Detecting harmful heavy metal ions in water sources, especially lead (Pb (II)), is essential to protecting the environment and human health. This work used differential pulse voltammetry (DPV) to effectively design and electrochemically evaluate a CdFe2O₄-modified carbon paste electrode (CdFe2O₄/MCPE) for the sensitive and selective detection of Pb (II). The effective production of CdFe2O₄ nanoparticles with a spinel cubic structure, nanoflake shape, and high electroactive surface area was validated by structural and morphological characterization utilizing XRD, FT-IR, TEM, and XPS. CdFe2O₄/MCPE is an effective sensing platform because of its increased conductivity, reduced charge transfer resistance (Rct), and better electron transfer kinetics, as shown by electrochemical characterization using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The most effective supporting electrolyte for Pb (II) detection among the many tested was 0.1 M HCl. With a low detection limit (LLOD) of 0.078 μM and good linear regression, the sensor demonstrated a broad linear range (1–11 μM). While repeatability and stability evaluations verified its steady performance and longevity over several cycles, selectivity investigations demonstrated a notable response for Pb (II) with little interference from competing metal ions. By detecting Pb (II) in tap water samples using the conventional addition technique, obtaining good recovery rates (98.9–99.8 %), and proving the sensor's effectiveness for real-world monitoring, its practical application was confirmed. CdFe₂O₄/MCPE demonstrated higher sensitivity, a lower detection limit, and good repeatability compared to previously reported sensors, making it an economical and dependable sensor for industrial and environmental applications. As a scalable and effective way to monitor heavy metals in water sources, this study identifies CdFe2O₄/MCPE as a viable electrochemical sensor for detecting traces of Pb (II). For more extensive industrial and environmental applications, future research can concentrate on multi-metal detection, real-time field applications, and sensor downsizing.
扫码关注我们
求助内容:
应助结果提醒方式:
