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Revisiting mechanisms of molecular contamination induced laser optic damage 分子污染诱导激光光学损伤的机理研究
Pub Date : 2007-10-10 DOI: 10.1117/12.753588
J. Canham
A revision of a theoretical mechanism proposed last year based upon the known chemical and physical interactions of laser radiation, fused silica, aromatic molecules and environmental factors will be presented, as relates to other proposed mechanisms. This paper specifically addresses the interaction of toluene with 1064nm laser radiation as related to the formation of benzyl radical, and to free radical photochemistry of toluene. This will address specifically, the effects of oxygen and water in the system, the effects of hydroxyl radical in the system, the interpretation of the XPS spectra of laser damaged silica in the presence and absence of aromatic hydrocarbons and the relationship of these points to the photochemistry of silica.
去年提出的一种理论机制的修订将基于已知的激光辐射、熔融二氧化硅、芳香分子和环境因素的化学和物理相互作用,并与其他提出的机制有关。本文重点研究了甲苯与1064nm激光辐射的相互作用与苯自由基形成的关系,以及甲苯的自由基光化学反应。这将具体讨论,系统中氧和水的影响,系统中羟基自由基的影响,在存在和不存在芳香烃的情况下激光损伤二氧化硅的XPS光谱的解释以及这些点与二氧化硅光化学的关系。
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引用次数: 2
Comparison of ns and sub-ns laser conditioning of KDP and DKDP crystals for high power lasers 高功率激光中KDP和DKDP晶体的ns和sub-ns激光调理比较
Pub Date : 2007-10-10 DOI: 10.1117/12.752826
C. Maunier, B. Bertussi, D. Damiani, T. Donval, G. Duchateau, A. Dyan, G. Gaborit, L. Lamaignère, X. Leborgne, M. Loiseau, H. Mathis, G. Razé
In this paper, we present various laser conditioning experiments which have been performed with KDP SHG and DKDP THG samples. The different conditioning facilities used delivered laser pulses at 351 nm in the nanosecond (from 3 to 12 ns) or in the sub-ns (600 ps) regime. Finally, the efficiency of the various conditioning protocols was compared: 526 nm-6 ns and 351 nm-3 ns damage tests were performed respectively on SHG and THG samples. The results show that laser-conditioning SHG KDP samples at 351 nm either with ns or sub-ns pulses allows reducing the laser damage density so that it becomes consistent with the specification of high power lasers. They also confirm that conditioning THG DKDP samples at 351 nm using sub-ns pulses is more efficient than using ns pulses.
本文介绍了用KDP SHG和DKDP THG样品进行的各种激光调理实验。所使用的不同调理设备以纳秒(从3到12纳秒)或次纳秒(600秒)的方式输出351nm的激光脉冲。最后,比较了不同调节方案的效率,分别对SHG和THG样品进行了526 nm-6 ns和351 nm-3 ns的损伤试验。结果表明,在351nm处用ns或亚ns脉冲对SHG - KDP样品进行激光调理,可以降低激光损伤密度,使其符合高功率激光器的要求。他们还证实,在351nm下使用亚毫微米脉冲比使用毫微米脉冲更有效地调节THG DKDP样品。
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引用次数: 6
Effect of instrumental response time in exponential-decay-based cavity ring-down techniques for high reflectivity measurement 高反射率测量中基于指数衰减的腔衰荡技术中仪器响应时间的影响
Pub Date : 2007-10-10 DOI: 10.1117/12.758948
Yuan Gong, Bincheng Li
Exponential-decay based cavity ring-down (CRD) techniques, such as the pulsed-CRD and continuous-wave (cw) CRD employing a fast switch to shut down the laser beam, are widely used for high reflectivity measurement. In this paper the influence of the response time of the experimental apparatus on the high reflectivity measurement is investigated theoretically and experimentally. Theoretical expressions taking into account the instrumental response time are given for both pulsed- and cw-CRD techniques, respectively. By establishing a simple cw-CRD setup employing detectors with different response time, the influence of the instrumental response time on the high reflectivity measurement is experimentally investigated. By applying a multi-parameter estimation technique to determine simultaneously the cavity decay time and the overall response time of the experimental apparatus via fitting the experimental CRD signal to the corresponding theoretical model, the influence of a long instrumental response time on the reflectivity determination is eliminated. The reflectivities of the cavity mirror measured with detectors with different rise time are in excellent agreement. On the other hand, the error of high reflectivity measurement increases with the increasing rise/fall time of the apparatus in cases that the CRD signals obtained by detectors with relatively slow rise time are simply treated with a single exponential decay fitting procedure.
基于指数衰减的腔衰荡(CRD)技术,如脉冲CRD和使用快速开关关闭激光束的连续波CRD,被广泛用于高反射率测量。本文从理论上和实验上研究了实验装置的响应时间对高反射率测量的影响。分别给出了考虑仪器响应时间的脉冲- crd和cw-CRD技术的理论表达式。通过建立一个简单的cw-CRD装置,采用不同响应时间的探测器,实验研究了仪器响应时间对高反射率测量的影响。通过将实验CRD信号拟合到相应的理论模型中,采用多参数估计技术同时确定实验装置的腔体衰减时间和总体响应时间,消除了仪器响应时间过长对反射率测定的影响。用不同上升时间的探测器测得的腔镜反射率非常一致。另一方面,对于上升时间相对较慢的探测器获得的CRD信号,简单地用单一的指数衰减拟合程序处理,高反射率测量的误差随着仪器上升/下降时间的增加而增加。
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引用次数: 7
Photothermal detuning: a sensitive technique for absorption measurement of optical thin films 光热失谐:一种用于光学薄膜吸收测量的灵敏技术
Pub Date : 2007-10-10 DOI: 10.1117/12.758949
H. Hao, Bincheng Li, Mingqiang Liu, Yuan Gong
A simple and sensitive photothermal technique-photothermal detuning (PTDT), which is based on the absorption-induced shift of reflectance or transmission spectrum of an optical coating, is developed to measure the absorption of coated optical components. A PTDT theory is developed to describe the signal's dependence on the structural parameters of the optical coatings and on the geometric parameters of the experimental configuration. An experiment is performed to measure the PTDT signal of a highly reflective multilayer coating used in 532nm by using a probe beam with a wavelength of 632.8nm. By optimizing the incident angle of the probe beam, the measurement sensitivity is maximized. Good agreements between the theoretical predictions and experimental results are obtained.
提出了一种简单、灵敏的光热失谐技术——光热失谐(PTDT),该技术基于光学涂层的反射光谱或透射光谱的吸收引起的位移,用于测量涂层光学元件的吸收。提出了一种PTDT理论来描述信号对光学涂层结构参数和实验配置几何参数的依赖。利用波长为632.8nm的探针束,对532nm高反射多层涂层的PTDT信号进行了测量。通过优化探测光束的入射角,使测量灵敏度达到最大。理论预测与实验结果吻合较好。
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引用次数: 2
Scattering-induced downstream beam modulation by plasma scalded mirrors 等离子体烫伤反射镜散射诱导的下游光束调制
Pub Date : 2007-10-10 DOI: 10.1117/12.748446
J. Schmidt, M. Runkel, K. E. Martin, C. Stolz
Previous work concluded that plasma scalds on laser-conditioned multilayer dielectric mirror coatings are a stable, benign damage morphology. Recent large-aperture measurements indicate that plasma scalds may lead to fratricide of down-stream optics by increasing beam contrast. This paper describes the results of measurements performed to examine the effect of quasi-periodic plasma scalds covering the entire clear aperture on downstream beam modulation. A collimated, linearly-polarized 1053-nm beamline was constructed that irradiated approximately 5 cm2 of the plasma scalded region. This beam was propagated ~8 meters and sampled with a 10-bit, megapixel CCD camera and analyzed for contrast (peak/average intensity). A lineout across the sample was built up by translating the optic across the beam. The contrast results were compared to a baseline wedged flat with surface figure of λ/100 and a contrast adder for the plasma scalds calculated. This was defined by. In all, optics with average plasma scald fractions of 0.9, 2.3, 4 and 14% were measured. Preliminary results indicate that plasma scald fractions of 4% and below contribute a contrast adder of less than 2.5%.
以往的研究表明,等离子体烫伤是一种稳定的、良性的损伤形态。最近的大孔径测量表明,等离子体烫伤可能会通过增加光束对比度导致下游光学元件的自相残杀。本文描述了覆盖整个透明孔径的准周期等离子体烫伤对下游光束调制影响的测量结果。构建了一条准直的线偏振1053 nm光束线,照射约5 cm2的等离子体烫伤区域。该光束传播~8米,用10位,百万像素CCD相机采样,并分析对比度(峰值/平均强度)。通过在光束上平移光学元件,在样品上建立了一条线。对比结果与基线楔形平面进行比较,表面图形为λ/100,对比加法器用于计算等离子烫伤。它的定义是。总共测量了平均等离子体烫伤分数分别为0.9、2.3、4%和14%的光学器件。初步结果表明,4%及以下的血浆烫伤分数对对比度加法器的贡献小于2.5%。
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引用次数: 10
Comparative studies of laser-induced damage threshold measurements in highly reflecting mirrors 高反射镜中激光损伤阈值测量的比较研究
Pub Date : 2007-10-10 DOI: 10.1117/12.753705
A. Melninkaitis, D. Mikšys, R. Grigonis, V. Sirutkaitis, M. Jupé, D. Ristau
S-on-1 laser-induced damage threshold (LIDT) dependence on the pulse duration at two different wavelengths was experimentally investigated in metallic and dielectric laser mirrors. LIDT's of high-reflective dielectric coatings made of alternating λ/4 layers of TiO2/SiO2 and Ta2O5/SiO2 and those of protected metallic Au and Ag coatings were tested at 800 nm and 400 nm wavelengths with Ti:Sapphire laser pulses of 46 fs, 130 fs and 1.8 ps duration. S-on-1 measurements were performed according to international ISO 11254-2 standard using 10000 pulses/per site and compared with 1-on-1 measurements.
在金属和介质激光反射镜中实验研究了不同波长S-on-1激光诱导损伤阈值(LIDT)与脉冲持续时间的关系。采用持续时间分别为46、130和1.8 ps的Ti:Sapphire激光脉冲,在800 nm和400 nm波长下测试了由TiO2/SiO2和Ta2O5/SiO2交替λ/4层制备的高反射介质涂层以及保护金属Au和Ag涂层的LIDT。S-on-1测量根据国际ISO 1154 -2标准进行,每个站点使用10000脉冲,并与1-on-1测量进行比较。
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引用次数: 2
Damage thresholds and morphology of the front- and back-irradiated SiO2 thin films containing gold nanoparticles as artificial absorbing defects 含金纳米粒子作为人工吸收缺陷的前后辐照SiO2薄膜的损伤阈值和形貌
Pub Date : 2007-10-10 DOI: 10.1117/12.752616
S. Papernov, A. Schmid, J. Oliver, A. Rigatti
Previous ultraviolet-pulsed, laser-damage studies using model thin films with gold nanoparticles as artificial absorbing defects revealed damage morphology in a form of submicrometer-scaled craters. It was also demonstrated that for defects smaller than 20 nm, crater formation is preceded by plasma-ball formation around absorbing defects. In this work an attempt is made to verify symmetry of the plasma ball by conducting film irradiation from the side of the air/film or substrate/film interfaces. In each case, crater-formation thresholds are derived and crater morphology is analyzed by means of atomic force microscopy.
先前的紫外脉冲、激光损伤研究使用带有金纳米粒子作为人工吸收缺陷的模型薄膜,揭示了亚微米尺度的陨石坑形式的损伤形态。研究还表明,对于小于20 nm的缺陷,在吸收缺陷周围先形成等离子体球形成坑。在这项工作中,试图通过从空气/膜或基板/膜界面的侧面进行膜照射来验证等离子体球的对称性。在每种情况下,都推导了陨石坑形成阈值,并利用原子力显微镜分析了陨石坑的形态。
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引用次数: 3
High-resolution 3D imaging of surface damage sites in fused silica with optical coherence tomography 光学相干层析成像熔融二氧化硅表面损伤部位的高分辨率三维成像
Pub Date : 2007-10-10 DOI: 10.1117/12.748452
G. Guss, I. Bass, R. Hackel, C. Mailhiot, S. Demos
In this work, we present the first successful demonstration of a non-contact technique to precisely measure the 3D spatial characteristics of laser induced surface damage sites in fused silica for large aperture laser systems by employing Optical Coherence Tomography (OCT). What makes OCT particularly interesting in the characterization of optical materials for large aperture laser systems is that its axial resolution can be maintained with working distances greater than 5 cm, whether viewing through air or through the bulk of thick optics. Specifically, when mitigating surface damage sites against further growth by CO2 laser evaporation of the damage, it is important to know the depth of subsurface cracks below the damage site. These cracks are typically obscured by the damage rubble when imaged from above the surface. The results to date clearly demonstrate that OCT is a unique and valuable tool for characterizing damage sites before and after the mitigation process. We also demonstrated its utility as an in-situ diagnostic to guide and optimize our process when mitigating surface damage sites on large, high-value optics.
在这项工作中,我们首次成功展示了一种非接触技术,通过光学相干断层扫描(OCT)精确测量大孔径激光系统中熔融二氧化硅激光诱导表面损伤部位的三维空间特征。使OCT在大孔径激光系统光学材料表征中特别有趣的是,无论是通过空气还是通过大块厚光学器件观察,其轴向分辨率都可以在大于5厘米的工作距离下保持。具体来说,当通过CO2激光蒸发损伤来减轻表面损伤部位的进一步增长时,了解损伤部位以下的次表面裂纹的深度是很重要的。当从地面上拍摄时,这些裂缝通常被损坏的碎石所掩盖。迄今为止的结果清楚地表明,OCT是一种独特而有价值的工具,可用于表征缓解过程前后的损伤部位。我们还展示了它作为原位诊断的实用性,以指导和优化我们的工艺,减轻大型高价值光学器件的表面损伤部位。
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引用次数: 13
High laser damage threshold surface relief micro-structures for anti-reflection applications 用于抗反射应用的高激光损伤阈值表面浮雕微结构
Pub Date : 2007-10-10 DOI: 10.1117/12.754223
D. S. Hobbs, B. MacLeod
Microstructures built into the surfaces of an optic or window, are an effective replacement for thin-film coatings in anti-reflection (AR) and narrow-band filter applications. AR microstructures exhibit particularly noteworthy performance where an average reflection loss of less than 0.2% over a four-octave range (400-1800nm) has been demonstrated, and a loss of less than 0.03% is routinely achieved for narrow-band applications. Because AR micro-textures provide a gradual change in the refractive index at a material boundary, it is expected that light can propagate through the boundary without material damage at energy levels that are much higher than that found with thin-film interference coatings. Recently, it was shown that the laser induced damage threshold (LIDT) of an inexpensive borosilicate glass window containing AR microstructures was nearly 57 J/cm2 at 1064nm (20ns pulse). This LIDT is two to three times greater than the damage threshold of single-layer sol-gel AR coatings on fused silica often reported in the literature. The development of surface relief AR textures for use in high-energy laser applications is presented. Data from scanning electron microscope (SEM) analysis, reflection measurements, and LIDT testing, is shown for high performance AR microstructures fabricated in fused silica, and borosilicate glass. Results of LIDT testing at wavelengths ranging from the near ultraviolet through the near infrared confirm the initial result that AR microstructures can operate at pulsed laser power levels at least two times higher than thin-film coatings. For near infrared applications such as laser weapons and fiber optic communications requiring high performance AR, LIDT levels for AR microstructures in fused silica are found to be at least five times greater than conventional multi-layer thin film coatings. An initial surface absorption test at 1064nm shows that AR microstructures may also exhibit improved lifetimes within continuous wave laser systems.
内置在光学或窗口表面的微结构是增透(AR)和窄带滤光片应用中薄膜涂层的有效替代品。AR微结构表现出特别值得注意的性能,在四倍频程范围内(400-1800nm)的平均反射损耗小于0.2%,并且在窄带应用中通常达到小于0.03%的损耗。由于AR微纹理在材料边界处提供了折射率的渐变变化,因此预计光可以在比薄膜干涉涂层高得多的能级上传播而不会损坏材料。最近的研究表明,在1064nm (20ns脉冲)下,含有AR微结构的廉价硼硅酸盐玻璃窗的激光诱导损伤阈值(LIDT)接近57 J/cm2。该LIDT比文献中经常报道的熔融二氧化硅单层溶胶-凝胶AR涂层的损伤阈值大两到三倍。介绍了用于高能激光应用的表面浮雕AR纹理的发展。从扫描电子显微镜(SEM)分析,反射测量和LIDT测试的数据,显示了在熔融二氧化硅和硼硅酸盐玻璃中制造的高性能AR微结构。从近紫外到近红外波长范围内的LIDT测试结果证实了初始结果,即AR微结构可以在脉冲激光功率水平至少比薄膜涂层高两倍的情况下工作。对于需要高性能AR的近红外应用,如激光武器和光纤通信,熔融二氧化硅中AR微结构的LIDT水平至少是传统多层薄膜涂层的五倍。在1064nm的初始表面吸收测试表明,在连续波激光系统中,AR微结构也可能表现出改善的寿命。
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引用次数: 45
Growth of laser damage in fused silica: diameter to depth ratio 熔融石英中激光损伤的生长:直径与深度比
Pub Date : 2007-10-10 DOI: 10.1117/12.748441
M. Norton, J. Adams, C. Carr, Eugene E. Donohue, M. Feit, R. Hackel, W. G. Hollingsworth, J. Jarboe, M. Matthews, A. Rubenchik, M. Spaeth
Growth of laser initiated damage plays a major role in determining optics lifetime in high power laser systems. Previous measurements have established that the lateral diameter grows exponentially. Knowledge of the growth of the site in the propagation direction is also important, especially so when considering techniques designed to mitigate damage growth, where it is required to reach all the subsurface damage. In this work, we present data on both the diameter and the depth of a growing exit surface damage sites in fused silica. Measured growth rates with both 351 nm illumination and with combined 351 nm and 1054 nm illumination are discussed.
激光引发损伤的生长对高功率激光系统的光学寿命起着重要的决定作用。先前的测量已经确定,外侧直径呈指数增长。了解传播方向上的部位生长情况也很重要,特别是在考虑设计减轻损伤生长的技术时,因为需要到达所有的地下损伤。在这项工作中,我们提供了在熔融二氧化硅中不断增长的出口表面损伤点的直径和深度的数据。讨论了351nm光照和351nm和1054nm联合光照下的生长速率。
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引用次数: 43
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SPIE Laser Damage
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