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Электронное строение и оптические свойства соединений изомеров фуллерена С-=SUB=-90-=/SUB=- с хлором 富勒伦的电子结构和光学特性c -=SUB -90-= - SUB -氯化合物
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.05.55722.4702-22
А. И. Мурзашев, Нина Владимировна Мельникова, А.П. Жуманазаров, М. Ю. Кокурин, С.К. Паймеров
Within the framework of Hubbard’s model using an approximation of static fluctuations, the electronic structure and optical properties of compounds of C90 fullerene isomers with chlorine atoms are investigated. The energy spectrum of π electron subsystem is shown to be divided into several unbound electronic subsystems when the number of the attached chlorine atoms becomes greater than (or about) 30. Each of subsystems behaves like a separate system in this case. The energy spectra and optical absorption spectra of ten different chlorine compounds C90@Cln have been calculated. Their optical properties are predicted.
在Hubbard模型的框架内,使用静态波动近似,研究了氯原子C90富勒烯同分异构体化合物的电子结构和光学性质。当所附氯原子数大于(或约)30时,π电子分系统的能谱被分成若干个非束缚电子分系统。在这种情况下,每个子系统的行为就像一个独立的系统。计算了十种不同氯化合物C90@Cln的能谱和光吸收谱。预测了它们的光学性质。
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引用次数: 0
Изотопический сдвиг ИК полос поглощения монокристаллов германия 德国单晶吸收带同位素位移
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.06.55926.4334-22
Г.И. Кропотов, В.Е. Рогалин, И.А. Каплунов, А.А. Шахмин, Сергей Александрович Филин, А. Д. Буланов
A clear correspondence between the position of the peak in the IR absorption spectrum of isotopically pure germanium single crystals and the mass number of the isotope was found. The dependence obtained can be used for express analysis of the mass composition of isotopically pure germanium single crystals.
发现同位素纯锗单晶的红外吸收光谱峰的位置与同位素的质量数有明显的对应关系。所获得的依赖关系可用于同位素纯锗单晶质量组成的快速分析。
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引用次数: 0
Влияние дополнительных монопольных выбросов электронов на зарядовые спектры конечных ионов при каскадном распаде электронных вакансий в атоме золота 额外的垄断电子排放对有限离子电荷谱的影响,当黄金原子中的电子空缺级崩溃时。
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55563.4560-22
А.П. Чайников, А. Г. Кочур, А.И. Дуденко, В. А. Явна
The probabilities of the formation of final ions produced by the cascade decays of vacancies in the K, L, M, N, and O shells of the gold atom are calculated. Simulation of the cascade decays of vacancies is performed by direct construction and analysis of decay trees using branching ratios and transition energies calculated in the Pauli–Fock approximation for multivacancy electron configurations arising in the course of the cascade decay. Accounting for additional monopole ejections of electrons (shake-off) accompanying the cascade transitions leads to a slight increase in the average charges of the final ions, by 0.15–0.23e. The largest relative increase in the calculated average charges of the final ions (by 3.6–3.9%) is observed upon the cascade decay of vacancies in 4p3/2, 4d3/2, and 4d5/2 subshells, and the smallest (by 0.8%) occurs in the decay of 4f-vacancy. Despite insignificant changes in the average ion charges, the structure of the charge spectra in some cases changes noticeably enough when additional electron ejections are taken into account. It is expected that in simulation of the cascade energy reemission processes when heavy atoms are used as radiosensitizers, the effect of accounting for shake-off processes will be insignificant.
计算了金原子K、L、M、N和O层空位级联衰变产生最终离子的概率。通过直接构建和分析衰变树来模拟空位的级联衰变,并使用在Pauli-Fock近似中计算的分支比和跃迁能量来模拟在级联衰变过程中产生的多空位电子构型。考虑到伴随级联跃迁的额外单极子电子抛射(振荡)导致最终离子的平均电荷略有增加,增加了0.15-0.23e。在4p3/2、4d3/2和4d5/2亚层空位的级联衰变中,最终离子的计算平均电荷的相对增加最大(3.6-3.9%),4f空位的衰减最小(0.8%)。尽管平均离子电荷的变化微不足道,但当考虑到额外的电子喷射时,在某些情况下,电荷谱的结构发生了足够明显的变化。期望在模拟以重原子为辐射敏化剂的级联能量再发射过程时,考虑振荡过程的影响不显著。
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引用次数: 0
Особенности возбуждения частицы в одноуровневой квантовой яме предельно коротким аттосекундным импульсом 单层量子坑中粒子刺激的特征,最小的atto秒脉冲
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.01.54540.4191-22
Ростислав Михайлович Архипов, Михаил Викторович Архипов, П. А. Белов, А. В. Пахомов, Николай Николаевич Розанов
Using the solution of the time Schrödinger equation, the features of the excitation of a bound state of a particle in a one-dimensional rectangular quantum well of small depth by an extremely short light pulse are studied. The case of a shallow well with only one energy level is considered. In this case, the system is excited by an attosecond pulse whose duration is shorter than the characteristic time associated with the energy of the bound state of the particle in the well. It is shown that in this case the population of the bound state and the ionization probability are determined by the ratio of the electric area of the pulse to its atomic measure, which is inversely proportional to the well width. The calculation results showed that unipolar subcycle pulses with nonzero electric area can excite the system faster and more efficiently than bipolar pulses with zero area. The possibility of using unipolar gamma-ray pulses of zeptosecond duration for deuteron excitation is discussed, and numerical estimates of the required duration and electric area of the pulse are given.
利用时间Schrödinger方程的解,研究了极短光脉冲在小深度一维矩形量子阱中激发粒子束缚态的特征。考虑了只有一个能级的浅井的情况。在这种情况下,系统被阿秒脉冲激发,其持续时间短于与阱中粒子束缚态能量相关的特征时间。结果表明,在这种情况下,束缚态的居数和电离概率是由脉冲的电面积与其原子测量的比值决定的,该比值与阱宽度成反比。计算结果表明,具有非零电面积的单极子周期脉冲比具有零电面积的双极脉冲能更快、更有效地激励系统。讨论了利用持续时间为10秒的单极伽马射线脉冲激发氘核的可能性,并给出了所需持续时间和脉冲电面积的数值估计。
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引用次数: 0
Особенности адсорбции метиленового синего и аскорбиновой кислоты на полимерной мембране "Нафион" 亚甲基蓝和抗坏血酸在纳菲翁聚合物膜上的吸附特性
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56140.3852-23
Николай Федорович Бункин, С. Л. Тимченко, Г. Н. Фадеев, Н А Богатов, Н. А. Задорожный
Transmittance coefficient of polymer membrane "Nafion" during adsorption of methylene blue and ascorbic acid from aqueous solutions onto the membrane was investigated by infrared (IR) Fourier spectrometry. A change in the membrane color and transmittance in the IR range during swelling of the polymer in the studied solutions was found, which is associated with chemical reactions occurring in the "membrane-solution" system. It was found experimentally that the adsorption and desorption rates of distilled water, oxidized Methylene blue (Mb^+) and reduced colorless leuco-form of methylene blue (MbH^0) on the polymer membrane are close and lie within the following limits: adsorption rate 0.029-0.031 min^-1, desorption rate 0.010-0.011 min^-1. The adsorption and desorption rates of ascorbic acid from aqueous solution were 0.021 and 0.08 min^-1, respectively. During the sorption of Мethylene blue leuco-form, we detected a change in membrane color. Thus, a redox reaction occurred in the membrane. Upon prolonged drying of the membrane, due to the proton-exchange properties of the membrane, the leuco-form of methylene blue oxidized to the initial state of Mb+. This fact may indicate the manifestation of metachromatic properties of the system "Nafion - Methylene blue". The system consisting of Methylene blue adsorbed on sulfonated perfluorocarbon can be considered as a model of dehydrogenase, a biocatalyst capable of hydrogen transfer. The Nafion membrane, due to its high cationic conductivity, promotes proton transfer and thus affects the rate of redox reactions involving Methylene blue.
采用红外傅立叶光谱法研究了聚合物膜“Nafion”吸附亚甲基蓝和抗坏血酸的透过系数。研究发现,聚合物在溶液中溶胀过程中,膜的颜色和红外透射率发生了变化,这与“膜-溶液”体系中发生的化学反应有关。实验发现,蒸馏水、氧化亚甲基蓝(Mb^+)和还原无色亚甲基蓝(MbH^0)在聚合物膜上的吸附速率和解吸速率相近,均在吸附速率0.029 ~ 0.031 min^-1、解吸速率0.010 ~ 0.011 min^-1范围内。对抗坏血酸水溶液的吸附速率为0.021 min^-1,解吸速率为0.08 min^-1。在Мethylene蓝色白色形态的吸收过程中,我们检测到膜颜色的变化。因此,在膜中发生了氧化还原反应。在膜长时间干燥后,由于膜的质子交换特性,亚甲基蓝的白色形式被氧化成Mb+的初始状态。这一事实可能表明“亚甲基蓝”体系具有异色性。亚甲基蓝吸附在磺化全氟碳上的体系可以被认为是脱氢酶的一种模型,脱氢酶是一种能够转移氢的生物催化剂。Nafion膜,由于其高阳离子导电性,促进质子转移,从而影响涉及亚甲基蓝的氧化还原反应的速率。
{"title":"Особенности адсорбции метиленового синего и аскорбиновой кислоты на полимерной мембране \"Нафион\"","authors":"Николай Федорович Бункин, С. Л. Тимченко, Г. Н. Фадеев, Н А Богатов, Н. А. Задорожный","doi":"10.21883/os.2023.07.56140.3852-23","DOIUrl":"https://doi.org/10.21883/os.2023.07.56140.3852-23","url":null,"abstract":"Transmittance coefficient of polymer membrane \"Nafion\" during adsorption of methylene blue and ascorbic acid from aqueous solutions onto the membrane was investigated by infrared (IR) Fourier spectrometry. A change in the membrane color and transmittance in the IR range during swelling of the polymer in the studied solutions was found, which is associated with chemical reactions occurring in the \"membrane-solution\" system. It was found experimentally that the adsorption and desorption rates of distilled water, oxidized Methylene blue (Mb^+) and reduced colorless leuco-form of methylene blue (MbH^0) on the polymer membrane are close and lie within the following limits: adsorption rate 0.029-0.031 min^-1, desorption rate 0.010-0.011 min^-1. The adsorption and desorption rates of ascorbic acid from aqueous solution were 0.021 and 0.08 min^-1, respectively. During the sorption of Мethylene blue leuco-form, we detected a change in membrane color. Thus, a redox reaction occurred in the membrane. Upon prolonged drying of the membrane, due to the proton-exchange properties of the membrane, the leuco-form of methylene blue oxidized to the initial state of Mb+. This fact may indicate the manifestation of metachromatic properties of the system \"Nafion - Methylene blue\". The system consisting of Methylene blue adsorbed on sulfonated perfluorocarbon can be considered as a model of dehydrogenase, a biocatalyst capable of hydrogen transfer. The Nafion membrane, due to its high cationic conductivity, promotes proton transfer and thus affects the rate of redox reactions involving Methylene blue.","PeriodicalId":24059,"journal":{"name":"Оптика и спектроскопия","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75549005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Универсальные особенности проявления взаимосвязи локальной и сегментальной динамики в стеклообразных полимерах на терагерцовых частотах в инфракрасных спектрах 在特雷赫德红外光谱频率上,玻璃状聚合物中局部和分割动力学的普遍特征
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.01.54534.4323-22
В. А. Рыжов
Low-frequency IR- spectra of glassy polymers were obtained and analyzed at temperatures from 90 to 400K. Temperature changes in the IR- spectra in the range from 10 to 140 cm-1 show three universal features: low-temperature, corresponding to the torsional-vibrational motion of monomer units, high-temperature, due to the influence of primary relaxation (glass transition) and intermediate, caused by the activation of conformational mobility in chains at a temperature of β - transition. This versatility extends both to polymers with universal chain-to-chain interactions and to those with hydrogen bonds.
在90 ~ 400K的温度范围内获得了玻璃状聚合物的低频红外光谱。在10 ~ 140 cm-1范围内的红外光谱温度变化显示出三个普遍特征:低温,对应单体单元的扭转振动运动;高温,由于初级弛豫(玻璃化转变)的影响;中间,由于β -转变温度下链中构象迁移的激活而引起。这种通用性既适用于具有普遍链对链相互作用的聚合物,也适用于具有氢键的聚合物。
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引用次数: 0
Люминесцентные свойства индивидуальных центров "кремний-вакансия" в CVD-наноалмазах, выращенных на различных подложках 在不同底座上生长的CVD-纳米钻石中,硅-空位中心的发光特性
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.02.55012.21-23
Д.Г. Пастернак, Д. А. Калашников, В Леонг, К. Чиа, А.М. Ромшин, С. В. Кузнецов, А. К. Мартьянов, В. С. Седов, Л.А. Кривицкий, И. И. Власов
The application of the technique of resonant excitation of photoluminescence at low temperatures using a narrow-band tunable laser significantly expands the possibilities of spectral investigation of individual luminescent centers in nanodiamonds, even in conditions of high concentrations of such centers. In this paper, a comparative analysis of the spectral characteristics of individual Silicon-Vacancy (SiV) centers in nanodiamonds grown with a spontaneous nucleation technique on germanium and silicon substrates is carried out. Studied diamond nanoparticles have a characteristic size of 300 nm and contain large ensembles of SiV centers. It was found that during the transition from silicon substrates, which are traditionally used in the CVD synthesis of diamonds, to germanium substrates, the spectral characteristics of the photoluminescence of SiV centers almost do not change.
利用窄带可调谐激光在低温下共振激发光致发光技术的应用,大大扩展了纳米金刚石中单个发光中心的光谱研究的可能性,即使在这种中心高浓度的条件下也是如此。本文对自发成核技术在锗和硅衬底上生长的纳米金刚石中单个硅空位(SiV)中心的光谱特征进行了比较分析。所研究的金刚石纳米颗粒的特征尺寸为300 nm,并且含有大量的SiV中心。研究发现,从传统上用于CVD合成金刚石的硅衬底到锗衬底的转变过程中,SiV中心的光致发光光谱特性几乎没有变化。
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引用次数: 0
Оптические спектры фотонно-кристаллической структуры со слоями графена 石墨烯层光晶体结构光学光谱
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56131.3260-23
С. В. Елисеева, Дмитрий Игоревич Семенцов
The transformation of the graphene-containing optical spectra photonic-crystal structure with a change in the chemical potential (μ) of graphene is studied. In the period of the structure, one layer is a graphene-containing periodic medium (SiO2/Gr)n , and the second layer is assumed to be made of pure silicon. In the case of unexcited graphene (μ = 0), the absorption in the structure exceeds the reflection and transmission for frequencies outside the photonic band gaps. Within these zones, most of the incident radiation is reflected, and there is no transmission at all. As μ increases outside the band gaps, the absorption decreases in the low-frequency region, and the transmission increases the stronger, the greater μ. In a structure with an inversion defect inside the band gaps, either suppression or significant rearrangement of the defect mode takes place.
研究了含石墨烯光谱光子晶体结构随石墨烯化学势(μ)变化的变化规律。在结构周期中,一层为含石墨烯的周期介质(SiO2/Gr)n,第二层假定为纯硅。在未激发石墨烯(μ = 0)的情况下,结构中的吸收超过了光子带隙外频率的反射和透射。在这些区域内,大部分入射辐射被反射,根本没有透射。在带隙外,随着μ的增大,低频区的吸收减小,透射率增加,μ越大。在带隙内具有反转缺陷的结构中,缺陷模式发生抑制或显著重排。
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引用次数: 0
Генерация и тушение в XeCl-=SUP=-*-=/SUP=- эксимерном лазере при накачке смешанным гамма-нейтронным излучением ядерного реактора XeCl-=SUP -= - /SUP -= - eximer激光
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56129.4549-23
А. И. Миськевич
Экспериментально обнаружено снижение коэффициента усиления активной среды эксимерного лазера с ядерной накачкой на В-Х- и С-А-переходах молекулы XeCl* (308 nm, 352 nm) при накачке среды Ar-Xe-CCl4 смешанным гамма-нейтронным излучением ядерного реактора. Эффект обусловлен тушащим действием вторичных электронов, образующихся в активной среде эксимерного лазера под действием мгновенного гамма-излучения. Эффект значительно усиливается при увеличении плотности потока гамма-излучения, и коэффициент потерь может достигать значений ~10-2-2·10-2 сm-1. Ключевые слова: ядерная накачка, эксимерный лазер, гамма-излучение, тушение электронами.
实验发现,在核反应堆混合伽马中子辐射下,XeCl分子(308 nm, 352 nm)的x - x和c - a活性激光器介质增益系数下降。这种效应是由二次电子在瞬时伽马辐射下在x光激光器活性介质中产生的抑制作用引起的。随着伽马射线通量密度的增加,其影响大大增加,损失系数可能达到10-2-2·10-2 cm -1的值。关键字:核泵,x射线激光器,伽马射线,电子抑制。
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引用次数: 0
Квантовое измерение амплитуды и фазы электромагнитного поля методом оптического гомодинирования 光同位素测定振幅和电磁场相
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.03.55391.3653-22
А. В. Козловский
The possibility of measuring the amplitude and phase of the electromagnetic field by optical light homodyning is shown. A new method for determining the relative phase of the field using the interference scheme of balanced homodyne detection is proposed. The method is based on direct measurement of the average complex amplitude of a quantum field mixed with a classical field using a passive symmetric beam splitter under conditions of a balanced homodyne measurement scheme. A "direct" measurement of the average field amplitude is a direct measurement of the real and imaginary parts of the average quantum mechanical value of the complex field amplitude by homodyning. By comparison with the quantum theory of the Hermitian phase operator of the electromagnetic field, the accuracy of this measurement is estimated for various quantum states of the microscopic electromagnetic field.
给出了用光学光同差法测量电磁场振幅和相位的可能性。提出了一种利用平衡差检测干涉方案确定场相对相位的新方法。该方法是在平衡同差测量方案的条件下,利用被动对称分束器直接测量量子场与经典场混合的平均复振幅。平均场振幅的“直接”测量是用同差法直接测量复场振幅的平均量子力学值的实部和虚部。通过与电磁场厄米相算符的量子理论进行比较,估计了该测量方法在微观电磁场的各种量子态下的精度。
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引用次数: 0
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Оптика и спектроскопия
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