Pub Date : 2023-04-13DOI: 10.1108/prt-12-2022-0150
Kaiyan Yang, Xiaowu Gong, Lanli Bai, Yun Zhang, Na Zhou
Purpose This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin. Design/methodology/approach The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained. Findings The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%. Practical implications The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application. Social implications The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health. Originality/value The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.
{"title":"Glucose-lignin-based phenolic resin: an environmentally friendly low-formaldehyde wood adhesive","authors":"Kaiyan Yang, Xiaowu Gong, Lanli Bai, Yun Zhang, Na Zhou","doi":"10.1108/prt-12-2022-0150","DOIUrl":"https://doi.org/10.1108/prt-12-2022-0150","url":null,"abstract":"\u0000Purpose\u0000This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin.\u0000\u0000\u0000Design/methodology/approach\u0000The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained.\u0000\u0000\u0000Findings\u0000The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%.\u0000\u0000\u0000Practical implications\u0000The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application.\u0000\u0000\u0000Social implications\u0000The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health.\u0000\u0000\u0000Originality/value\u0000The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78972259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Guest editorial: Environmental science and sustainable energy: colorants and coatings","authors":"Z. Ranjbar, M. Hosseinnezhad, K. Gharanjig","doi":"10.1108/prt-05-2023-153","DOIUrl":"https://doi.org/10.1108/prt-05-2023-153","url":null,"abstract":"","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91243373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-11DOI: 10.1108/prt-09-2022-0106
Qi Yang, Zhiqiang Feng, R. Zhang, Yunpu Wang, Dengle Duan, Qin Wang, Xiaoyu Zou, Yuhuan Liu
Purpose This study aims to develop a green, economical and efficient ultrasonic-/microwave assisted extraction (UMAE) process for the extraction of anthocyanins. Design/methodology/approach After optimizing the extraction conditions by response surface methodology, three assays including DPPH, ABTS·+, FRAP were applied to analyze the antioxidant activity of the extracted anthocyanins. The stability under different temperatures, reductant concentrations and pHs was also discussed. The components of anthocyanins in blueberry were analyzed by HPLC-QTOF-MS2. Findings The optimal extraction parameters were ultrasonic power of 300 W, microwave power of 365.28 W and solid–liquid ratio of 30 (g/mL). The possible structures can be speculated as Delphinidin-3-O-galactoside, Delphinidin, Petunidin, Delphinidin-3-O-glucoside, Petunidin-3-O-glucoside, Cyanidin-3-O-glucoside. The results demonstrated that the UMAE can improve the yield of anthocyanins in shorter extraction time with higher activity. Originality/value The present study may provide a promising and feasible route for extracting anthocyanins from blueberries and studying their physicochemical properties, ultimately promoting the utilization of blueberry anthocyanins.
目的研究一种绿色、经济、高效的超声/微波辅助提取花青素的工艺。设计/方剂/方法采用响应面法优化提取条件，采用DPPH、ABTS·+、FRAP三种方法对提取的花青素进行抗氧化活性分析。讨论了其在不同温度、还原剂浓度和ph值下的稳定性。采用HPLC-QTOF-MS2对蓝莓中花青素的成分进行了分析。结果最佳提取工艺为超声功率300 W、微波功率365.28 W、料液比30 (g/mL)。可能的结构可以推测为:飞鸽苷-3- o -半乳糖苷、飞鸽苷、矮牵牛花苷、飞鸽苷-3- o -葡萄糖苷、矮牵牛花苷-3- o -葡萄糖苷、花青花苷-3- o -葡萄糖苷。结果表明，该方法可在较短的提取时间内提高花青素的提取率，并具有较高的提取活性。本研究为从蓝莓中提取花青素并研究其理化性质提供了一条有前景的可行途径，最终促进蓝莓花青素的开发利用。
{"title":"Extraction and identification of anthocyanin from blueberries: effects of ultrasound-/microwave-assisted parameters","authors":"Qi Yang, Zhiqiang Feng, R. Zhang, Yunpu Wang, Dengle Duan, Qin Wang, Xiaoyu Zou, Yuhuan Liu","doi":"10.1108/prt-09-2022-0106","DOIUrl":"https://doi.org/10.1108/prt-09-2022-0106","url":null,"abstract":"\u0000Purpose\u0000This study aims to develop a green, economical and efficient ultrasonic-/microwave assisted extraction (UMAE) process for the extraction of anthocyanins.\u0000\u0000\u0000Design/methodology/approach\u0000After optimizing the extraction conditions by response surface methodology, three assays including DPPH, ABTS·+, FRAP were applied to analyze the antioxidant activity of the extracted anthocyanins. The stability under different temperatures, reductant concentrations and pHs was also discussed. The components of anthocyanins in blueberry were analyzed by HPLC-QTOF-MS2.\u0000\u0000\u0000Findings\u0000The optimal extraction parameters were ultrasonic power of 300 W, microwave power of 365.28 W and solid–liquid ratio of 30 (g/mL). The possible structures can be speculated as Delphinidin-3-O-galactoside, Delphinidin, Petunidin, Delphinidin-3-O-glucoside, Petunidin-3-O-glucoside, Cyanidin-3-O-glucoside. The results demonstrated that the UMAE can improve the yield of anthocyanins in shorter extraction time with higher activity.\u0000\u0000\u0000Originality/value\u0000The present study may provide a promising and feasible route for extracting anthocyanins from blueberries and studying their physicochemical properties, ultimately promoting the utilization of blueberry anthocyanins.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80904826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-11DOI: 10.1108/prt-10-2022-0117
Saima Habib, Farzana Kishwar, Z. A. Raza, S. Abid
Purpose This study aims to present a sustainable approach in the natural dyeing of cellulose fabric followed by nanosilver finishing through a green crosslinker of citric acid for potential antibacterial surgical gown fabrication. Design/methodology/approach The nanosilver finish was reproduced using the chemical reduction method. The fabric dyeing was performed on a lab-scale dyeing machine, whereas silver nano-finishing through a pad-dry-cure approach. Citric acid was used as an eco-friendly crosslinker. The specimens were characterized for antibacterial activity, surface chemical, textile, color properties and finish release trend. Findings The results demonstrated the successful application of curcumin dye followed by silver nano-finishing. The resultant fabric exhibited appropriate textile, dyeing performance indicators, hydrophobic behavior and sustainable broad-spectrum antibacterial activity. Practical implications The prepared nanosilver-finished/curcumin-treated fabric expressed desirable properties for potential applications in the fabrication of surgical gowns. Originality/value The authors found no reports on an extensive examination of nanosilver finishing on the color parameters of curcumin-dyed cellulose fabric while retaining its textile and comfort properties for possible surgical gown fabrication.
{"title":"Citrate-crosslinked silver nanoparticles impregnation on curcumin-dyed cellulose fabric for potential surgical applications","authors":"Saima Habib, Farzana Kishwar, Z. A. Raza, S. Abid","doi":"10.1108/prt-10-2022-0117","DOIUrl":"https://doi.org/10.1108/prt-10-2022-0117","url":null,"abstract":"\u0000Purpose\u0000This study aims to present a sustainable approach in the natural dyeing of cellulose fabric followed by nanosilver finishing through a green crosslinker of citric acid for potential antibacterial surgical gown fabrication.\u0000\u0000\u0000Design/methodology/approach\u0000The nanosilver finish was reproduced using the chemical reduction method. The fabric dyeing was performed on a lab-scale dyeing machine, whereas silver nano-finishing through a pad-dry-cure approach. Citric acid was used as an eco-friendly crosslinker. The specimens were characterized for antibacterial activity, surface chemical, textile, color properties and finish release trend.\u0000\u0000\u0000Findings\u0000The results demonstrated the successful application of curcumin dye followed by silver nano-finishing. The resultant fabric exhibited appropriate textile, dyeing performance indicators, hydrophobic behavior and sustainable broad-spectrum antibacterial activity.\u0000\u0000\u0000Practical implications\u0000The prepared nanosilver-finished/curcumin-treated fabric expressed desirable properties for potential applications in the fabrication of surgical gowns.\u0000\u0000\u0000Originality/value\u0000The authors found no reports on an extensive examination of nanosilver finishing on the color parameters of curcumin-dyed cellulose fabric while retaining its textile and comfort properties for possible surgical gown fabrication.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90258034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-11DOI: 10.1108/prt-04-2022-0038
G. Monrós, M. Llusar, J. Badenes
Purpose The purpose of this study is the synthesis and characterization of a CMYK palette (cyan of Cr-BiVO4, magenta of Pr-CeO2, yellow of Bi-(Ce,Zr)O2 composite and black of YMnO3) as an eco-friendly polyfunctional palette that combines (a) high near-infrared reflectance (cool pigments) that allows moderate temperatures in indoor environments and the urban heat island effect; (b) photocatalytic activity for the degradation of organic contaminants of emerging concern of substrates in solution (such as Orange II or methylene blue) and gaseous (NOx and volatile organic compounds such as acetaldehyde or toluene); (c) X-ray radiation attenuators associated with bismuth ions; and (d) biocidal effect combined with co-doping with bactericidal agents. Design/methodology/approach Pigments were prepared by a solid-state reaction and characterized by X-ray diffraction, diffuse reflectance spectroscopy, photocatalytic activity over Orange II and scanning electron microscopy. Findings The behaviour of the proposed palette was compared to that of a commercial inkjet palette, and an improvement in all functionalities was observed. Social implications The functionalities of pigments allow the building envelope and indoor walls to exhibit temperature-moderating effects (with the additional effects of moderating global warming and increasing air conditioning efficiency), purification and disinfection of both indoor and outdoor air, and radiation attenuation. Originality/value The proposed palette and its polyfunctional characterization are novel.
{"title":"Eco-friendly polyfunctional ceramic pigments: an approach","authors":"G. Monrós, M. Llusar, J. Badenes","doi":"10.1108/prt-04-2022-0038","DOIUrl":"https://doi.org/10.1108/prt-04-2022-0038","url":null,"abstract":"\u0000Purpose\u0000The purpose of this study is the synthesis and characterization of a CMYK palette (cyan of Cr-BiVO4, magenta of Pr-CeO2, yellow of Bi-(Ce,Zr)O2 composite and black of YMnO3) as an eco-friendly polyfunctional palette that combines (a) high near-infrared reflectance (cool pigments) that allows moderate temperatures in indoor environments and the urban heat island effect; (b) photocatalytic activity for the degradation of organic contaminants of emerging concern of substrates in solution (such as Orange II or methylene blue) and gaseous (NOx and volatile organic compounds such as acetaldehyde or toluene); (c) X-ray radiation attenuators associated with bismuth ions; and (d) biocidal effect combined with co-doping with bactericidal agents.\u0000\u0000\u0000Design/methodology/approach\u0000Pigments were prepared by a solid-state reaction and characterized by X-ray diffraction, diffuse reflectance spectroscopy, photocatalytic activity over Orange II and scanning electron microscopy.\u0000\u0000\u0000Findings\u0000The behaviour of the proposed palette was compared to that of a commercial inkjet palette, and an improvement in all functionalities was observed.\u0000\u0000\u0000Social implications\u0000The functionalities of pigments allow the building envelope and indoor walls to exhibit temperature-moderating effects (with the additional effects of moderating global warming and increasing air conditioning efficiency), purification and disinfection of both indoor and outdoor air, and radiation attenuation.\u0000\u0000\u0000Originality/value\u0000The proposed palette and its polyfunctional characterization are novel.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89260435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-05DOI: 10.1108/prt-01-2022-0010
M. Hosseinnezhad, Z. Ranjbar
Purpose The purpose of this paper is to introduce flexible dye-sensitized solar cells (FDSSCs). Design/methodology/approach In the third generation solar cells, glass was used as a substrate, which due to its high weight and fragility, was not possible to produce continuously. However, in flexible solar cells, flexible substrates are used as new technology. The most important thing may choose a suitable substrate to produce a photovoltaic (PV) device with optimal efficiency. Findings Conductive plastics or metallic foils are the two main candidates for glass replacement, each with its advantages and disadvantages. As some high-temperature methods are used to prepare solar cells, metal substrates can be used to prepare PV devices without any problems. In contrast to the advantage of high thermal resistance in metals, metal substrates are dark and do not transmit enough light. In other words, metal substrates have a high loss of photon energy. Like all technologies, PV devices with polymer substrates have technical disadvantages. Practical implications In this study, the development of FDSSCs offers improved photovoltaic properties. Social implications The most important challenge is the poor thermal stability of polymers compared to glass and metal, which requires special methods to prepare polymer solar cells. The second important point is choosing the suitable components and materials for this purpose. Originality/value Dependence of efficiency and performance of the device on the angle of sunlight, high-cost preparation devices components, limitations of functional materials such as organic-mineral sensitizers, lack of close connection between practical achievements and theoretical results and complicated fabrication process and high weight.
{"title":"A review on flexible dye-sensitized solar cells as new sustainable energy resources","authors":"M. Hosseinnezhad, Z. Ranjbar","doi":"10.1108/prt-01-2022-0010","DOIUrl":"https://doi.org/10.1108/prt-01-2022-0010","url":null,"abstract":"\u0000Purpose\u0000The purpose of this paper is to introduce flexible dye-sensitized solar cells (FDSSCs).\u0000\u0000\u0000Design/methodology/approach\u0000In the third generation solar cells, glass was used as a substrate, which due to its high weight and fragility, was not possible to produce continuously. However, in flexible solar cells, flexible substrates are used as new technology. The most important thing may choose a suitable substrate to produce a photovoltaic (PV) device with optimal efficiency.\u0000\u0000\u0000Findings\u0000Conductive plastics or metallic foils are the two main candidates for glass replacement, each with its advantages and disadvantages. As some high-temperature methods are used to prepare solar cells, metal substrates can be used to prepare PV devices without any problems. In contrast to the advantage of high thermal resistance in metals, metal substrates are dark and do not transmit enough light. In other words, metal substrates have a high loss of photon energy. Like all technologies, PV devices with polymer substrates have technical disadvantages.\u0000\u0000\u0000Practical implications\u0000In this study, the development of FDSSCs offers improved photovoltaic properties.\u0000\u0000\u0000Social implications\u0000The most important challenge is the poor thermal stability of polymers compared to glass and metal, which requires special methods to prepare polymer solar cells. The second important point is choosing the suitable components and materials for this purpose.\u0000\u0000\u0000Originality/value\u0000Dependence of efficiency and performance of the device on the angle of sunlight, high-cost preparation devices components, limitations of functional materials such as organic-mineral sensitizers, lack of close connection between practical achievements and theoretical results and complicated fabrication process and high weight.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77838326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-29DOI: 10.1108/prt-12-2022-0147
Shan Peng, Ranran Yang, B. Lei, Yun Gao, Renhua Chen, X. Xia, K. Homewood
Purpose This paper aims to systematically demonstrate a methodology to determine the relative and absolute encapsulation efficiencies (αRe and αAb) for thermally- and chemically-robust inorganic pigments, typically like ZrSiO4-based pigments, thereby enhancing their coloring performance. Design/methodology/approach The authors designed a route, surplus alkali-decomposition and subsequently strong-acid dissolution (SAD2) to completely decompose three classic zircon pigments (Pr–ZrSiO4, Fe2O3@ZrSiO4 and CdS@ZrSiO4) into clear solutions and preferably used inductively coupled plasma-optical emission spectrometry (ICP-OES) to determine the concentrations of host elements and chromophores, thereby deriving the numeric data and interrelation of αRe and αAb. Findings Zircon pigments can be thoroughly decomposed into some dissoluble zirconate–silicate resultants by SAD2 at a ratio of the fluxing agent to pigment over 6. ICP-OES is proved more suitable than some other quantification techniques in deriving the compositional concentrations, thereby the values of αRe and αAb, and their transformation coefficient KRA, which maintains stably within 0.8–0.9 in Fe2O3@ZrSiO4 and CdS@ZrSiO4 and is slightly reduced to 0.67–0.85 in Pr–ZrSiO4. Practical implications The SAD2 method and encapsulation efficiencies are well applicable for both zircon pigments and the other pigmental or non-pigmental inhomogeneous systems in characterizing their accurate composition. Originality/value The authors herein first proposed strict definitions for the relative and absolute encapsulation efficiencies for inorganic pigments, developed a relatively stringent methodology to determine their accurate values and interrelation.
{"title":"The encapsulation efficiency of zircon pigments from robust solids to clear solutions","authors":"Shan Peng, Ranran Yang, B. Lei, Yun Gao, Renhua Chen, X. Xia, K. Homewood","doi":"10.1108/prt-12-2022-0147","DOIUrl":"https://doi.org/10.1108/prt-12-2022-0147","url":null,"abstract":"\u0000Purpose\u0000This paper aims to systematically demonstrate a methodology to determine the relative and absolute encapsulation efficiencies (αRe and αAb) for thermally- and chemically-robust inorganic pigments, typically like ZrSiO4-based pigments, thereby enhancing their coloring performance.\u0000\u0000\u0000Design/methodology/approach\u0000The authors designed a route, surplus alkali-decomposition and subsequently strong-acid dissolution (SAD2) to completely decompose three classic zircon pigments (Pr–ZrSiO4, Fe2O3@ZrSiO4 and CdS@ZrSiO4) into clear solutions and preferably used inductively coupled plasma-optical emission spectrometry (ICP-OES) to determine the concentrations of host elements and chromophores, thereby deriving the numeric data and interrelation of αRe and αAb.\u0000\u0000\u0000Findings\u0000Zircon pigments can be thoroughly decomposed into some dissoluble zirconate–silicate resultants by SAD2 at a ratio of the fluxing agent to pigment over 6. ICP-OES is proved more suitable than some other quantification techniques in deriving the compositional concentrations, thereby the values of αRe and αAb, and their transformation coefficient KRA, which maintains stably within 0.8–0.9 in Fe2O3@ZrSiO4 and CdS@ZrSiO4 and is slightly reduced to 0.67–0.85 in Pr–ZrSiO4.\u0000\u0000\u0000Practical implications\u0000The SAD2 method and encapsulation efficiencies are well applicable for both zircon pigments and the other pigmental or non-pigmental inhomogeneous systems in characterizing their accurate composition.\u0000\u0000\u0000Originality/value\u0000The authors herein first proposed strict definitions for the relative and absolute encapsulation efficiencies for inorganic pigments, developed a relatively stringent methodology to determine their accurate values and interrelation.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91047412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-28DOI: 10.1108/prt-08-2022-0096
Zheqing Gong, Lijun Chen
Purpose Fluorinated silicon polymers are expected to be adopted in specific coatings to afford outstanding advantages, such as high chemical and photochemical resistance, low surface tension and low refractive index. The modified acrylate resin is prepared via solution polymerization of fluorine and silicon monomers, acrylate monomers and other functional monomers. The purpose of this paper is that the fluorine and silicon monomers such as vinyltriethoxysilane (VTES) and hexafluorobutyl methacrylate (HFMA) and some cheap monomers such as styrene are used to prepare the cationic acrylic resin. Design/methodology/approach The fluorine and silicon modified cationic acrylic resin is prepared via solution polymerization technology, which uses butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), HFMA, VTES, dimethylaminoethyl methacrylate (DMAEMA) and hydroxypropyl methacrylate (HPMA) as the co-polymerized monomers, propylene glycol monomethyl ether (PGME) as solvent and 2,2-Azo-bis-iso-butyronitrile (AIBN) as the initiator to create a resin to introduce the Si–O and C–F into the polymer chains. The cathodic electrodeposition (CED) coatings were prepared by mixing the synthetic resin and blocked isocyanate. Findings The influence of the amounts of HFMA and VETS on the resin and the resultant CED coatings is investigated in detail. The optimum amounts of HFMA and VETS are obtained, which is 7–8% and 4–5%, respectively. The hydrophobicity and the acid and alkaline resistance of the film are improved when VETS and HFMA are introduced to co-polymerize with other monomers. Originality/value The fluorine and silicon monomers such as VTES and HFMA and some cheap monomers such as styrene, which are used to prepare the cationic acrylic resin, are seldom reported in the open literature.
{"title":"Preparation of fluorine and silicon modified cationic acrylic resin and its application in cathodic electrodeposition coatings","authors":"Zheqing Gong, Lijun Chen","doi":"10.1108/prt-08-2022-0096","DOIUrl":"https://doi.org/10.1108/prt-08-2022-0096","url":null,"abstract":"\u0000Purpose\u0000Fluorinated silicon polymers are expected to be adopted in specific coatings to afford outstanding advantages, such as high chemical and photochemical resistance, low surface tension and low refractive index. The modified acrylate resin is prepared via solution polymerization of fluorine and silicon monomers, acrylate monomers and other functional monomers. The purpose of this paper is that the fluorine and silicon monomers such as vinyltriethoxysilane (VTES) and hexafluorobutyl methacrylate (HFMA) and some cheap monomers such as styrene are used to prepare the cationic acrylic resin.\u0000\u0000\u0000Design/methodology/approach\u0000The fluorine and silicon modified cationic acrylic resin is prepared via solution polymerization technology, which uses butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), HFMA, VTES, dimethylaminoethyl methacrylate (DMAEMA) and hydroxypropyl methacrylate (HPMA) as the co-polymerized monomers, propylene glycol monomethyl ether (PGME) as solvent and 2,2-Azo-bis-iso-butyronitrile (AIBN) as the initiator to create a resin to introduce the Si–O and C–F into the polymer chains. The cathodic electrodeposition (CED) coatings were prepared by mixing the synthetic resin and blocked isocyanate.\u0000\u0000\u0000Findings\u0000The influence of the amounts of HFMA and VETS on the resin and the resultant CED coatings is investigated in detail. The optimum amounts of HFMA and VETS are obtained, which is 7–8% and 4–5%, respectively. The hydrophobicity and the acid and alkaline resistance of the film are improved when VETS and HFMA are introduced to co-polymerize with other monomers.\u0000\u0000\u0000Originality/value\u0000The fluorine and silicon monomers such as VTES and HFMA and some cheap monomers such as styrene, which are used to prepare the cationic acrylic resin, are seldom reported in the open literature.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90643670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-20DOI: 10.1108/prt-10-2022-0118
Emad S. Shafik, N. Rozik, N. Youssef, S. Abd-El-Messieh
Purpose The purpose of this study is to utilize two types of gypsum mold wastes from two different factories as novel and economical reinforcing fillers for composites that may be useful for building materials and floors. Two types of gypsum mold wastes from two different factories as raw materials were incorporated into linear low density polyethylene (LLDPE) aiming to get rid of that waste in one hand and obtaining useful economical composites suitable for building materials and floors. Design/methodology/approach Composites were prepared from two types of gypsum mold wastes substituted with different ratios from raw gypsum and LLDPE throughout the melt blending technique. The physico-mechanical and electrical investigations in addition to the morphology of the composites were included. Findings The mechanical results illustrate that substituting commercial gypsum with gypsum mold waste positively affects tensile strength, flexural strength and hardness shore D for the LLDPE composites. The tensile strength increased from 5 MPa for LLDPE filled with commercial gypsum as blank samples to 11.2 and 13.2 MPa for LLDPE filled with D and S waste. Also, electrical properties which include both permittivity ɛ′ and dielectric loss ɛ″ increased with increasing the waste content in the LLDPE matrix. In addition to the electrical conductivity values, σ lies in the order of insulation materials. Consequently, it is possible to produce materials with a gypsum matrix by adding industrial waste, improving the behavior of the traditional gypsum and enabling those composites to be applied in various construction applications as eco-friendly tiles. Originality/value This study aims to prepare eco-friendly composites based on LLDPE and waste gypsum mold to preserve resources for the coming generations, other than lowering the environmental footprint and saving the costs of getting rid of it.
{"title":"Eco-friendly tiles: fabrication and testing of composite tile made from industrial gypsum wastes","authors":"Emad S. Shafik, N. Rozik, N. Youssef, S. Abd-El-Messieh","doi":"10.1108/prt-10-2022-0118","DOIUrl":"https://doi.org/10.1108/prt-10-2022-0118","url":null,"abstract":"\u0000Purpose\u0000The purpose of this study is to utilize two types of gypsum mold wastes from two different factories as novel and economical reinforcing fillers for composites that may be useful for building materials and floors. Two types of gypsum mold wastes from two different factories as raw materials were incorporated into linear low density polyethylene (LLDPE) aiming to get rid of that waste in one hand and obtaining useful economical composites suitable for building materials and floors.\u0000\u0000\u0000Design/methodology/approach\u0000Composites were prepared from two types of gypsum mold wastes substituted with different ratios from raw gypsum and LLDPE throughout the melt blending technique. The physico-mechanical and electrical investigations in addition to the morphology of the composites were included.\u0000\u0000\u0000Findings\u0000The mechanical results illustrate that substituting commercial gypsum with gypsum mold waste positively affects tensile strength, flexural strength and hardness shore D for the LLDPE composites. The tensile strength increased from 5 MPa for LLDPE filled with commercial gypsum as blank samples to 11.2 and 13.2 MPa for LLDPE filled with D and S waste. Also, electrical properties which include both permittivity ɛ′ and dielectric loss ɛ″ increased with increasing the waste content in the LLDPE matrix. In addition to the electrical conductivity values, σ lies in the order of insulation materials. Consequently, it is possible to produce materials with a gypsum matrix by adding industrial waste, improving the behavior of the traditional gypsum and enabling those composites to be applied in various construction applications as eco-friendly tiles.\u0000\u0000\u0000Originality/value\u0000This study aims to prepare eco-friendly composites based on LLDPE and waste gypsum mold to preserve resources for the coming generations, other than lowering the environmental footprint and saving the costs of getting rid of it.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74020148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-07DOI: 10.1108/prt-10-2022-0125
Shahin Hossain, M. Jalil, Rois U Mahmud, A. Kader
Purpose In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic dyes. Natural dyes can provide special aesthetic qualities as well as the ethical significance of a product which is environmentally friendly. By keeping this burning issue in mind, this study aims to explore the dyeing properties of various unexplored environmentally friendly natural dyes. Design/methodology/approach In this study, the aqueous extract of coconut leaves is used for dyeing purpose. The silk and jute fabrics were dyed with the extract alone as well as in combination with metal salts as mordants by employing pre-, meta- and postmordanting techniques. The dyeing properties of the colored samples were evaluated by measuring their color strength; CIEL*a*b* values; and color fastness to washing, light and rubbing. Findings A yellow shade was achieved when the fabric samples were dyed solely with the extract. However, shade variations were observed when different mordants and mordanting techniques were applied. In all the cases, metallic salts improved the color fastness properties of dyed samples to washing, light and rubbing especially for the silk fabric. Originality/value To the best of the authors’ knowledge, this is the first report on a natural dye extracted from the leaves of coconut. Leaf as the source of dye has added an extra advantage, as it is reproducible and can be collected easily without harming the plants. The reported dye could be an attractive choice for sustainable and eco-friendly dyeing.
目的近年来，由于公众对合成染料对环境和健康危害的认识日益提高，天然染料引起了全球的广泛关注。天然染料可以提供特殊的审美品质，以及产品的伦理意义，是环保的。考虑到这一燃烧问题，本研究旨在探索各种尚未开发的环保天然染料的染色性能。设计/方法/方法本研究采用椰子叶水提液进行染色。采用前染剂、中染剂和后染剂技术，对丝织品和黄麻织物进行单独染色，并与金属盐结合作为媒染剂。通过测定染色样品的颜色强度来评价染色样品的染色性能;雪露* a * b *值;耐水洗、耐光、耐摩擦色牢度高。当织物样品仅用提取物染色时，可获得黄色阴影。然而，当使用不同的媒染剂和媒染剂技术时，观察到阴影变化。在所有情况下，金属盐都提高了染色样品的耐洗涤、耐光照和耐摩擦的色牢度，特别是对真丝织物。原创性/价值据作者所知，这是从椰子叶中提取的天然染料的第一份报告。叶子作为染料的来源有一个额外的优势，因为它是可再生的，可以很容易地收集而不伤害植物。据报道，这种染料可能是一种有吸引力的可持续和环保染色选择。
{"title":"Natural dyeing of silk and jute fabric with the aqueous extract of coconut leaves – an eco-friendly approach","authors":"Shahin Hossain, M. Jalil, Rois U Mahmud, A. Kader","doi":"10.1108/prt-10-2022-0125","DOIUrl":"https://doi.org/10.1108/prt-10-2022-0125","url":null,"abstract":"\u0000Purpose\u0000In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic dyes. Natural dyes can provide special aesthetic qualities as well as the ethical significance of a product which is environmentally friendly. By keeping this burning issue in mind, this study aims to explore the dyeing properties of various unexplored environmentally friendly natural dyes.\u0000\u0000\u0000Design/methodology/approach\u0000In this study, the aqueous extract of coconut leaves is used for dyeing purpose. The silk and jute fabrics were dyed with the extract alone as well as in combination with metal salts as mordants by employing pre-, meta- and postmordanting techniques. The dyeing properties of the colored samples were evaluated by measuring their color strength; CIEL*a*b* values; and color fastness to washing, light and rubbing.\u0000\u0000\u0000Findings\u0000A yellow shade was achieved when the fabric samples were dyed solely with the extract. However, shade variations were observed when different mordants and mordanting techniques were applied. In all the cases, metallic salts improved the color fastness properties of dyed samples to washing, light and rubbing especially for the silk fabric.\u0000\u0000\u0000Originality/value\u0000To the best of the authors’ knowledge, this is the first report on a natural dye extracted from the leaves of coconut. Leaf as the source of dye has added an extra advantage, as it is reproducible and can be collected easily without harming the plants. The reported dye could be an attractive choice for sustainable and eco-friendly dyeing.\u0000","PeriodicalId":20147,"journal":{"name":"Pigment & Resin Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78355451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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