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Conference Record of the Twenty Sixth IEEE Photovoltaic Specialists Conference - 1997最新文献

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23.5% efficient silicon solar cell with rear micro contacts of c-Si//spl mu/c-Si:H heterostructure 具有后微接触c-Si//spl μ /c-Si:H异质结构的23.5%高效硅太阳能电池
S. Okamoto, M. Nishida, T. Shindo, Y. Komatsu, S. Yasue, M. Kaneiwa, T. Nanmori
To obtain high efficiency silicon solar cells, we have investigated the rear heterostructure comprising a p-type single crystalline silicon (c-Si) substrate and a highly boron doped (p/sup +/) hydrogenated microcrystalline silicon (/spl mu/c-Si:H) film. This heterostructure was formed by rear micro contacts where a SiO/sub 2/ film was opened on the rear surface of the substrate. Voc was improved by an effective BSF using this heterostructure. With optimal design of finger electrode patterns, a conversion efficiency of 23.5% (AM1.5, 25/spl deg/C, 100 mW/cm/sup 2/) was obtained for a single crystalline silicon solar cell in 5/spl times/5 cm/sup 2/ area.
为了获得高效率的硅太阳能电池,我们研究了由p型单晶硅(c-Si)衬底和高硼掺杂(p/sup +/)氢化微晶硅(/spl mu/c-Si:H)薄膜组成的后部异质结构。这种异质结构是通过在衬底后表面打开SiO/ sub2 /薄膜的后微接触形成的。利用该异质结构制备的BSF有效地改善了Voc。通过手指电极图案的优化设计,在5/spl次/5 cm/sup 2/面积下,单晶硅太阳能电池的转换效率达到23.5% (AM1.5, 25/spl℃,100 mW/cm/sup 2/)。
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引用次数: 8
Effect of the irradiation temperature on the spectral response of Si solar cells 辐照温度对硅太阳能电池光谱响应的影响
J. Bourgoin
The authors describe the variation of the spectral response of LILT, Si solar cells especially designed for deep space missions irradiated with 10/sup 16/ cm/sup -2/, 1 MeV, electrons versus the temperature of irradiation in the range 80-300 K. Since the spectral response SR(/spl lambda/) is temperature dependent, the degradation is given in terms of the quantity 1-SR(/spl lambda/)/SR/sub 0/(/spl lambda/) where SR/sub 0/ is the spectral response of the unirradiated cell. These data are correlated with the changes induced by the irradiation in the short circuit current. Information on the main recombination centers introduced by the irradiation at various temperatures can then be extracted.
作者描述了深空任务专用LILT, Si太阳能电池在10/sup 16/ cm/sup -2/, 1 MeV电子辐照下的光谱响应随辐照温度在80-300 K范围内的变化。由于光谱响应SR(/spl lambda/)与温度有关,因此退化以数量1-SR(/spl lambda/)/SR/sub 0/(/spl lambda/)给出,其中SR/sub 0/是未辐照电池的光谱响应。这些数据与辐照引起的短路电流变化有关。然后可以提取在不同温度下辐照引入的主要重组中心的信息。
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引用次数: 2
Optimizing metalization patterns for yearly yield [solar cell fabrication] 优化年产量的金属化模式[太阳能电池制造]
A. Burgers, J. Eikelboom
Normally solar cells are optimized for maximum efficiency at standard test conditions. It is recognized ever more widely that cells and modules should be optimized for maximum yield at their operating conditions. The metalization pattern is one aspect of this optimization. An optimized pattern can be implemented at no cost in, for instance, the case of screen-printed solar cells, as it merely requires changing the screen printing mask. The authors demonstrate that most H-grid metalization programs can be used without any modification for optimization for yearly yield. They then use this method to optimize for both yearly yield for irradiation conditions as they occur in the Netherlands and standard test conditions. It turns out that we arrive for yearly optimization at fewer busbars and a much lower number of fingers. The total yield is improved by 1%.
通常,在标准测试条件下,太阳能电池被优化为最高效率。人们越来越广泛地认识到,电池和组件应该在其操作条件下优化以获得最大产量。金属化模式是这种优化的一个方面。例如,在丝网印刷太阳能电池的情况下,优化的图案可以免费实现,因为它只需要改变丝网印刷掩模。作者证明,大多数h网金属化方案都可以在不进行任何修改的情况下用于优化年产量。然后,他们使用这种方法来优化荷兰辐照条件和标准测试条件下的年产量。事实证明,我们在更少的母线和更少的手指数量下达到了年度优化。总产量提高了1%。
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引用次数: 6
Transport analysis for polycrystalline silicon solar cells on glass substrates
R. Brendel, R. Bergmann, B. Fischer, J. Krinke, R. Plieninger, U. Rau, J. Reiss, H. Strunk, H. Wanka, J.H. Wernel
The authors fabricate polycrystalline silicon solar cells on glass by Si deposition on solid phase crystallized seed layers and derive an effective diffusion length L/sub eff,QE/=3 /spl mu/m from quantum efficiency measurements. Three-dimensional transport modeling reveals that L/sub eff,QE/ differs from the diffusion length L/sub eff,IV/ in the diode saturation current j/sub o/=(q n/sub i//sup 2/D)/(N/sub A/ L/sub eff,IV/). Here q, n/sub i/, D, and N/sub A/ denote the elementary charge, intrinsic carrier concentration, diffusion constant and doping concentration, respectively. However, the difference is small for their polycrystalline Si solar cells. Dominant recombination in the space charge region limits the open circuit voltage to 340 mV.
通过在固相晶化种子层上沉积硅,在玻璃上制备了多晶硅太阳能电池,并通过量子效率测量得到了有效扩散长度L/sub / eff,QE/=3 /spl mu/m。三维输移模型表明,二极管饱和电流中的L/sub - eff,QE/不同于扩散长度L/sub - eff,IV/ j/sub - o/=(q n/sub - i//sup 2/D)/(n/sub - A/ L/sub - eff,IV/)。其中q、n/下标i/、D和n/下标A/分别表示基本电荷、本征载流子浓度、扩散常数和掺杂浓度。然而,对于他们的多晶硅太阳能电池来说,差别很小。空间电荷区的主导复合将开路电压限制在340 mV。
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引用次数: 11
Preparation of high-quality /spl mu/c-Si:H films by a hydrogen-radical CVD method [solar cells] 氢自由基CVD法制备高质量/spl mu/c-Si:H薄膜[太阳能电池]
L. Lo, M. Hatta, N. Andoh, H. Nagayoshi, K. Kamisako
Undoped, phosphorus-, and boron-doped microcrystalline silicon (/spl mu/c-Si:H) solar cell thin films have been prepared by using hydrogen radical chemical vapor deposition (HR-CVD) method. The relationship between deposition conditions and the structural, optical and electrical properties of /spl mu/c-Si:H films were investigated. Doped /spl mu/c-Si:H films with high conductivity and compensated material applicable to i-layers were obtained with high deposition rate. The crystalline volume fraction calculated from Raman spectrum showed a value over 0.9.
采用氢自由基化学气相沉积(HR-CVD)法制备了未掺杂、磷掺杂和硼掺杂微晶硅(/spl mu/c-Si:H)太阳电池薄膜。研究了沉积条件与/spl mu/c-Si:H薄膜结构、光学和电学性能的关系。获得了具有高电导率的掺杂/spl mu/c-Si:H薄膜和适用于i层的补偿材料,沉积速率高。拉曼光谱计算的晶体体积分数大于0.9。
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引用次数: 0
The World Photovoltaic Scale: an international reference cell calibration program 世界光伏标度:国际参考电池校准程序
Carl R. Osterwald, S. Anevsky, K. Bucher, A. Barua, P. Chaudhuri, J. Dubard, K. Emery, B. Hansen, D. King, J. Metzdorf, F. Nagamine, R. Shimokawa, Y. Wang, T. Wittchen, W. Zaaiman, A. Zastrow, J. Zhang
This paper presents an overview of the World Photovoltaic Scale (WPVS) international reference cell calibration program. The WPVS provides a scale for PV performance measurements that has been established through round-robin calibration of a group of primary reference cells and is traceable to Systeme International (SI) units. Procedures for recalibration of the reference cell group have been devised, along with procedures for admittance and calibration of new reference cells. A reference cell package has been designed that meets the unique needs of the WPVS. It is hoped that the existing WPVS group will eventually be replaced with cells of the new design that have passed an acceptance test procedure.
本文介绍了世界光伏比例尺(wpv)国际基准电池校准计划的概况。WPVS为PV性能测量提供了一个尺度,该尺度是通过一组主要参考电池的循环校准建立的,可追溯到国际系统(SI)单位。重新校准参考单元组的程序,以及新参考单元的导纳和校准程序都已制定。设计了一个参考电池包,以满足wpv的独特需求。希望现有的wpv组最终将被通过验收测试程序的新设计单元所取代。
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引用次数: 72
Growth and properties of silicon filaments for photovoltaic applications 光伏应用硅丝的生长和性能
T.F. Clszek, T. Wang
Thin silicon filaments were grown from the melt by three different methods: (a) RF-heated float-zone pedestal growth of high-purity, dislocation-free, single-crystal filaments, (b) growth of <112> axis, (111) face, dendrite filaments at high pulling rates from a supercooled melt in a quartz crucible, and (c) capillary die growth of thin-walled, small-diameter Si tube-filaments with high ratio of surface area to volume and concomitant device structure advantages. Minority-carrier lifetime /spl tau/ was used to assess the filaments. For the three growth methods listed above, values as high as 660 /spl mu/sec, 53 /spl mu/sec, and 42 /spl mu/sec were observed, respectively. Thin silicon filaments with good crystallographic perfection, grown at high speeds, may be useful as active semiconductor elements in multiple linear-concentrator-array PV systems and in other optoelectronic applications.
通过三种不同的方法从熔体中生长出薄硅细丝:(a) rf加热浮区基座生长出高纯度、无位错的单晶细丝,(b)从石英坩埚中过冷熔体中以高拉拔速率生长出轴、(111)面、枝晶细丝,以及(c)毛细管模生长出薄壁、小直径的硅管细丝,具有高表面积体积比和相应的器件结构优势。使用少数载流子寿命/spl tau/来评估细丝。对于上述三种生长方式,其值分别高达660 /spl亩/秒、53 /spl亩/秒和42 /spl亩/秒。在高速生长下,具有良好晶体结构的硅细丝可以作为有源半导体元件在多个线性聚光器阵列PV系统和其他光电应用中发挥作用。
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引用次数: 1
FTIR, EPMA, Auger, and XPS analysis of impurity precipitates in CdS films FTIR, EPMA,俄歇和XPS分析cd薄膜中的杂质沉淀
J. Webb, D. Rose, D. Niles, A. Swartzlander, M. Al‐Jassim
Impurities in cadmium sulfide (CdS) films are a concern in the fabrication of copper (indium, gallium) diselenide (CIGS) and cadmium telluride (CdTe) photovoltaic devices. Films of CdS grown using chemical bath deposition (CBD) generally yield better devices than purer CdS films grown using vacuum deposition techniques, despite the higher impurity concentrations typically observed in the CBD CdS films. In this work, we present Fourier transform infrared (FTIR), Auger, electron microprobe (EPMA), X-ray photoelectron spectroscopic (XPS), and secondary ion mass spectroscopic (SIMS) analyses of the impurities in CBD CdS films, and show that these differ as a function of substrate type and film deposition conditions. We also show that some of these impurities exist as 10/sup 2/ micron-scale precipitates.
在铜(铟,镓)二硒化(CIGS)和碲化镉(CdTe)光伏器件的制造中,硫化镉(cd)薄膜中的杂质是一个值得关注的问题。使用化学浴沉积(CBD)生长的CdS薄膜通常比使用真空沉积技术生长的纯CdS薄膜产生更好的器件,尽管在CBD CdS薄膜中通常观察到更高的杂质浓度。在这项工作中,我们对CBD CdS薄膜中的杂质进行了傅里叶变换红外(FTIR)、俄歇(Auger)、电子探针(EPMA)、x射线光电子能谱(XPS)和二次离子质谱(SIMS)分析,并表明这些杂质随衬底类型和薄膜沉积条件的不同而不同。我们还表明,其中一些杂质以10/sup /微米尺度的沉淀物存在。
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引用次数: 3
Poly-silicon thin films and solar cells prepared by rapid thermal CVD 快速热CVD制备多晶硅薄膜和太阳能电池
Yuwen Zhao, X. Jiang, Wenjing Wang, Zhongming Li, Yuan Yu, Xianbo Liao
Polycrystalline silicon (poly-Si) films (10-20 /spl mu/m) were grown from SiH/sub 2/Cl/sub 2/ or SiCl/sub 4/ by a rapid thermal chemical vapor deposition (RTCVD) technique, with a growth rate up to 100 A/s at the substrate temperature (T/sub s/) of above 1030/spl deg/C. The average grain size and carrier mobility of the films were found to be dependent on T/sub s/ and the substrate materials. By using the poly-Si film, the solar cells have been prepared on the heavily phosphorus-doped Si wafer, and the energy conversion efficiency of the best cell is 9.88% (AM 1.5G, 100 mW/cm/sup 2/, 25/spl deg/C).
采用快速热化学气相沉积(RTCVD)技术,从SiH/sub 2/Cl/sub 2/或SiCl/sub 4/中生长出10-20 μ l/ m的多晶硅(poly-Si)薄膜,在1030/spl℃以上的衬底温度(T/sub s/)下生长速率可达100 a /s。发现薄膜的平均晶粒尺寸和载流子迁移率取决于T/sub /和衬底材料。利用多晶硅薄膜在重掺磷硅片上制备了太阳能电池,最佳电池的能量转换效率为9.88% (AM 1.5G, 100 mW/cm/sup 2/, 25/spl℃)。
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引用次数: 1
3.75 MeV electron irradiation of III-V concentrator tandem cells 3.75 MeV电子辐照III-V浓缩器串联电池
V. Andreev, O.I. Chosta, V. Khvostikov, E.V. Paleeva, M. Shvarts
3.75 MeV electron irradiation of LPE-grown AlGaAs/GaAs monolithic two-terminal tandem solar cells was studied. In addition, Al/sub 0.35/Ga/sub 0.65/As and GaAs single-junction cells with various junction depths prepared to simulate the top and bottom cells of the tandems were irradiated. The cell degradation was characterized by spectral response and by illuminated current-voltage measurements. The degradation of minority-carrier diffusion length were measured on the AlGaAs and GaAs structures for optimization of the tandem solar cells.
3.75 MeV电子辐照lpe生长的AlGaAs/GaAs单片双端串联太阳能电池。此外,还制备了不同结深的Al/sub 0.35/Ga/sub 0.65/As和GaAs单结电池,模拟了串联的顶部和底部电池。通过光谱响应和照明电流-电压测量来表征细胞的降解。为了优化串联太阳能电池的结构,在AlGaAs和GaAs结构上测量了少数载流子扩散长度的退化。
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引用次数: 0
期刊
Conference Record of the Twenty Sixth IEEE Photovoltaic Specialists Conference - 1997
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