EA’s or experimental Ered’s for the isostructural sulfonium PAGs studied. Instead, we found that iodonium PAGs make more efficient use of the available EUV power due to their higher photoabsorption cross-section. Additionally, we determined a cation size effect for both PAG groups, which is able to further modulate the acid generation efficiency. Finally, we present a formal explanation for the unselective response towards photoelectron harvesting based on the stabilization of the PAG cation by bulky substituent groups, the spatial and temporal range of the transient photoelectron and the differences in electron transfer processes for the different systems studied.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"42 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116916111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 24
CD bias control on hole pattern 孔型的CD偏置控制
Pub Date : 2016-03-25 DOI: 10.1117/12.2218961
K. Koike, A. Hara, Sakurako Natori, Shohei Yamauchi, Masatoshi Yamato, K. Oyama, H. Yaegashi
Gridded design rules[1] is major process in configuring logic circuit used 193-immersion lithography. In the scaling of grid patterning, we can make 10nm order line and space pattern by using multiple patterning techniques such as self-aligned multiple patterning (SAMP) and litho-etch- litho-etch (LELE)[2][3][5] . On the other hand, Line cut process has some error parameters such as pattern defect, placement error, roughness and X-Y CD bias with the decreasing scale. Especially roughness and X-Y CD bias are paid attention because it cause cut error and pattern defect. In this case, we applied some smoothing process to care hole roughness[4]. Each smoothing process showed different effect on X-Y CD bias. In this paper, we will report the pattern controllability comparison of trench and block + inverse. It include X-Y CD bias, roughness and process usability. Furthermore we will discuss optimum method focused on X-Y CD bias when we use additional process such as smoothing and shrink etching .
网格化设计规则[1]是193浸没光刻逻辑电路配置的主要过程。在网格图形的缩放方面,我们可以利用自对准多重图形(SAMP)和光刻-光刻(LELE)[2][3][5]等多种图形技术制作10nm的有序线和空间图形。另一方面,线切割过程中存在一些误差参数,如图案缺陷、放置误差、粗糙度和X-Y CD偏差。特别是粗糙度和X-Y CD偏差引起了切割误差和图案缺陷。在这种情况下,我们应用了一些平滑处理来照顾孔的粗糙度[4]。每种平滑处理对X-Y - CD偏置的影响不同。在本文中,我们将报道沟槽和块体+逆的模式可控性比较。它包括X-Y CD偏差,粗糙度和工艺可用性。此外,我们将讨论在使用平滑和收缩蚀刻等附加工艺时,以X-Y CD偏置为重点的最佳方法。
{"title":"CD bias control on hole pattern","authors":"K. Koike, A. Hara, Sakurako Natori, Shohei Yamauchi, Masatoshi Yamato, K. Oyama, H. Yaegashi","doi":"10.1117/12.2218961","DOIUrl":"https://doi.org/10.1117/12.2218961","url":null,"abstract":"Gridded design rules[1] is major process in configuring logic circuit used 193-immersion lithography. In the scaling of grid patterning, we can make 10nm order line and space pattern by using multiple patterning techniques such as self-aligned multiple patterning (SAMP) and litho-etch- litho-etch (LELE)[2][3][5] . On the other hand, Line cut process has some error parameters such as pattern defect, placement error, roughness and X-Y CD bias with the decreasing scale. Especially roughness and X-Y CD bias are paid attention because it cause cut error and pattern defect. In this case, we applied some smoothing process to care hole roughness[4]. Each smoothing process showed different effect on X-Y CD bias. In this paper, we will report the pattern controllability comparison of trench and block + inverse. It include X-Y CD bias, roughness and process usability. Furthermore we will discuss optimum method focused on X-Y CD bias when we use additional process such as smoothing and shrink etching .","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"9779 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130252315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Enhancing the Novolak resin resist resolution by adding phenol to fractionated resin 在分馏树脂中加入苯酚,提高Novolak树脂抗拆分能力
Pub Date : 2016-03-25 DOI: 10.1117/12.2218948
A. Sekiguchi, Y. Matsumoto, H. Tanaka, T. Horiuchi, Yoshihisa Sensu, S. Takei, M. Hanabata
Novolak resists have been widely used in IC production and are still used in the production of flat panel displays (FPDs) and MEMS. However, with the advent of high-definition products, FPDs increasingly face requirements for finer dimensions. These trends have generated requirements for higher sensitivity, higher resolution, and wider process margin for novolak resists. Using a lithography simulator with the goal of improving the performance of novolak resists, we examined various approaches to improving resist materials. This report discusses efforts to improve resolution and sensitivity using highly fractionated novolak resins and adding low molecular weight phenol resins.
诺瓦拉克电阻已广泛应用于集成电路生产,并仍用于生产平板显示器(FPDs)和MEMS。然而,随着高清晰度产品的出现,FPDs越来越面临更精细尺寸的要求。这些趋势产生了对诺瓦拉克电阻更高灵敏度、更高分辨率和更宽工艺裕度的要求。利用光刻模拟器,以提高诺瓦拉克电阻的性能为目标,我们研究了改善诺瓦拉克电阻材料的各种方法。本报告讨论了利用高分馏诺沃拉克树脂和添加低分子量苯酚树脂来提高分辨率和灵敏度的努力。
{"title":"Enhancing the Novolak resin resist resolution by adding phenol to fractionated resin","authors":"A. Sekiguchi, Y. Matsumoto, H. Tanaka, T. Horiuchi, Yoshihisa Sensu, S. Takei, M. Hanabata","doi":"10.1117/12.2218948","DOIUrl":"https://doi.org/10.1117/12.2218948","url":null,"abstract":"Novolak resists have been widely used in IC production and are still used in the production of flat panel displays (FPDs) and MEMS. However, with the advent of high-definition products, FPDs increasingly face requirements for finer dimensions. These trends have generated requirements for higher sensitivity, higher resolution, and wider process margin for novolak resists. Using a lithography simulator with the goal of improving the performance of novolak resists, we examined various approaches to improving resist materials. This report discusses efforts to improve resolution and sensitivity using highly fractionated novolak resins and adding low molecular weight phenol resins.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"103 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134022493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Characterization of 'metal resist' for EUV lithography EUV光刻用“金属抗蚀剂”的表征
Pub Date : 2016-03-25 DOI: 10.1117/12.2219030
M. Toriumi, Y. Sato, R. Kumai, Y. Yamashita, K. Tsukiyama, T. Itani
We characterized EIDEC metal resist for EUV lithography by various measurement methods. The low-voltage aberration-corrected scanning transmission electron microscopy combined with electron energy-loss spectroscopy showed the morphology of metal resists in nanometer regions and enabled studying the distribution of resist component in the resist film. The zirconium oxide metal resist kept the core-shell structure in the resist films and the titanium oxide metal resist showed the aggregation in the film. X-ray diffractometry and ab initio molecular dynamics simulation showed the amorphous structure with short-range order of the zirconium oxide metal resist. X-ray Photoelectron spectroscopy of the zirconium oxide-methacrylic acid metal resist showed the decomposition of the shell molecules and the increase of electron density at zirconium atoms after the EUV exposure. Infrared (IR) spectra indicated that the shell molecules made the various bindings to the metal core and the specific vibrational mode of shell molecules showed the divergent responsivity to the irradiation wavenumber of the IR Free electron laser.
采用各种测量方法对EIDEC金属抗蚀剂进行了表征。低压像差校正扫描透射电子显微镜结合电子能量损耗谱显示了金属抗蚀剂在纳米区域的形态,从而研究了抗蚀剂成分在抗蚀膜中的分布。氧化锆金属抗蚀剂在抗蚀膜中保持核壳结构,氧化钛金属抗蚀剂在膜中呈聚集状。x射线衍射和从头算分子动力学模拟表明,氧化锆金属抗蚀剂具有短程有序的非晶态结构。氧化锆-甲基丙烯酸金属抗蚀剂的x射线光电子能谱显示,EUV照射后,氧化锆-甲基丙烯酸金属抗蚀剂的壳层分子分解,锆原子处的电子密度增加。红外光谱表明,壳层分子与金属核发生了不同的结合,壳层分子的特定振动模式对红外自由电子激光的辐照波数表现出发散性响应。
{"title":"Characterization of 'metal resist' for EUV lithography","authors":"M. Toriumi, Y. Sato, R. Kumai, Y. Yamashita, K. Tsukiyama, T. Itani","doi":"10.1117/12.2219030","DOIUrl":"https://doi.org/10.1117/12.2219030","url":null,"abstract":"We characterized EIDEC metal resist for EUV lithography by various measurement methods. The low-voltage aberration-corrected scanning transmission electron microscopy combined with electron energy-loss spectroscopy showed the morphology of metal resists in nanometer regions and enabled studying the distribution of resist component in the resist film. The zirconium oxide metal resist kept the core-shell structure in the resist films and the titanium oxide metal resist showed the aggregation in the film. X-ray diffractometry and ab initio molecular dynamics simulation showed the amorphous structure with short-range order of the zirconium oxide metal resist. X-ray Photoelectron spectroscopy of the zirconium oxide-methacrylic acid metal resist showed the decomposition of the shell molecules and the increase of electron density at zirconium atoms after the EUV exposure. Infrared (IR) spectra indicated that the shell molecules made the various bindings to the metal core and the specific vibrational mode of shell molecules showed the divergent responsivity to the irradiation wavenumber of the IR Free electron laser.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"42 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123371140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
A physical resist shrinkage model for full-chip lithography simulations 全片光刻模拟的物理抗蚀收缩模型
Pub Date : 2016-03-25 DOI: 10.1117/12.2239243
Peng-xin Liu, Leiwu Zheng, M. Ma, Qian Zhao, Yongfa Fan, Qiang Q. Zhang, Mu Feng, Xin Guo, Tom Wallow, K. Gronlund, R. Goossens, Gary Zhang, Yen-Wen Lu
Strong resist shrinkage effects have been widely observed in resist profiles after negative tone development (NTD) and therefore must be taken into account in computational lithography applications. However, existing lithography simulation tools, especially those designed for full-chip applications, lack resist shrinkage modeling capabilities because they are not needed until only recently when NTD processes begin to replace the conventional positive tone development (PTD) processes where resist shrinkage effects are negligible. In this work we describe the development of a physical resist shrinkage (PRS) model for full-chip lithography simulations and present its accuracy evaluation against experimental data.
在负色调显影(NTD)后的抗蚀剂轮廓中广泛观察到强烈的抗蚀剂收缩效应,因此在计算光刻应用中必须考虑到这一点。然而,现有的光刻模拟工具,特别是那些为全芯片应用而设计的工具,缺乏抗缩建模能力,因为直到最近NTD工艺开始取代传统的正色调显影(PTD)工艺时,才需要它们,而PTD工艺的抗缩效应可以忽略不计。在这项工作中,我们描述了全芯片光刻模拟的物理抗收缩(PRS)模型的发展,并根据实验数据提出了其准确性评估。
{"title":"A physical resist shrinkage model for full-chip lithography simulations","authors":"Peng-xin Liu, Leiwu Zheng, M. Ma, Qian Zhao, Yongfa Fan, Qiang Q. Zhang, Mu Feng, Xin Guo, Tom Wallow, K. Gronlund, R. Goossens, Gary Zhang, Yen-Wen Lu","doi":"10.1117/12.2239243","DOIUrl":"https://doi.org/10.1117/12.2239243","url":null,"abstract":"Strong resist shrinkage effects have been widely observed in resist profiles after negative tone development (NTD) and therefore must be taken into account in computational lithography applications. However, existing lithography simulation tools, especially those designed for full-chip applications, lack resist shrinkage modeling capabilities because they are not needed until only recently when NTD processes begin to replace the conventional positive tone development (PTD) processes where resist shrinkage effects are negligible. In this work we describe the development of a physical resist shrinkage (PRS) model for full-chip lithography simulations and present its accuracy evaluation against experimental data.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115195619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Spin-on metal oxide materials with high etch selectivity and wet strippability 具有高蚀刻选择性和湿剥离性的自旋金属氧化物材料
Pub Date : 2016-03-25 DOI: 10.1117/12.2220293
H. Yao, S. Mullen, E. Wolfer, D. Mckenzie, D. Rahman, JoonYeon Cho, M. Padmanaban, C. Petermann, Sungeun Hong, Y. Her
Metal oxide or metal nitride films are used as hard mask materials in semiconductor industry for patterning purposes due to their excellent etch resistances against the plasma etches. Chemical vapor deposition (CVD) or atomic layer deposition (ALD) techniques are usually used to deposit the metal containing materials on substrates or underlying films, which uses specialized equipment and can lead to high cost-of-ownership and low throughput. We have reported novel spin-on coatings that provide simple and cost effective method to generate metal oxide films possessing good etch selectivity and can be removed by chemical agents. In this paper, new spin-on Al oxide and Zr oxide hard mask formulations are reported. The new metal oxide formulations provide higher metal content compared to previously reported material of specific metal oxides under similar processing conditions. These metal oxide films demonstrate ultra-high etch selectivity and good pattern transfer capability. The cured films can be removed by various chemical agents such as developer, solvents or wet etchants/strippers commonly used in the fab environment. With high metal MHM material as an underlayer, the pattern transfer process is simplified by reducing the number of layers in the stack and the size of the nano structure is minimized by replacement of a thicker film ACL. Therefore, these novel AZ® spinon metal oxide hard mask materials can potentially be used to replace any CVD or ALD metal, metal oxide, metal nitride or spin-on silicon-containing hard mask films in 193 nm or EUV process.
由于金属氧化物或金属氮化膜具有优异的抗等离子体腐蚀性能,因此在半导体工业中用作图像化用途的硬掩膜材料。化学气相沉积(CVD)或原子层沉积(ALD)技术通常用于在衬底或底层薄膜上沉积含金属材料,这需要使用专门的设备,并且可能导致高拥有成本和低吞吐量。我们报道了一种新的自旋涂层,它提供了一种简单而经济的方法来生成具有良好蚀刻选择性的金属氧化物膜,并且可以被化学剂去除。本文报道了新的自旋氧化铝和氧化锆硬掩膜配方。与先前报道的在类似加工条件下的特定金属氧化物材料相比,新的金属氧化物配方提供了更高的金属含量。这些金属氧化物薄膜具有超高的蚀刻选择性和良好的图案转移能力。固化的薄膜可以用各种化学试剂去除,如显影剂、溶剂或工厂环境中常用的湿蚀刻剂/剥离剂。使用高金属MHM材料作为底层,通过减少堆叠层数来简化图案转移过程,并通过替换较厚的薄膜ACL来最小化纳米结构的尺寸。因此,这些新型的AZ®自旋金属氧化物硬掩膜材料可以潜在地用于取代任何CVD或ALD金属,金属氧化物,金属氮化物或自旋含硅硬掩膜在193nm或EUV工艺。
{"title":"Spin-on metal oxide materials with high etch selectivity and wet strippability","authors":"H. Yao, S. Mullen, E. Wolfer, D. Mckenzie, D. Rahman, JoonYeon Cho, M. Padmanaban, C. Petermann, Sungeun Hong, Y. Her","doi":"10.1117/12.2220293","DOIUrl":"https://doi.org/10.1117/12.2220293","url":null,"abstract":"Metal oxide or metal nitride films are used as hard mask materials in semiconductor industry for patterning purposes due to their excellent etch resistances against the plasma etches. Chemical vapor deposition (CVD) or atomic layer deposition (ALD) techniques are usually used to deposit the metal containing materials on substrates or underlying films, which uses specialized equipment and can lead to high cost-of-ownership and low throughput. We have reported novel spin-on coatings that provide simple and cost effective method to generate metal oxide films possessing good etch selectivity and can be removed by chemical agents. In this paper, new spin-on Al oxide and Zr oxide hard mask formulations are reported. The new metal oxide formulations provide higher metal content compared to previously reported material of specific metal oxides under similar processing conditions. These metal oxide films demonstrate ultra-high etch selectivity and good pattern transfer capability. The cured films can be removed by various chemical agents such as developer, solvents or wet etchants/strippers commonly used in the fab environment. With high metal MHM material as an underlayer, the pattern transfer process is simplified by reducing the number of layers in the stack and the size of the nano structure is minimized by replacement of a thicker film ACL. Therefore, these novel AZ® spinon metal oxide hard mask materials can potentially be used to replace any CVD or ALD metal, metal oxide, metal nitride or spin-on silicon-containing hard mask films in 193 nm or EUV process.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114896664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel ArF extension technique by applying Dry Development Rinse Process (DDRP) and Materials (DDRM) 基于干显影漂洗工艺(DDRP)和材料(DDRM)的新型ArF扩展技术
Pub Date : 2016-03-25 DOI: 10.1117/12.2219521
Wataru Shibayama, Shuhei Shigaki, S. Takeda, R. Onishi, M. Nakajima, Rikimaru Sakamoto
ArF lithography is still major process to develop N7/N5 devices. Especially in resist materials, DOF, roughness and CD uniformity are the biggest key parameters in fine pitches. To improve these issues, we newly propose to apply Dry Development Rinse Process (DDRP) and Materials (DDRM) as the ArF extension approach. In EUV lithography, DDRP is already one of the approaches to achieve high resolution. However, the performance of DDRP for ArF lithography was never demonstrated in detail. In this paper, we especially focus to improve DOF, CD uniformity and roughness by applying DDRP for ArF generation. Finally we succeeded to enhance every parameter at the same time by controlling DDRM etching condition. This new DDRP technology can be the promising approach for ArF extension stages in N7/N5 and beyond.
ArF光刻仍然是开发N7/N5器件的主要工艺。特别是在抗蚀剂材料中,自由度、粗糙度和CD均匀性是精细节距的最大关键参数。为了改善这些问题,我们新提出将干显影漂洗工艺(DDRP)和材料(DDRM)作为ArF的延伸方法。在极紫外光刻技术中,DDRP已经成为实现高分辨率的方法之一。然而,DDRP在ArF光刻中的性能从未得到详细的证明。在本文中,我们特别关注通过DDRP生成ArF来改善DOF、CD均匀性和粗糙度。最后通过控制DDRM刻蚀条件,成功地同时提高了各参数的精度。这种新的DDRP技术可能是N7/N5及以后的ArF扩展阶段的有希望的方法。
{"title":"Novel ArF extension technique by applying Dry Development Rinse Process (DDRP) and Materials (DDRM)","authors":"Wataru Shibayama, Shuhei Shigaki, S. Takeda, R. Onishi, M. Nakajima, Rikimaru Sakamoto","doi":"10.1117/12.2219521","DOIUrl":"https://doi.org/10.1117/12.2219521","url":null,"abstract":"ArF lithography is still major process to develop N7/N5 devices. Especially in resist materials, DOF, roughness and CD uniformity are the biggest key parameters in fine pitches. To improve these issues, we newly propose to apply Dry Development Rinse Process (DDRP) and Materials (DDRM) as the ArF extension approach. In EUV lithography, DDRP is already one of the approaches to achieve high resolution. However, the performance of DDRP for ArF lithography was never demonstrated in detail. In this paper, we especially focus to improve DOF, CD uniformity and roughness by applying DDRP for ArF generation. Finally we succeeded to enhance every parameter at the same time by controlling DDRM etching condition. This new DDRP technology can be the promising approach for ArF extension stages in N7/N5 and beyond.","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"132 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122619589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Contact/Via placement management for N7 logic and beyond N7逻辑和更高版本的Contact/Via放置管理
Pub Date : 2016-03-25 DOI: 10.1117/12.2218976
K. Oyama, A. Hara, K. Koike, Masatoshi Yamato, Shohei Yamauchi, Sakurako Natori, H. Yaegashi
The continuously scaling of complex device geometries is driving by the self-aligned multiple patterning techniques. Depending on such simplified LS scaling, FinFET design rule has been accelerated to unidirectional design layout. [1] In particular Fin, Gate and Metal layers are based on grating with cutting/blocking scheme, these process have become high volume manufacturing techniques in N14 and beyond.[2,3] On the other hand, immersions based pitch scaling of contact hole, via and cutmask processes are required multiple lithography and etching passes.[4] Overlay management is not only the overlay accuracy of layer to layer, to determine the placement error and patterning fidelity in single layer. In this work, focusing on the placement in hole pattern, total placement error budget will be discussed from the viewpoints of metrology, inspection, Mask, OPC and wafer processing. In addition, hole shrink and hole healing techniques have more significant factors in terms of design-process technology co-optimization for N7 and beyond.[5]
复杂器件几何形状的不断缩放是由自对齐多模式技术驱动的。基于这种简化的LS缩放,FinFET的设计规则已经加速到单向设计布局。[1]特别是鳍,栅极和金属层是基于光栅的切割/阻塞方案,这些工艺已成为N14及以后的大批量制造技术。[2,3]另一方面,基于浸没的接触孔、通孔和掩膜工艺的螺距缩放需要多个光刻和蚀刻通道[4]。覆盖管理不仅仅是层与层之间的覆盖精度,还要决定单层的放置误差和图案保真度。本文将从计量、检测、掩模、OPC和晶圆加工等角度,对孔型布局的总体布局误差预算进行讨论。此外,孔收缩和孔愈合技术在N7及以后的设计-工艺技术协同优化方面具有更显著的因素。[5]
{"title":"Contact/Via placement management for N7 logic and beyond","authors":"K. Oyama, A. Hara, K. Koike, Masatoshi Yamato, Shohei Yamauchi, Sakurako Natori, H. Yaegashi","doi":"10.1117/12.2218976","DOIUrl":"https://doi.org/10.1117/12.2218976","url":null,"abstract":"The continuously scaling of complex device geometries is driving by the self-aligned multiple patterning techniques. Depending on such simplified LS scaling, FinFET design rule has been accelerated to unidirectional design layout. [1] In particular Fin, Gate and Metal layers are based on grating with cutting/blocking scheme, these process have become high volume manufacturing techniques in N14 and beyond.[2,3] On the other hand, immersions based pitch scaling of contact hole, via and cutmask processes are required multiple lithography and etching passes.[4] Overlay management is not only the overlay accuracy of layer to layer, to determine the placement error and patterning fidelity in single layer. In this work, focusing on the placement in hole pattern, total placement error budget will be discussed from the viewpoints of metrology, inspection, Mask, OPC and wafer processing. In addition, hole shrink and hole healing techniques have more significant factors in terms of design-process technology co-optimization for N7 and beyond.[5]","PeriodicalId":193904,"journal":{"name":"SPIE Advanced Lithography","volume":"57 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116527023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
SPIE Advanced Lithography
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1