Pub Date : 2021-05-31DOI: 10.1177/14777606211019423
Nilay Tuccar Kilic, B. N. Can, M. Kodal, G. Özkoç
In this study, the compatibilization effects of triglycidylisobutyl polyhedral oligomeric silsesquioxane (TEpPOSS) on biodegradable poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends were investigated. All blends were prepared via melt blending and PLA/TPU (80/20, 70/30, 50/50 wt%) ratio was selected as the experimental parameter. In order to predict the selective localization of TEpPOSS thermodynamically, wetting coefficient were determined by means of surface energy measurements. Morphological analyses were carried out by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Moreover, rheological, mechanical, thermomechanical and thermal properties of the blends were performed via rheometer, universal tensile tester, dynamic mechanic analyses and differential scanning calorimeter (DSC), respectively. Morphological test results revealed that TEpPOSSs were mostly located at the interfaces of the PLA and TPU phases. According to the rheological studies, the interfacial interactions between PLA and TPU were improved with the addition of TEpPOSS, which resulted from the potential reactions between epoxy-carboxylic acid and/or epoxy-hydroxyl functional groups. The addition of TEpPOSS enhanced the mechanical properties of PLA/TPU blends. DSC test results revealed a decrease in the glass transition temperatures of PLA in the presence of TEpPOSS, which was an another indication of improved compatibility between PLA and TPU.
{"title":"Reactive compatibilization of biodegradable PLA/TPU blends via hybrid nanoparticle","authors":"Nilay Tuccar Kilic, B. N. Can, M. Kodal, G. Özkoç","doi":"10.1177/14777606211019423","DOIUrl":"https://doi.org/10.1177/14777606211019423","url":null,"abstract":"In this study, the compatibilization effects of triglycidylisobutyl polyhedral oligomeric silsesquioxane (TEpPOSS) on biodegradable poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends were investigated. All blends were prepared via melt blending and PLA/TPU (80/20, 70/30, 50/50 wt%) ratio was selected as the experimental parameter. In order to predict the selective localization of TEpPOSS thermodynamically, wetting coefficient were determined by means of surface energy measurements. Morphological analyses were carried out by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Moreover, rheological, mechanical, thermomechanical and thermal properties of the blends were performed via rheometer, universal tensile tester, dynamic mechanic analyses and differential scanning calorimeter (DSC), respectively. Morphological test results revealed that TEpPOSSs were mostly located at the interfaces of the PLA and TPU phases. According to the rheological studies, the interfacial interactions between PLA and TPU were improved with the addition of TEpPOSS, which resulted from the potential reactions between epoxy-carboxylic acid and/or epoxy-hydroxyl functional groups. The addition of TEpPOSS enhanced the mechanical properties of PLA/TPU blends. DSC test results revealed a decrease in the glass transition temperatures of PLA in the presence of TEpPOSS, which was an another indication of improved compatibility between PLA and TPU.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"46 3","pages":"301 - 326"},"PeriodicalIF":2.6,"publicationDate":"2021-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72582108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-05-31DOI: 10.1177/14777606211019419
Vishantini Tangavaloo, N. Y. Yuhana, Yu Lih Jiun
In natural polyisoprene glove manufacturing industries, the selection of accelerators in the curing system is mainly determined by the curing characteristics, maturation time required, cross-link density and mechanical properties of gloves. In this study, a new accelerator replacing conventional ones in a typical glove manufacturing process, was studied in order to produce free carcinogen dipped article. The glove properties and performance prepared by using both conventional and new proposed accelerators were studied and compared. The use of a conventional accelerator tends to release carcinogenic chemicals namely N-nitrosamine and N-nitrosatable substances. These chemicals are restrained on dipped articles under the requirement of EN 71-12:2013. Xanthogen accelerators promote the reduction of carcinogenic chemicals, but they are associated with prolonged maturation hour, which is unfavourable in the manufacturing industry. This study used a mixture of a benign accelerator, namely, diisononyldithiocarbamate and diisopropyl xanthogen polysulfide, to substitute the usage of conventional accelerators zinc dibutyl dithiocarbamate and zinc diethyl dithiocarbamate. The effects of benign accelerator loading in latex compounds were studied by focusing on the swelling index, maturation hour, carcinogenic chemical released and mechanical properties, thermal degradation and stability. Results showed no presence of N-nitrosamines and N-nitrosatable substances in the final dipped products by using 0.3 and 0.5 phr of benign accelerator. This study showed that 0.5 phr of benign accelerator achieved a moderate pre-vulcanising rate and improved the pre-ageing tensile strength and elongation by 11% and 7.0%, respectively. Moreover, its thermal stability was higher and discolouration intensity was lower as compared with the conventional accelerator.
{"title":"Production and properties of natural rubber glove using sustainable benign accelerator","authors":"Vishantini Tangavaloo, N. Y. Yuhana, Yu Lih Jiun","doi":"10.1177/14777606211019419","DOIUrl":"https://doi.org/10.1177/14777606211019419","url":null,"abstract":"In natural polyisoprene glove manufacturing industries, the selection of accelerators in the curing system is mainly determined by the curing characteristics, maturation time required, cross-link density and mechanical properties of gloves. In this study, a new accelerator replacing conventional ones in a typical glove manufacturing process, was studied in order to produce free carcinogen dipped article. The glove properties and performance prepared by using both conventional and new proposed accelerators were studied and compared. The use of a conventional accelerator tends to release carcinogenic chemicals namely N-nitrosamine and N-nitrosatable substances. These chemicals are restrained on dipped articles under the requirement of EN 71-12:2013. Xanthogen accelerators promote the reduction of carcinogenic chemicals, but they are associated with prolonged maturation hour, which is unfavourable in the manufacturing industry. This study used a mixture of a benign accelerator, namely, diisononyldithiocarbamate and diisopropyl xanthogen polysulfide, to substitute the usage of conventional accelerators zinc dibutyl dithiocarbamate and zinc diethyl dithiocarbamate. The effects of benign accelerator loading in latex compounds were studied by focusing on the swelling index, maturation hour, carcinogenic chemical released and mechanical properties, thermal degradation and stability. Results showed no presence of N-nitrosamines and N-nitrosatable substances in the final dipped products by using 0.3 and 0.5 phr of benign accelerator. This study showed that 0.5 phr of benign accelerator achieved a moderate pre-vulcanising rate and improved the pre-ageing tensile strength and elongation by 11% and 7.0%, respectively. Moreover, its thermal stability was higher and discolouration intensity was lower as compared with the conventional accelerator.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"84 1","pages":"340 - 353"},"PeriodicalIF":2.6,"publicationDate":"2021-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80914926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-05-31DOI: 10.1177/14777606211019415
V. Das, Akhileshwar Pandey, Dn Tripathi, N. Prasad
In present study, rheological properties of polypropylene impact copolymer (PPcp) and polyolefin elastomer (POE) blend melts were evaluated on a capillary rheometer under shear and elongational flows. The flow and melt elastic properties (die swell and first normal stress difference) studied at varied extrusion conditions were correlated with blend morphology and elastomer content by means of image analysis and theoretical models. Dispersed particle break-up and coalescence were observed to be influenced by POE content and the viscosities of the constituent polymers which were in turn affected by the capillary extrusion conditions (shear rate in particular). The blend melts demonstrated typical pseudoplastic behavior obeying Cross model under shear flow. The elongational flow also corroborated well with the shear flow behavior. All the blends illustrated prominent dependence of melt elastic properties on POE content and the capillary extrusion conditions. The melt elastic properties were also found to critically rely on the inter-particle distance of the POE phase.
{"title":"Melt elasticity and flow properties of polypropylene impact copolymer/polyolefin elastomer blends subjected to varied capillary extrusion conditions","authors":"V. Das, Akhileshwar Pandey, Dn Tripathi, N. Prasad","doi":"10.1177/14777606211019415","DOIUrl":"https://doi.org/10.1177/14777606211019415","url":null,"abstract":"In present study, rheological properties of polypropylene impact copolymer (PPcp) and polyolefin elastomer (POE) blend melts were evaluated on a capillary rheometer under shear and elongational flows. The flow and melt elastic properties (die swell and first normal stress difference) studied at varied extrusion conditions were correlated with blend morphology and elastomer content by means of image analysis and theoretical models. Dispersed particle break-up and coalescence were observed to be influenced by POE content and the viscosities of the constituent polymers which were in turn affected by the capillary extrusion conditions (shear rate in particular). The blend melts demonstrated typical pseudoplastic behavior obeying Cross model under shear flow. The elongational flow also corroborated well with the shear flow behavior. All the blends illustrated prominent dependence of melt elastic properties on POE content and the capillary extrusion conditions. The melt elastic properties were also found to critically rely on the inter-particle distance of the POE phase.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"50 1","pages":"147776062110194"},"PeriodicalIF":2.6,"publicationDate":"2021-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81783586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-05-27DOI: 10.1177/14777606211019428
Zefeng Wang, Yutao Jiang, Chao Pan
The resource reclamation of waste tire rubber (WTR) is regarded as the most suitable strategy for these solid wastes. Water jet pulverization (WJPul) is a sustainable reclamation technique for WTR, since both size reduction and rubber devulcanization can be achieved. Aiming at understanding the mechanisms related with pulverization and devulcanization of WTR, this work detailed the interactions between WTR and high pressure water jet (HPWJ). The results show that WJPul can be defined as a mechanochemical process for WTR. The compressive shear failure of rubber mainly induces rubber devulcanization and results in fine ground tire rubber (GTR) particles, HPWJ erosion mainly intensifies rubber depolymerization and results in coarse GTR particles. Chemical reactions can be detected between the devulcanized GTR from WJPul and asphalts, thus resulting in better modification performances of GTR from WJPul in asphalt. The results can help better understand the WJPul mechanisms and provide guidelines for WJPul application.
{"title":"Mechanochemical devulcanization of waste tire rubber in high pressure water jet pulverization","authors":"Zefeng Wang, Yutao Jiang, Chao Pan","doi":"10.1177/14777606211019428","DOIUrl":"https://doi.org/10.1177/14777606211019428","url":null,"abstract":"The resource reclamation of waste tire rubber (WTR) is regarded as the most suitable strategy for these solid wastes. Water jet pulverization (WJPul) is a sustainable reclamation technique for WTR, since both size reduction and rubber devulcanization can be achieved. Aiming at understanding the mechanisms related with pulverization and devulcanization of WTR, this work detailed the interactions between WTR and high pressure water jet (HPWJ). The results show that WJPul can be defined as a mechanochemical process for WTR. The compressive shear failure of rubber mainly induces rubber devulcanization and results in fine ground tire rubber (GTR) particles, HPWJ erosion mainly intensifies rubber depolymerization and results in coarse GTR particles. Chemical reactions can be detected between the devulcanized GTR from WJPul and asphalts, thus resulting in better modification performances of GTR from WJPul in asphalt. The results can help better understand the WJPul mechanisms and provide guidelines for WJPul application.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"32 1","pages":"279 - 300"},"PeriodicalIF":2.6,"publicationDate":"2021-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87957277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-05-25DOI: 10.1177/14777606211019414
Muhammad Shoaib, B. Subeshan, W. Khan, E. Asmatulu
Plastic waste has been growing every year, and as a result, environmental concern has been a topic of much attention. Many properties of plastics, such as their lightweight, durability, and versatility, are significant factors in achieving sustainable development. The exponential increase of plastic production produces every year approximately 100 million tons of waste plastic, which could be converted into hydrocarbon fuels by employing a process appropriately called pyrolysis. Pyrolysis, which is thermal or catalytical, can be performed under different experimental conditions that affect the type and amount of product obtained. With the pyrolysis process, products can be obtained with high added value, such as fuel oils and feedstock for new products. In this study, magnesium silicate (MgO3Si) and Cloisite 30B were used as catalysts for the decomposition of different plastics, and the results were compared with the zeolite catalyst. In the case of high-density polyethylene (HDPE), the oil yield with a zeolite catalyst was found to be 71%, whereas with MgO3Si and Cloisite 30B, this was 68% and 67%, respectively. Zeolite produced better results in the decomposition of polypropylene (PP) compared to MgO3Si and Cloisite 30B. Fourier-transform infrared spectroscopy (FTIR), and gas chromatography (GC) were conducted in this work. The spectra results for all samples were consistent and in the fuel range.
{"title":"Catalytic pyrolysis of recycled HDPE, LDPE, and PP","authors":"Muhammad Shoaib, B. Subeshan, W. Khan, E. Asmatulu","doi":"10.1177/14777606211019414","DOIUrl":"https://doi.org/10.1177/14777606211019414","url":null,"abstract":"Plastic waste has been growing every year, and as a result, environmental concern has been a topic of much attention. Many properties of plastics, such as their lightweight, durability, and versatility, are significant factors in achieving sustainable development. The exponential increase of plastic production produces every year approximately 100 million tons of waste plastic, which could be converted into hydrocarbon fuels by employing a process appropriately called pyrolysis. Pyrolysis, which is thermal or catalytical, can be performed under different experimental conditions that affect the type and amount of product obtained. With the pyrolysis process, products can be obtained with high added value, such as fuel oils and feedstock for new products. In this study, magnesium silicate (MgO3Si) and Cloisite 30B were used as catalysts for the decomposition of different plastics, and the results were compared with the zeolite catalyst. In the case of high-density polyethylene (HDPE), the oil yield with a zeolite catalyst was found to be 71%, whereas with MgO3Si and Cloisite 30B, this was 68% and 67%, respectively. Zeolite produced better results in the decomposition of polypropylene (PP) compared to MgO3Si and Cloisite 30B. Fourier-transform infrared spectroscopy (FTIR), and gas chromatography (GC) were conducted in this work. The spectra results for all samples were consistent and in the fuel range.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"6 1","pages":"264 - 278"},"PeriodicalIF":2.6,"publicationDate":"2021-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87581180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-20DOI: 10.1177/1477760620958944
R. Salih, Ahmed S. J. Al-Zubaydi
This research reports the study of epoxy reinforced with human hair as a potential building material for the purpose of acoustic and thermal insulation for building industry. The sound insulation and thermal conductivity were studied for an epoxy composite reinforced with 15% human hair, together with a set of mechanical properties (tensile strength and flexural strength). The sound insulation results proved that the addition of hair led to about 75% loss of the sound intensity compared to the sound intensity noticed for the unreinforced specimen. Thermal conductivity decreased by about 20% with reinforcement. Mechanical properties show a significant improvement, such that flexural strength increased by 25%. The tensile test results showed a higher Young’s modulus and tensile strength for the reinforced specimen by about 50% and 27% respectively. Finally, flexural strength also showed an increase by about 20% after reinforcement.
{"title":"Study of the insulation and mechanical properties of hair-reinforced epoxy","authors":"R. Salih, Ahmed S. J. Al-Zubaydi","doi":"10.1177/1477760620958944","DOIUrl":"https://doi.org/10.1177/1477760620958944","url":null,"abstract":"This research reports the study of epoxy reinforced with human hair as a potential building material for the purpose of acoustic and thermal insulation for building industry. The sound insulation and thermal conductivity were studied for an epoxy composite reinforced with 15% human hair, together with a set of mechanical properties (tensile strength and flexural strength). The sound insulation results proved that the addition of hair led to about 75% loss of the sound intensity compared to the sound intensity noticed for the unreinforced specimen. Thermal conductivity decreased by about 20% with reinforcement. Mechanical properties show a significant improvement, such that flexural strength increased by 25%. The tensile test results showed a higher Young’s modulus and tensile strength for the reinforced specimen by about 50% and 27% respectively. Finally, flexural strength also showed an increase by about 20% after reinforcement.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"92 1","pages":"247 - 263"},"PeriodicalIF":2.6,"publicationDate":"2021-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/1477760620958944","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72434913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-03-15DOI: 10.1177/14777606211001074
Z. I. Khan, Z. Mohamad, A. Rahmat, U. Habib, N. Abdullah
This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratio...
{"title":"A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend","authors":"Z. I. Khan, Z. Mohamad, A. Rahmat, U. Habib, N. Abdullah","doi":"10.1177/14777606211001074","DOIUrl":"https://doi.org/10.1177/14777606211001074","url":null,"abstract":"This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratio...","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"125 1","pages":"147776062110010"},"PeriodicalIF":2.6,"publicationDate":"2021-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86022126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-23DOI: 10.1177/1477760620977501
Neethumol Varghese, S. Varghese, A. Shybi, T. Kurian
The mechanical properties of both radiation (RVNRL) and peroxide vulcanized natural rubber latex (PVNRL) are low when compared to sulphur prevulcanized natural rubber latex (SVNRL). This paper deals with the effect of peroxide on the mechanical properties of radiation vulcanized NR latex film. Here, n-butyl acrylate (n-BA) was used as sensitizer and t-butyl hydroperoxide (t-BHPO) as co-vulcanizing agent during irradiation. It was found that the addition of t-BHPO is more practical method to reduce the vulcanization dose. Thermal ageing study showed that the best retention in tensile properties was shown by RIPV vulcanizates.
{"title":"Enhanced mechanical properties of radiation vulcanized natural rubber latex by using t-butyl hydroperoxide","authors":"Neethumol Varghese, S. Varghese, A. Shybi, T. Kurian","doi":"10.1177/1477760620977501","DOIUrl":"https://doi.org/10.1177/1477760620977501","url":null,"abstract":"The mechanical properties of both radiation (RVNRL) and peroxide vulcanized natural rubber latex (PVNRL) are low when compared to sulphur prevulcanized natural rubber latex (SVNRL). This paper deals with the effect of peroxide on the mechanical properties of radiation vulcanized NR latex film. Here, n-butyl acrylate (n-BA) was used as sensitizer and t-butyl hydroperoxide (t-BHPO) as co-vulcanizing agent during irradiation. It was found that the addition of t-BHPO is more practical method to reduce the vulcanization dose. Thermal ageing study showed that the best retention in tensile properties was shown by RIPV vulcanizates.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"13 1","pages":"203 - 215"},"PeriodicalIF":2.6,"publicationDate":"2020-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78247213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-23DOI: 10.1177/1477760620977502
Ahmed S. J. Al-Zubaydi, R. Salih, B. Al-dabbagh
A composite material was prepared using epoxy as a matrix, and carbon fiber (20% volume fraction) together with nano titanium dioxide (TiO2) particles in varying weight fractions (0,2,4 and 6%) as hybrid reinforcement. Mechanical tests (impact strength and wear resistance) were carried out, in addition to the study of liquid uptake behavior during immersion in chemical solutions, and inspection with scanning electron microscope imaging to reveal the microscopic details. The results showed that the addition of TiO2 have improved the mechanical properties of the composites, as the specimen reinforced with 4% TiO2 showed the highest impact strength, in addition to improved wear resistance. The scanning electron images for the specimens showed finely dispersed carbon fibers surrounded by the ultrafine TiO2 nano powder, suggesting a uniform distribution of reinforcement throughout the whole matrix for all the prepared specimens. The liquid uptake results showed that the specimen reinforced with 20% carbon fibers and 6% nano TiO2 had the highest diffusion rate, especially when immersed in hydrochloric acid. The results show that the prepared composite could be a good alternative to traditional materials whenever good wear resistance is involved, together with impact and chemical resistance, such as in anti-skid flooring applications.
{"title":"Effect of nano TiO2 particles on the properties of carbon fiber-epoxy composites","authors":"Ahmed S. J. Al-Zubaydi, R. Salih, B. Al-dabbagh","doi":"10.1177/1477760620977502","DOIUrl":"https://doi.org/10.1177/1477760620977502","url":null,"abstract":"A composite material was prepared using epoxy as a matrix, and carbon fiber (20% volume fraction) together with nano titanium dioxide (TiO2) particles in varying weight fractions (0,2,4 and 6%) as hybrid reinforcement. Mechanical tests (impact strength and wear resistance) were carried out, in addition to the study of liquid uptake behavior during immersion in chemical solutions, and inspection with scanning electron microscope imaging to reveal the microscopic details. The results showed that the addition of TiO2 have improved the mechanical properties of the composites, as the specimen reinforced with 4% TiO2 showed the highest impact strength, in addition to improved wear resistance. The scanning electron images for the specimens showed finely dispersed carbon fibers surrounded by the ultrafine TiO2 nano powder, suggesting a uniform distribution of reinforcement throughout the whole matrix for all the prepared specimens. The liquid uptake results showed that the specimen reinforced with 20% carbon fibers and 6% nano TiO2 had the highest diffusion rate, especially when immersed in hydrochloric acid. The results show that the prepared composite could be a good alternative to traditional materials whenever good wear resistance is involved, together with impact and chemical resistance, such as in anti-skid flooring applications.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"24 1","pages":"216 - 232"},"PeriodicalIF":2.6,"publicationDate":"2020-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75945331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-11DOI: 10.1177/1477760620977499
I. Samarasinghe, S. Walpalage, D. Edirisinghe, S. Egodage
An outstanding interest on elimination of nitrosamine generation in traditional sulfur vulcanization systems has led to introduce nitrosamine safe accelerator/s to produce safe natural rubber (NR) vulcanizates. It is an effective way to prevent formation of carcinogenic N-nitroso compounds during manufacture of rubber products. In the present study, behavior of nitrosamine safe binary accelerator system consisting of diisopropyl xanthogen polysulfide (DIXP) with commonly used non-regulated accelerator N-tert-butyl-2-benzothiazole sulfenamide (TBBS) was investigated in efficient sulfur vulcanization of NR. Cure characteristics, physico-mechanical properties and crosslink density of vulcanizates prepared with different combinations of the accelerator system were evaluated and compared with those of individual accelerators. The study reveals that moduli and strength properties of the vulcanizate prepared with DIXP accelerator are inferior to those of the vulcanizate prepared with TBBS accelerator. Nevertheless, optimum cure time of the DIXP compounds is lower in comparison to TBBS compounds. Moreover, progressive replacement of DIXP with TBBS in the accelerator system showed a synergistic effect in regard to cure characteristics and physico-mechanical properties.
{"title":"Study on sulfur vulcanized natural rubber formulated with nitrosamine safe diisopropyl xanthogen polysulfide/tertiary butyl benzothiazole sulphenamide binary accelerator system","authors":"I. Samarasinghe, S. Walpalage, D. Edirisinghe, S. Egodage","doi":"10.1177/1477760620977499","DOIUrl":"https://doi.org/10.1177/1477760620977499","url":null,"abstract":"An outstanding interest on elimination of nitrosamine generation in traditional sulfur vulcanization systems has led to introduce nitrosamine safe accelerator/s to produce safe natural rubber (NR) vulcanizates. It is an effective way to prevent formation of carcinogenic N-nitroso compounds during manufacture of rubber products. In the present study, behavior of nitrosamine safe binary accelerator system consisting of diisopropyl xanthogen polysulfide (DIXP) with commonly used non-regulated accelerator N-tert-butyl-2-benzothiazole sulfenamide (TBBS) was investigated in efficient sulfur vulcanization of NR. Cure characteristics, physico-mechanical properties and crosslink density of vulcanizates prepared with different combinations of the accelerator system were evaluated and compared with those of individual accelerators. The study reveals that moduli and strength properties of the vulcanizate prepared with DIXP accelerator are inferior to those of the vulcanizate prepared with TBBS accelerator. Nevertheless, optimum cure time of the DIXP compounds is lower in comparison to TBBS compounds. Moreover, progressive replacement of DIXP with TBBS in the accelerator system showed a synergistic effect in regard to cure characteristics and physico-mechanical properties.","PeriodicalId":20860,"journal":{"name":"Progress in Rubber Plastics and Recycling Technology","volume":"126 1","pages":"190 - 202"},"PeriodicalIF":2.6,"publicationDate":"2020-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79803820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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