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Селективная лазерная спектроскопия примесных центров ионов Ho-=SUP=-3+-=/SUP=- в кристалле SrY-=SUB=-2-=/SUB=-O-=SUB=-4-=/SUB=- Ho-=SUP -3+ /SUP=- SrY- 2 = =SUB -O- 4 =- SUB
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55546.77-22
Сергей Иванович Никитин, Е.М. Куташова, Р. В. Юсупов, Р.Г. Батулин, А. Г. Киямов, Иван Энверович Мумджи, Б. З. Малкин
Detailed studies of emission and excitation spectra of impurity Ho3+ centers in the SrY2O4 single crystal performed by means of the site-selective laser spectroscopy are reported. The energy levels patterns for the 5I8, 5I7, 5I6, 5S2 and 5F4 multiplets of Ho3+ ions which substitute for the Y3+ ions at the two structurally nonequivalent sites Y1 and Y2 with the local Cs symmetry are constructed by making use of the measured spectra. These energy schemes are well described in the framework of the crystal field theory, the sets of 15 crystal field parameters are determined for Ho3+ ions at both Y1 and Y2 sites. The calculated parameters of the EPR spectra agree with the earlier published experimental data.
本文报道了用位置选择激光光谱法对SrY2O4单晶中杂质Ho3+中心的发射和激发光谱进行了详细的研究。利用实测光谱构造了在Y1和Y2两个结构不等效位置上取代Y3+的Ho3+离子的5I8、5I7、5I6、5S2和5F4多重态具有局域Cs对称的能级图。这些能量方案在晶体场理论的框架中得到了很好的描述,并在Y1和Y2两个位置确定了Ho3+离子的15个晶体场参数集。计算得到的EPR谱参数与先前发表的实验数据一致。
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引用次数: 0
Теория кристаллических полей и спектров возбуждения в Fe-=SUB=-2-=/SUB=-Mo-=SUB=-3-=/SUB=-O-=SUB=-8-=/SUB=- 在Fe-= -2-= -2-= -3-= -3-= -O-= -8-= - SUB -= - SUB -
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55551.66-22
М. В. Еремин, К. В. Васин, А. Р. Нурмухаметов
The parameters of even and odd crystal fields acting on iron ions in tetrahedral and octahedral positions of the Fe2Mo3O8 crystal are calculated. The obtained energy level schemes of the lowest multiplets are discussed in the context of the available experimental data. By comparing the calculated intensities of magnetic and electric dipole transitions with experimental data, the parameters of the effective Hamiltonian of the interaction of 3d electrons with an electric field are refined. It is found that the main absorption lines at T < TN in the region of terahertz frequencies are due to excitations of iron ions and are not associated with collective oscillations of magnetic moments. The splitting of absorption lines upon application of an external magnetic field is a consequence of the difference in the orientations of the magnetic sublattices relative to the crystallographic axes.
计算了铁离子在Fe2Mo3O8晶体四面体和八面体位置上的偶、奇晶体场参数。结合现有的实验数据,讨论了得到的最低多重态能级格式。通过将计算得到的磁偶极子和电偶极子跃迁强度与实验数据进行比较,得到了三维电子与电场相互作用的有效哈密顿量参数。在T < TN的太赫兹区,主要吸收谱线是由铁离子激发产生的,与磁矩的集体振荡无关。在外加磁场作用下吸收线的分裂是磁亚晶格相对于结晶轴取向不同的结果。
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引用次数: 0
Метод лазерной допплеровской флоуметрии в оценке влияния лираглутида на микроциркуляцию у крыс с диет-индуцированным ожирением 激光多普勒浮选法评估利尿剂对超重老鼠微循环的影响
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.06.55920.120-23
Э. Б. Попыхова, Т. Е. Пылаев, А.А. Абрамов, Ю. И. Васильев, Л. И. Высоцкий, А. В. Назарова, Э.К. Погосян
The state of the microcirculatory bed in rats with obesity caused by the "cafeteria diet" was studied using laser Doppler flowmetry during therapy with liraglutide. It has been shown that obesity causes a decrease in the perfusion index and normalized amplitudes of endothelial and neurogenic oscillations on the skin of the dorsal foot of experimental animals. Therapy with liraglutide contributed to the reduction of excess body weight and the Lee index, which resulted in the restoration of disturbed microcirculation of the skin of the dorsal foot of rats, as well as the normalization of the functional activity of target organs.
采用激光多普勒血流仪研究了利拉鲁肽治疗“自助饮食”引起的肥胖大鼠微循环床的状态。研究表明,肥胖导致实验动物足背皮肤的灌注指数和内皮和神经源性振荡的归一化幅度下降。利拉鲁肽治疗有助于减轻超重和Lee指数,从而恢复大鼠足背皮肤紊乱的微循环,并使靶器官的功能活动正常化。
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引用次数: 0
Особенности люминесценции керамики на основе кубического (ZR-=SUB=-0.82-x-=/SUB=-HF-=SUB=-x-=/SUB=-Y-=SUB=-0.17-=/SUB=-Eu-=SUB=-0.01-=/SUB=-)O-=SUB=-1.91-=/SUB=-
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.05.55713.76-22
А. А. Шакирова, Е. В. Дементьева, Т.Б. Попова, М. В. Заморянская
The ceramics based on cubic (Zr0.82-xHfxY0.17Eu0.1)O1.91 with different contents of hafnium were studied. In the work, the elemental composition of the samples was obtained, the cathodoluminescence (CL) spectra and decay kinetics of europium luminescence were studied. The researched showed increase in the content of hafnium doesn’t affect the position and number of observed bands in the luminescence spectrum. The electric dipole and magnetic dipole radiative transitions ratio was estimated for all samples. It’s demonstrated that a decrease in the local symmetry of the europium ion associated with an increase in the hafnium content. It’s shown the 5D0-7F1 transition Eu3+ decay time doesn’t depend on the hafnium content, but varies significantly in different regions of the sample, which can be attributed to the influence of grain boundaries.
研究了不同铪含量的立方(Zr0.82-xHfxY0.17Eu0.1)O1.91陶瓷。测定了样品的元素组成,研究了铕的阴极发光光谱和衰变动力学。研究表明,铪含量的增加不影响发光光谱中观测波段的位置和数目。估计了所有样品的电偶极子和磁偶极子辐射跃迁比。结果表明,铕离子局部对称性的降低与铪含量的增加有关。结果表明,5D0-7F1跃迁Eu3+衰变时间与铪含量无关,但在样品的不同区域变化明显,这可归因于晶界的影响。
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引用次数: 0
Моделирование кристаллического поля, магнитоупругих взаимодействий и случайных деформаций решетки в пирохлоре Pr-=SUB=-2-=/SUB=-Zr-=SUB=-2-=/SUB=-O-=SUB=-7-=/SUB=- 晶体场模拟、磁弹性相互作用和热氯化钾中的随机格栅变形
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55552.65-22
В.В. Клековкина, Н.М. Абишев
We present the results of simulations of the spectral and thermodynamic properties of frustrated Pr2Zr2O7 crystals using the distribution function of random strains induced by point defects in an elastically anisotropic continuum.
利用点缺陷引起的随机应变在弹性各向异性连续介质中的分布函数,对受挫Pr2Zr2O7晶体的光谱和热力学性质进行了模拟。
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引用次数: 0
Взаимодействие электромагнитной Н-волны с наноструктурой "диэлектрик-полупроводник-диэлектрик" с учетом анизотропии зонной структуры полупроводника 考虑到半导体区域结构的各向异性,电磁波与“介质-半导体-介质”纳米结构的相互作用
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56132.4865-23
Инна Александровна Кузнецова, О. В. Савенко
The problem of electromagnetic H-wave interaction with a layered "insulator-semiconductor- insulator" nanostructure is solved. We assume that the semiconductor layer thickness can be comparable to or less than the charge carrier de Broglie wavelength. Charge carrier surface scattering is taken into account by the Soffer boundary conditions. The electromagnetic wave frequency is less than the plasma resonance frequency. The constant energy surface is an ellipsoid of revolution. Analytical expressions are obtained for the reflection, transmission and absorption coefficients. Calculations are performed for the limiting cases of a degenerate and nondegenerate electron gas. We analyze the dependences of the optical coefficients on dimensionless parameters: the semiconductor layer thickness, the electromagnetic wave frequency and incidence angle, the chemical potential, the ellipticity parameter, the insulating layer permittivities, and the semiconductor-insulator interface roughness parameters.
解决了层状“绝缘体-半导体-绝缘体”纳米结构的电磁波相互作用问题。我们假设半导体层厚度可以与载流子德布罗意波长相当或小于。采用软边界条件考虑载流子表面散射。电磁波频率小于等离子体共振频率。恒能面是一个旋转椭球面。得到了反射系数、透射系数和吸收系数的解析表达式。对简并电子气和非简并电子气的极限情况进行了计算。我们分析了光学系数与无量纲参数的关系:半导体层厚度、电磁波频率和入射角、化学势、椭圆率参数、绝缘层介电常数和半导体-绝缘体界面粗糙度参数。
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引用次数: 0
Температурные характеристики люминесцирующих центров "кремний-вакансия" в алмазных частицах, синтезированных различными методами 钻石微粒中的发光发光中心的温度特征是由不同的方法合成的
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.02.54995.18-23
А.М. Ромшин, Д.Г. Пастернак, А. С. Алтахов, Р. Х. Баграмов, В. П. Филоненко, И. И. Власов
Recently, we have developed a new approach to measuring local temperatures and controlled heating using diamond particles containing luminescent “silicon-vacancy” centers (SiV). Here, in the development of this approach, the two dependencies are investigated by confocal laser spectroscopy. First, spectral characteristics of SiV-centers in diamond microparticles of various synthesis on the ambient temperature are studied. Second, the heating temperatures of diamond particles on the optical power are analyzed. The maximum temperature sensitivity of SiV-luminescence is determined for diamonds obtained at high pressures, while the maximum heating efficiency is observed for diamonds synthesized by chemical vapor deposition.
最近,我们开发了一种测量局部温度和控制加热的新方法,使用含有发光“硅空位”中心(SiV)的金刚石颗粒。在此,在此方法的发展,这两个依赖关系的研究共聚焦激光光谱学。首先,研究了不同合成方式的金刚石微粒中siv中心在室温下的光谱特征。其次,分析了金刚石颗粒的加热温度对光功率的影响。测定了高压下合成的金刚石的siv发光的最大温度灵敏度,而化学气相沉积合成的金刚石的最大加热效率。
{"title":"Температурные характеристики люминесцирующих центров \"кремний-вакансия\" в алмазных частицах, синтезированных различными методами","authors":"А.М. Ромшин, Д.Г. Пастернак, А. С. Алтахов, Р. Х. Баграмов, В. П. Филоненко, И. И. Власов","doi":"10.21883/os.2023.02.54995.18-23","DOIUrl":"https://doi.org/10.21883/os.2023.02.54995.18-23","url":null,"abstract":"Recently, we have developed a new approach to measuring local temperatures and controlled heating using diamond particles containing luminescent “silicon-vacancy” centers (SiV). Here, in the development of this approach, the two dependencies are investigated by confocal laser spectroscopy. First, spectral characteristics of SiV-centers in diamond microparticles of various synthesis on the ambient temperature are studied. Second, the heating temperatures of diamond particles on the optical power are analyzed. The maximum temperature sensitivity of SiV-luminescence is determined for diamonds obtained at high pressures, while the maximum heating efficiency is observed for diamonds synthesized by chemical vapor deposition.","PeriodicalId":24059,"journal":{"name":"Оптика и спектроскопия","volume":"34 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87078879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Спектральные проявления механизмов межмолекулярного взаимодействия модифицированных малеимидом полиэлектролитных капсул, используемых в таргетной терапии 分子间相互作用机制的光谱表现,经过修改的多电解质胶囊,用于目标疗法。
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.06.55904.117-23
И. Л. Пластун, А. А. Захаров, Анатолий Александрович Наумов
Mechanisms of intermolecular interaction between components of polyelectrolyte target delivery capsules and maleimide, which enhances the therapeutic action of the capsule, are investigated by quantum chemical modeling methods based on Density Functional Theory (DFT). Molecules of polymer polyelectrolyte capsule components - polyarginine and dextran sulfate and maleimide molecule are investigated. Based on calculation of molecular complexes structures and corresponding IR spectra with analysis of formed hydrogen bonds parameters it was revealed that there was a strong enough hydrogen bonding between maleimide and arginine, included in capsule composition. This allows us to conclude that modification of arginine with maleimide promotes stronger hydrogen bonding with amino acids contained in human body, which is confirmed by calculations, and gives the possibility of using maleimide as an "anchor" to hold the capsule in the tissue.
采用基于密度泛函理论(DFT)的量子化学建模方法,研究了聚电解质靶向递送胶囊组分与马来酰亚胺分子间相互作用的机制,从而增强了胶囊的治疗作用。研究了高分子聚电解质胶囊组分——聚精氨酸、硫酸葡聚糖和马来酰亚胺分子。通过分子配合物结构的计算和相应的红外光谱以及形成的氢键参数的分析,发现马来酰亚胺与胶囊成分中的精氨酸之间存在足够强的氢键。这使我们得出结论,用马来酰亚胺修饰精氨酸促进了与人体所含氨基酸更强的氢键,这是通过计算证实的,并提供了使用马来酰亚胺作为“锚”将胶囊固定在组织中的可能性。
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引用次数: 0
Проявление локальных колебаний в спектрах фотолюминесценыии ZnO : Fe-=SUP=-3+-=/SUP=- ZnO: Fe =SUP=-3+ /SUP=-显示局部波动
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55556.52-22
Владимир Иванович Соколов, Н. Б. Груздев, В. В. Меньшенин, А. Н. Киряков, А. Ф. Зацепин, В. А. Важенин, Г. А. Емельченко
In this paper photoluminescense spectra and EPR-signals of ZnO single crystals, doped with manganese and containing (from EPR data) uncontrolled impurity of iron, were investigated. At the temperature of 4.5 K in photoluminescense spectrum the band in energy interval of 1.55-1.8 eV (12493 – 14508 cm-1) was observed. This band contains some intensive lines; these lines are caused by Fe3+ ions (d5-configuration). The first and most intensive line at the energy of 1.79 eV corresponds to irradiative transition 4T1 (G) → 6A1 (S) in Fe3+ ions. The other peaks are electronic-vibrational structure. This structure may be caused by force interaction in deformed Fe3+ - 4O2- - cluster.
本文研究了掺杂锰和含铁杂质(根据EPR数据)的ZnO单晶的光致发光光谱和EPR信号。在光致发光光谱温度为4.5 K时,观察到能量区间为1.55 ~ 1.8 eV (12493 ~ 14508 cm-1)。这个波段包含一些密集的线;这些线是由Fe3+离子(d5结构)引起的。在能量为1.79 eV时,第一个也是最密集的谱线对应于Fe3+离子中的辐射跃迁4T1 (G)→6A1 (S)。其他峰是电子振动结构。这种结构可能是由变形的Fe3+ - 4O2-团簇中的力相互作用引起的。
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引用次数: 0
Моделирование эквивалентной передаточной функции и импульсного отклика схемы голографии Фурье для высокочастотных голограмм 高频全息图傅里叶全息图等效传递函数和脉冲响应模拟
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56127.4540-23
А. В. Павлов, А.О. Гаугель
An approach for modeling the transfer function and approximating the impulse response in the +1 diffraction order of the 4f holography scheme of the Fourier holography under usage of high-frequency holograms characterized by the presence of an inverse section of the dependence of the local diffraction efficiency on the spatial frequency in the frequency range below the frequency of equality of local amplitudes of the reference spectrum and the reference beam by the model of “Difference of Gaussians” is proposed and justified. The expediency of using, when implementing processing models that involve working only with the global maximum of the circuit response, a transfer function that is equivalent in terms of the minimum mean square error of the impulse response, as providing a more accurate approximation of the impulse response compared to the approximation of the direct transfer function, is shown. The validity of the approach is confirmed by comparing the simulation results with experimental data.
在参考光谱和参考光束的局部幅值相等的频率以下的频率范围内,局部衍射效率与空间频率的依赖关系存在逆截面,利用“差”模型对傅里叶全息的4f全息方案在+1衍射阶上的传递函数建模和脉冲响应逼近的方法提出并证明了高斯函数。在实现只涉及处理电路响应的全局最大值的处理模型时,使用与脉冲响应的最小均方误差相等的传递函数,与直接传递函数的近似相比,可以提供更准确的脉冲响应近似值,这是一种便利。将仿真结果与实验数据进行对比,验证了该方法的有效性。
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引用次数: 0
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Оптика и спектроскопия
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