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Elemental mobility patterns and metallogenic implications of the Tongshan porphyry Cu-Mo-Au deposit, Heilongjiang Province, NE China 黑龙江省铜山斑岩型铜钼金矿床元素迁移模式及成矿意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107076
Jie Chen , Guiqing Xie , Qiaoqiao Zhu , Chenglin Bai , Hui Chen
Quantifying element mobility within the well-defined alteration zones of porphyry Cu systems is critical for reconstructing metallogenesis and defining exploration vectors. This study integrates whole-rock geochemistry and chlorite mineral chemistry to constrain fluid-rock interaction processes in the Tongshan porphyry Cu deposit. Chlorite geothermometry indicates that the Chlorite-Epidote ± Muscovite mineral assemblages occurred at 280–320 °C, with compositional variations (e.g., SiO2, Al2O3, FeO and MgO) tracking the physicochemical evolution of ore-forming fluids. Chlorite crystallization might be elevated fluid pH, thereby exerting a primary control on the mobility of trace elements such as Fe, Mg, Cr, As, and Sr. Mass-balance calculations reveal that intense hydration (LOI gains up to + 56 %) induced rock volume expansion and pressure reduction, likely triggering fluid boiling and subsequent metal precipitation. The propylitic zone is identified as the primary host for ore deposition in the deposit, exhibiting extreme Cu enrichment (up to + 5423 %) that contrasts with widespread REE depletion (−27.4 % to −77.3 %). This geochemical decoupling reflects the differential stability of metal complexes, wherein high-temperature fluids mobilized REEs while promoting the destabilization and precipitation of Cu. A robust geochemical footprint was also identified, in which W, Bi, Tl, Zr, and Hf strongly correlate with Cu (R2 > 0.56). These elements, combined with the distinct REE depletion pattern, serve as effective vectoring indicators for targeting concealed orebodies. These findings in this study establish a comprehensive element-mobility framework that elucidates metal enrichment mechanisms in the propylitic zone and provides a practical geochemical toolkit for exploration in the Tongshan porphyry Cu deposit and analogous porphyry systems.
在明确的斑岩型铜系统蚀变带内定量元素迁移对于重建成矿作用和确定找矿方向至关重要。结合全岩地球化学和绿泥石矿物化学对铜山斑岩型铜矿流体-岩石相互作用过程进行了研究。绿泥石地温测定表明,绿泥石-绿帘石±白云母矿物组合发生在280 ~ 320℃,其组成变化(SiO2、Al2O3、FeO和MgO)跟踪了成矿流体的物理化学演化。亚绿泥石结晶可能会导致流体pH值升高,从而对Fe、Mg、Cr、as和sr等微量元素的迁移率起主要控制作用。质量平衡计算表明,强烈的水化作用(LOI增加至+ 56%)会导致岩石体积膨胀和压力降低,可能引发流体沸腾和随后的金属沉淀。在矿床中,丙基岩带是主要的矿床寄主,Cu富集(+ 5423%),而REE富集(- 27.4% ~ - 77.3%)较为普遍。这种地球化学解耦反映了金属配合物的差异性稳定性,高温流体在调动稀土元素的同时促进了Cu的失稳和沉淀。此外,还发现了一个强大的地球化学足迹,其中W、Bi、Tl、Zr和Hf与Cu密切相关(R2 > 0.56)。这些元素与明显的稀土元素枯竭模式相结合,可作为找矿隐伏矿体的有效矢量指标。研究结果为铜山斑岩型铜矿床及类似斑岩系统的勘查提供了实用的地球化学工具,建立了全面的元素迁移框架,阐明了丙岩带金属富集机制。
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引用次数: 0
Geochemical fingerprints of ore-forming fluids in skarn copper systems: Implications for evaluating mineralization mechanisms and potential 矽卡岩型铜系统成矿流体的地球化学指纹图谱:对成矿机制和成矿潜力评价的意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107099
Xin Zhang , Pei Ni , Guo-Guang Wang , Jun-Ying Ding , Jun-Yi Pan , Jian-Ming Cui , Yao-Hui Jiang
The Tongshan skarn copper deposit is situated in the North Wuyi area of South China.
Three distinct paragenetic stages have been identified: the pre-mineralization prograde stage, the syn-mineralization retrograde stage, and the post-mineralization carbonate stage. This study systematically conducted fluid inclusion petrography on gangue minerals from different stages, identifying three typical types of fluid inclusions: brine inclusions, vapor-rich inclusions, and liquid-rich inclusions. These inclusions were subsequently subjected to detailed microthermometry and LA-ICP-MS composition analysis. The analytical results show that in the pre-mineralization stage, garnet-hosted brine inclusions and vapor-rich inclusions exhibit homogenization temperatures of 455–529 °C and 470–535 °C, with salinities of 30.5–35.2 wt% NaCl equiv. and 1.74–3.06 wt% NaCl equiv., respectively. Liquid-rich inclusions in syn-mineralization stage quartz have homogenization temperatures of 290–400 °C and salinities of 0.88–9.21 wt% NaCl equiv. In the post-mineralization stage, calcite-hosted liquid-rich inclusions show homogenization temperatures of 122–221 °C and salinities of 0.70–4.96 wt% NaCl equiv. The marked decrease in fluid inclusion homogenization temperature and salinity values from the pre-mineralization to syn-mineralization stage suggests the involvement of meteoric water. Additionally, the depletion of major elements such as Rb, Na, and K in the syn-mineralization fluids correlates with the declining temperature, further supporting the notion of meteoric water dilution. These observations indicate that the mixing of magmatic fluids with meteoric water was instrumental in facilitating metal precipitation. Moreover, the elevated Ca/K ratios observed in mineralizing fluids associated with quartz imply substantial interaction between fluids and calcareous rock. In line with this, retrograde alteration assemblages (chlorite ± epidote), formed through fluid–rock interaction, are closely spatially associated with sulfide mineralization. This relationship underscores fluid–rock interaction as another critical mechanism driving metal precipitation. Comparative analysis of the fluid geochemical characteristics in global porphyry-skarn copper systems reveals that mineralized systems have higher Cu/Na ratios and moderate Cs/Na ratios, whereas barren systems exhibit lower Cu/Na ratios and higher Cs/Na ratios. The mineralization potential of these systems may primarily depend on the copper content in the early exsolved fluids from the granitic parental magma. The level of parental magma fractionation appears not to enhance the initial copper endowment in these systems.
铜山矽卡岩型铜矿床位于中国南方武夷地区北部。共成岩阶段分为成矿前递进阶段、同成矿逆进阶段和成矿后碳酸盐岩阶段。本研究对不同阶段脉石矿物进行了系统的流体包裹体岩石学研究,确定了三种典型的流体包裹体类型:卤水包裹体、富气包裹体和富液包裹体。这些内含物随后进行了详细的显微测温和LA-ICP-MS成分分析。分析结果表明,成矿前阶段,含石榴石卤水包裹体和富气包裹体均质温度分别为455 ~ 529℃和470 ~ 535℃,盐度分别为30.5 ~ 35.2%和1.74 ~ 3.06 wt% NaCl当量。同成矿阶段石英富液包裹体均一温度为290 ~ 400℃,盐度为0.88 ~ 9.21 wt% NaCl,成矿后阶段方解石型富液包裹体均一温度为122 ~ 221℃,盐度为0.70 ~ 4.96 wt% NaCl,成矿前至同成矿阶段流体包裹体均一温度和盐度显著降低,表明有大气水的参与。此外,同矿化流体中Rb、Na、K等主要元素的耗竭与温度的下降有关,进一步支持了大气水稀释的观点。这些观测结果表明,岩浆流体与大气水的混合有助于促进金属的沉淀。此外,在与石英相关的矿化流体中观察到的Ca/K比值升高意味着流体与钙质岩石之间存在实质性的相互作用。与此相对应,流体-岩石相互作用形成的逆蚀变组合(绿泥石±绿帘石)在空间上与硫化物成矿作用密切相关。这种关系强调了流体-岩石相互作用是驱动金属沉淀的另一个关键机制。全球斑岩—矽卡岩铜体系流体地球化学特征对比分析表明,成矿体系具有较高的Cu/Na比值和中等的Cs/Na比值,而贫瘠体系具有较低的Cu/Na比值和较高的Cs/Na比值。这些体系的成矿潜力可能主要取决于花岗岩母岩浆早期溶蚀流体中的铜含量。母岩浆分选水平似乎并没有提高这些体系的初始铜禀赋。
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引用次数: 0
The indicative significance of apatite in the Ganfang region for lithium mineralization 甘方地区磷灰石对锂成矿的指示意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2026.107105
Ke Huang , Miao Yu , Chunli Guo , Xinghua Ma , JianZhong Niu , Junxing Zhao , Fangyang Hu , Xiaochi Liu
Granite-related Li-Nb-Ta deposits, characterized by extensive albitization within plutons, represent a novel lithium resource. The Ganfang area, one of the important granite-type lithium deposits in South China, features a vertical lithological sequence from top to bottom of stockscheider, albitized granite, and K-feldspar granite. The ore-bearing stratum is dominated by albitized granite. Our study focuses on elucidating the connection between magmatic differentiation, hydrothermal alteration, and lithium mineralization in albitized granites. By analyzing geochemical trends in apatite from stockscheiders, pegmatite veins, and altered granites, we aim to unravel the petrogenetic and metallogenic mechanisms of rare metal lithium. Apatite serves as a geochemical tracer, recording the intensity of fluid alteration processes and their impact on lithium enrichment. The U-Pb dating results (142.2–143.2 Ma and 128.8 Ma) of apatite from the stockscheiders and pegmatite vein show that mineralization in the Ganfang area occurred during the Late Yanshanian period and associated with the melting of the lower crust. Strontium (Sr), (La/Yb) N, and (La/Sm) N can indicate that mineralization in this area is closely associated with fluid activity. Our findings highlight distinct differences in trace element contents of apatite between upper ore-bearing albitized granite and lower barren K-feldspar granite, with specific trace element ratios (e.g., Ge-Ga, Ce/Pb-Th/U, ΣREE + Y-Mn/Fe, and Sr/Y-ΣLREE) serving as indicators of metallogenic potential. The ore-bearing albitized granite exhibits high concentrations of Ga and Ge, with a strong positive correlation between the two elements, this phenomenon may be related to the hydrothermal metasomatism of topaz. In addition, the ore-bearing granite exhibits relatively high Ce/Pb, light rare earth element (LREE), and total rare earth elements plus yttrium (ΣREE + Y) contents. This study indicates that lithium mineralization in the Ganfang area is closely linked to multistage fluid activity in a sealed-system, with a formation process involving the upward dissolution of Na and Li-rich fluids to form stockscheider, and followed by downward migration to replace fresh monzonite granites, forming ore-bearing albitized granite and barren K-feldspar granite.
与花岗岩相关的Li-Nb-Ta矿床是一种新型的锂资源,其特征是岩体内广泛的钠长岩化。甘方地区是华南地区重要的花岗岩型锂矿床之一,其垂直岩性序列由上至下为长石岩-钠长花岗岩-钾长石花岗岩。含矿层以钠长花岗岩为主。本文的研究重点是阐明岩浆岩分异、热液蚀变与钠长花岗岩中锂矿化的关系。通过分析石岩、伟晶岩脉和蚀变花岗岩中磷灰石的地球化学变化趋势,揭示稀有金属锂的成岩成矿机制。磷灰石作为地球化学示踪剂,记录了流体蚀变过程的强度及其对锂富集的影响。石堆石和伟晶岩脉磷灰石的142.2 ~ 143.2 Ma和128.8 Ma U-Pb定年结果表明,甘方地区的成矿作用发生在燕山晚期,与下地壳的熔融作用有关。锶(Sr)、(La/Yb) N和(La/Sm) N指示该区成矿与流体活动密切相关。研究结果表明,磷灰石的微量元素含量在上部含矿化钾长石花岗岩与下部贫钾长石花岗岩之间存在显著差异,具体的微量元素比值(Ge-Ga、Ce/Pb-Th/U、ΣREE + Y- mn /Fe、Sr/Y-ΣLREE)可作为成矿潜力指标。含矿钠长花岗岩中Ga和Ge含量较高,两者呈较强的正相关关系,可能与黄玉的热液交代作用有关。此外,含矿花岗岩具有较高的Ce/Pb、轻稀土元素(LREE)和稀土总元素+钇(ΣREE + Y)含量。研究表明,甘方地区的锂成矿作用与封闭体系中的多期流体活动密切相关,其形成过程是富钠、富锂流体向上溶蚀形成储层,再向下运移取代新鲜的二长花岗岩,形成含矿钠长花岗岩和贫钾长石花岗岩。
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引用次数: 0
Petrogenesis of the Bingzhou rare metal pegmatites, West Kunlun: Implications for regional exploration 西昆仑冰州稀有金属伟晶岩成因及其区域找矿意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107094
Liang Huang , He Wang , Xiao-Yu Zhang , Jin-Heng Liu , Hong-Yang Bai , Kun-Yu Wang , Song Zhang , Zhi-Qiang Sun
Understanding the petrogenesis and evolution of lithium-rich pegmatites is crucial for regional exploration. The world-class Dahongliutan–Bailongshan orefield hosts seven large to super-large lithium deposits distributed around the Bailongshan granite complex. However, its petrogenesis remains controversial, and most previous studies have focused on the northern deposits (e.g., Dahongliutan, Bailongshan, Xuefengling), with limited attention to the southern deposits. These limitations collectively hinder regional exploration efforts. This study addresses this gap by focusing on the Bingzhou lithium deposit, located on the southern side of the Bailongshan granite complex. Geochronology, REE geochemistry, and in-situ Nd isotopic analyses of monazite, along with the geochronology of columbite–tantalite group minerals, were conducted to constrain the emplacement ages, material sources, and genetic relationships between the granites and pegmatites. This study aims to utilize these findings to guide regional exploration. U–(Th)–Pb dating of monazite and columbite-tantalite group minerals constrains the emplacement ages to ca. 212.7 Ma for the two-mica granites, ca. 206.1–205.4 Ma for the spodumene-absent pegmatites, and ca. 207.2–206.7 Ma for the spodumene-bearing pegmatites. The close temporal relationship between the two-mica granites and pegmatites, as well as their spatial proximity observed in the field, suggests a genetic link between the two-mica granites and pegmatites. The εNd(t) values of monazite from the two-mica granite, spodumene-absent pegmatite, and spodumene-bearing pegmatite are similar (–10.0 to –8.0) and are consistent with the whole-rock εNd(t) values of Triassic Bayanharshan Group metapelites (–11.5 to –7.1). These characteristics indicate that metapelites are the source rocks of the two-mica granites, while the pegmatites represent the products of fractional crystallization of the two-mica granitic magma. The systematic variations in the Sm/Nd ratio and Eu anomaly coefficient in monazite, along with their strong positive correlation with lithium content, further suggest that fractional crystallization is the key process in the formation of rare metal pegmatites. The Bingzhou deposit shares similar metallogenic ages, material sources, and petrogenetic characteristics with its northern counterparts, reinforcing the exploration potential of the southern orefield.
了解富锂伟晶岩的成因和演化规律对区域勘探具有重要意义。世界一流的大红柳坛-白龙山矿田拥有7个大型至超大型锂矿床,分布在白龙山花岗岩杂岩周围。然而,其成因仍存在争议,以往的研究多集中在北部矿床(如大红流滩、白龙山、雪峰岭),对南部矿床的研究较少。这些限制共同阻碍了区域勘探工作。本研究以位于白龙山花岗岩杂岩南侧的冰州锂矿床为研究对象,填补了这一空白。通过对独居石的年代学、稀土元素地球化学和原位Nd同位素分析,以及对铌钽矿群矿物的年代学分析,确定了花岗岩和伟晶岩的侵位年龄、物质来源和成因关系。本研究旨在利用这些发现来指导区域勘探。二云母花岗岩、无锂辉石伟晶岩和含锂辉石伟晶岩的侵位年龄分别为212.7 Ma、206.1 ~ 205.4 Ma和207.2 ~ 206.7 Ma。二云母花岗岩与伟晶岩在时间上的密切关系,以及野外观测到的空间上的接近,表明二云母花岗岩与伟晶岩在成因上存在联系。二云母花岗岩、不含锂辉石伟晶岩和含锂辉石伟晶岩的独居石εNd(t)值相似(-10.0 ~ -8.0),与三叠系巴彦哈山群变质岩的全岩εNd(t)值(-11.5 ~ -7.1)一致。这些特征表明,变长岩是二云母花岗岩的源岩,伟晶岩是二云母花岗岩岩浆分馏结晶的产物。独居石中Sm/Nd比值和Eu异常系数的系统变化,以及它们与锂含量的强正相关,进一步表明分步结晶是稀有金属伟晶岩形成的关键过程。冰州矿床与北部成矿年龄、物质来源及成因特征相似,增强了南部矿田的找矿潜力。
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引用次数: 0
Mafic magma injection as a driver for the formation of Au-rich porphyry–hydrothermal systems in thickened crustal setting 基性岩浆注入对增厚地壳背景下富金斑岩-热液体系形成的驱动作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2026.107106
Chen-Hao Luo , Rui Wang , Haijun Yu , Anlin Liu , Ruoyu Mao
Gold-rich mineralization in porphyry systems, including porphyry-type and related hydrothermal deposits, generally requires Au-enriched magmas, followed by efficient hydrothermal extraction and precipitation. While moderately oxidized magmas with delayed sulfide saturation are typically favorable in thin-crust settings, the Yao’an Au–polymetallic deposit, associated with Cenozoic alkaline magmatism at the western margin of the Yangtze Craton, represents a distinctive exception. The orebody morphology and alteration zoning suggest mineralization of this deposit is characteristic of a hydrothermal vein-type rather than a typical porphyry system. Geochemical evidence from this study shows that the felsic porphyries in the deposit underwent early sulfide saturation, while Fe isotope and zircon oxybarometry results indicate that they were characterized by high oxidation states (δ56Fe = 0.14–0.59 ‰; ΔFMQ + 2.89 to +3.41). Such conditions were unfavorable for Au enrichment, consistent with the low and stable Au contents (3.11–4.61 ppb) in the peripheral intrusions. Exsolved fluids from these magmas produced specularite-dominated orebodies but likely hindered effective chalcophile metal retention. Thus, this magmatic–hydrothermal stage was unlikely to solely form an economic deposit. Instead, the subsequent emplacement of mafic ultrapotassic dikes likely played an important role in facilitating further Au enrichment. Mineralogical and geochemical evidence indicates they became sulfide-saturated and host elevated Au (up to 64.1 ppb). They also display light Fe isotope signatures (δ56Fe = 0.05–0.07 ‰), implying a relatively low oxidation state. We propose that these mafic magmas intruded into oxidized felsic porphyries, triggering sulfide breakdown, metal remobilization, and promoting further Au concentration in the orebodies.
斑岩系统(包括斑岩型及相关热液矿床)的富金成矿通常需要富金岩浆,然后进行高效的热液萃取和沉淀。虽然具有延迟硫化物饱和度的中度氧化岩浆在薄壳环境中具有典型的有利条件,但与扬子克拉通西缘新生代碱性岩浆作用相关的姚安金多金属矿床却是一个独特的例外。矿体形态和蚀变分带特征表明该矿床成矿为热液脉型,而非典型斑岩系统。地球化学证据表明,矿床长英质斑岩经历了较早的硫化物饱和,铁同位素和锆石氧压测定结果显示其具有高氧化态特征(δ56Fe = 0.14 ~ 0.59‰;ΔFMQ + 2.89 ~ +3.41)。这种条件不利于Au富集,与外围侵入体中Au含量低且稳定(3.11 ~ 4.61 ppb)一致。这些岩浆的溶解流体产生了以镜铁矿为主的矿体,但可能阻碍了亲铜金属的有效保留。因此,这一岩浆-热液阶段不太可能单独形成一个经济矿床。相反,随后基性超经典岩脉的侵位可能对进一步富集金起了重要作用。矿物学和地球化学证据表明,它们变得硫化物饱和,并含有较高的金(高达64.1 ppb)。铁同位素δ56Fe = 0.05 ~ 0.07‰,表明其氧化态较低。这些基性岩浆侵入氧化长英质斑岩,引发硫化物击穿、金属再活化,促进了矿体中金的进一步富集。
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引用次数: 0
SWIR spectroscopy and mineral chemistry of Li-bearing micas in NW Jiangxi: Implications for the genesis and exploration of granite-related Li deposits 赣西北含锂云母的SWIR光谱及矿物化学特征:对花岗岩相关锂矿床成因及找矿意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107086
Yan Zhou , Jiandong Sun , Longming Li , Feipeng Fan , Guangfu Xing , Liancun Xiu , Weimin Guo , Kai Yang , Haili Li , Xuehui Zhang
The granite-related Li deposit has emerged as a significant source of lithium metal globally, thanks to advancements in the metallurgical process of Li-bearing micas. The total proven Li2O reserve of granite-type in the Northwest Jiangxi of China is over 9.2 Mt. To gain deeper insights into the evolution, enrichment mechanisms, and exploration indicators of Li-rich micas, short wavelength infrared (SWIR) spectroscopy, EPMA, and LA-ICP-MS analyses were conducted at the Dagang Li deposit, the Yashan Li-Nb-Ta deposit, and the Ganfang prospecting area. Obvious zoning textures were observed in the white mica of Dagang and Ganfang, with a compositional shift from magmatic Li-Fe mica and zinnwaldite in the core to post-magmatic hydrothermal Li-Fe mica at the edge. Meanwhile, Yashan’s white micas show core-rim textures, with the core dominated by magmatic lepidolite with minor altered Li-Fe mica on the rim. The Li, Si, Rb, and F contents of all white micas show similar varied trends, indicating comparable geochemical behaviors, with Li showing a positive linear relationship with Si. The substitution of Li for Al and Fe in the octahedral site played a crucial role in the Li supernormal enrichment during the granitic fractionation and evolution. However, post-magmatic hydrothermal alteration can potentially decrease the Li grade. Notably, the Yashan granite exhibits a higher degree of evolution compared to the Dagang and Ganfang granites. The coupling of the SWIR parameters with the chemical composition of Li-rich micas holds the potential for establishing exploration indicators for Li. Specifically, the Li-rich mica exhibits distinctive absorption at 550 and 960 nm, along with a lower Al-OH absorption peak position (Pos2200) than common muscovite. The absorption depth at 960 nm can be used to assess Li enrichment and identify lepidolite, while the Pos2200 value can reflect the substitution relationship between Li and Al.
由于含锂云母的冶金工艺的进步,与花岗岩相关的锂矿床已成为全球锂金属的重要来源。为深入了解富锂云母的演化、富集机制和找矿指标,对赣西地区大港李矿、丫山Li- nb - ta矿和赣方找矿区进行了波长红外光谱、EPMA和LA-ICP-MS等分析。大港和甘方白色云母具有明显的分带结构,其组成由岩心的岩浆期锂铁云母和锌walite向边缘岩浆期后热液期锂铁云母转变。崖山白色云母呈核-缘结构,岩心以岩浆云母为主,边缘有少量蚀变的Li-Fe云母。所有白色云母中Li、Si、Rb和F的含量变化趋势相似,具有相似的地球化学行为,Li与Si呈正线性关系。在花岗岩分馏演化过程中,八面体位置上Li取代Al和Fe对Li的超常富集起着至关重要的作用。岩浆期后热液蚀变可能降低锂品位。值得注意的是,丫山花岗岩的演化程度高于大港和甘方花岗岩。SWIR参数与富Li云母化学组成的耦合,为建立Li的找矿指标提供了可能。具体来说,富锂云母在550和960 nm处表现出独特的吸收,并且比普通白云母的Al-OH吸收峰位置(Pos2200)更低。960 nm处的吸收深度可用于评价Li富集程度和鉴定锂云母,Pos2200值可反映Li和Al之间的取代关系。
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引用次数: 0
Genesis of the Paleoproterozoic Heiyuting Fe deposit in the Jiao-Liao-Ji Belt, North China Craton: Constraints from geochronology and geochemistry 华北克拉通胶辽基带古元古代黑玉亭铁矿成因:地球化学和年代学的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2026.107107
Xiao-Hui Wang , Yu-Bo Ma , Xiu-Ling Zhao , Li-Xing Li , Hou-Min Li , Yi Wang , Yang Dai , Xuan Wu , Xiao-Yang Fan , Xi-Long Liu
Paleoproterozoic metamorphic rock series are widely distributed and hosts several iron deposits. The Heiyuting iron (Fe) deposit is hosted by typical Paleoproterozoic leptite of the Li’eryu Formation and represents a key example for constraining the mineralization process of Paleoproterozoic iron deposits within the Liaohe Group. This type of deposit has great exploration potential, but the precise timing of iron mineralization, the sources of ore-forming materials, and iron mineralization processes remain unclear. We conducted zircon and monazite U-Pb geochronology together with monazite electron probe microanalysis (EPMA) to constrain iron mineralization. Zircon cores from the migmatitic granite yield an age of 2174 ± 23 Ma, representing protolith formation, whereas the rims yield 1892 ± 14 Ma, consistent with ∼ 1900 Ma granulite-facies metamorphism. Monazite grains associated with magnetite yielded an age of 1848 ± 5 Ma, constraining Fe mineralization and coinciding with regional partial melting (1870–1840 Ma). Monazites observed under back-scattered electron (BSE) imaging show embayed structures and concentric coronas composed of apatite, allanite, and epidote. Based on the major-, trace-, and REE-element compositions of monazite, a metamorphic-hydrothermal origin is suggested. We propose that the apatite-allanite-epidote coronas developed on early-formed monazite through disequilibrium reactions with F-Ca-Fe-Si-Al-rich fluids during the retrograde metamorphic stage. The Li’eryu Formation and the 2.2–2.1 Ga magmatism provided the primary sources of iron. The iron was subsequently concentrated by hydrothermal activity during late metamorphism-anatexis at ∼ 1850 Ma. Our results refine the age, source, and mechanisms of iron mineralization in the Heiyuting Fe deposit, provide geochronological and geochemical constraints for similar deposits, and highlight the role of regional metamorphism-anatexis in polymetallic enrichment.
古元古代变质岩系分布广泛,拥有多处铁矿床。黑玉亭铁矿为典型的李尔玉组古元古代轻铁矿赋存,是制约辽河群古元古代铁矿成矿过程的重要例证。该类型矿床具有较大的找矿潜力,但其成矿时间、成矿物质来源及成矿过程尚不明确。利用锆石和独居石U-Pb年代学和独居石电子探针微量分析(EPMA)对铁矿进行了约束。混染花岗岩的锆石岩心年龄为2174±23 Ma,代表原岩形成,而边缘年龄为1892±14 Ma,符合~ 1900 Ma麻粒岩相变质作用。与磁铁矿相关的独居石颗粒的年龄为1848±5 Ma,限制了铁的成矿作用,与区域部分熔融(1870-1840 Ma)相吻合。在背散射电子(BSE)成像下观察到的独居石显示出由磷灰石、allanite和绿帘石组成的椭圆形结构和同心日冕。单独居石的主量、微量和ree元素组成表明其成因为变质热液。我们认为,早期独居石与富f - ca - fe - si -al流体在逆变质阶段发生不平衡反应,形成磷灰石-allanite-绿帘石冕状。黎洱峪组和2.2 ~ 2.1 Ga岩浆活动是铁的主要来源。铁随后在~ 1850 Ma的晚变质-深熔过程中被热液活动浓缩。研究结果细化了黑玉亭铁矿的成矿年龄、成矿来源和成矿机制,为类似矿床提供了年代学和地球化学约束条件,并突出了区域变质-深熔作用在多金属富集中的作用。
{"title":"Genesis of the Paleoproterozoic Heiyuting Fe deposit in the Jiao-Liao-Ji Belt, North China Craton: Constraints from geochronology and geochemistry","authors":"Xiao-Hui Wang ,&nbsp;Yu-Bo Ma ,&nbsp;Xiu-Ling Zhao ,&nbsp;Li-Xing Li ,&nbsp;Hou-Min Li ,&nbsp;Yi Wang ,&nbsp;Yang Dai ,&nbsp;Xuan Wu ,&nbsp;Xiao-Yang Fan ,&nbsp;Xi-Long Liu","doi":"10.1016/j.oregeorev.2026.107107","DOIUrl":"10.1016/j.oregeorev.2026.107107","url":null,"abstract":"<div><div>Paleoproterozoic metamorphic rock series are widely distributed and hosts several iron deposits. The Heiyuting iron (Fe) deposit is hosted by typical Paleoproterozoic leptite of the Li’eryu Formation and represents a key example for constraining the mineralization process of Paleoproterozoic iron deposits within the Liaohe Group. This type of deposit has great exploration potential, but the precise timing of iron mineralization, the sources of ore-forming materials, and iron mineralization processes remain unclear. We conducted zircon and monazite U-Pb geochronology together with monazite electron probe microanalysis (EPMA) to constrain iron mineralization. Zircon cores from the migmatitic granite yield an age of 2174 ± 23 Ma, representing protolith formation, whereas the rims yield 1892 ± 14 Ma, consistent with ∼ 1900 Ma granulite-facies metamorphism. Monazite grains associated with magnetite yielded an age of 1848 ± 5 Ma, constraining Fe mineralization and coinciding with regional partial melting (1870–1840 Ma). Monazites observed under back-scattered electron (BSE) imaging show embayed structures and concentric coronas composed of apatite, allanite, and epidote. Based on the major-, trace-, and REE-element compositions of monazite, a metamorphic-hydrothermal origin is suggested. We propose that the apatite-allanite-epidote coronas developed on early-formed monazite through disequilibrium reactions with F-Ca-Fe-Si-Al-rich fluids during the retrograde metamorphic stage. The Li’eryu Formation and the 2.2–2.1 Ga magmatism provided the primary sources of iron. The iron was subsequently concentrated by hydrothermal activity during late metamorphism-anatexis at ∼ 1850 Ma. Our results refine the age, source, and mechanisms of iron mineralization in the Heiyuting Fe deposit, provide geochronological and geochemical constraints for similar deposits, and highlight the role of regional metamorphism-anatexis in polymetallic enrichment.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"188 ","pages":"Article 107107"},"PeriodicalIF":3.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling late cretaceous Sn mineralization in the southern Baoshan Block, SW China: evidence from U–Pb dating and trace element analysis of cassiterite in the Dalong deposit 揭示宝山地块南部晚白垩世锡矿化:来自大龙矿床锡石U-Pb定年和微量元素分析的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107067
Chuanyu Zhang , Meng Yang , Jianze Sha , Wanting Li , Haijun Yu , Shusheng Yang , Yongyan Lu
The Baoshan Block is considered an integral part of the northern continuation of the world-class Southeast Asian Sn Belt. Its exceptional metallogenic geological settings make it a prime focus for Sn prospecting and exploration. In recent years, several Sn deposits have been successively discovered in the northern Baoshan Block, with formation ages clustering around 77–76 Ma, consistent with the metallogenic peak (∼80 Ma) of the Southeast Asian Sn Belt. However, despite its intermediary position, owing to the lack of outcrops of Late Cretaceous granites, Sn deposits in the southern Baoshan block remain unexplored. The scarcity of reliable geochronological data in this area severely constrains genetic models for mineralization and hinders effective exploration planning. This study presents the first high-precision cassiterite U-Pb ages (77.0 ± 1.4 Ma and 78.6 ± 4.2 Ma) for the newly discovered Dalong Sn deposit in the southern Baoshan Block, which was previously attributed to Triassic magmatism. Cassiterite from the Dalong deposit is enriched in Ti, W, and Fe, but depleted in Nb, Ta, Zr, and Mn, with high Nb/Ta ratios (3.16–545, with an average of 7.26). These geochemical signatures, combined with deposit geological characteristics, support a model in which the Dalong Sn deposit is a hydrothermal vein system sourced from Late Cretaceous concealed granites, formed during Neo-Tethyan subduction-induced back-arc extension. The results reveal that among the four Sn mineralization episodes in the Tengchong-Baoshan Block (Early Cretaceous: 124–118 Ma; Late Cretaceous: 79–69 Ma; Early Eocene: 52–47 Ma; and Oligocene: 33–22 Ma), the Late Cretaceous Sn mineralization was spatially the most extensive, forming a coherent belt from the Southeast Asian Sn Belt northward through the Baoshan Block (both southern and northern parts) and into the Tengchong Block. We propose that future ore exploration in the Baoshan Block should prioritize the concealed Late Cretaceous granites and associated Sn mineralization.
宝山地块被认为是世界级东南亚锡带北延的组成部分。得天独厚的成矿地质条件,使其成为我国找矿找锡的重点地区。近年来,在宝山地块北部先后发现了几处锡矿床,其形成年龄集中在77 ~ 76 Ma,与东南亚锡带成矿高峰(~ 80 Ma)一致。然而,尽管处于中间位置,但由于缺乏晚白垩世花岗岩露头,宝山地块南部的锡矿床仍未被发现。该地区缺乏可靠的地质年代学资料,严重制约了成矿成因模型的建立,阻碍了有效的勘探规划。本文首次对宝山地块南部新发现的大隆锡矿床进行了高精度锡石U-Pb年龄测定(77.0±1.4 Ma和78.6±4.2 Ma),前人认为该矿床为三叠纪岩浆作用所致。大隆矿锡石富Ti、W、Fe,贫Nb、Ta、Zr、Mn,具有较高的Nb/Ta比值(3.16 ~ 545,平均7.26)。这些地球化学特征结合矿床地质特征,支持大龙锡矿床为晚白垩世隐伏花岗岩热液脉系,形成于新特提斯俯冲诱发弧后伸展时期。结果表明,在腾冲-宝山地块的4期(早白垩世124 ~ 118 Ma、晚白垩世79 ~ 69 Ma、早始新世52 ~ 47 Ma、渐新世33 ~ 22 Ma)中,晚白垩世的锡矿化在空间上最为广泛,形成了一条从东南亚锡带向北经宝山地块(南、北)进入腾冲地块的连贯带。建议宝山地块今后找矿应优先找隐伏晚白垩世花岗岩及其伴生锡成矿。
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引用次数: 0
3D mineral prospectivity modeling for concealed gold deposits based on 3DCNN and numerical modeling of ore-forming process in the Wuhe area, Anhui Province, China 基于3DCNN的隐伏金矿三维找矿模拟及成矿过程数值模拟
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107075
Xiaohui Li , Shengfei Ye , Feng Yuan , Deyuan Meng , Jiajia Zhang , Xuhuang Miao , Ying Xiao , Xiangling Li , Can Ge , Chaojie Zheng , Zhiqiang Wang , Yue Li
The Wuhe area is located in the southeastern margin of the North China Craton (NCC), adjacent to the Dabie–Sulu orogenic belt. It is considered an extension of the Zhaoyuan–Yexian gold belt to the west of the Tan–Lu Fault Zone. However, only a limited number of small- to medium-sized deposits have been discovered thus far in the Wuhe area. Recently, three-dimensional mineral prospectivity modeling (3DMPM) has become a powerful tool for targeting deep concealed deposits. The generation of 3D predictive maps associated with mineralization is a crucial step in 3DMPM. The numerical modeling of ore-forming process has gradually been integrated into 3DMPM. Numerical modeling can provide useful predictive information for 3DMPM. However, better ways to integrate these additional 3D predictive maps during 3DMPM require further exploration and research. Besides, the 3D convolutional neural network (3DCNN) model has demonstrated excellent data fusion capabilities when applied to 3DMPM for Skarn-type ore deposits. However, the application of 3DCNN in mineral prospectivity modeling for lode gold deposits has not yet been explored. Therefore, this study initially adopts the implicit 3D geological modeling method to build 3D geological models. Subsequently, 3D spatial analysis and numerical modeling are employed to generate 3D predictive maps. Finally, a 3DCNN model incorporating a spatial attention mechanism and an Inception module (MSAM-3DCNN) is employed to integrate the 3D predictive maps and delineate several highly prospective areas for future exploration. The high prospectivity areas not only delineate the data-driven deposits but also include the other deposits in the Wuhe area which demonstrates that the methods employed in this paper can map the mineral prospectivity of lode gold deposits efficiently. Numerical modeling can provide a series of 3D maps that significantly enhance the effectiveness of the 3DMPM, especially in modeling the potential mineralization of the lode gold deposits, where 3D predictive maps are limited. The MSAM-3DCNN model has significant advantages in multi-source predictive data integration compared to the Logistic Regression (LR) and Random Forest (RF) models, particularly by integrating more 3D maps generated by numerical modeling.
五河地区位于华北克拉通东南缘,毗邻大别-苏鲁造山带。它被认为是郯庐断裂带西侧招远—邺县金带的延伸。然而,迄今为止,在五河地区只发现了有限的中小型矿床。近年来,三维找矿建模(3DMPM)已成为找准深部隐伏矿床的有力工具。生成与矿化相关的三维预测图是3DMPM的关键步骤。成矿过程的数值模拟已逐渐融入三维点法中。数值模拟可以为3DMPM提供有用的预测信息。然而,在3DMPM期间整合这些额外的3D预测地图的更好方法需要进一步的探索和研究。此外,将三维卷积神经网络(3DCNN)模型应用于夕卡岩型矿床的3DMPM中,显示出良好的数据融合能力。然而,3DCNN在矿脉金矿找矿建模中的应用尚未见探索。因此,本研究初步采用隐式三维地质建模方法建立三维地质模型。随后,利用三维空间分析和数值模拟生成三维预测图。最后,采用一个包含空间注意机制和盗梦模块的3DCNN模型(MSAM-3DCNN)来整合3D预测地图,并描绘出未来勘探的几个极具前景的区域。高找矿区不仅圈定了数据驱动型矿床,而且还圈定了五河地区的其他矿床,表明本文所采用的方法可以有效地圈定矿脉金矿床的找矿远景。数值模拟可以提供一系列的三维地图,大大提高了3DMPM的有效性,特别是在模拟矿脉金矿床的潜在成矿作用方面,3D预测地图是有限的。与Logistic回归(LR)和随机森林(RF)模型相比,MSAM-3DCNN模型在多源预测数据集成方面具有显著优势,特别是在集成数值模拟生成的更多3D地图方面。
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引用次数: 0
Petrogenesis and metallogenesis of the Kalatage mafic intrusions associated with Fe–Ti oxide ores in the Eastern Tianshan, Central Asian Orogenic Belt 中亚造山带东天山与铁钛氧化物矿相关的钾化基性侵入体的岩石成因及成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107071
Yu Shi , Yu-Wang Wang , Lie-Meng Chen , Guo-Chao Zhou , Qi-Gui Mao , Cheng-Biao Leng , Shui-Long Wang
Small-scale layered mafic intrusions hosting Fe–Ti oxide ores within orogenic belts are unconventional, and their geodynamic background, petrogenesis and metallogenic mechanisms remain poorly understood. To address this issue, our study focuses on investigating two recently discovered layered mafic Shaxi and Shaxinan intrusions from Eastern Tianshan belt in the Central Asian Orogenic Belt (CAOB). The Shaxi and Shaxinan intrusions are characterized as layered gabbro, intricately composed of alternating strata of hornblende gabbro and gabbro. Notably, the Fe–Ti oxide ores are specifically hosted within the basal sections of the hornblende gabbro layers. The zircon U–Pb dating yields an age of 307.9 ± 4.0 Ma for the Shaxi gabbro, which is coeval with the Shaxinan intrusion and Late Carboniferous mafic magmatism in East Tianshan. Both intrusions are tholeiitic and exhibit enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE, e.g., Ba and U), and high field strength elements (HFSE, e.g., Nb and Zr) with obvious positive Eu anomalies. The Shaxi and Shaxinan intrusions have limited ranges of the εNd(t) values from 1.78 to 1.86 and 2.07 to 2.29 respectively but a relatively high (87Sr/86Sr)i from 0.7072 to 0.7075 and from 0.7067 to 0.7069, respectively. In combination with previous studies, our new geochemical and isotopic data suggest that the parental magmas of the Shaxi and Shaxinan intrusions likely originated from the partial melting of a metasomatized lithospheric mantle, a process that was likely initiated by the influx of hot, rising asthenospheric melts. The Shaxi and Shaxinan intrusions display highly differentiated chemical signatures, indicating their parental magmas underwent intense fractional crystallization, leading the residual melts enriched in ore-forming elements and H2O. During ascent and emplacement, these magmas likely assimilated country rocks of the Xingxingxia Group, introducing additional H2O and CO2 into the system. This contamination elevated magmatic oxygen fugacity and played a key role in the formation of Fe–Ti oxide deposits.
造山带内含铁钛氧化物矿的小型层状基性侵入体是非常规的,其地球动力学背景、岩石成因和成矿机制尚不清楚。为了解决这一问题,本文重点研究了中亚造山带(CAOB)东天山带新近发现的两个层状基性岩体沙溪和沙新南。沙溪、沙溪岩体为层状辉长岩,由角闪辉长岩与辉长岩交替地层复杂组成。值得注意的是,铁钛氧化物矿石特别赋存于角闪石辉长岩的基底部分。锆石U-Pb定年结果表明,沙溪辉长岩的年龄为307.9±4.0 Ma,与沙溪南岩体和东天山晚石炭世基性岩浆活动同时代。两种侵入体均为拉斑岩,均富集轻稀土元素(LREE)、大离子亲石元素(LILE,如Ba、U)和高场强元素(HFSE,如Nb、Zr),且Eu正异常明显。沙溪岩体和沙溪岩体的εNd(t)值范围较窄,分别为1.78 ~ 1.86和2.07 ~ 2.29,但εNd(t)值较高,分别为0.7072 ~ 0.7075和0.7067 ~ 0.7069。结合前人的研究,我们新的地球化学和同位素数据表明,沙溪和沙溪南侵入岩的母岩浆可能起源于交代岩石圈地幔的部分熔融,这一过程可能是由热的上升软流圈熔体的涌入引起的。沙溪岩体和沙溪岩体具有高度分化的化学特征,表明母岩岩浆经历了强烈的分离结晶,导致残余熔体富集成矿元素和水。在上升和侵位过程中,这些岩浆可能吸收了星星峡群的乡村岩石,向系统中引入了额外的H2O和CO2。这种污染提高了岩浆氧逸度,并在铁钛氧化物矿床的形成中发挥了关键作用。
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Ore Geology Reviews
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