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Elevated blood lead levels of refugee children in the United States: a systematic review of recent literature (2011-2021). 美国难民儿童血铅水平升高:近期文献的系统回顾(2011-2021)。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-04-21 Print Date: 2023-06-27 DOI: 10.1515/reveh-2022-0015
Joanna S Balza, Jean C Bikomeye, Kirsten M M Beyer, Caitlin Rublee, Kathryn E Flynn

Lead is an environmental hazard; even small elevations in blood lead level can cause serious negative health effects in children, including irreversible impacts such as learning difficulties, attention disorders, and behavioral issues. Previous research has shown that some groups are at higher risk for lead poisoning including racial/ethnic minorities, those with low economic status, and immigrants, especially refugees. This systematic review explores recent literature studying disparities in lead poisoning in refugee children. Search terms were chosen with the assistance of a medical librarian, and two independent reviewers assessed articles using a PICOS criteria (Population, Intervention, Comparison, Outcome, Study Design) following the Preferred Reporting Items for Systematic review and Meta-Analysis Protocols (PRIMSA-P) guidelines, a set of evidence-based minimum standards for reporting in systematic reviews. 321 article titles were reviewed, 61 abstracts screened, and 17 methods sections reviewed, ultimately including 13 studies. The studies found a high prevalence of elevated blood lead level among refugee populations when compared to reference populations. Both pre-migration and post-migration factors were identified as contributors to the disparity, and associations were identified between elevated blood lead levels and factors such as country of origin, age, and other health variables. Health providers and resettlement workers should be aware of these disparities and related factors. Testing, care, education and consistent follow-up should be provided.

铅是一种环境危害;即使血铅水平小幅升高,也会对儿童的健康造成严重的负面影响,包括学习困难、注意力障碍和行为问题等不可逆转的影响。以前的研究表明,一些群体铅中毒的风险更高,包括种族/少数民族、经济地位低的人以及移民,特别是难民。本系统综述探讨了最近研究难民儿童铅中毒差异的文献。在医学图书管理员的协助下选择检索词,两位独立审稿人根据系统评价和meta分析方案(PRIMSA-P)指南的首选报告项目,使用PICOS标准(人群、干预、比较、结果、研究设计)对文章进行评估,PRIMSA-P是一套系统评价中报告的循证最低标准。我们回顾了321篇文章标题,筛选了61篇摘要,回顾了17个方法部分,最终包括13项研究。研究发现,与参考人群相比,难民人群中血铅水平升高的发生率很高。移徙前和移徙后的因素都被确定为造成这种差异的因素,并确定了血铅水平升高与原籍国、年龄和其他健康变量等因素之间的关联。保健提供者和重新安置工作人员应了解这些差异和相关因素。应提供检测、护理、教育和持续的随访。
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引用次数: 0
A systematic review on photo-Fenton process as an efficient advanced oxidation for degradation of amoxicillin in aqueous environments. 系统综述了光- fenton法在水环境中高效降解阿莫西林的研究进展。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-04-18 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0155
Meghdad Pirsaheb, Hiwa Hossaini, Nazanin Kiani Raad, Sara Kianpour, Hooshyar Hossini

Amoxicillin (AMX) is one of the antibiotics in the penicillin category that is used in various fields. Considering the harmful effects of its remains, it is necessary to survey the ways to remove this compound. Advanced oxidation process (AOPs), specially photo-Fenton has been used for the removal of AMX. This study has been conducted based on PubMed, Google Scholar, DOAJ, Web of Science, and Scopus databases during the years 2008-2019. Some factors such as the aquatic solution, light source characteristics, iron, and H2O2 concentration, AMX degradation percentage, removal of total organic carbon percentage, and AMX concentration have been surveyed to optimize the process. Studies showed that the photo-Fenton process is highly dependent on pH, and in most studies, the highest efficiency has been observed in acidic pH values. Using a more energy light source can be effective in reducing the use of catalysts and oxidizers. The combined methods of AOPs such as photo-Fenton, electro-Fenton, and photo-electro-Fenton have higher efficiency in increasing mineralization than the photon process. The use of synthetic wastewater has a higher efficiency in the degradation of AMX than in real wastewater in the photo-Fenton process, which can be due to the absence of the interfering agents in synthetic environments.

阿莫西林(AMX)是青霉素类抗生素中的一种,广泛应用于各个领域。考虑到其残留的有害影响,有必要研究去除该化合物的方法。高级氧化法(AOPs),特别是光fenton法已被用于AMX的去除。本研究基于2008-2019年间的PubMed、b谷歌Scholar、DOAJ、Web of Science和Scopus数据库进行。考察了水溶液、光源特性、铁、H2O2浓度、AMX降解率、总有机碳去除率、AMX浓度等因素,对工艺进行了优化。研究表明,光- fenton工艺高度依赖于pH值,在大多数研究中,在酸性pH值下观察到最高的效率。使用能量更高的光源可以有效地减少催化剂和氧化剂的使用。光- fenton、电- fenton、光电- fenton等AOPs组合方法在增加矿化方面比光子方法效率更高。在光- fenton工艺中,使用合成废水对AMX的降解效率高于使用真实废水,这可能是由于合成环境中没有干扰剂。
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引用次数: 0
Comparison of medical waste management methods in different countries: a systematic review. 不同国家医疗废物管理方法的比较:系统综述。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-04-18 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0170
Abdolmajid Fadaei

Medical waste status is a severe public health problem worldwide. Proper medical waste management is of paramount importance. However, there is insufficient information about medical waste management and lack of management in different countries. The aim of this research was to investigate and evaluate the present status of medical waste management in different countries. We systematically searched Embase, PubMed/MEDLINE, Scopus, PubMed Central, Google Scholar databases, as well as medRxiv using the following keywords: medical waste, waste management, disposal, healthcare per-capita generation, gross domestic product (GDP), and hospital. A total of 38 eligible articles were identified. Correlations were calculated between the amount of medical waste generated (kg bed.day-1) vs. GDP per capita ($) and ranking of healthcare system performance. A negative correlation was found between medical waste generation rate and ranking of healthcare system performance. According to the findings of this study, the medical waste generation rate in different countries ranged from 0.14 to 6.10 kg bed.day-1. About 25% of countries segregated medical waste, and about 17% used standard storage for all medical waste. Shortcomings were also found in waste collection, storage, transportation and transfer, and disposal of medical waste management activities in different countries. Only about 25% of countries simultaneously used three techniques, such as autoclaving, incineration, and landfill for disposal and treatment of medical waste, and 91% used incineration method. This study highlights an essential need for particular medical waste management guidelines and regulations, technologies, knowledge and financing to upgrade medical waste management worldwide. This study can be considered to be a good guide for further research on medical waste management in developing and developed countries.

医疗废物状况是世界范围内一个严重的公共卫生问题。适当的医疗废物管理至关重要。然而,关于医疗废物管理的信息不足,而且不同国家缺乏管理。本研究的目的是调查和评估不同国家医疗废物管理的现状。我们系统地检索了Embase、PubMed/MEDLINE、Scopus、PubMed Central、谷歌Scholar数据库以及medRxiv数据库,使用以下关键词:医疗废物、废物管理、处置、人均医疗产出、国内生产总值(GDP)和医院。总共确定了38个符合条件的条目。计算了医疗废物产生量(kg beds .day-1)与人均GDP($)和医疗保健系统绩效排名之间的相关性。医疗废弃物产生率与医疗系统绩效排名呈负相关。根据本研究结果,不同国家的医疗废物产生率在0.14 - 6.10 kg / d -1之间。约25%的国家对医疗废物进行分类,约17%的国家对所有医疗废物采用标准储存。不同国家在废物收集、储存、运输和转移以及处置医疗废物管理活动方面也存在不足。只有约25%的国家同时使用高压灭菌、焚烧和填埋等三种技术处置和处理医疗废物,91%的国家使用焚烧法。这项研究强调,迫切需要制定特定的医疗废物管理准则和法规、技术、知识和资金,以提升全球医疗废物管理水平。本研究可为发展中国家和发达国家医疗废物管理的进一步研究提供良好的指导。
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引用次数: 0
Advanced oxidation processes for the removal of phthalate esters (PAEs) in aqueous matrices: a review. 高级氧化法去除水性基质中邻苯二甲酸酯(PAEs)的研究进展。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-04-08 Print Date: 2023-06-27 DOI: 10.1515/reveh-2022-0001
Meghdad Pirsaheb, Monireh Nouri, Hooshyar Hossini

Over the past few decades, phthalate esters (PAEs) used as additives to improve the persistence and flexibility of polymeric materials. They are also used in cosmetics, insect repellents, and propellants, and their continuous input into drinking waters has constituted a serious risk to human health and the environment. DBPs are compounds classified as hazardous substances and have teratogenic properties. Due to the high bioaccumulation of DBP, they have toxic properties in different organisms, making it very important to remove PAEs before discharging them into environments. In this study a systematic review was designed to evaluate Advanced oxidation processes (AOPs) studies which have successfully treated contaminated water with PAEs. Among AOPs, particularly photocatalytic, UV/H2O2 photolysis, sonolysis, and ozone-based processes were more tried to degrade PAEs in aqueous solutions. Additionally, a more detail of each AOPs was explained. Findings showed that all advanced oxidation processes, especially combined AOPs have good results in the degradation of PAEs in water.

在过去的几十年里,邻苯二甲酸酯(PAEs)作为添加剂被用于提高聚合物材料的持久性和柔韧性。它们还被用于化妆品、驱虫剂和推进剂中,它们不断进入饮用水中,对人类健康和环境构成严重威胁。dbp是被归类为有害物质的化合物,具有致畸特性。由于DBP的高生物蓄积性,它们在不同的生物体中具有毒性,因此在将PAEs排放到环境中之前将其去除非常重要。在本研究中,系统评价了先进氧化工艺(AOPs)的研究,这些研究已成功地处理了PAEs污染的水。在AOPs中,特别是光催化、UV/H2O2光解、声解和臭氧基工艺更倾向于降解水溶液中的PAEs。此外,还解释了每个aop的更多细节。研究结果表明,所有高级氧化工艺,特别是组合AOPs对水中PAEs的降解效果都很好。
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引用次数: 0
A systematic review of the anxiety-alleviation benefits of exposure to the natural environment. 对暴露在自然环境中减轻焦虑的益处的系统回顾。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-03-24 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0157
Xiaofeng Zhang, Yiping Zhang, Jiayue Yun, Wenfei Yao

Research suggests that exposure to natural environments can be beneficial for health, such as reducing physical illness and improving mood and cognitive ability. The potential benefits of nature have come into focus at a time when mental health issues are growing globally. Here, we have selected 24 studies from four databases for meta-analysis to explore the effects of exposure to the natural environment on the anxiety of the human body and summarize the influencing factors on the anxiety relief effect. A random-effect meta-analysis of anxiety state changes before and after exposure to natural environment shows that natural exposure effectively alleviated human anxiety (SMD -1.28, 95% CI: -1.65 to -0.92). The overall quality of the included papers, assessed using the PEDro scale, is considered to vary considerably, but most of the papers are rated between 4 and 7 which is considered fair or good. In addition, we have also investigated the potential moderators of anxiety-relieving effects of the nature. Our results shows that the age and exposure time of the subjects are related to the effect of anxiety relief. The results of the subgroup analysis of moderators prove that compared with the middle-aged people (SMD -0.63, 95% CI: -1.13 to -0.12), young people (SMD -1.50, 95% CI: -1.90 to -1.10) get better anxiety alleviation effect in the natural environment. In terms of exposure time, compared with 0.5-2 h (SMD -0.18, 95% CI: -0.59 to -0.23) and >2 h (SMD -0.84, 95% CI: -1.40 to -0.27) exposure periods, subjects get the maximum anxiety relief benefit when they spent <0.5 h (SMD -1.60, 95% CI: -1.93 to -1.27) in the natural environment. However, the quality of the included studies varies greatly and there is a significant heterogeneity in the meta-analysis. Study location, natural environment type and other moderator factors have no obvious correlation with anxiety-alleviation effect of the nature. A higher quality and more comprehensive study needs to be carried out to find out more moderators about the effects of the natural environment on anxiety alleviation. Further experimental studies should also be conducted to determine the mechanism by which natural exposure reduces anxiety so as to provide strong support for the construction and improvement of healthy natural environment.

研究表明,接触自然环境对健康有益,比如减少身体疾病、改善情绪和认知能力。在全球心理健康问题日益严重的时候,大自然的潜在益处已经成为人们关注的焦点。在此,我们从4个数据库中选取24项研究进行meta分析,探讨自然环境暴露对人体焦虑的影响,总结影响焦虑缓解效果的因素。暴露于自然环境前后焦虑状态变化的随机效应荟萃分析显示,自然暴露有效缓解了人类的焦虑(SMD为-1.28,95% CI为-1.65 ~ -0.92)。使用佩德罗量表评估的纳入论文的整体质量被认为差异很大,但大多数论文的评分在4到7之间,被认为是公平或良好。此外,我们还研究了自然缓解焦虑作用的潜在调节因子。结果表明,被试的年龄和暴露时间与焦虑缓解效果有关。调节因子亚组分析结果证明,与中年人(SMD -0.63, 95% CI: -1.13 ~ -0.12)相比,年轻人(SMD -1.50, 95% CI: -1.90 ~ -1.10)在自然环境中获得更好的焦虑缓解效果。在暴露时间方面,与0.5-2小时(SMD -0.18, 95% CI: -0.59至-0.23)和0.5-2小时(SMD -0.84, 95% CI: -1.40至-0.27)暴露时间相比,受试者在花时间时获得最大的焦虑缓解效果
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引用次数: 0
Exposure to magnetic fields and childhood leukemia: a systematic review and meta-analysis of case-control and cohort studies. 暴露于磁场和儿童白血病:病例对照和队列研究的系统回顾和荟萃分析。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-03-15 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0112
Christian Brabant, Anton Geerinck, Charlotte Beaudart, Ezio Tirelli, Christophe Geuzaine, Olivier Bruyère
<p><p>The association between childhood leukemia and extremely low frequency magnetic fields (ELF-MF) generated by power lines and various electric appliances has been studied extensively during the past 40 years. However, the conditions under which ELF-MF represent a risk factor for leukemia are still unclear. Therefore, we have performed a systematic review and meta-analysis to clarify the relation between ELF-MF from several sources and childhood leukemia. We have systematically searched Medline, Scopus, Cochrane Database of Systematic Review and DARE to identify each article that has examined the relationship between ELF-MF and childhood leukemia. We have performed a global meta-analysis that takes into account the different measures used to assess magnetic field exposure: magnetic flux density measurements (<0.2 µT vs. >0.2 µT), distances between the child's home and power lines (>200 m vs. <200 m) and wire codings (low current configuration vs. high current configuration). Moreover, meta-analyses either based on magnetic flux densities, on proximity to power lines or on wire codings have been performed. The association between electric appliances and childhood leukemia has also been examined. Of the 863 references identified, 38 studies have been included in our systematic review. Our global meta-analysis indicated an association between childhood leukemia and ELF-MF (21 studies, pooled OR=1.26; 95% CI 1.06-1.49), an association mainly explained by the studies conducted before 2000 (earlier studies: pooled OR=1.51; 95% CI 1.26-1.80 vs. later studies: pooled OR=1.04; 95% CI 0.84-1.29). Our meta-analyses based only on magnetic field measurements indicated that the magnetic flux density threshold associated with childhood leukemia is higher than 0.4 µT (12 studies, >0.4 µT: pooled OR=1.37; 95% CI 1.05-1.80; acute lymphoblastic leukemia alone: seven studies, >0.4 µT: pooled OR=1.88; 95% CI 1.31-2.70). Lower magnetic fields were not associated with leukemia (12 studies, 0.1-0.2 µT: pooled OR=1.04; 95% CI 0.88-1.24; 0.2-0.4 µT: pooled OR=1.07; 95% CI 0.87-1.30). Our meta-analyses based only on distances (five studies) showed that the pooled ORs for living within 50 m and 200 m of power lines were 1.11 (95% CI 0.81-1.52) and 0.98 (95% CI 0.85-1.12), respectively. The pooled OR for living within 50 m of power lines and acute lymphoblastic leukemia analyzed separately was 1.44 (95% CI 0.72-2.88). Our meta-analyses based only on wire codings (five studies) indicated that the pooled OR for the very high current configuration (VHCC) was 1.23 (95% CI 0.72-2.10). Finally, the risk of childhood leukemia was increased after exposure to electric blankets (four studies, pooled OR=2.75; 95% CI 1.71-4.42) and, to a lesser extent, electric clocks (four studies, pooled OR=1.27; 95% CI 1.01-1.60). Our results suggest that ELF-MF higher than 0.4 µT can increase the risk of developing leukemia in children, probably acute lymphoblastic leukemia. Prolonged exposure t
儿童白血病与电力线和各种电器产生的极低频磁场(ELF-MF)之间的关系在过去的40年里得到了广泛的研究。然而,ELF-MF代表白血病危险因素的条件仍不清楚。因此,我们进行了一项系统综述和荟萃分析,以阐明几种来源的ELF-MF与儿童白血病之间的关系。我们系统地检索了Medline、Scopus、Cochrane系统评价数据库和DARE,以确定每一篇研究ELF-MF与儿童白血病关系的文章。我们进行了一项全球荟萃分析,考虑了用于评估磁场暴露的不同测量方法:磁通量密度测量(0.2µT),儿童家与电力线之间的距离(>200 m vs. 0.4µT:汇总OR=1.37;95% ci 1.05-1.80;单纯急性淋巴细胞白血病:7项研究,>0.4µT:合并OR=1.88;95% ci 1.31-2.70)。低磁场与白血病无关(12项研究,0.1-0.2µT:合并OR=1.04;95% ci 0.88-1.24;0.2-0.4µT: pooled OR=1.07;95% ci 0.87-1.30)。我们的荟萃分析仅基于距离(五项研究)显示,居住在距离输电线50米和200米范围内的综合or分别为1.11 (95% CI 0.81-1.52)和0.98 (95% CI 0.85-1.12)。居住在输电线50米范围内和急性淋巴细胞白血病的合并OR分别分析为1.44 (95% CI 0.72-2.88)。我们的荟萃分析仅基于电线编码(五项研究)表明,甚高电流配置(VHCC)的合并OR为1.23 (95% CI 0.72-2.10)。最后,接触电热毯后儿童白血病的风险增加(4项研究,合并OR=2.75;95% CI 1.71-4.42),以及较小程度的电子钟(4项研究,合并OR=1.27;95% ci 1.01-1.60)。我们的研究结果表明,高于0.4µT的ELF-MF会增加儿童发生白血病的风险,可能是急性淋巴细胞白血病。长时间接触产生高于0.4µT磁场的电器,如电热毯,会增加儿童患白血病的风险。
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引用次数: 0
Arsenic in drinking water and kidney cancer: a systematic review. 饮用水中的砷与肾癌:一项系统综述。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-03-15 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0168
Nematollah Jaafarzadeh, Ali Poormohammadi, Halime Almasi, Zeinab Ghaedrahmat, Fakher Rahim, Amir Zahedi

Object: Arsenic as a chemical is found in rock, soil, air and used in various industries and their products, such as colors, hairs, and fertilizers. Humans may be exposed to arsenic mainly through food and drinking water. Due to its adverse health effects, its presence in drinking water has become a public health concern.

Methods: In this systematic review, we investigated the relationship between arsenic concentration in drinking water and the risk of kidney cancer in humans. For this reason, various electronic databases were searched from 1992 February to November 2021. In this review, three ecological studies, two case-control studies, and four cohort studies were investigated.

Results: High levels of arsenic (100 μg/L) have been reported in many countries such as southwest Taiwan, Niigata, Argentine, and northern Chile. A significant relationship was observed between kidney cancer incidence and its mortality rate with high arsenic levels in drinking water.

Conclusions: Despite the limitations in some previous studies, reviewing and comparing the data of different regions indicates a scientific relationship between kidney cancer incidence and high concentrations of arsenic in drinking water.

目的:砷作为一种化学物质存在于岩石、土壤、空气中,并用于各种工业及其产品,如颜色、头发和肥料。人类可能主要通过食物和饮用水接触到砷。由于其对健康的不利影响,它在饮用水中的存在已成为一个公共卫生问题。方法:在这篇系统综述中,我们调查了饮用水中砷浓度与人类肾癌风险的关系。为此,从1992年2月到2021年11月,检索了各种电子数据库。本综述包括3项生态学研究、2项病例对照研究和4项队列研究。研究发现,饮用水中砷含量高与肾癌发病率及其死亡率之间存在显著关系。结论:尽管以往的一些研究存在局限性,但回顾和比较不同地区的数据表明,肾癌发病率与饮用水中高浓度砷之间存在科学关系。
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引用次数: 0
Dariusz Leszczynski responds to comments of Maël Dieudonné on Leszczynski's review of the scientific evidence on the individual sensitivity to electromagnetic fields (EHS). Dariusz Leszczynski回应了Maël dieudonn<e:1>对Leszczynski关于个体对电磁场敏感性(EHS)的科学证据的评论。
IF 3.9 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-03-09 Print Date: 2023-09-26 DOI: 10.1515/reveh-2022-0034
Dariusz Leszczynski

While Dieudonné has praised thoroughness of Leszczynski's review of EHS studies, he was critical of the final conclusions. Leszczynski strongly disagrees with argumentation of Dieudonné that EHS issue is settled and that biomarker research is unnecessary because it is expensive and might produce false positives. Leszczynski's opinion is that his review has demonstrated how very poor scientifically and inadequate statistically is the to-date executed research on EHS. Dieudonné's approach of using such poor science to justify claim that EHS issue is settled and there is no causality link between EHS and EMF exposures, is completely unjustified and simply false.

虽然Dieudoné赞扬了Leszczynski对EHS研究的全面审查,但他对最终结论持批评态度。Leszczynski强烈反对Dieudoné的论点,即EHS问题已经解决,生物标志物研究是不必要的,因为它成本高昂,可能会产生假阳性。Leszczynski的观点是,他的综述已经证明了迄今为止执行的EHS研究在科学上是多么糟糕,在统计上是多么的不充分。Dieudoné利用如此糟糕的科学来证明EHS问题已经解决,EHS和EMF暴露之间没有因果关系的说法是完全不合理的,完全是错误的。
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引用次数: 0
Frontmatter Frontmatter
IF 3.9 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-03-01 DOI: 10.1515/reveh-2022-frontmatter1
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引用次数: 0
Advanced oxidation processes for phthalate esters removal in aqueous solution: a systematic review. 高级氧化法去除水溶液中邻苯二甲酸酯:系统综述。
IF 3 4区 医学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2022-02-14 Print Date: 2023-06-27 DOI: 10.1515/reveh-2021-0147
Hoda Amiri, Susana Silva Martinez, Marziyeh Ansari Shiri, Mohammad Mahdi Soori

This study addresses a systematic review of the scientific literature to evaluate the most common advanced oxidation processes (AOP) for the removal of phthalate esters (PE) in aqueous matrices. Six AOP were reviewed for PE degradation such as processes based on photolysis, Fenton, ozonation and sulfate radicals ( SO 4 - ), combined AOP and other processes. The PE degradation efficiencies by AOP processes ranged from 40.3 to 100%. In the reviewed literature, an initial PE concentration within 0.04-250 mg/L was applied. The H2O2 concentrations used in the UV/H2O2 process and O3 concentrations in ozonation-based processes ranged between 0.85-1,360.6 mg/L and 2-4,971 mg/L, respectively. Based on the reported results, the PE oxidation data fit well to the pseudo-first order kinetic model. A review of the studies revealed that many oxidant species are produced in the AOP, including hydroxyl radicals (OH), SO 4 - , superoxide radical anions ( O 2 - ), hydroperoxyl radicals (HO2 ), hydrogen peroxide (H2O2), and singlet oxygen (O2). Among these oxidants, OH play a key role in the degradation of PE. However, SO 4 - are more effective and efficient than OH since SO 4 - has a higher oxidation power (E = 2.5-3.1 V) compared to OH radicals (E = 1.8-2.7 V). In different AOP processes, the aromatic rings of PE are destroyed by OH and produce intermediates such as phthalic acid (C6H4(CO2H)2), benzoic acid ethyl ester (C9H10O2), 2, 5-dihydroxybenzoic acid (C7H6O4), formic acid (CH2O2), acetic acid (CH3COOH), and oxalic acid (C2H2O4), among some others. Until now, limited data have been reported on PE toxicity assessment. The reviewed literature has shown that AOP can be used effectively to degrade PE from aqueous matrices. However, this systematic study suggests focusing more on the evaluation of the toxicity of the effluent resulting from AOP for the decomposition of PE in future studies.

本研究解决了科学文献的系统审查,以评估最常见的高级氧化过程(AOP)去除邻苯二甲酸酯(PE)在水性基质。综述了基于光解、Fenton、臭氧和硫酸盐自由基(so4•-)的六种AOP降解PE的方法,以及联合AOP和其他方法。AOP过程对PE的降解效率从40.3到100%不等。在文献综述中,PE的初始浓度在0.04-250 mg/L之间。UV/H2O2工艺中使用的H2O2浓度和臭氧化工艺中使用的O3浓度分别在0.85-1,360.6 mg/L和2-4,971 mg/L之间。根据已报道的结果,PE氧化数据符合准一级动力学模型。研究表明,AOP中产生了多种氧化剂,包括羟基自由基(•OH)、so4•-、超氧自由基阴离子(O2 -•)、羟基自由基(HO2•)、过氧化氢(H2O2)和单线态氧(O2)。在这些氧化剂中,•OH在PE的降解中起关键作用。然而,so4•-比•OH更有效和高效,因为so4•-比•OH自由基(E = 1.8-2.7 V)具有更高的氧化能力(E = 2.5-3.1 V)。在不同的AOP过程中,PE的芳香环被•OH破坏,生成邻苯二甲酸(C6H4(CO2H)2)、苯甲酸乙酯(C9H10O2)、2,5 -二羟基苯甲酸(C7H6O4)、甲酸(CH2O2)、乙酸(CH3COOH)和草酸(C2H2O4)等中间体。到目前为止,关于PE毒性评估的数据报道有限。综述的文献表明,AOP可以有效地用于从水性基质中降解PE。然而,这项系统的研究建议在未来的研究中更多地关注AOP产生的废水对PE分解的毒性评价。
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Reviews on Environmental Health
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