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Controls on REE mineralization in the Tioueine ring complex (Western Hoggar, Algeria): examination of magmatic vs hydrothermal processes 阿尔及利亚西部Hoggar Tioueine环杂岩中稀土矿化的控制因素:岩浆与热液作用的检验
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107078
Youcef Cherfi , Abdelhak Boutaleb , Chris Yakymchuk , David R. Lentz , Hanafi Benali , Mammar Amieur , Chakib Naoufel Groucene , Djamel-Eddine Aissa
The Hoggar is a rare metal endowed province within the Tuareg shield with variably mineralized post Pan-African granitoid complexes. The investigated Tioueine Ring Complex is among them, with two major units: a weakly evolved calc-alkaline central unit containing monzogranite and granodiorite, and a highly evolved alkali feldspar granite-dominated major outer unit that hosts magmatic to magmatic-hydrothermal LREE-dominant mineralization. The Tioueine Ring Complex is a mantle-derived A1-type granitoid complex that crystallized at ca. 600 Ma during a post-orogenic to anorogenic episode of the Pan-African orogeny. Its parental magmatic system is characterized by high concentrations of alkali elements, with moderate total REE2O3 (TREE2O3) contents up to 0.2 wt%; allanite is the major REE-rich mineral, with limited proportions of apatite, xenotime, and rare monazite. Primary mineralization resulted from low degrees of partial melting of an enriched mantle source that produced reduced ferroan REE-rich magma following advective mantle heat input. The derivative melt may have experienced crustal assimilation and crystal fractionation that caused further enrichment in HFSE and REE before reaching the solidus. A late- to post-magmatic-hydrothermal event allowed limited secondary enrichment of REE by causing allanite breakdown to form REE-fluorocarbonate minerals. Fluid—rock interaction likely resulted from magmatic-hydrothermal F- and CO2-rich aqueous fluids and late meteoric hydrothermal fluids that circulated through ring faults. The Tioueine Ring Complex exhibits elevated REE concentrations that warrant follow-up sampling and drilling to assess its economic viability. However, despite REE enrichment in A-type granites globally, the role of F-rich fluids in remobilizing REE from magmatic allanite to form hydrothermal REE-fluorocarbonates remains poorly constrained. The Tioueine Ring Complex offers a case study to elucidate this process.
Hoggar是图阿雷格盾内一个稀有的金属矿省份,具有不同矿化的后泛非花岗岩复合体。所研究的Tioueine环杂岩体包括两个主要单元:一个弱演化的钙碱性中心单元,含二长花岗岩和花岗闪长岩;一个以高演化的碱长石花岗岩为主的主要外部单元,以岩浆-岩浆热液lree为主成矿。Tioueine环杂岩是一个源自地幔的a1型花岗岩杂岩,形成于约600 Ma的泛非造山后—造山后时期。母岩浆体系以碱元素含量高为特征,总REE2O3 (TREE2O3)含量中等,可达0.2 wt%;黝帘石是主要的富稀土矿物,磷灰石、xenotime和稀有的独居石的比例有限。原生矿化是由于地幔源的低程度部分熔融,在地幔对流热输入后产生了还原的富稀土铁岩浆。衍生熔体在到达固相之前可能经历了地壳同化和晶体分馏,导致HFSE和REE进一步富集。岩浆期晚期至岩浆期后的热液事件使稀土元素有限度的二次富集,形成稀土氟碳酸盐矿物。流体-岩石相互作用可能是由岩浆-热液富F和富co2的水流体和晚期大气热液流经环状断层引起的。Tioueine环杂岩显示出较高的稀土元素浓度,需要进行后续采样和钻探,以评估其经济可行性。然而,尽管全球a型花岗岩中稀土元素富集,但富f流体在岩浆allanite中再活化稀土元素形成热液中稀土氟碳酸盐的作用仍不明确。Tioueine环复合体提供了一个案例研究来阐明这一过程。
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引用次数: 0
Central Asian uranium mega province (Uzbekistan and Kazakhstan) and its evolution during the late Neogene-Quaternary 中亚铀大省(乌兹别克斯坦和哈萨克斯坦)及其晚新近纪—第四纪演化
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107077
Bekzodjon Abdixalikovich Elibaev, Gerard Fries, Baxtiyar Ismailovich Mirhodjaev, Xusniddin Xujahmatovich Olovov, Sherali Izzatullayevich Jurayev
In the present study, we analyze the relation between the recent and active tectonic deformation of the Turan-South Kazakh platforms and the three main uranium provinces (Shu Sarysu, Syr Darya and Kyzylkum). The evolution of these regions has been largely studied and active deformation with important vertical (several hundred meters) and horizontal (up to 100 km) movements has been demonstrated in a North-South compressive context linked to the Pamir indentation. In these three regions, uranium mineralization, as stacked roll fronts, is hosted by sands ranging from Upper Cretaceous to Paleocene-Eocene age. The faults offset vertically and horizontally the host formations as well as the ore bodies, proving that the main mineralization phases occurred before these faults. A middle to upper Quaternary age of the main tectonic faults movements that affect the uranium deposits has been assessed by the age of the youngest sediments involved, compatible with a main mineralization phase dated of the upper Miocene (Tortonian, −8.7 Ma). The regional mapping of the successive roll fronts (Turonian, Coniacian, Santonian, Campanian, Maastrichtian, Paleocene, Eocene) suggests that the three regions (Shu Sarysu, Syr Darya and Kyzylkum) where forming one unique sedimentary basin. At the time of mineralization, individual roll fronts of more than 1000 km long were formed creating a unique uranium mega-province that the most recent deformation has teared apart.
Palinspastic reconstruction of the Kyzylkum – Syr Darya – Shu Sarysu regions before the recent deformation will help assess the initial geometry of the roll fronts and better understand these large-scale mineralization processes.
本文分析了图兰-南哈萨克地台近期和活动构造变形与3个主要铀矿省(Shu Sarysu、Syr Darya和Kyzylkum)的关系。这些地区的演化已经得到了大量的研究,在与帕米尔凹陷相关的南北压缩背景下,已经证明了具有重要垂直(数百米)和水平(高达100公里)运动的活动变形。在这三个地区,铀矿化以叠卷锋面的形式赋存于上白垩世至古新世—始新世的砂岩中。断层在垂直和水平方向上与寄主地层及矿体发生偏移,说明主要成矿阶段发生在这些断层之前。根据最年轻沉积物的年龄,确定了影响铀矿床的主要构造断裂运动的中至上第四纪年龄,与上中新世(托尔顿期,−8.7 Ma)的主要成矿期相一致。连续滚动前缘(Turonian、Coniacian、Santonian、Campanian、Maastrichtian、古新世、始新世)的区域填图表明,Shu Sarysu、Syr Darya和Kyzylkum三个区域形成了一个独特的沉积盆地。在成矿时期,超过1000公里长的单个卷锋形成了一个独特的铀巨型省,最近的变形将其撕裂。近期变形前Kyzylkum - Syr Darya - Shu Sarysu地区的古形体重建将有助于评估滚动锋面的初始几何形状,更好地理解这些大规模成矿作用过程。
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引用次数: 0
The geology and genesis of the Jiaojia-Xincheng gold district (∼1200 t) in the Jiaodong Peninsula, China: A review 胶东半岛焦家—新城金矿带(~ 1200t)地质与成因综述
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107068
Leilei Dong , Mingchun Song , Jian Li , Laijun Wang , Naijie Chi , Runsheng Wang , Zhenliang Yang , Runqian Zhao
The Jiaojia fault in the Jiaodong Peninsula is the main host for several large gold deposits. The overall gold endowment in this fault zone exceeds 1200 tons. The localization of gold orebodies is strictly controlled by the Jiaojia fault and they are mainly beneath and parallel to the fault plane. The wall rocks are primarily Linglong granite and partially Precambrian metamorphic rocks. Along the dip direction, the mineralization mainly occurs at the site where the dip angles of the fault plane change to gentle angles. Alteration and mineralization styles, veins, and fluid chemistry in these deposits share many similarities. The potassium alteration is mainly in the form of alteration halos along fractures or pervasive dissemination. Quartz-sericite dominated alteration overprinted on the potassium alteration, while most of the gold bearing pyrite in dissemination or quartz-pyrite veins form during the alteration process. Ore-forming fluid is characterized by low salinity H2O-NaCl-CO2 system and moderate to low temperatures (150–400 °C). In most cases, gold deposition is related to fluid immiscibility during the relaxation of regional stress field. Genetic models for the Jiaodong gold deposit include magmatic and non-magmatic categories. The non-magmatic models involve devolatilization processes, including those from the Paleo-Pacific subducted slab, metasomatized mantle, and—more recently—the Sulu terrane. Regardless of which genetic model dominates, the most crucial point is that the multiplicity and uncertainty in the interpretation of isotopic data have led to prolonged debates over the sources of gold and fluids.
胶东半岛焦家断裂是几个大型金矿床的主要宿主。该断裂带的黄金总储量超过1200吨。金矿体的定位受焦家断裂的严格控制,主要在断面的下方和平行。围岩主要为玲珑花岗岩,部分为前寒武纪变质岩。沿倾角方向,矿化主要发生在断面倾角变缓的部位。这些矿床的蚀变和矿化样式、矿脉和流体化学有许多相似之处。钾蚀变主要以沿裂缝蚀变晕或普遍浸染的形式存在。石英-绢云母为主的蚀变叠加于钾蚀变之上,而含金黄铁矿大多呈浸染状或石英-黄铁矿脉状形成于蚀变过程中。成矿流体具有低矿化度H2O-NaCl-CO2体系、中低温(150 ~ 400℃)的特征。在大多数情况下,金的沉积与区域应力场松弛过程中的流体不混溶有关。胶东金矿床成因模式分为岩浆成因和非岩浆成因两类。非岩浆模式涉及脱挥发过程,包括古太平洋俯冲板块、交代地幔以及最近的苏鲁地体的脱挥发过程。无论哪种遗传模型占主导地位,最关键的一点是,同位素数据解释的多样性和不确定性导致了对金和流体来源的长期争论。
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引用次数: 0
Smithsonite geochemistry revealing telescoped mineralization at the Huoshaoyun giant non-sulfide Zn-Pb deposit, Karakorum 喀喇昆仑霍少云巨型非硫化物铅锌矿地球化学揭示望远镜成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107097
Jianatiguli Wusiman , Nuo Li , Dengfeng Li , Mingjie Tuo , Yongqi Xia , Xiaojian Zhao , Xinyu Zhang , Hong Xiao
The Huoshaoyun giant Zn-Pb deposit in the Karakorum region, NW China, consists of both non-sulfide (>95 %) and sulfide (<5%) ores, with smithsonite as the dominant phase. The ore genesis remains a subject of debate, primarily due to uncertainties surrounding the paragenesis of smithsonite and its relationship with sulfide mineralization. In this study, combined petrographic, cold cathodoluminescence, electron microprobe analyses, in-situ LA-ICPMS trace elements analyses of smithsonite and thermodynamic modeling were carried out, revealing two groups of smithsonite. The former group is characterized by elevated rare earth elements (REE) abundance, negligible Ce anomalies, and enrichment in Fe, Mn, Ca, Na, As, Li, B and P, while the latter group exhibits lower ΣREE, pronounced negative Ce anomalies, and enrichment in Mg and Cd. These two groups are separated by a stage of sulfide mineralization, during which Cd-rich sphalerite, greenockite, galena and pyrite/marcasite were deposited, followed by minor gypsum, barite and Fe-Mn oxides. We interpret the non-sulfide Zn-Pb mineralization as a combined wall-rock replacement and direct replacement supergene system, while the sulfide mineralization may present either a MVT-type system or another episode of supergene mineralization.
喀喇昆仑地区火少云巨型铅锌矿床为非硫化物(> 95%)和硫化物(<5%)两种矿石组成,以辉钼矿为主。矿石成因仍然是一个有争议的话题,主要是由于围绕菱锌矿共生及其与硫化物矿化关系的不确定性。本研究结合岩石学、冷阴极发光、电子探针分析、原位LA-ICPMS微量元素分析和热力学建模等方法,揭示了两组铁钼矿。前一组稀土元素(REE)丰度升高,Ce异常可忽略,富集Fe、Mn、Ca、Na、As、Li、B、P元素;后一组稀土元素(ΣREE)含量较低,Ce负异常明显,富集Mg和Cd元素。这两组之间存在一段硫化物成矿阶段,主要沉积富Cd闪锌矿、绿辉石、方铅矿和黄铁矿/黄铁矿,其次是少量的石膏、重晶石和Fe-Mn氧化物。非硫化物锌铅矿化可以解释为一个围岩置换和直接置换相结合的表生系统,而硫化物矿化可能是mvt型系统,也可能是另一段表生成矿作用。
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引用次数: 0
White mica SWIR spectral and geochemical signatures: Key exploration vectors for the giant Dahutang tungsten ore field, Jiangxi Province, South China 白云母SWIR光谱与地球化学特征:江西大湖塘钨矿田重点找矿向量
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107064
Changyu Wu , Jingjing Dai , Yang Song , Bo Xu
<div><div>Infrared hyperspectral technology, characterized by its high efficiency and non-destructive nature, is capable of accurately identifying minerals and can be effectively applied to prospecting. As a widely developed alteration mineral in magmatic-hydrothermal deposits, white mica has been successfully applied to the exploration of porphyry, epithermal, volcanogenic massive sulfide (VMS) deposits based on its short-wave infrared (SWIR) spectrum. However, the exploration vectors of white mica vary among different types of deposits. The hyperspectral exploration vector of white mica in tungsten ore remains to be improved, and the study on the significance of trace element indication of white mica is still immature. In this study, the giant Dahutang tungsten ore field in Jiangxi Province is selected as the research object. The research focuses on five types of intrusions associated with mineralization in Dahutang: biotite granodiorite, porphyritic biotite granite, porphyritic fine-grained biotite granite, fine-grained muscovite granite, and granite porphyry. The significance of spectral and geochemical characteristics of white mica for tungsten ore exploration is discussed through comprehensive study on the characteristic parameters, major and trace elements of white mica SWIR spectrum in different intrusions. The results show that the high Pos2200 (Pos2200 > 2209 nm) and low SWIR-IC (SWIR-IC < 0.9) values of white mica in Dahutang can be used as important vectors of mineralization, which mainly occurred in the inner and outer contact zone of biotite granodiorite of Jinningian period (Tonian, ∼1000–800 Ma) and Yanshanian period (Jurassic to Cretaceous, 200–90 Ma). The white mica in ore-bearing intrusions are characterized by high Si, Mg, Fe, F, Li, Sn, Cs and low Al, Na, whereas those in ore-barren intrusions show the opposite features. In addition, the Pos2200 value of SWIR spectrum of white mica in intrusions is positively correlated with Si, Mg, Fe, F, Li, Sn and Cs, and negatively correlated with Al and Na. The value of SWIR-IC is primarily controlled by temperature and exhibits a weak correlation with the major and trace elements in white mica. The high contents of F, Li and Cs in magmatic white mica also indicate that the magmatic evolution of ore-bearing intrusions has higher degree than ore-barren intrusions. The hydrothermal white mica in biotite granodiorite and porphyritic biotite granite all show higher content of V, Sc and W, indicating that metallogenic environment is relatively reduction conditions. Contrasting with other types of deposits, the decline in temperature and rise in fluid pH value prompt the substitution of Tschermak’s component towards Si, Mg, and Fe enrichment, rendering phengite a crucial mineralization indicator in tungsten deposits. Compared with geochemical analysis, SWIR technology has economic, rapid, convenient advantages. The SWIR spectral and geochemical characteristics of white mica can be used a
红外高光谱技术具有高效、无损的特点,能够准确识别矿物,可有效地应用于找矿。白云母是一种广泛发育于岩浆热液矿床的蚀变矿物,其短波红外光谱已成功应用于斑岩、浅成热液、火山块状硫化物(VMS)矿床的勘查。然而,不同类型的白云母矿床的找矿方向不同。钨矿白云母的高光谱勘查矢量有待完善,白云母微量元素指示意义的研究尚不成熟。本研究以江西大湖塘钨矿田为研究对象。重点研究了大湖塘地区5种与成矿有关的岩体类型:黑云母花岗闪长岩、斑岩型黑云母花岗岩、斑岩型细粒黑云母花岗岩、细粒白云母花岗岩和花岗斑岩。通过对不同侵入体中白云母SWIR光谱特征参数及主微量元素的综合研究,探讨了白云母光谱及地球化学特征对钨矿找矿的意义。结果表明,大湖塘白云母的高Pos2200 (Pos2200 > 2209 nm)和低siw - ic (siw - ic < 0.9)值可作为成矿的重要载体,主要产于金宁期(~ 1000 ~ 800 Ma)和燕山期(侏罗纪~白垩纪,200 ~ 90 Ma)黑云母花岗闪长岩的内外接触带。含矿侵入体中的白云母具有高Si、Mg、Fe、F、Li、Sn、Cs和低Al、Na的特征,而无矿侵入体中的白云母则具有相反的特征。此外,侵入体中白色云母的SWIR光谱Pos2200值与Si、Mg、Fe、F、Li、Sn、Cs呈正相关,与Al、Na负相关。SWIR-IC值主要受温度控制,与白云母中主微量元素呈弱相关。岩浆白色云母中F、Li、Cs的高含量也表明含矿侵入体的岩浆演化程度高于无矿侵入体。黑云母花岗闪长岩和斑状黑云母花岗岩中的热液白色云母均表现出较高的V、Sc、W含量,表明成矿环境为相对还原条件。与其他类型的矿床相比,温度的下降和流体pH值的升高促使Tschermak组分向Si、Mg和Fe富集方向转变,使得云母岩成为钨矿重要的成矿指示物。与地球化学分析相比,SWIR技术具有经济、快速、方便等优点。白云母的SWIR光谱和地球化学特征可作为找矿的有效方法。
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引用次数: 0
Apatite and scheelite geochemistry constraints on the properties and evolution of the Yechangping Mo-W Deposit, East Qinling, central China 东秦岭冶厂坪钼钨矿性质与演化的磷灰石和白钨矿地球化学约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107055
Zhuang Zhao , Mengqi Jin , Xiaoyong Yang , Lei Liu , Zhikun Hu , Xinyu Liu
The Yechangping deposit is a representative Mo-W deposit located in the East Qinling Orogen, China. This study presents an integrated geochemical investigation of apatite from the barren monzogranite porphyry (BMP) and ore-related granite porphyry (OGP), alongside scheelite from successive mineralization stages (prograde skarn, retrograde skarn, and quartz-sulfide), to decipher the petrogenetic and hydrothermal evolution. Apatite from the OGP exhibits distin ct geochemical signatures, including lower contents of FeO, MgO, and Sr, a stronger negative Eu anomaly, and higher HREE and Y contents, suggesting a higher degree of fractional crystallization compared to the BMP. Additionally, the lower SO3 content, higher MnO content, and more pronounced negative Eu anomaly in OGP apatite indicate that the ore-forming magma evolved under reduced conditions. The extremely low Cl content and XF/XCl ratios in OGP apatite provide definitive evidence for large-scale fluid saturation and exsolution from the magma. The geochemical signature of scheelite, characterized by its Y/Ho ratios, Sr and Mo contents, and LREE-enriched patterns, points to a predominant magmatic origin for the ore-forming fluids. Notably, variations in Mo content, Eu and Ce anomalies across different scheelite generations reflect significant fluctuations in fluid oxygen fugacity (ƒO2) during mineralization. During the prograde skarn stage (Sch-I), which formed under relatively reduced conditions, Mo-poor scheelite was precipitated. In the retrograde skarn stage (Sch-II), a sharp increase in ƒO2 led to the incorporation of Mo6+ into the scheelite lattice, forming Mo-rich scheelite. During the quartz-sulfide stage (Sch-III), ƒO2 decreased back to relatively reduced conditions, triggering the reduction of Mo6+ to Mo4+, which subsequently precipitated as MoS2, generating Mo-poor scheelite in late-stage. This study highlights that the interplay of intense magmatic differentiation, evolving redox conditions, and timely fluid release governs the formation of porphyry-skarn Mo-W systems in collisional orogens like the East Qinling.
冶厂坪矿床是中国东秦岭造山带具有代表性的钼钨矿床。本文通过对贫二长花岗斑岩(BMP)和与矿有关的花岗斑岩(OGP)中的磷灰石、顺行矽卡岩、逆行矽卡岩和石英硫化物成矿阶段的白钨矿进行综合地球化学研究,以揭示其成岩和热液演化过程。OGP磷灰石具有明显的地球化学特征,FeO、MgO和Sr含量较低,Eu负异常较强,HREE和Y含量较高,表明与BMP相比磷灰石具有较高的分异结晶程度。OGP磷灰石中SO3含量较低,MnO含量较高,Eu负异常较为明显,表明成矿岩浆在还原条件下演化。OGP磷灰石中极低的Cl含量和XF/XCl比值为岩浆的大规模流体饱和和溶出提供了明确的证据。白钨矿的Y/Ho比值、Sr、Mo含量、lree富集模式等地球化学特征表明成矿流体主要来源于岩浆。值得注意的是,不同白钨矿代间Mo含量、Eu和Ce异常的变化反映了成矿过程中流体氧逸度的显著波动(ƒO2)。在相对简化条件下形成的渐进矽卡岩阶段(Sch-I),贫钼白钨矿析出。在逆行矽卡岩阶段(Sch-II), ƒO2的急剧增加导致Mo6+掺入白钨矿晶格中,形成富mo白钨矿。在石英硫化物阶段(Sch-III), ƒO2还原到相对还原状态,触发Mo6+还原为Mo4+, Mo4+随后沉淀为MoS2,在后期生成贫钼白钨矿。研究结果表明,东秦岭等碰撞造山带的斑岩-矽卡岩Mo-W体系的形成受强烈岩浆分异、不断演化的氧化还原条件和及时的流体释放的相互作用控制。
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引用次数: 0
Magnetitites in the Upper Zone of the Bushveld Complex – continuous LIBS and µXRF data of magnetitite layer 17 with a focus on cryptic variation of mineral chemistry Bushveld杂岩上带磁铁矿——第17层磁铁矿连续LIBS和µXRF数据与矿物化学的隐蔽性变化
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107072
Wilhelm Nikonow , Malte Junge , Dieter Rammlmair , Jeannet Meima , Simon Goldmann , Frederick Roelofse , François Holtz
The Bushveld Complex in South Africa holds the largest ultramafic–mafic intrusion on earth with world-class resources of chromium, vanadium and platinum-group elements. Vanadium mostly occurs in the magnetitite layers of the Upper Zone. Their formation is still under debate and several models have been published. Cryptic variation is characteristic for the magnetitites with a general trend of upward depletion of the Cr concentrations in magnetite, which is occasionally inverted. This work applies Laser Induced Breakdown Spectroscopy (LIBS) and micro-X-ray Fluorescence (µXRF) mapping to examine the element trends in magnetitites on a µm-scale along a drill core. These methods provide continuous 2D element and mineral distribution maps. The LIBS and µXRF data were validated using thin section microscopy and electron probe microanalysis. The Cr distribution confirms the general trend of upward depletion and shows repeated increases which mostly correlate with plagioclase or sulfide lenses. Vanadium shows an upward increase within the magnetitite layer which rules out simple fractional crystallization models for the magnetitite formation. Furthermore, the contact zones of magnetitite and anorthosite exhibit abundant symplectic intergrowth of olivine and plagioclase with significantly higher An# in the symplectic plagioclase and higher Mg# in olivine accompanied by amphibole and mica, suggesting a flow of a more mafic melt and the interaction with a hydrous melt. In general, the combination of the LIBS and µXRF presents enormous potential for applications where continuous data at both the micro- and the meso-scale are necessary to understand complex processes such as magnetitite layer formation.
南非的布什维尔德综合体拥有地球上最大的超镁铁侵入物,拥有世界级的铬、钒和铂族元素资源。钒主要赋存于上带的磁铁矿层中。它们的形成仍在争论中,已经发表了几个模型。磁铁矿中Cr含量的变化具有隐蔽性,总体呈上升递减趋势,偶尔也有反转。这项工作应用激光诱导击穿光谱(LIBS)和微x射线荧光(µXRF)作图,沿着钻芯在µm尺度上检查磁铁矿中的元素趋势。这些方法提供了连续的二维元素和矿物分布图。利用薄片显微镜和电子探针微量分析验证了LIBS和µXRF数据。Cr的分布与斜长石或硫化物透镜体有关,显示出上升枯竭的总体趋势和反复增加的趋势。钒在磁铁矿层内呈上升趋势,排除了磁铁矿形成的简单分步结晶模型。在磁铁矿与斜长岩接触带中,橄榄石与斜长石呈丰富的辛共生,辛共生斜长石中An#含量较高,橄榄石中Mg#含量较高,并伴有角闪孔和云母,表明该区存在基性熔体流动,与含水熔体相互作用。总的来说,LIBS和µXRF的结合为了解磁铁矿层形成等复杂过程所需的微观和中尺度连续数据的应用提供了巨大的潜力。
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引用次数: 0
Ore-forming process of the Zhengchong lithium deposit, Nanling Range: constraints from geochronology and mineral chemistry 南岭正冲锂矿床成矿过程:地质年代学和矿物化学的制约
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107088
Jianfeng Li , Zunzun Zhang , Hongyan Quan , Youyue Lu , Jianming Fu , Wei Fang , Yanfeng Su
The Zhongchong lithium deposit, located within the Jinjiling pluton, is a representative large greisen-type lithium deposit in the Nanling metallogenic belt. To constrain its metallogenic age, we obtained 40Ar–39Ar plateau and isochron ages of zinnwaldite (Fe–Li mica) of 152.1 ± 1.4 Ma and 151.6 ± 1.8 Ma, respectively, and a concordant cassiterite U–Pb age of 151.3 ± 2.6 Ma. These results are consistent, within error, with the emplacement age of the fine-grained porphyritic monzogranite (154–150 Ma), indicating that Li–Sn polymetallic mineralization in the Jiuyishan area occurred during the Early Yanshanian period. Two main granite types are developed in the Zhongchong deposit: medium- to coarse-grained porphyritic-like syenogranite and fine-grained porphyritic monzogranite. Geochemical analyses show that both granites are silica- and alkali-rich but depleted in Ca and Mg, with peraluminous to weakly peraluminous compositions (A/CNK = 0.98–1.19). The syenogranite contains significantly higher total REE contents than the monzogranite, with LREE-enriched, right-inclined patterns, whereas the latter exhibits a pronounced tetrad effect. Both granite types are enriched in Rb, K, Th, U, Nd, and Hf but depleted in Ba, Sr, Nb, and Ti, with the fine-grained monzogranite showing stronger enrichment–depletion signatures. These characteristics suggest that the syenogranite and monzogranite represent cumulates and residual melts derived from a common parental magma, with the latter showing higher degrees of differentiation and stronger rare-metal enrichment, thereby possessing greater metallogenic potential. Electron microprobe analyses of zinnwaldite from greisen ores in the Zhongchong deposit are presented in this study. The results show that micas from the medium- to coarse-grained syenogranite, fine-grained monzogranite, greisen, and quartz veins display consistent geochemical trends: SiO2 correlates positively with Al2O3, MnO, and K2O, but negatively with TiO2, FeO, MgO, and Na2O, indicating progressively enhanced magmatic differentiation. Trioctahedral micas dominate the assemblage and define an evolutionary sequence from annite → ferroan biotite → siderophyllite → protolithionite → zinnwaldite → lepidolite, reflecting a clear trend toward lithium enrichment. In addition, mica compositions reveal that the magmatic–hydrothermal system evolved toward higher oxygen fugacity from early to late stages, which facilitated the migration and re-enrichment of multivalent elements. By integrating geological, geochronological, and geochemical evidence, we propose a genetic model for the Zhongchong lithium deposit, providing important guidance for rare-metal exploration in the Nanling region.
中冲锂矿床位于金鸡岭岩体内,是南岭成矿带中具有代表性的大型格纹型锂矿床。为限定其成矿年龄,获得了锌瓦尔石(Fe-Li云母)的40Ar-39Ar平台年龄和等时线年龄分别为152.1±1.4 Ma和151.6±1.8 Ma,锡石的U-Pb年龄为151.3±2.6 Ma。这些结果与细粒斑岩型二长花岗岩的侵位年龄(154 ~ 150 Ma)在误差范围内一致,表明九一山地区Li-Sn多金属成矿作用发生在燕山早期。中冲矿床主要发育两种花岗岩类型:中粗粒斑岩类正长花岗岩和细粒斑岩类二长花岗岩。地球化学分析表明,两种花岗岩均富硅、富碱,缺钙、缺镁,具有过铝质至弱过铝质组成(A/CNK = 0.98 ~ 1.19)。正长花岗岩的总稀土含量明显高于二长花岗岩,呈现低稀土富集、右倾模式,而二长花岗岩则表现出明显的四分体效应。两种花岗岩均富集Rb、K、Th、U、Nd、Hf,而富集Ba、Sr、Nb、Ti,细粒二长花岗岩表现出较强的富贫特征。这些特征表明,正长花岗岩和二长花岗岩是源自同一母岩浆的堆积物和残余熔体,后者分异程度更高,稀土富集程度更强,具有更大的成矿潜力。本文对中冲矿床矿石中的锌walite进行了电子探针分析。结果表明,中粗粒正长花岗岩、细粒二长花岗岩、灰岩和石英脉云母的地球化学变化趋势一致,SiO2与Al2O3、MnO、K2O呈正相关,与TiO2、FeO、MgO、Na2O负相关,岩浆分异逐渐增强。三八面体云母在组合中占主导地位,并确定了从铁黑云母→铁橄榄石→原橄榄石→锌walite→锂云母的演化顺序,反映出明显的锂富集趋势。云母组成表明岩浆-热液系统从早期到晚期向高氧逸度演化,有利于多价元素的迁移和再富集。综合地质、年代学和地球化学证据,提出了中冲锂矿床成因模式,为南岭地区稀有金属勘查提供重要指导。
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引用次数: 0
Genesis of the giant Zhaoxian gold deposit in the Jiaodong Peninsula, China: Constraints from geochronology, fluid inclusion, and H-O-He-Ar isotope 胶东半岛兆县巨型金矿床成因:来自年代学、流体包裹体和H-O-He-Ar同位素的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107070
Wen Zhang , Zuo-Zhen Han , Xue Dong , Bin Sun , Li-Gong Wang , Xiao-Wei Yu , Ying-Peng Wang , Jin-Hui Wang , Feng Yuan
The Zhaoxian gold deposit is an important deep-exploration discovery in the Jiaojia goldfield of the Jiaodong Peninsula, with orebodies extending to depths exceeding 2000 m. To assess whether its genesis differs from that of shallow gold deposits, this study conducted a systematic investigation involving petrography, fluid inclusions, geochronology, and isotope geochemistry. Four stages of hydrothermal veins were identified: pre-ore veins containing milky quartz and minor disseminated pyrite; main-ore veins consisting of gold-bearing pyrite, quartz, and minor muscovite; late-ore stage veins consisting of (gold-bearing) pyrite, galena, chalcopyrite, and quartz; and post-ore veins characterized by calcite, quartz, and minor pyrite. Gold mineralization primarily occurred during the main-ore stage, with minor mineralization in the last-ore stage. Hydrothermal monazite and apatite U-Pb dating constrain the timing of gold mineralization to approximately 120 Ma. The ore-forming fluid was a CO2-H2O-NaCl ± CH4 system with salinity of 1.0–12.2 wt% NaCl equiv. and temperatures of 195 °C–372 °C. Fluid immiscibility during the main- and late-ore stages, coupled with water–rock interaction led to gold precipitation. The δ18O and δD values of fluids from the pre-ore, main-ore, and post-ore stages range from 2.7 to 6.3 ‰ and −83.3 to −78.1 ‰, respectively while pyrite from the main-ore stage exhibits 3He/4He values of 1.45–2.16 Ra. These isotopic characteristics indicate that the Zhaoxian deposit shares a common fluid source with other deposits in the Jiaojia goldfield and across the Jiaodong Peninsula, likely derived from devolatilization of the metasomatized subcontinental lithospheric mantle. Overall, these results suggest that the Zhaoxian deposit follows the same genetic model as shallow gold deposits in the Jiaojia goldfield, and formed in a transpressional setting driven by Paleo-Pacific plate rollback at approximately 120 Ma.
赵县金矿床是胶东半岛焦家金矿的一个重要深部找矿发现,矿体延伸深度超过2000 m。为评价其成因是否与浅层金矿床不同,本文从岩石学、流体包裹体、年代学、同位素地球化学等方面进行了系统的研究。确定了4期热液脉:含乳状石英和少量浸染黄铁矿的成矿前脉;主矿脉由含金黄铁矿、石英和少量白云母组成;由(含金)黄铁矿、方铅矿、黄铜矿和石英组成的晚期矿脉;后矿脉以方解石、石英和少量黄铁矿为特征。金矿化主要发生在主矿期,末矿期少量成矿。热液独居石和磷灰石U-Pb定年将金成矿时间限定在120 Ma左右。成矿流体为CO2-H2O-NaCl±CH4体系,盐度为1.0 ~ 12.2 wt% NaCl当量,温度为195℃~ 372℃。成矿主期和成矿晚期流体不混溶,加之水岩相互作用,导致金的析出。成矿前、主、后阶段流体的δ18O和δD值分别为2.7 ~ 6.3‰和- 83.3 ~ - 78.1‰,主阶段黄铁矿的3He/4He值为1.45 ~ 2.16 Ra。这些同位素特征表明,赵县矿床与焦家金矿及胶东半岛其他矿床具有共同的流体来源,可能来源于变质的次大陆岩石圈地幔的脱挥发作用。综上所述,昭县金矿床与焦家金矿区的浅层金矿床具有相同的成因模式,形成于约120 Ma古太平洋板块回滚作用下的跨洋环境。
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引用次数: 0
Corrigendum to “Fingerprinting hydrothermal alteration associated with pegmatite-type Li-(Be) mineralization using titanite” [Ore Geol. Rev. 187 (2025) 106993] “利用钛矿与伟晶岩型Li- Be矿化相关的热液蚀变指纹”[矿石地质]的勘误。Rev. 187 (2025) 106993]
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107036
Ming-Jie Tuo , Yong-Qi Xia , Nuerkanati Madayipu , Deng-feng Li , Jie Yu , Nuo Li
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引用次数: 0
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Ore Geology Reviews
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