Xun Jian, Ke Gong, Vicente Moritz, Alexandre Portela, Yinshi Lu, Wenyi Du, Ian Major
This study explores the use of vat polymerization stereolithography (SLA) for fabricating mold tooling, subsequently utilized in injection molding (IM) and overmolding of tensile specimens and directly compared to those produced using metal molds. The results first find the manufacturing time for an SLA‐fabricated mold is remarkably short, approximately 6 h, presenting a substantial improvement over traditional methods. Mechanical testing revealed that the tensile specimens from the SLA‐fabricated molds exhibited the highest tensile strength among all overmolding batches. This performance was consistent with the tensile bars produced using metal molds, demonstrating the viability of SLA‐fabricated molds for overmolding applications and highlighting the potential of FDM to customize the properties of final products. However, variations in mold types impacted the dimensional tolerance and tensile strength of the final specimens. Metal mold‐fabricated tensile bars exhibited superior dimensional accuracy and maximum tensile strength (50.6–61.7 MPa) compared to those produced with SLA‐fabricated molds (46.9–55.9 MPa). These differences are attributed to the rougher surface finish inherent to the layer‐by‐layer construction of SLA and the internal stresses and defects resulting from lower thermal conductivity and uneven cooling. In conclusion, this study underscores the promising future applications of SLA‐fabricated molds in overmolding, offering reduced manufacturing costs and enhanced design freedom. The findings support the potential of SLA to revolutionize mold fabrication, thereby extending its utility and optimizing the production of polymer components with customized properties.HighlightsSLA molds compared to metal molds for direct injection molding and overmolding.FFF preforms with varied geometries were overmolded to finalize the specimens.Joint configurations in overmolding improved tensile performance.Overmolding showed better dimensional accuracy than FFF specimens.SLA mold preparation significantly reduced manufacturing costs.
{"title":"Comparative evaluation of vat photopolymerization and steel tool molds on the performance of injection molded and overmolded tensile specimens","authors":"Xun Jian, Ke Gong, Vicente Moritz, Alexandre Portela, Yinshi Lu, Wenyi Du, Ian Major","doi":"10.1002/pen.26949","DOIUrl":"https://doi.org/10.1002/pen.26949","url":null,"abstract":"<jats:label/>This study explores the use of vat polymerization stereolithography (SLA) for fabricating mold tooling, subsequently utilized in injection molding (IM) and overmolding of tensile specimens and directly compared to those produced using metal molds. The results first find the manufacturing time for an SLA‐fabricated mold is remarkably short, approximately 6 h, presenting a substantial improvement over traditional methods. Mechanical testing revealed that the tensile specimens from the SLA‐fabricated molds exhibited the highest tensile strength among all overmolding batches. This performance was consistent with the tensile bars produced using metal molds, demonstrating the viability of SLA‐fabricated molds for overmolding applications and highlighting the potential of FDM to customize the properties of final products. However, variations in mold types impacted the dimensional tolerance and tensile strength of the final specimens. Metal mold‐fabricated tensile bars exhibited superior dimensional accuracy and maximum tensile strength (50.6–61.7 MPa) compared to those produced with SLA‐fabricated molds (46.9–55.9 MPa). These differences are attributed to the rougher surface finish inherent to the layer‐by‐layer construction of SLA and the internal stresses and defects resulting from lower thermal conductivity and uneven cooling. In conclusion, this study underscores the promising future applications of SLA‐fabricated molds in overmolding, offering reduced manufacturing costs and enhanced design freedom. The findings support the potential of SLA to revolutionize mold fabrication, thereby extending its utility and optimizing the production of polymer components with customized properties.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>SLA molds compared to metal molds for direct injection molding and overmolding.</jats:list-item> <jats:list-item>FFF preforms with varied geometries were overmolded to finalize the specimens.</jats:list-item> <jats:list-item>Joint configurations in overmolding improved tensile performance.</jats:list-item> <jats:list-item>Overmolding showed better dimensional accuracy than FFF specimens.</jats:list-item> <jats:list-item>SLA mold preparation significantly reduced manufacturing costs.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"122 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the context of environmental protection and energy consumption reduction, reducing the rolling resistance of mining machinery tires is one of the important methods to achieve the goal of green mining. This study probes the effects of wet mixing with a wet carbon black masterbatch on the rolling resistance and grounding performance of wide‐body vehicle tire treads by investigating the cross‐linking structure, rubber–filler (R–F) interaction force, and physicomechanical properties of the wet mixing rubber compounded with a wet carbon black masterbatch. The results indicate decreases in the maximum torque‐minimum torque difference, cross‐link density, and R–F interaction of the wet mixing rubber and increased filler–filler (F–F) interaction and carbon black dispersion. Meanwhile, the tensile elongation of the wet mixing rubber increases, its DIN abrasion property improves, and its Tanδ decreases at 60°C. A numerical method to estimate tire steady‐state rolling resistance is also developed. Finite element simulation analysis reveals that the steady‐state rolling resistance of the wet mixing rubber is reduced by 7.04% at 100% standard load, and its grounding performance is enhanced. By proposing a method to reduce the rolling resistance of tires, this study also provides a reference for the development of wide‐body vehicle tires.HighlightsExplored the filler interaction of wet mixing rubber.Explained the low energy loss of wet mixing rubber.Proposed a new finite element method for calculating tire rolling resistance.
{"title":"Application of wet carbon black masterbatch in green mining radial tires","authors":"Kangyu Luo, Zifeng Wang, Zhanfu Yong","doi":"10.1002/pen.26952","DOIUrl":"https://doi.org/10.1002/pen.26952","url":null,"abstract":"<jats:label/>In the context of environmental protection and energy consumption reduction, reducing the rolling resistance of mining machinery tires is one of the important methods to achieve the goal of green mining. This study probes the effects of wet mixing with a wet carbon black masterbatch on the rolling resistance and grounding performance of wide‐body vehicle tire treads by investigating the cross‐linking structure, rubber–filler (R–F) interaction force, and physicomechanical properties of the wet mixing rubber compounded with a wet carbon black masterbatch. The results indicate decreases in the maximum torque‐minimum torque difference, cross‐link density, and R–F interaction of the wet mixing rubber and increased filler–filler (F–F) interaction and carbon black dispersion. Meanwhile, the tensile elongation of the wet mixing rubber increases, its DIN abrasion property improves, and its Tanδ decreases at 60°C. A numerical method to estimate tire steady‐state rolling resistance is also developed. Finite element simulation analysis reveals that the steady‐state rolling resistance of the wet mixing rubber is reduced by 7.04% at 100% standard load, and its grounding performance is enhanced. By proposing a method to reduce the rolling resistance of tires, this study also provides a reference for the development of wide‐body vehicle tires.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Explored the filler interaction of wet mixing rubber.</jats:list-item> <jats:list-item>Explained the low energy loss of wet mixing rubber.</jats:list-item> <jats:list-item>Proposed a new finite element method for calculating tire rolling resistance.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"9 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Çağın Bolat, Abdulkadir Çebi, Sinan Maraş, Berkay Ergene
The importance of recycling engineering components and thus obtaining low‐cost production solutions has become prominent in today's world. In this study, the mechanical and dynamic behaviors of three‐dimensional‐printed recycled polyethylene terephthalate glycol (RePET‐G) beams were investigated numerically and experimentally for the first time in the literature. Initially, the governing equations of the beams were determined according to the Bernoulli–Euler beam theory, and these equations were numerically solved using the differential quadrature method and ANSYS program. Subsequently, to validate the accuracy of the numerical models, the obtained natural frequencies were compared with experimental results. It was observed that the numerical results showed good agreement with the experimental results. Finally, the effects of beam length, infill rate, and building direction on the natural frequencies of RePET‐G beams were investigated. The outcomes showed that as the beam length changed, natural frequencies were significantly affected. Increasing the infill rate, especially for beams with vertical building direction, from 20% to 100% led to a slight decrease in the natural frequency values of the structure. Moreover, it was found that for beams with an infill rate of 100%, the natural frequency values obtained in the horizontal building direction were higher than those obtained in the vertical building direction.HighlightsPrintable recycled filaments have great potential for vibration applications.Sample length affects the first natural frequency value of RePETG parts.Differential quadrature and ANSYS methods can be utilized for the vibration.For the 3D‐printed samples, rising infill rate causes a natural frequency drop.
{"title":"An experimental and numerical effort on the vibration behavior of additively manufactured recycled polyethylene terephthalate glycol components","authors":"Çağın Bolat, Abdulkadir Çebi, Sinan Maraş, Berkay Ergene","doi":"10.1002/pen.26954","DOIUrl":"https://doi.org/10.1002/pen.26954","url":null,"abstract":"<jats:label/>The importance of recycling engineering components and thus obtaining low‐cost production solutions has become prominent in today's world. In this study, the mechanical and dynamic behaviors of three‐dimensional‐printed recycled polyethylene terephthalate glycol (RePET‐G) beams were investigated numerically and experimentally for the first time in the literature. Initially, the governing equations of the beams were determined according to the Bernoulli–Euler beam theory, and these equations were numerically solved using the differential quadrature method and ANSYS program. Subsequently, to validate the accuracy of the numerical models, the obtained natural frequencies were compared with experimental results. It was observed that the numerical results showed good agreement with the experimental results. Finally, the effects of beam length, infill rate, and building direction on the natural frequencies of RePET‐G beams were investigated. The outcomes showed that as the beam length changed, natural frequencies were significantly affected. Increasing the infill rate, especially for beams with vertical building direction, from 20% to 100% led to a slight decrease in the natural frequency values of the structure. Moreover, it was found that for beams with an infill rate of 100%, the natural frequency values obtained in the horizontal building direction were higher than those obtained in the vertical building direction.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Printable recycled filaments have great potential for vibration applications.</jats:list-item> <jats:list-item>Sample length affects the first natural frequency value of RePETG parts.</jats:list-item> <jats:list-item>Differential quadrature and ANSYS methods can be utilized for the vibration.</jats:list-item> <jats:list-item>For the 3D‐printed samples, rising infill rate causes a natural frequency drop.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"38 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This research aims to explore the influence of post‐curing time and layer thickness on the tensile characteristics of various triply periodic minimal surface (TPMS) structures produced by mask stereolithography (MSLA). The study determined the best post‐curing duration, layer thickness, and TPMS lattice type to improve ultimate tensile strength (UTS) and absorbed energy. To experimentally evaluate the tensile characteristics, a dog bone‐shaped specimen was utilized. Three distinct TPMS structures, Gyroid (G), Neovius (N), and Diamond (D), were present in the test region. After investigating many process factors with response surface methodology (RSM), optimization methods are applied to find their best printing procedure. The work shows the novel use of RSM to optimize post‐curing and printing parameters on TPMS structure mechanical properties during manufacturing. According to the optimization results, the biggest factor affecting UTS is layer thickness, while the most significant factor increasing energy is curing time. The optimal operating parameters for MSLA printing based on the optimization results are a layer thickness of 0.05 mm, a post‐curing period of 40 min, and a lattice type of N. The optimum responses corresponding to the optimum parameters were determined as 7.16 MPa for UTS and 18.16 J for energy.HighlightsOptimized the production process parameters of TPMS geometries.Compared TPMS structures for mechanical performance.Identified optimal input parameters to improve UTS and energy absorption.Conducted comprehensive experimental evaluations to validate the optimization.
{"title":"Enhancing tensile properties of polymer‐based triply periodic minimal surface metamaterial structures: Investigating the impact of post‐curing time and layer thickness via response surface methodology","authors":"Fatih Pehlivan","doi":"10.1002/pen.26958","DOIUrl":"https://doi.org/10.1002/pen.26958","url":null,"abstract":"<jats:label/>This research aims to explore the influence of post‐curing time and layer thickness on the tensile characteristics of various triply periodic minimal surface (TPMS) structures produced by mask stereolithography (MSLA). The study determined the best post‐curing duration, layer thickness, and TPMS lattice type to improve ultimate tensile strength (UTS) and absorbed energy. To experimentally evaluate the tensile characteristics, a dog bone‐shaped specimen was utilized. Three distinct TPMS structures, Gyroid (G), Neovius (N), and Diamond (D), were present in the test region. After investigating many process factors with response surface methodology (RSM), optimization methods are applied to find their best printing procedure. The work shows the novel use of RSM to optimize post‐curing and printing parameters on TPMS structure mechanical properties during manufacturing. According to the optimization results, the biggest factor affecting UTS is layer thickness, while the most significant factor increasing energy is curing time. The optimal operating parameters for MSLA printing based on the optimization results are a layer thickness of 0.05 mm, a post‐curing period of 40 min, and a lattice type of N. The optimum responses corresponding to the optimum parameters were determined as 7.16 MPa for UTS and 18.16 J for energy.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Optimized the production process parameters of TPMS geometries.</jats:list-item> <jats:list-item>Compared TPMS structures for mechanical performance.</jats:list-item> <jats:list-item>Identified optimal input parameters to improve UTS and energy absorption.</jats:list-item> <jats:list-item>Conducted comprehensive experimental evaluations to validate the optimization.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"9 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Slow rebound polyurethane foam (SPUF) has been widely used due to its advantages such as sound insulation, energy absorption, and good tactile sensation. However, SPUF is prone to harden at low temperature, and its application in medical equipment and households requires significant antibacterial properties. In this paper, self‐made silicone modified polyethylene glycol (Si‐APEG) and graphene oxide supported allicin (Alc@GO) were prepared and used as low‐temperature resistant agent and antibacterial agent, respectively. Low‐temperature resistant polyurethane foam (LSPUF) and antibacterial LSPUF (ALSPUF) were prepared respectively with water as foaming agent. The morphology of ALSPUF was observed by scanning electron microscope. Properties studied include apparent core density and porosity, mechanical properties including tensile strength, 40% compressive hardness, and rebound resilience, as well as low‐temperature resistance. Effects of Si‐APEG content on the structures and properties were analyzed and the LSPUF with an Si‐APEG content of 10 wt.% showed the best comprehensive performance. Therefore, ALSPUFs with Si‐APEG content of 10 wt.% and Alc@GO content of 0–3 wt.% were prepared. The addition of Alc@GO increased the antibacterial ratio significantly without obvious effect on the structure and mechanical properties of LSPUF. The antibacterial ratio of ALSPUF reached 99.07% at a Alc@GO content of 2.5 wt.% and testing time of 60 min. This work provides an effective and feasible method for the preparation of ALSPUF which can be widely used in medical devices and households.HighlightsSilicone modified polyether is a suitable low‐temperature resistant agent for PU foam.Allicin supported on GO provides good antibacterial property for PU foam.ALSPUF has better mechanical properties than SPU.
{"title":"Synthesis and characterization of antibacterial and low‐temperature resistant slow rebound polyurethane foams","authors":"Jing Cao, Li Wang, Yuying Zheng","doi":"10.1002/pen.26875","DOIUrl":"https://doi.org/10.1002/pen.26875","url":null,"abstract":"<jats:label/>Slow rebound polyurethane foam (SPUF) has been widely used due to its advantages such as sound insulation, energy absorption, and good tactile sensation. However, SPUF is prone to harden at low temperature, and its application in medical equipment and households requires significant antibacterial properties. In this paper, self‐made silicone modified polyethylene glycol (Si‐APEG) and graphene oxide supported allicin (Alc@GO) were prepared and used as low‐temperature resistant agent and antibacterial agent, respectively. Low‐temperature resistant polyurethane foam (LSPUF) and antibacterial LSPUF (ALSPUF) were prepared respectively with water as foaming agent. The morphology of ALSPUF was observed by scanning electron microscope. Properties studied include apparent core density and porosity, mechanical properties including tensile strength, 40% compressive hardness, and rebound resilience, as well as low‐temperature resistance. Effects of Si‐APEG content on the structures and properties were analyzed and the LSPUF with an Si‐APEG content of 10 wt.% showed the best comprehensive performance. Therefore, ALSPUFs with Si‐APEG content of 10 wt.% and Alc@GO content of 0–3 wt.% were prepared. The addition of Alc@GO increased the antibacterial ratio significantly without obvious effect on the structure and mechanical properties of LSPUF. The antibacterial ratio of ALSPUF reached 99.07% at a Alc@GO content of 2.5 wt.% and testing time of 60 min. This work provides an effective and feasible method for the preparation of ALSPUF which can be widely used in medical devices and households.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Silicone modified polyether is a suitable low‐temperature resistant agent for PU foam.</jats:list-item> <jats:list-item>Allicin supported on GO provides good antibacterial property for PU foam.</jats:list-item> <jats:list-item>ALSPUF has better mechanical properties than SPU.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"11 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amirhossein Jalali Kandeloos, Saeed Bastani, Mehdi Ghahari, Mojtaba Jalili, Jacques Lalevée
NIR‐induced upconversion‐assisted photopolymerization has gained growing attention in the past two decades because of its numerous advantages over conventional UV/visible photopolymerization and two‐photon polymerization processes. However, research in this area is still in its early stages. To extend the practical application of NIR‐induced radiation curing, it is essential to optimize the factors affecting the photopolymerization reactions. Researchers have been constantly trying to improve these factors to tune the photo‐physical characteristics (luminescence intensity and color) of upconversion particles (UCPs), enhance curing depths and degree of double bond conversion (DC), and investigate the application of UCPs in emerging fields. In this review, first, a brief discussion of the upconversion mechanisms and upconversion efficiency is provided. Then, a detailed discussion of the factors influencing the upconversion‐assisted photopolymerization comprising UCP nature and characteristics, UCP content, presence of fillers/pigments/additives, laser intensity, photoinitiator content, and maximum absorption wavelength of photoinitiator is provided, and recent progress in improving these factors is presented. Finally, the advantages and drawbacks of the UC‐initiated polymerization are discussed, and perspectives for future directions are suggested.HighlightsNIR‐induced upconversion‐assisted photopolymerization garners growing interest.Influential factors in upconversion‐assisted photopolymerization are thoroughly discussed.The recent progress on improving these factors and the future directions are provided.
{"title":"NIR‐induced upconversion‐assisted photopolymerization: Key factors, challenges, and future directions","authors":"Amirhossein Jalali Kandeloos, Saeed Bastani, Mehdi Ghahari, Mojtaba Jalili, Jacques Lalevée","doi":"10.1002/pen.26908","DOIUrl":"https://doi.org/10.1002/pen.26908","url":null,"abstract":"<jats:label/>NIR‐induced upconversion‐assisted photopolymerization has gained growing attention in the past two decades because of its numerous advantages over conventional UV/visible photopolymerization and two‐photon polymerization processes. However, research in this area is still in its early stages. To extend the practical application of NIR‐induced radiation curing, it is essential to optimize the factors affecting the photopolymerization reactions. Researchers have been constantly trying to improve these factors to tune the photo‐physical characteristics (luminescence intensity and color) of upconversion particles (UCPs), enhance curing depths and degree of double bond conversion (DC), and investigate the application of UCPs in emerging fields. In this review, first, a brief discussion of the upconversion mechanisms and upconversion efficiency is provided. Then, a detailed discussion of the factors influencing the upconversion‐assisted photopolymerization comprising UCP nature and characteristics, UCP content, presence of fillers/pigments/additives, laser intensity, photoinitiator content, and maximum absorption wavelength of photoinitiator is provided, and recent progress in improving these factors is presented. Finally, the advantages and drawbacks of the UC‐initiated polymerization are discussed, and perspectives for future directions are suggested.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>NIR‐induced upconversion‐assisted photopolymerization garners growing interest.</jats:list-item> <jats:list-item>Influential factors in upconversion‐assisted photopolymerization are thoroughly discussed.</jats:list-item> <jats:list-item>The recent progress on improving these factors and the future directions are provided.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"79 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mert Işılay, Ahmet Çay, Çiğdem Akduman, Emriye Perrin Akçakoca Kumbasar, Hasan Ertaş
In this study, polyvinyl alcohol/Nafion nanofibrous composite membranes were produced to investigate their possible application as a polymer electrolyte membrane (PEM) in direct methanol fuel cells. Electrospinning method was used for nanofibrous membrane production, in which the mixture of polyvinyl alcohol (PVA) and Nafion solutions was directly electrospun. Produced nanofibers were subjected to physical stabilization, filler application, and sulfonating to produce composite nanofibrous membranes. PVA and Nafion polymers were used also as filler materials. The properties of resultant composite membranes were compared in terms of water swelling, weight loss in water and methanol solution, thermal stability, morphology, proton conductivity, and methanol permeability. Proton conductivity of the membranes depending on the humidity was also investigated. TGA analysis showed that the membranes had adequate thermal properties regardless of the filler material. The nanofibrous structure was shown to be preserved by scanning electron microscopy (SEM) after treatment with water and methanol solution. It was shown that PVA/Nafion nanofibers displayed proton conductivity after filling process. The use of PVA as a filler material led to higher proton conductivity at 100 RH%. It was reported that proton conductivity could only be obtained at higher relative humidity values (>80% RH). A lower methanol permeability of PVA‐filled membranes was reported.HighlightsPVA/Nafion nanofibrous membranes were produced by electrospinning.PVA and Nafion were also used as pore filling materials.PVA‐filled membranes had higher proton conductivity and lower methanol permeability.Proton conductivity could only be obtained at higher RH% values.
{"title":"Effects of filler material on the characteristics of electrospun polyvinyl alcohol/Nafion nanofibrous membranes","authors":"Mert Işılay, Ahmet Çay, Çiğdem Akduman, Emriye Perrin Akçakoca Kumbasar, Hasan Ertaş","doi":"10.1002/pen.26943","DOIUrl":"https://doi.org/10.1002/pen.26943","url":null,"abstract":"<jats:label/>In this study, polyvinyl alcohol/Nafion nanofibrous composite membranes were produced to investigate their possible application as a polymer electrolyte membrane (PEM) in direct methanol fuel cells. Electrospinning method was used for nanofibrous membrane production, in which the mixture of polyvinyl alcohol (PVA) and Nafion solutions was directly electrospun. Produced nanofibers were subjected to physical stabilization, filler application, and sulfonating to produce composite nanofibrous membranes. PVA and Nafion polymers were used also as filler materials. The properties of resultant composite membranes were compared in terms of water swelling, weight loss in water and methanol solution, thermal stability, morphology, proton conductivity, and methanol permeability. Proton conductivity of the membranes depending on the humidity was also investigated. TGA analysis showed that the membranes had adequate thermal properties regardless of the filler material. The nanofibrous structure was shown to be preserved by scanning electron microscopy (SEM) after treatment with water and methanol solution. It was shown that PVA/Nafion nanofibers displayed proton conductivity after filling process. The use of PVA as a filler material led to higher proton conductivity at 100 RH%. It was reported that proton conductivity could only be obtained at higher relative humidity values (>80% RH). A lower methanol permeability of PVA‐filled membranes was reported.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>PVA/Nafion nanofibrous membranes were produced by electrospinning.</jats:list-item> <jats:list-item>PVA and Nafion were also used as pore filling materials.</jats:list-item> <jats:list-item>PVA‐filled membranes had higher proton conductivity and lower methanol permeability.</jats:list-item> <jats:list-item>Proton conductivity could only be obtained at higher RH% values.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"15 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Oumaima Boughanmi, Lamis Allegue, Haykel Marouani, Ahmed Koubaa, Yasser Fouad
Due to its biodegradability, biocompatibility, and mechanical properties, poly‐lactic acid (PLA) is a leading biomaterial for numerous applications, especially for fused deposition modeling and fused filament fabrication. Nonetheless, the absence of a comprehensive recycling strategy may emerge as a significant source of plastic pollution in the future. Indeed, the polymer undergoes deterioration during melt recycling, resulting in a decrease in some mechanical properties that can compromise recyclability. To improve the properties of recycled PLA, the utilization of organic fillers coming from renewable materials can be considered as a sustainable solution. The objective of this work is then to evaluate the effect of recycling (reprocessing) on a virgin raw material as well as on biocomposites based on spent coffee grounds (incorporating 5% of spend coffee grounds in weight). The different types of filaments are extruded and re‐extruded and characterized under tensile, melt flow index, and hardness tests. The results show that the increase in the number of extrusions whether for virgin PLA or the composite contributes to the diameter fluctuation. Regarding the tensile properties, the rise in the frequency of recycling shows a weakness in the tensile strength and the elongation at break. On the other hand, Young's modulus values exhibit fluctuations. Concerning the addition of the spent coffee grounds filler, no major enhancement is observed in the tensile strength and the elongation at break, which is attributed to the poor adhesion between the matrix and the filler. The recycling process affects the hardness values of PLA, leading to an increase in these values, as well as those of the composite, which can be associated with the increased crystallinity caused by the recycling process and the SCG incorporation.HighlightsRecycling and reusability strategy for poly‐lactic acid (PLA) and PLA/spent coffee grounds (SCG) filaments.Assessment of recycling effects on PLA and PLA/SCG.Mechanical characterization through tensile and hardness testing.
{"title":"Repetitive recycling effects on mechanical characteristics of poly‐lactic acid and PLA/spent coffee grounds composite used for 3D printing filament","authors":"Oumaima Boughanmi, Lamis Allegue, Haykel Marouani, Ahmed Koubaa, Yasser Fouad","doi":"10.1002/pen.26938","DOIUrl":"https://doi.org/10.1002/pen.26938","url":null,"abstract":"<jats:label/>Due to its biodegradability, biocompatibility, and mechanical properties, poly‐lactic acid (PLA) is a leading biomaterial for numerous applications, especially for fused deposition modeling and fused filament fabrication. Nonetheless, the absence of a comprehensive recycling strategy may emerge as a significant source of plastic pollution in the future. Indeed, the polymer undergoes deterioration during melt recycling, resulting in a decrease in some mechanical properties that can compromise recyclability. To improve the properties of recycled PLA, the utilization of organic fillers coming from renewable materials can be considered as a sustainable solution. The objective of this work is then to evaluate the effect of recycling (reprocessing) on a virgin raw material as well as on biocomposites based on spent coffee grounds (incorporating 5% of spend coffee grounds in weight). The different types of filaments are extruded and re‐extruded and characterized under tensile, melt flow index, and hardness tests. The results show that the increase in the number of extrusions whether for virgin PLA or the composite contributes to the diameter fluctuation. Regarding the tensile properties, the rise in the frequency of recycling shows a weakness in the tensile strength and the elongation at break. On the other hand, Young's modulus values exhibit fluctuations. Concerning the addition of the spent coffee grounds filler, no major enhancement is observed in the tensile strength and the elongation at break, which is attributed to the poor adhesion between the matrix and the filler. The recycling process affects the hardness values of PLA, leading to an increase in these values, as well as those of the composite, which can be associated with the increased crystallinity caused by the recycling process and the SCG incorporation.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Recycling and reusability strategy for poly‐lactic acid (PLA) and PLA/spent coffee grounds (SCG) filaments.</jats:list-item> <jats:list-item>Assessment of recycling effects on PLA and PLA/SCG.</jats:list-item> <jats:list-item>Mechanical characterization through tensile and hardness testing.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"43 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In a multi‐cavity mold, parts from each cavity have consistent properties if the runner system ensures balanced melt‐front advancement. An unbalanced mold, however, narrows the processing window, complicating quality control and making it harder to maintain standards. Molds with an inherently balanced filling, such as the H‐type runner system, are preferred. However, as the number of cavities increases, improvements are needed to address the issues caused by shear heating. Additionally, the material waste in the H‐type runner system is significantly greater than in the fishbone runner system. Based on the rheological concept, a two‐stage analytical approach is established to optimize the fishbone runner system. The diameter of each runner in the fishbone runner system is optimized by controlling pressure drop and remaining time to achieve balanced filling. The impact of these factors is thoroughly examined, as well as why they must be controlled during optimization. The proposed work links the physical situation to its mathematical model, proving highly beneficial for new runner system designs, especially without commercial software assistance.HighlightsA new approach to solving unbalanced filling in multi‐cavity molds.Pressure drop and remaining time are key factors for optimization.Two‐stage analytical approach ensures optimization accuracy.The optimal runner system reduces injection pressure for molding.An alternative method for designing fishbone runners without CAE assistance.
{"title":"Optimal runner design for balanced filling in a multi‐cavity mold using a two‐stage analytical approach","authors":"Bo‐Yu Yang, Chung‐Chih Lin","doi":"10.1002/pen.26945","DOIUrl":"https://doi.org/10.1002/pen.26945","url":null,"abstract":"<jats:label/>In a multi‐cavity mold, parts from each cavity have consistent properties if the runner system ensures balanced melt‐front advancement. An unbalanced mold, however, narrows the processing window, complicating quality control and making it harder to maintain standards. Molds with an inherently balanced filling, such as the H‐type runner system, are preferred. However, as the number of cavities increases, improvements are needed to address the issues caused by shear heating. Additionally, the material waste in the H‐type runner system is significantly greater than in the fishbone runner system. Based on the rheological concept, a two‐stage analytical approach is established to optimize the fishbone runner system. The diameter of each runner in the fishbone runner system is optimized by controlling pressure drop and remaining time to achieve balanced filling. The impact of these factors is thoroughly examined, as well as why they must be controlled during optimization. The proposed work links the physical situation to its mathematical model, proving highly beneficial for new runner system designs, especially without commercial software assistance.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>A new approach to solving unbalanced filling in multi‐cavity molds.</jats:list-item> <jats:list-item>Pressure drop and remaining time are key factors for optimization.</jats:list-item> <jats:list-item>Two‐stage analytical approach ensures optimization accuracy.</jats:list-item> <jats:list-item>The optimal runner system reduces injection pressure for molding.</jats:list-item> <jats:list-item>An alternative method for designing fishbone runners without CAE assistance.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"7 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142227303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Adsorptive nanofiber electrospun membranes (ANEMs) show promise for heavy metal removal, particularly in dilute solutions. Nanofibrous polyacrylonitrile (PAN) membranes incorporating Cloisite 20A (C20) organoclay were fabricated via electrospinning for As(V) removal. The impact of C20 on structural properties and As(V) removal efficiency of the nanofiber membranes was investigated. The results indicated that the PAN‐C20 membranes morphology was uniform, with fiber diameters mostly falling within the 100–300 nm range. Incorporation of C20, especially in an exfoliated structure, led to increased hydrophilicity, mechanical strength, and roughness of the membranes. Batch adsorption results revealed that the adding C20 up to 1.5 wt.% significantly enhanced adsorption capacity due to the higher concentration and proper C20 dispersion. Dynamic filtration showed that the PAN‐C20(1.0) membrane achieved over 90% As(V) removal efficiency for 960 min and demonstrated excellent regeneration ability.HighlightsCloisite 20A organoclay was incorporated into PAN by electrospinning to prepare adsorptive membrane.Adsorptive membranes were used for As(V) removal from water.Type of Cloisite 20A dispersion in PAN in dynamic filtration was more important than in static adsorptionPAN‐C20‐1.0 with exfoliated structure showed higher removal efficiency than PAN‐C20‐1.0 with intercalated structure.PAN‐C20‐1.0 membrane was usable for multiple adsorption–desorption cycles.
{"title":"Arsenic removal from contaminated water using adsorptive electrospun nanofibrous membrane of polyacrylonitrile/organoclay","authors":"Elham Shokri, Elham Naghashzargar, Kosar Behamaram","doi":"10.1002/pen.26885","DOIUrl":"https://doi.org/10.1002/pen.26885","url":null,"abstract":"<jats:label/>Adsorptive nanofiber electrospun membranes (ANEMs) show promise for heavy metal removal, particularly in dilute solutions. Nanofibrous polyacrylonitrile (PAN) membranes incorporating Cloisite 20A (C20) organoclay were fabricated via electrospinning for As(V) removal. The impact of C20 on structural properties and As(V) removal efficiency of the nanofiber membranes was investigated. The results indicated that the PAN‐C20 membranes morphology was uniform, with fiber diameters mostly falling within the 100–300 nm range. Incorporation of C20, especially in an exfoliated structure, led to increased hydrophilicity, mechanical strength, and roughness of the membranes. Batch adsorption results revealed that the adding C20 up to 1.5 wt.% significantly enhanced adsorption capacity due to the higher concentration and proper C20 dispersion. Dynamic filtration showed that the PAN‐C20(1.0) membrane achieved over 90% As(V) removal efficiency for 960 min and demonstrated excellent regeneration ability.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Cloisite 20A organoclay was incorporated into PAN by electrospinning to prepare adsorptive membrane.</jats:list-item> <jats:list-item>Adsorptive membranes were used for As(V) removal from water.</jats:list-item> <jats:list-item>Type of Cloisite 20A dispersion in PAN in dynamic filtration was more important than in static adsorption</jats:list-item> <jats:list-item>PAN‐C20‐1.0 with exfoliated structure showed higher removal efficiency than PAN‐C20‐1.0 with intercalated structure.</jats:list-item> <jats:list-item>PAN‐C20‐1.0 membrane was usable for multiple adsorption–desorption cycles.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"67 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142219306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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