Plexcitonics, an interdisciplinary field focused on the study of plasmon-exciton coupling, is rapidly evolving and holds significant promise for advancing optical and optoelectronic devices. Experimental observations and mechanistic investigations of the plexcitonic phenomenon of ZnO/Au heterostructure film based on propagating surface plasmon polaritons in the gold layer and excitons confined within a continuous ZnO layer are presented using detailed characterizations. Diverging from conventional localized plasmon systems, this work establishes that the high electron affinity and static permittivity of the ZnO layer induce deep quantum spillover of metallic electrons, drastically increasing plasmon energy dissipation. Using the Thomas-Fermi approximation to model the interfacial electronics, we theoretically confirm that this spillover leads to a stronger spatial confinement and an effective compression of the SPP evanescent field. As a main application for plexcitons, a wide-field surface plasmon resonance microscope based on ZnO/Au heterostructure film is introduced to enhance the sensitivity of discrete particle detection. The ZnO/Au heterostructure film achieved a remarkable enhancement in the detection signal, resulting in a maximum intensity of 110 a.u. (Au control) to 190 a.u. for 100 nm silica nanoparticles. Our results provide insight into the enhancement of sensitivity and capabilities of discrete particle detection across a range of biomedical applications.
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