We demonstrate a room‑temperature, high‑fidelity, binder‑free aqueous nanoimprint process that patterns pre‑crystallized anatase titanium dioxide (TiO2) nanoparticles into subwavelength gratings without any polymeric or sol-gel precursor matrix. A perfluoropolyether (PFPE) soft mold combined with transient UV‑induced surface energy modulation enables complete cavity filling and preserves line‑edge definition during demolding, providing a low‑shrinkage and scalable alternative to resin‑ or sol–gel‑based nanoimprint. The nanoparticle‑derived TiO2 gratings furnish broadband photonic scattering and diffraction‑assisted optical path lengthening, while subsequent Au nanoparticle (AuNP) decoration introduces localized surface plasmon resonances and near‑field hotspots that couple to grating modes, jointly intensifying ultraviolet field confinement and extending responsivity into the red and near‑infrared. The AuNP-decorated device achieves a responsivity of 9.24 A/W and a detectivity of 7.83 × 1012 Jones at 365 nm, along with more than 600-fold enhancement in responsivity at 740 nm compared to the pristine TiO2 device. This water‑based, additive‑minimal route avoids high‑temperature crystallization, reduces carbon contamination risk, and is compatible with temperature‑sensitive and large‑area substrates. These results establish a manufacturable nanoparticle‑derived photonic–plasmonic platform for high‑performance broadband oxide photodetectors.
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