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A magnetic head-based eddy current array for defect detection in ferromagnetic steels 用于铁磁钢缺陷检测的磁头式涡流阵列
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-11 DOI: 10.1016/j.sna.2024.115862

Defects on the surface and subsurface of the ferromagnetic steels can easily lead to structural failures. Eddy current testing is one of the most popular techniques for defect detection. In this paper, the direct current (DC) magnetization and a magnetic head-based eddy current array (MHECA) are integrated to propose the DCMHECA technique. This method can address the low testing efficiency of single probe testing and the channel multiplexing of array testing, and meanwhile detect deep surface and subsurface defects. The experimental results verify that the proposed DCMHECA can be used to locate rectangular and hole defects and quantify their depths with little channel interferences, which are indicated by low difference rates.

铁磁钢表面和次表面的缺陷很容易导致结构失效。涡流检测是最常用的缺陷检测技术之一。本文将直流(DC)磁化与磁头涡流阵列(MHECA)相结合,提出了 DCMHECA 技术。该方法可以解决单探头检测效率低和阵列检测通道复用的问题,同时还能检测深层表面和地下缺陷。实验结果验证了所提出的 DCMHECA 可用于定位矩形和孔洞缺陷并量化其深度,且通道干扰小,差值率低。
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引用次数: 0
High-precision dynamic gesture recognition based on microfiber sensor and EMT-Net 基于微纤维传感器和 EMT-Net 的高精度动态手势识别
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-11 DOI: 10.1016/j.sna.2024.115852

Dynamic gesture recognition, which utilizes flexible wearable sensors and deep learning, is invaluable for human–computer interaction. Nevertheless, the primary challenges persist are the rapid detection of intricate gestures and the accurate recognition of dynamic signals. In this study, we suggest utilizing a microfiber sensor to identify the variations in wrist skin and detect dynamic gesture. In order to tackle the issue of insufficient feature extraction in the detected signals, resulting in reduced accuracy in recognition, we introduce a network dubbed EMT-Net (improve multi-head attention transformer network). This network utilizes a transformer encoder to capture and represent the characteristics of dynamic gesture signal and uses a CNN to classify the encoded features. To ensure that the model comprehensively captures the temporal and statistical characteristics of the signals, we enhance the multi-head attention mechanism by restricting certain attention heads to concentrate solely on the statistical features of the signals while allowing others to focus on the temporal features and global dependencies. Furthermore, because of the varying discriminatory abilities of different characteristics, we have developed an attention module to redistribution the attention weights on statistical features. The experimental results demonstrate that the microfiber sensor effectively recognizes ten distinct forms of dynamic gesture signals. Simultaneously, EMT-Net attains proficient identification with an accuracy of 98.80%, precision of 98.81%, recall of 98.80%, and an F1 score of 98.80%. The application value of this dynamic gesture recognition technology, which utilizes microfiber sensors and EMT-Net, is significant. The forthcoming alterations in human–computer interaction, virtual reality, and various other domains are anticipated.

动态手势识别利用灵活的可穿戴传感器和深度学习技术,对人机交互具有重要价值。然而,快速检测复杂的手势和准确识别动态信号仍是主要挑战。在这项研究中,我们建议利用超细纤维传感器来识别手腕皮肤的变化并检测动态手势。为了解决检测信号特征提取不足导致识别准确率降低的问题,我们引入了一个名为 EMT-Net(改进型多头注意力变压器网络)的网络。该网络利用变压器编码器捕捉和表示动态手势信号的特征,并使用 CNN 对编码特征进行分类。为确保模型全面捕捉信号的时间和统计特征,我们增强了多头注意力机制,限制某些注意力头只关注信号的统计特征,而让其他注意力头关注时间特征和全局依赖性。此外,由于不同特征的分辨能力各不相同,我们还开发了一个注意力模块,以重新分配统计特征上的注意力权重。实验结果表明,超细纤维传感器能有效识别十种不同形式的动态手势信号。同时,EMT-Net 的识别准确率为 98.80%,精确率为 98.81%,召回率为 98.80%,F1 分数为 98.80%。这项利用超细纤维传感器和 EMT-Net 的动态手势识别技术具有重要的应用价值。预计在人机交互、虚拟现实和其他各种领域即将发生变化。
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引用次数: 0
OneTip: A soft tactile interface for 6-D fingertip pose acquisition in human-computer interaction OneTip:用于在人机交互中获取 6-D 指尖姿势的软触觉界面
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-11 DOI: 10.1016/j.sna.2024.115896

Advances in display technology have created the need for more efficient and natural multi-degree-of-freedom interaction devices. The movement of a single fingertip has six degrees of freedom (DOFs), but traditional rigid touchscreens usually sense only 2-D information. This article proposes a new deformable tactile interface, OneTip, for single-fingertip human-computer interaction with 6 DOFs. It is manufactured based on the principle of vision-based tactile sensing using virtual stereoscopic cameras, and its size is about twice that of a thumb. The contact surface of OneTip has a specially designed structure and material to mimic the sensitivity and softness of human skin. Also, OneTip employs a new sensing method to address the problem of soft fingertip pose estimation (measuring relative change only) with incipient slip effects. Experiments show that OneTip has good 6-D pose estimation accuracy, with root mean square errors (RMSE) of translation and rotation not exceeding 0.1 mm and 2.6°, respectively, within the linear interval (x and y: 1.2–1.2 mm; z: 0–3 mm; yaw: 15–15 deg; pitch and roll: 40–40 deg). Experiments were also conducted to explore the application of OneTip in typical virtual manipulation tasks and the possibility of combining it with other interaction devices.

随着显示技术的进步,人们需要更高效、更自然的多自由度交互设备。单个指尖的运动有六个自由度(DOF),但传统的刚性触摸屏通常只能感知二维信息。本文提出了一种新的可变形触觉界面 OneTip,用于具有 6 个自由度的单指人机交互。它是根据基于视觉的触觉传感原理,利用虚拟立体摄像机制造的,其大小约为拇指的两倍。OneTip 的接触面采用了特殊设计的结构和材料,以模仿人体皮肤的敏感度和柔软度。此外,OneTip 还采用了一种新的传感方法,以解决软指尖姿势估计(仅测量相对变化)和初期滑动效应的问题。实验表明,OneTip 具有良好的 6-D 姿势估计精度,在线性范围内(x 和 y:-1.2-1.2 mm;y 和 x:-1.2-1.2 mm),平移和旋转的均方根误差(RMSE)分别不超过 0.1 mm 和 2.6°:x 和 y:-1.2-1.2 毫米;z:0-3 毫米;偏航:-15-15度;俯仰和滚动:-40-40度)。实验还探讨了 OneTip 在典型虚拟操作任务中的应用,以及与其他交互设备相结合的可能性。
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引用次数: 0
BaTiO3 boosted silver-based SPR sensor for efficient urine-glucose detection in pre-diabetic and early-diabetic stages 用于高效检测糖尿病前期和早期尿糖的氧化钡银基 SPR 传感器
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-10 DOI: 10.1016/j.sna.2024.115895

The current work studies the impact of BaTiO3 along with the various monosulfide on the sensing performance of a silver-coated surface plasmonic resonance sensor (SPR) for the noninvasive detection of glucose via urine samples. The considered monosulfides are GeS, ZnS, CdS, and CuS. After the optimization of the BaTiO3 thickness to 13 nm over the silver based SPR sensor, all above mentioned monosulfides are investigated over the BaTiO3 (BTO) layer individually. It is shown that GeS shows better performance compared to others. Maximum obtained sensitivity for the optimized structure (Prism (BK7)/ Ag (50 nm)/BaTiO3 (13 nm)/GeS (01 Layer)/Urine sample) is 527 °/RIU (the highest ever reported to date) for urine sample refractive indices range 1.335, 1.336, 1.337, 1.338, and 1.341 for corresponding glucose concentration of 0 g/dl (non-diabetic), 0.625 g/dl (pre-diabetic), 1.25 g/dl (early diabetic), 2.5 g/dl (diabetic), and 5 g/dl (high-diabetic), respectively. The investigation produced a thorough picture of the distribution of electric fields for distinct monosulfide layers. Other investigated sensing performance parameters such as detection accuracy (DA), quality factor (QF), limit of detection (LOD) are also numerically calculated and are 0.227 deg−1, 97 RIU−1 and 1.25e-5 respectively. The contrast of the suggested structure to similar relevant published work demonstrates its ability to be used as an efficient label-free biosensor.

目前的工作研究了 BaTiO3 和各种单硫化物对银涂层表面等离子体共振传感器(SPR)传感性能的影响,该传感器用于通过尿液样本对葡萄糖进行无创检测。所考虑的单硫化物包括 GeS、ZnS、CdS 和 CuS。在将银基 SPR 传感器上的 BaTiO3 厚度优化为 13 纳米后,对 BaTiO3 (BTO) 层上的上述所有单硫化物进行了单独研究。结果表明,与其他单硫化物相比,GeS 的性能更好。优化结构(棱镜(BK7)/Ag(50 纳米)/BaTiO3(13 纳米)/GeS(01 层)/尿液样品)在尿液样品折射率范围为 1.335、1.336、1.337、1.338 和 1.341,相应的葡萄糖浓度分别为 0 g/dl(非糖尿病)、0.625 g/dl(糖尿病前期)、1.25 g/dl(糖尿病早期)、2.5 g/dl(糖尿病)和 5 g/dl(糖尿病后期)。这项调查全面了解了不同单硫化物层的电场分布情况。其他调查的传感性能参数,如检测精度(DA)、品质因数(QF)和检测限(LOD)也都经过数值计算,分别为 0.227 deg-1、97 RIU-1 和 1.25e-5。所建议的结构与已发表的类似相关工作的对比表明,它有能力用作一种高效的无标记生物传感器。
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引用次数: 0
Engineering a vacuum-actuated peristaltic micropump with novel microchannel design to rapidly separate blood plasma with extremely low hemolysis 采用新型微通道设计的真空驱动蠕动微泵,可快速分离溶血率极低的血浆
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-10 DOI: 10.1016/j.sna.2024.115845

A need exists for scalable, automated lab-on-chip systems to separate blood plasma for medical diagnostics. In this study, a vacuum-actuated peristaltic micropump (VPM) was developed, incorporating with the inertial microfluidic technique for the separation and collection of blood plasma from diluted blood. The features of the micropump were investigated by varying parameters such as frequency, vacuum pressure, and the number of microchannels. The highest achievable flow rate was found to be 832 µL/min. Subsequently, to minimize the occurrence of red blood cell rupture during the separation process and significantly reduce hemolysis, the configuration of the vertical wall inside the microchannel was modified to an inclined wall. This improvement was validated through experiments using high-speed cameras and fluorescent particles. Blood plasma separation was achieved with high efficiency (98.5 %), rapidity (<1 min), automation, and minimal whole blood usage (5 µL). Importantly, the vacuum actuator with an inclined wall obstruction design demonstrated very low hemolysis (less than 2 %).

医学诊断需要可扩展的自动化片上实验室系统来分离血浆。本研究开发了一种真空驱动蠕动微泵(VPM),结合惯性微流体技术,用于从稀释血液中分离和收集血浆。通过改变频率、真空压力和微通道数量等参数,研究了微泵的特性。结果发现,可达到的最高流速为 832 微升/分钟。随后,为了最大限度地减少分离过程中红细胞破裂的发生,并显著降低溶血率,将微通道内垂直壁的配置改为倾斜壁。使用高速摄像机和荧光颗粒进行的实验验证了这一改进。血浆分离效率高(98.5%),速度快(1 分钟),自动化程度高,全血用量少(5 µL)。重要的是,采用斜壁阻塞设计的真空致动器溶血率非常低(低于 2%)。
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引用次数: 0
YAG:Dy co-doped with Tb for lifetime-based phosphor thermometry from room temperature to 1600 °C YAG:Dy 与 Tb 共掺,用于从室温到 1600 °C 的基于寿命的荧光粉温度测定法
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-08 DOI: 10.1016/j.sna.2024.115890

Phosphor thermometry has demonstrated significant potential for nondestructive high-temperature measurements in gas turbines. To expand the measurement range through lifetime-based phosphor thermometry, we developed a novel phosphor, YAG:Dy co-doped with Tb (YAG:Dy,Tb). Three YAG:Dy,Tb samples with varying Tb concentrations were synthesized through the sol–gel method. A fiber-optic-coupled measurement system was established to capture multiple emission peaks of YAG co-doped with Dy3+ and Tb3+ at 544 nm, 484 nm, and 458 nm. Efficient energy transfer from Dy3+ to Tb3+ resulted in a substantial enhancement of Tb3+ emission at 544 nm under 355 nm excitation. Owing to the energy transfer, the temperature measurement range under the lifetime method was extended from room temperature to 1600 °C using the combination of Tb3+ emission at 544 nm and Dy3+ emission at 458 nm. YAG:Dy,Tb samples with higher concentrations of Tb3+ exhibited superior temperature measurement performance, mainly owing to their stronger signal-to-noise ratio at >1000 °C. The performances of different emission peaks were also compared according to temperature uncertainty, which generally ranged from 0.1 °C to 2.7 °C across the entire measurement range.

荧光粉测温法在燃气轮机的无损高温测量方面具有巨大潜力。为了通过基于寿命的荧光粉测温法扩大测量范围,我们开发了一种新型荧光粉--掺杂铽元素的 YAG:Dy (YAG:Dy,Tb)。我们通过溶胶-凝胶法合成了三种不同铽浓度的 YAG:Dy,Tb 样品。建立的光纤耦合测量系统可捕捉到掺杂了 Dy3+ 和 Tb3+ 的 YAG 在 544 nm、484 nm 和 458 nm 处的多个发射峰。在 355 nm 激发下,Dy3+ 向 Tb3+ 的有效能量转移导致 Tb3+ 在 544 nm 处的发射大大增强。由于能量转移,利用 544 nm 处的 Tb3+ 发射和 458 nm 处的 Dy3+ 发射组合,寿命法的温度测量范围从室温扩展到 1600 °C。Tb3+ 浓度较高的 YAG:Dy,Tb 样品表现出更优越的温度测量性能,这主要归功于其在 1000 °C 时更高的信噪比。我们还根据温度不确定性对不同发射峰的性能进行了比较,在整个测量范围内,温度不确定性一般在 0.1 ℃ 至 2.7 ℃ 之间。
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引用次数: 0
A novel design of a MEMS resonant accelerometer with adjustable sensitivity 灵敏度可调的新型 MEMS 谐振加速度计设计
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-07 DOI: 10.1016/j.sna.2024.115859

This paper presents the design and experimental evaluation of a silicon micro-machined resonant accelerometer featuring adjustable sensitivity. By integrating an electrostatic tuning module into the fundamental accelerometer structure, dynamic sensitivity adjustment becomes feasible, leveraging the softening effect of electrostatic negative stiffness to optimize range, noise, and bandwidth. Notably, the electrostatic tuning module integrates seamlessly with the core accelerometer structure, minimizing structural alterations. Through theoretical analysis and finite element simulation of the electrostatic negative stiffness principle, we have designed a novel accelerometer with adjustable sensitivity, which can enhance the sensitivity and reduces the bias-instability of the accelerometer with a relatively small adjustment voltage, without increasing structural complexity. The performance of the accelerometer was assessed through open-loop, closed-loop, and dynamic experiments, revealing that sensitivity increased from 843 Hz/g to 2611 Hz/g within a linear range of ±1 g when employing a sensitivity-enhancing bias voltage of 9 V. Moreover, the bias-instability is lowered down from 17.3 μg to 6.8 μg. This design offers a promising avenue for sensitivity tuning in MEMS resonant accelerometers.

本文介绍了具有灵敏度可调功能的硅微型机械谐振加速度计的设计和实验评估。通过将静电调谐模块集成到基本加速度计结构中,可以利用静电负稳态的软化效应来优化量程、噪声和带宽,从而实现动态灵敏度调节。值得注意的是,静电调谐模块与加速度计核心结构无缝集成,最大限度地减少了结构改动。通过对静电负稳态原理的理论分析和有限元模拟,我们设计出了一种新型的灵敏度可调式加速度计,只需相对较小的调节电压,就能提高加速度计的灵敏度并降低偏置不稳定性,同时不会增加结构的复杂性。通过开环、闭环和动态实验对加速度计的性能进行了评估,结果表明,当采用 9 V 灵敏度增强偏置电压时,在 ±1 g 的线性范围内,灵敏度从 843 Hz/g 提高到 2611 Hz/g。此外,偏压不稳定性也从 17.3 μg 降低到 6.8 μg。这种设计为微机电系统谐振加速度计的灵敏度调整提供了一条很有前景的途径。
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引用次数: 0
FBG-based force sensing with temperature self-compensation for smart bolts 基于 FBG 的力传感技术,用于智能螺栓的温度自我补偿
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-06 DOI: 10.1016/j.sna.2024.115872

Small variations in bolt component connection can have significant impacts on equipment operating safety and efficiency. A comprehensive understanding of the bolted status supports the equipment optimizing in in-situ health monitoring. Therefore, an improved bolt force measurement method is looking forward. Given the minimally invasive nature, potential for multi-parameter measuring, and ability to operate in harsh conditions, optic fiber sensors present an opportunity for equipment in-situ health monitoring. This paper first strengthened the confidence in embedding optic fiber force sensors within the bolts. Additionally, the FBG temperature self-compensation method is employed and successfully improved the force measurement accuracy, compared with the existing studies. The smart bolt configuration (addictively manufactured) refers to the standard bolt dimensions and integrates a metallized FBG optical fiber with a diameter of less than 0.5 mm. Then, the sensor performance was investigated through a series of routine mechanics tests and reports the force sensitivity of the designed smart bolt is 13.06 pm/kN (for M10 bolts) and 14.59 pm/kN (for M12 bolts), respectively. In dynamic force loading tests, the error of the sensor is within 4.95 %, and the maximum force detection error after temperature compensation is within 8.03 %, indicating an improved bolt force measuring accuracy. The anti-creep and anti-torque interference tests were undertaken to confirm the designed smart bolts are adequate for long-term service. The bolt vibration and connection test results have proved the mechanical solidity and reliability under extreme working conditions. This investigation confirms the viability of installing optic fiber force sensors in a bolt component. Confidence was established that the smart bolts have the advantages of compact structure, improved force detection accuracy, good reliability, and support for modern equipment in-situ health monitoring.

螺栓部件连接的微小变化都会对设备的运行安全和效率产生重大影响。全面了解螺栓连接状态有助于在现场健康监测中优化设备。因此,改进的螺栓力测量方法值得期待。鉴于光纤传感器的微创性、多参数测量的潜力以及在恶劣条件下工作的能力,光纤传感器为设备现场健康监测带来了机遇。本文首先增强了在螺栓内嵌入光纤力传感器的信心。此外,与现有研究相比,本文还采用了 FBG 温度自补偿方法,并成功提高了力测量精度。智能螺栓配置(瘾君子制造)参考了标准螺栓尺寸,并集成了直径小于 0.5 毫米的金属化 FBG 光纤。随后,通过一系列常规力学测试对传感器性能进行了研究,结果表明所设计的智能螺栓的力灵敏度分别为 13.06 pm/kN(M10 螺栓)和 14.59 pm/kN(M12 螺栓)。在动态力加载测试中,传感器的误差在 4.95 % 以内,温度补偿后的最大力检测误差在 8.03 % 以内,表明螺栓测力精度有所提高。抗蠕变和抗扭矩干扰测试证实了所设计的智能螺栓足以长期使用。螺栓振动和连接测试结果证明了其在极端工作条件下的机械稳固性和可靠性。这项调查证实了在螺栓部件中安装光纤力传感器的可行性。研究证实,智能螺栓具有结构紧凑、力检测精度高、可靠性好以及支持现代设备现场健康监测等优点。
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引用次数: 0
Exploring electrochemical kinetic behaviors and interfacial charge transfer of pure and Ni-doped ZnFe2O4 nanoparticles-based sensing nanoplatform for ultra-sensitive detection of chloramphenicol 探索基于纯 ZnFe2O4 纳米粒子和掺杂镍的 ZnFe2O4 纳米粒子的电化学动力学行为和界面电荷转移,以实现对氯霉素的超灵敏检测
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-05 DOI: 10.1016/j.sna.2024.115875

ZnFe2O4 (ZFO) nanomaterial was doped with a divalent transition metal cation of Ni2+ (NixZn1-xFe2O4, x=0, 0.2, 0.4, and 0.8) and characterized by various analytical techniques. Powder X-ray diffraction revealed the formation of a single-phase cubic spinel structure, while the stabilization of crystal structure for Ni2+-doped samples was observed. The average crystalline size, d-spacing, and lattice parameters increased with increasing in Ni2+ concentration within NixZn1-xFe2O4, due to differences in the ionic radius, the cation distribution at A-B sites, and the creation of surface oxygen vacancies within ZFO structure. From electrochemical measurements, NixZn1-xFe2O4-based electrodes showed excellent enhancements in charge transfer ability and conductivity with the highest rate constant (0.018 ms−1), the lowest peak-to-peak separation (206 mV), the lowest Rct (118 Ω), and the largest electrochemical active area (0.248 cm2), compared to that of bare SPE. Among them, Ni0.8Zn0.2Fe2O4/SPE provided outstanding electrochemical behaviors and achieved the best sensing performance with the widened concentration linear range from 0.25 to 50 μM and a rather low detection limit of 0.2 μM for chloramphenicol detection. The most important reason for this positive advance comes from the unique synergistic effects of Ni doping into the ZFO host structure. The excellent enhancements in adsorption capacity (Г) (1.4 times higher), number of oxygen vacancies, charge transfer rate constant (approximately 1.15 times higher), and catalytic rate constant (30 times greater) were recorded at Ni-doped ZFO-based electrodes, compared to pure ZFO-based electrode. Furthermore, the detailed hypotheses and possible mechanisms explaining these impressive enhancements were explored. Our work provides insight into the correlation between the Ni-doping and electrochemical characteristics, which has implications for tailoring the electrochemical performance of spinel ferrites across diverse applications and the design of novel spinel ferrite nanomaterials.

纳米 ZnFe2O4(ZFO)材料掺杂了二价过渡金属阳离子 Ni2+(NixZn1-xFe2O4,x=0、0.2、0.4 和 0.8),并通过各种分析技术对其进行了表征。粉末 X 射线衍射显示形成了单相立方尖晶石结构,同时观察到掺杂 Ni2+ 的样品晶体结构趋于稳定。随着 NixZn1-xFe2O4 中 Ni2+ 浓度的增加,平均结晶尺寸、d-间距和晶格参数也随之增加,这是由于离子半径、A-B 位点的阳离子分布以及 ZFO 结构中表面氧空位的产生造成的。从电化学测量结果来看,与裸 SPE 相比,NixZn1-xFe2O4 基电极在电荷转移能力和电导率方面都有很好的提高,具有最高的速率常数(0.018 ms-1)、最低的峰-峰分离电压(206 mV)、最低的 Rct(118 Ω)和最大的电化学活性面积(0.248 cm2)。其中,Ni0.8Zn0.2Fe2O4/SPE 具有出色的电化学性能,实现了最佳的传感性能,浓度线性范围从 0.25 μM 扩大到 50 μM,氯霉素的检测限低至 0.2 μM。取得这一积极进展的最重要原因是在 ZFO 主结构中掺入镍的独特协同效应。与纯 ZFO 基电极相比,掺杂了镍的 ZFO 基电极在吸附容量 (Г)(高出 1.4 倍)、氧空位数、电荷转移速率常数(高出约 1.15 倍)和催化速率常数(高出 30 倍)方面都有显著提高。此外,我们还探讨了解释这些令人印象深刻的增强效果的详细假设和可能机制。我们的研究深入探讨了掺镍与电化学特性之间的相关性,这对于在各种应用中定制尖晶铁氧体的电化学性能以及设计新型尖晶铁氧体纳米材料具有重要意义。
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引用次数: 0
Fabrication of dual-functional smart materials: 2D-WO3/rGO nanocomposite for electrochemical detection and photocatalytic degradation of tetracycline 制备双功能智能材料:用于电化学检测和光催化降解四环素的 2D-WO3/rGO 纳米复合材料
IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-09-05 DOI: 10.1016/j.sna.2024.115873

The extensive utilization of the antibacterial agent tetracycline (TC) in pharmaceuticals and livestock farming has sparked considerable health apprehensions for the welfare of both animals and humans. The presence of TC drug residues in soil, rivers, lakes, and groundwater further exacerbates these concerns. To address these issues, we synthesized WO3/rGO nanocomposites using a simple hydrothermal method and explored their bifunctional catalyst properties for the first time. These nanocomposites were investigated for their potential applications in electrochemical sensing and photocatalytic degradation of TC drug. The electrocatalytic oxidation of TC drug using the WO3/rGO/Glassy Carbon Electrode (GCE) nanocomposites demonstrated good sensitivity, low detection limit, low quantification limit and wide linear range of 1.708 µA µM−1 cm−2, 202 nM, 0.202 µM and 0.1–400 µM, respectively. Moreover, we assessed the WO3/rGO/GCE nanocomposites effectiveness in detecting TC drug in real samples, including milk, lake water, fish, and tap water, and found the recovery results to be satisfactory. Additionally, the nanocomposites displayed noteworthy photocatalytic activity in degrading the TC drug. The as-prepared WO3/rGO nanocomposites exhibited an impressive degradation efficiency of 87.5 % over 120 minutes under UV–visible light irradiation. Radical trapping tests confirmed that the *OH- radicals played a significant role in the degradation process. Our study highlights the outstanding electrochemical and photocatalytic properties of WO3/rGO nanocomposites, positioning them as highly promising materials for future biomedical and environmental applications.

抗菌剂四环素(TC)在医药和畜牧业中的广泛使用引发了人们对动物和人类健康的极大担忧。土壤、河流、湖泊和地下水中存在的四环素药物残留进一步加剧了这些问题。为了解决这些问题,我们采用简单的水热法合成了 WO3/rGO 纳米复合材料,并首次探索了它们的双功能催化剂特性。我们研究了这些纳米复合材料在电化学传感和 TC 药物光催化降解中的潜在应用。使用 WO3/rGO/Glassy Carbon Electrode (GCE) 纳米复合材料对 TC 药物进行电催化氧化,结果表明其灵敏度高、检出限低、定量限低且线性范围宽,分别为 1.708 µA µM-1 cm-2、202 nM、0.202 µM 和 0.1-400 µM。此外,我们还评估了 WO3/rGO/GCE 纳米复合材料在牛奶、湖水、鱼类和自来水等实际样品中检测 TC 药物的效果,结果令人满意。此外,纳米复合材料在降解 TC 药物方面也表现出了显著的光催化活性。在紫外可见光照射下,制备的 WO3/rGO 纳米复合材料在 120 分钟内的降解效率高达 87.5%,令人印象深刻。自由基捕获测试证实,*OH- 自由基在降解过程中发挥了重要作用。我们的研究凸显了 WO3/rGO 纳米复合材料出色的电化学和光催化性能,使其成为未来生物医学和环境应用中极具前景的材料。
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Sensors and Actuators A-physical
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