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Применение спектральных методов для исследования родопсина ---рецептора, сопряженного с G-белком. III. Эффект осмотического давления 使用光谱技术研究紫质——与G蛋白相关的受体。III。渗透压力效应
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.01.54549.4261-22
А.В. Струц, А В Бармасов, M. F. Brown
We review osmotic stress studies of G-protein-coupled receptor rhodopsin. Despite the established presence of small amounts of structural water in these receptors, the influence of bulk water on their function remains unknown. Investigations of osmotic stress effects on the GPCR archetype rhodopsin have provided unique data about the role of water in receptor activation. It was discovered that osmolytes shift the rhodopsin equilibrium after photoactivation, either to the active or inactive conformations depending on their molar mass. Experimentally at least 80 water molecules have been found to enter rhodopsin in the transition to the active state. We propose that this influx of water is a necessary condition for receptor activation. If the water movement is blocked, e.g., by large osmolytes or by dehydration, then the receptor does not undergo its functional transition. The results suggest a new model whereby rhodopsin becomes swollen and partially unfolded in the activation mechanism. Water thus acts as a powerful allosteric modulator of functioning for rhodopsin-like receptors.
本文综述了g蛋白偶联受体视紫红质的渗透胁迫研究。尽管这些受体中存在少量结构水,但大量水对其功能的影响尚不清楚。渗透胁迫对GPCR原型紫红质影响的研究为水在受体激活中的作用提供了独特的数据。人们发现,在光激活后,渗透细胞会将视紫红质的平衡转移到活性构象或非活性构象,这取决于它们的摩尔质量。实验发现至少有80个水分子进入视紫红质进入活性状态。我们认为水的流入是受体激活的必要条件。如果水的运动被阻断,例如,被大的渗透物或脱水,那么受体就不会经历其功能转变。结果提示了一种新的模型,即视紫红质在激活机制中肿胀和部分展开。因此,水作为视紫红质样受体功能的强大变构调节剂。
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引用次数: 0
Фотокаталитические и адсорбционные свойства нанокомпозитов ZnO/ZnAl-=SUB=-2-=/SUB=-O-=SUB=-4-=/SUB=-/Cu 纳米作曲家ZnO/ZnAl-= 2- 2 =- SUB -= 4- 4 =- SUB - c - u的光催化和吸附性能
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.03.55392.4154-22
Experimental results on photobleaching of Chicago Sky Blue diazo dye solutions using ZnO/ZnAl2O4/Cu photocatalytic nanocomposites are presented. Data on the crystal structure and morphology of these nanocomposites obtained by the polymer-salt method are presented. The results of studies of the kinetics of the processes of photobleaching of dye solutions and its adsorption on the surface of powdered nanocomposites showed that the experimental data correspond to known kinetic models using the first and second order rate equations for these processes.
介绍了用ZnO/ZnAl2O4/Cu光催化纳米复合材料对芝加哥天蓝重氮染料溶液进行光漂白的实验结果。介绍了聚合物-盐法制备的纳米复合材料的晶体结构和形貌。对染料溶液的光漂白及其在粉末纳米复合材料表面的吸附动力学进行了研究,结果表明实验数据符合已知的一阶和二阶速率方程的动力学模型。
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引用次数: 0
Новые апконверсионные объемные и нанолюминофоры на основе Sr-=SUB=-2-=/SUB=-Y-=SUB=-8-x-y-=/SUB=-Yb-=SUB=-y-=/SUB=-Tm-=SUB=-x-=/SUB=-Si-=SUB=-6-=/SUB=-O-=SUB=-26-=/SUB=- 新апконверсионнанолюминофор庞大和基于Sr - = SUB - 2 = / SUB - Y = SUB - 8 - x - Y = / SUB - Yb - = SUB - Y = / SUB - Tm = SUB - x = / SUB - Si - SUB = = / SUB - O - 6 = SUB - 26 / SUB = =
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.05.55721.55-22
Михаил Георгиевич Зуев, А.А. Васин, Владислав Генрихович Ильвес, С.Ю. Соковнин
Polycrystalline phosphors with a Sr2Y8-x-yYbyTmxSi6O26 (x=0.005-0.5, y=0.2,0.3) total formula were synthesized. Nanoluminophor has been obtained from the Sr2Y7.695Yb0.3Tm0.005Si6O26 microcrystalline sample by the vacuum electron been evaporation, in the amorphous state, with the ~10.6 nm particle size. It is found, raman spectra undergoing modification by the transition from bulk- to nanosize state. Photoluminescene spectra micro- and nanophosphors are studied. Intensity of the blue emission, by the UV ligth excitation, grows in the x=0.005-0.02 region, with the x increasing. Upconversion photoluminescence (UPCL) spectra of the bulk phosphors and nanosample based on the Sr2Y7.695Yb0.3Tm0.005Si6O26 were measurd. At the pumping power around 70.8 mW, by the laser source with the λ=980 nm, thereshold population of the 3F3 level of Tm3+ ions exist. At a power higher 70.8 mW, a sharp increase of the luminescence intensityof the bulk- and nanophosphor occurs. For the 3H4->3H6 transition thereshold pumping power absent. This indicates that, pumping, during Yb->Tm energy transer, is a single photon process.
合成了总分子式为Sr2Y8-x-yYbyTmxSi6O26 (x=0.005-0.5, y=0.2,0.3)的多晶荧光粉。采用真空电子蒸发法制备了Sr2Y7.695Yb0.3Tm0.005Si6O26微晶样品,得到了粒径为~10.6 nm的非晶态纳米发光材料。发现喇曼光谱发生了从体态到纳米态的转变。研究了微、纳米荧光粉的光致发光光谱。紫外光激发下的蓝色辐射强度在x=0.005-0.02范围内随x的增大而增大。测量了基于Sr2Y7.695Yb0.3Tm0.005Si6O26的本体荧光粉和纳米样品的上转换光致发光(UPCL)光谱。λ=980 nm的激光源在70.8 mW左右的泵浦功率下,Tm3+离子存在3F3能级的阈值居数。在70.8 mW以上的功率下,体磷光体和纳米磷光体的发光强度急剧增加。对于3H4->3H6过渡,没有阈值泵浦功率。这表明,在Yb->Tm能量传递过程中,抽运是一个单光子过程。
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引用次数: 0
Кинетика изменения оптической прозрачности нанопленок палладия при взаимодействии с водородом 钯纳米薄膜与氢相互作用时光学透明变化动力学
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.03.55393.4368-22
В.А. Шутаев, Е. А. Гребенщикова, В. А. Матвеев, Надежда Николаевна Губанова, Ю.П. Яковлев
The kinetics of changing in optical transmittance of palladium (Pd) nanolayers (about 10 nm thick, deposited on object glass substrates by thermal evaporation in vacuum) in hydrogen flow (100 vol.%) in the temperature range of 300-335 K are studied. It is shown that the rate of changing of palladium optical transmittance at hydrogen flow rises linearly with increasing the temperature due to sorption of hydrogen by Pd layer. The rate of changing in optical transmittance of Pd layer during sorption and desorption of hydrogen is established to rise by about one order with increasing the temperature from 300 to 335 K. The curves describing the changing in optical transmittance of palladium nanolayer during hydrogen desorption have two distinct sections: linear and nonlinear. The linear section of the curve weakly depends on temperature, while the nonlinear section sharply rises with increasing the temperature. Such the changing of the rate in optical transmittance can be associated with phase transition from β- to α-phase during hydrogen desorption from palladium.
研究了钯(Pd)纳米层(厚度约10 nm,通过真空热蒸发沉积在物体玻璃衬底上)在300-335 K温度范围内氢气流(100 vol.%)下的透光率变化动力学。结果表明,由于钯层对氢气的吸附作用,钯在氢气流中的透过率随温度的升高呈线性上升。在300 ~ 335 K的温度范围内,钯层在吸氢和解吸氢过程中透过率的变化率随温度的升高而升高约一个数量级。描述钯纳米层在解吸氢过程中透过率变化的曲线分为线性和非线性两部分。曲线的线性部分对温度的依赖性较弱,而非线性部分随着温度的升高而急剧上升。这种透过率的变化可能与钯脱氢过程中β-相向α-相的转变有关。
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引用次数: 0
Влияние фокусировки на нестационарное ВКР 0.3 ps лазерных импульсов в кристалле BaWO-=SUB=-4-=/SUB=- с самозаправкой ФСМ 聚焦聚焦0.3 ps激光脉冲在BaWO-= -4-= - SUB -= - SUB -自动加油的影响
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.02.55006.6-23
И. О. Киняевский, Анатолий Валериевич Корибут, И.В. Гриценко, А.М. Сагитова, М.В. Ионин, Е. Э. Дунаева, А. А. Ионин
The effect of focusing, taking into account self-focusing, on the interference of SRS (stimulated Raman scattering) and self-phase modulation in a 8-mm BaWO4 crystal pumped by laser pulses with a duration of 0.3 ps and a wavelength of 515 nm is experimentally studied. The maximum efficiency of SRS conversion (~23%) to the Stokes component of the ν1 = 925 cm–1 strongest mode is obtained with a lens with a focal length of 40 mm at the linear focus shift towards the rear facet of the crystal. The increase in efficiency, when the linear focus is shifted to the rear facet, is associated with an increase in the distance between the linear and nonlinear foci, which results in an increase in the effective length of the nonlinear interaction.
实验研究了在波长为515 nm、持续时间为0.3 ps的激光脉冲泵浦下,在考虑自聚焦的情况下,聚焦对8mm BaWO4晶体受激拉曼散射(SRS)干扰和自相位调制的影响。当透镜的焦距为40 mm时,在晶体的线性焦移处,获得了ν1 = 925 cm-1最强模式的Stokes分量的最大SRS转换效率(~23%)。当线性焦点移到后面时,效率的提高与线性和非线性焦点之间的距离增加有关,这导致非线性相互作用的有效长度增加。
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引用次数: 0
Угловые распределения и поляризационные корреляции двухфотонных сферических состояний 双光子球体状态的角分布和极化相关
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.05.55725.1027-22
Moorad Alexanian, Vanik E. Mkrtchian
Подробно проанализированы свойства угловой поляризации в центре отсчета масс системы двухфотонных сферических состояний Ландау в импульсном пространстве. Угловые распределения при фиксированных значениях J и M не зависят от четности P, а определяются двумя разными функциями полярного угла между относительным импульсом и осями квантования. Матрицы плотности двухфотонной поляризации выведены для каждого значения J, M и P. Подробно проанализированы корреляции линейной поляризации отдельных фотонов. Rроме обычных законов корреляции для J ≥ 2, выраженных через sin и cos угла между ориентациями анализаторов, найдены корреляции по сумме углов ориентаций анализаторов. Ключевые слова: двухфотонные состояния, квантовая перепутанность, четность, правила отбора, спиральность, поляризация, угловой момент, функция Вигнера, параметры Стокса.
详细分析了脉冲空间中朗道双光子球体状态基准中心角偏振的性质。固定值J和M的角分布不取决于P的相等性,而是由相对脉冲和量子化轴之间的两个不同的极角函数决定。双光子极化密度矩阵对于每个值J、M和p进行了详细分析,分析了单个光子线性极化的相关性。J . 2的常规相关定律,通过sin和cos之间的分析角表示,在分析器的方向上有相关性。关键词:双光子状态,量子交换,量子交换,选择规则,螺旋,偏振,角动量函数,维格纳函数,斯托克斯参数。
{"title":"Угловые распределения и поляризационные корреляции двухфотонных сферических состояний","authors":"Moorad Alexanian, Vanik E. Mkrtchian","doi":"10.21883/os.2023.05.55725.1027-22","DOIUrl":"https://doi.org/10.21883/os.2023.05.55725.1027-22","url":null,"abstract":"Подробно проанализированы свойства угловой поляризации в центре отсчета масс системы двухфотонных сферических состояний Ландау в импульсном пространстве. Угловые распределения при фиксированных значениях J и M не зависят от четности P, а определяются двумя разными функциями полярного угла между относительным импульсом и осями квантования. Матрицы плотности двухфотонной поляризации выведены для каждого значения J, M и P. Подробно проанализированы корреляции линейной поляризации отдельных фотонов. Rроме обычных законов корреляции для J ≥ 2, выраженных через sin и cos угла между ориентациями анализаторов, найдены корреляции по сумме углов ориентаций анализаторов. Ключевые слова: двухфотонные состояния, квантовая перепутанность, четность, правила отбора, спиральность, поляризация, угловой момент, функция Вигнера, параметры Стокса.","PeriodicalId":24059,"journal":{"name":"Оптика и спектроскопия","volume":"59 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86214198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Оптические и люминесцентные свойства керамик MgAl-=SUB=-2-=/SUB=-O-=SUB=-4-=/SUB=-, активированных ионами Eu в высокой концентрации 陶瓷MgAl- 2-= -2- O-= -4-= - SUB,由Eu高浓度激活
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.05.55709.53-22
Д. Т. Валиев, О. Л. Хасанов, Э. С. Двилис, В. Д. Пайгин, Ч. Линь, Сергей Анатольевич Степанов
The series of MgAl2O4 ceramics doped with high level of europium oxide (Eu2O3) up to 15 wt.% was fabricated by the Spark Plasma Sintering technique. The prepared ceramics have been tested using the various experimental techniques: X-ray diffraction, scanning electron microscopy, as well as optical and cathodoluminescence spectroscopy. The influence of europium oxide on the complex of optical and luminescent characteristics of MgAl2O4:Eu ceramics is discussed. The nature of the luminescence centers and the luminescence decay parameters are considered in detail.
采用火花等离子烧结技术制备了掺量高达15 wt.%的氧化铕(Eu2O3)的MgAl2O4系列陶瓷。所制备的陶瓷已经使用各种实验技术进行了测试:x射线衍射,扫描电子显微镜,以及光学和阴极发光光谱。讨论了氧化铕对MgAl2O4:Eu陶瓷光学和发光配合物特性的影响。详细讨论了发光中心的性质和发光衰减参数。
{"title":"Оптические и люминесцентные свойства керамик MgAl-=SUB=-2-=/SUB=-O-=SUB=-4-=/SUB=-, активированных ионами Eu в высокой концентрации","authors":"Д. Т. Валиев, О. Л. Хасанов, Э. С. Двилис, В. Д. Пайгин, Ч. Линь, Сергей Анатольевич Степанов","doi":"10.21883/os.2023.05.55709.53-22","DOIUrl":"https://doi.org/10.21883/os.2023.05.55709.53-22","url":null,"abstract":"The series of MgAl2O4 ceramics doped with high level of europium oxide (Eu2O3) up to 15 wt.% was fabricated by the Spark Plasma Sintering technique. The prepared ceramics have been tested using the various experimental techniques: X-ray diffraction, scanning electron microscopy, as well as optical and cathodoluminescence spectroscopy. The influence of europium oxide on the complex of optical and luminescent characteristics of MgAl2O4:Eu ceramics is discussed. The nature of the luminescence centers and the luminescence decay parameters are considered in detail.","PeriodicalId":24059,"journal":{"name":"Оптика и спектроскопия","volume":"62 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85397254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Характерные особенности низкочастотной области инфракрасных спектров и кластерная модель строения жидкостей 红外光谱低频区域和液体结构集群模型的特征
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.03.55386.4535-22
Г.А. Мельников, Н.М. Игнатенко, К. Н. Болдырев, О.А. Манжос, А.С. Громков
The results of experimental and theoretical studies of the low-frequency region of infrared spectra and Raman scattering spectra in liquid cyclic hydrocarbons (arenes) and their halogen-substituted ones are analyzed. The results of experimental studies of 13 liquids in the range 20–700 cm–1 using a high-resolution all-wavelength vacuum Fourier spectrometer (Bruker IFS 125 HR) are presented. It is shown that the appearance of spectral bands in the low-frequency region (the region of the “boson” peak) of the infrared spectra of liquids is due to the formation and decay of cluster formations in the structure of the liquid.
分析了液态环烃(芳烃)及其卤代烃红外光谱低频区和拉曼散射光谱的实验和理论研究结果。本文介绍了高分辨率全波长真空傅立叶光谱仪(Bruker IFS 125 HR)对20-700 cm-1范围内13种液体的实验研究结果。结果表明,液体红外光谱低频区(玻色子峰区域)出现谱带是由于液体结构中团簇形成和衰变所致。
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引用次数: 0
Усиление коротковолновых субаттоимпульсов в лазере нa свободных электронах при помощи электронов, ускоренных в лазерной плазме 自由电子激光器中短波次级脉冲放大,电子在激光等离子体中加速。
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.02.55002.14-23
А. А. Андреев, Л. А. Литвинов, К. Ю. Платонов
The amplification in a free-electron laser undulator of a short-wavelength subattosecond pulse formed in a laser plasma upon its interaction with a relativistic electron bunch produced by a petawatt laser is considered. The aim of this work is to find the parameters of the system at which it is possible to amplify ultrashort pulses with a duration of up to hundreds of zeptoseconds.
研究了激光等离子体中短波亚阿秒脉冲与千瓦激光产生的相对论电子束相互作用后,在自由电子激光波动器中的放大问题。这项工作的目的是找到系统的参数,在该参数下,可以放大持续时间长达数百zeptos的超短脉冲。
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引用次数: 0
Параллельная многокубитная эволюция в протоколе квантового неразрушающего взаимодействия 量子不破坏耦合协议中的平行多边形进化
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56130.4902-23
Е.Н. Башмакова, Е.А. Вашукевич, Т Ю Голубева
To date, two-qubit quantum logic gates have become an essential part of quantum computing. The study of methods for their implementation is an important practical problem for various quantum optical and information applications. In this paper, we have considered a protocol for multimode quantum non demolition interaction between an atomic ensemble and multimode light with orbital angular momentum in order to analyze the applicability of this protocol in discrete variables computing. We have developed a multimode interaction Hamiltonian and analyzed the dynamics of field and atomic variables depending on the structure of the driving field. We discuss in detail the procedure for separating qubit noninteracting subsystems on a set of atomic and field modes for various values of the orbital angular momentum of the driving field. Such a procedure helps to reduce the considered protocol to the parallel evolution of two-qubit closed systems.
迄今为止,双量子位量子逻辑门已经成为量子计算的重要组成部分。研究它们的实现方法是各种量子光学和信息应用的重要实际问题。本文考虑了原子系综与轨道角动量的多模光之间的多模量子不破坏相互作用的协议,并分析了该协议在离散变量计算中的适用性。我们建立了一个多模相互作用的哈密顿量,并根据驱动场的结构分析了场和原子变量的动力学。我们详细讨论了在不同驱动场的轨道角动量值下,在一组原子和场模式上分离量子比特非相互作用子系统的过程。该过程有助于将所考虑的协议简化为双量子位封闭系统的并行演化。
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引用次数: 0
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