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Conference Record of the Twenty Sixth IEEE Photovoltaic Specialists Conference - 1997最新文献

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Contactless measurement of recombination lifetime in photovoltaic materials 光伏材料复合寿命的非接触测量
R. Ahrenkiel, S. Johnston
Contactless measurement of important semiconductor parameters has become a popular trend of current semiconductor technology. Here we describe an improved version of radio frequency photoconductive decay (RFPCD) operating in the ultra-high frequency (UHF) region. This work shows that the improved technique is capable of measuring samples ranging in size from submicron thin films to large silicon ingots. The UHF region is an ideal compromise for volume penetration and lifetime resolution with system response of 10 ns or less.
半导体重要参数的非接触式测量已成为当前半导体技术的发展趋势。在这里,我们描述了在超高频(UHF)区域工作的射频光导衰减(RFPCD)的改进版本。这项工作表明,改进后的技术能够测量从亚微米薄膜到大硅锭的样品。UHF区域是体积穿透和寿命分辨率的理想折衷,系统响应小于等于10ns。
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引用次数: 29
Anti-phase domain-free GaAs on Ge substrates grown by molecular beam epitaxy for space solar cell applications 应用于空间太阳能电池的分子束外延生长在Ge衬底上的反相无畴GaAs
S. Ringel, R. Sieg, S. Ting, E. Fitzgerald
Elimination of anti-phase domains (APDs), threading dislocations and uncontrolled interface diffusion are critical considerations for achieving maximum design flexibility and high efficiency in multi-bandgap III-V solar cells on Ge. In this paper, we identify critical growth steps to eliminate each of these problems and present an optimum molecular beam epitaxy (MBE) growth procedure which yields APD-free, near-dislocation-free GaAs/Ge with greatly suppressed interdiffusion in both the GaAs overlayer and Ge substrate. For solid source MBE, elimination of APDs requires a double-stepped, clean Ge surface and a prelayer consisting of a complete monolayer of either As or Ga. Correct conditions can be observed and maintained by real-time in-situ monitoring to ensure reproducibility. Initiating growth at low temperature with migration enhanced epitaxy virtually eliminates Ge diffusion into GaAs and Ga diffusion into Ge, while As diffusion into Ge is substantially suppressed.
消除反相畴(APDs)、螺纹位错和不受控制的界面扩散是实现Ge多带隙III-V太阳能电池最大设计灵活性和高效率的关键考虑因素。在本文中,我们确定了消除这些问题的关键生长步骤,并提出了一种最佳的分子束外延(MBE)生长过程,该过程可以产生无apd,近无位错的GaAs/Ge,并且大大抑制了GaAs覆盖层和Ge衬底中的相互扩散。对于固体源MBE,消除apd需要双台阶、清洁的Ge表面和由完整的单层As或Ga组成的预层。通过实时现场监测,可以观察和维持正确的条件,以确保再现性。通过迁移增强外延在低温下启动生长,实际上消除了Ge向GaAs的扩散和Ga向Ge的扩散,而As向Ge的扩散基本上受到抑制。
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引用次数: 11
Investigation of carrier lifetime instabilities in Cz-grown silicon cz生长硅中载流子寿命不稳定性的研究
J. Schmidt, A. Aberle, R. Hezel
In the literature it is well known that the low-injection bulk carrier lifetime of boron-doped Cz-grown silicon is not a constant material property but, depending on previous thermal treatments and light exposure, varies between two states corresponding to a high and a low lifetime value. The upper state is obtained by means of low-temperature annealing, while illumination degrades the lifetime towards the value of the lower state. In order to improve the understanding of this phenomenon, we performed comprehensive carrier lifetime measurements on solar- and electronic-grade boron, gallium, and phosphorus doped Cz wafers obtained from different manufacturers. Based on the experimental results, a new model is introduced which attributes the disappointingly low stable lifetimes of illuminated boron-doped Cz silicon with resistivity around 1 /spl Omega/cm to boron-oxygen pairs. From this model, simple recipes are derived which might lead to an improvement of the efficiency of commercial Cz silicon solar cells.
在文献中,众所周知,掺硼的cz生长硅的低注入散体载体寿命不是一个恒定的材料性质,而是取决于先前的热处理和光暴露,在对应于高和低寿命值的两种状态之间变化。上层状态是通过低温退火获得的,而照明使寿命向下层状态的值降低。为了提高对这一现象的理解,我们对不同制造商获得的太阳能级和电子级掺杂硼、镓和磷的Cz晶圆进行了全面的载流子寿命测量。基于实验结果,提出了一个新的模型,将电阻率约为1 /spl ω /cm的掺硼Cz硅的低稳定寿命归因于硼氧对。从这个模型中,我们得到了简单的配方,这可能会提高商用Cz硅太阳能电池的效率。
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引用次数: 212
Dry processing of mc-silicon thin-film solar cells on foreign substrates leading to 11% efficiency 在国外衬底上干加工mc-硅薄膜太阳能电池,效率达到11%
R. Ludemann, S. Schaefer, C. Schule, C. Hebling
A dry-chemical solar cell process has been developed by substituting conventional wet etching steps by reactive ion etching. The performance of mc-Si solar cells that have been made by this new technology is comparable to that of conventionally processed cells. Thin-film solar cells have been prepared by applying zone melting recrystallisation of CVD-grown, highly doped p/sup +/-Si layers, that were used as seeding layers for the growth of the active Si-layers. Graphite with two kinds of encapsulation have been used as a foreign substrate for the silicon deposition: (a) covered with conducting SiC, the graphite acts as base contact of the cells; and (b) graphite encapsulated with insulating SiC- and SiO/sub 2//SiN/SiO/sub 2/-layers (ONO) leads to solar cells on insulating foreign substrates, with front side base contact. The graphite/SiC/Si layer system was developed by ASE; ONO deposition and recrystallisation were realised at Fraunhofer ISE. Applying the authors' dry solar cell technology, conversion efficiencies up to 11% were achieved.
用反应离子刻蚀法代替传统的湿法刻蚀,提出了一种干化学太阳能电池工艺。用这种新技术制成的mc-Si太阳能电池的性能与传统处理的电池相当。利用cvd生长的高掺杂p/sup +/-Si层进行区域熔融再结晶制备了薄膜太阳能电池,并将其用作生长活性硅层的播种层。有两种封装的石墨被用作硅沉积的外源衬底:(a)覆盖有导电SiC的石墨作为电池的基极接触;(b)石墨封装绝缘SiC-和SiO/sub - 2//SiN/SiO/sub - 2/-层(ONO),使得太阳能电池在绝缘的外源衬底上,具有正面基底接触。采用ASE开发了石墨/SiC/Si层体系;ONO沉积和再结晶在弗劳恩霍夫ISE完成。应用作者的干式太阳能电池技术,转换效率可达11%。
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引用次数: 21
Tandem GaSb/InGaAsSb thermophotovoltaic cells 串联GaSb/InGaAsSb热光伏电池
V. Andreev, V. Khvostikov, V. Larionov, V. Rumyantsev, S. Sorokina, M. Shvarts, V. I. Vasil’ev, A. Vlasov
Computer modelling of a tandem thermophotovoltaic (TPV) system has been carried out. The monolithic GaSb/InGaAsSb tandem TPV devices have been designed and fabricated by LPE. The cell consists of: nGaSb (substrate); (n-p)In/sub x/Ga/sub 1-x/As/sub y/Sb/sub 1-y/ (E/sub g//spl ap/0.56 eV, bottom cell); p/sup ++/-n/sup ++/GaSb (tunnel junction); (n-p)-GaSb (top cell). External quantum yields of 80% at 800-1600 nm wavelength (top cell) and of about 75% at 1800-2100 nm (bottom cell) have been measured. V/sub OC/=0.61 V and FF=0.75 were achieved in a tandem cell at current density of 0.7 A/cm/sup 2/.
对串联热光伏(TPV)系统进行了计算机建模。采用LPE技术设计和制作了单片GaSb/InGaAsSb串联TPV器件。细胞由:nGaSb(底物)组成;(n-p)In/sub x/Ga/sub 1-x/As/sub y/Sb/sub 1-y/ (E/sub g//spl ap/0.56 eV,底部电池);p/sup ++/-n/sup ++/GaSb(隧道结);(n-p)-GaSb(上单元格)。在800-1600 nm波长处(上电池)的外量子产率为80%,在1800-2100 nm(下电池)的外量子产率约为75%。在电流密度为0.7 a /cm/sup 2/的串联电池中,V/sub OC/=0.61 V, FF=0.75。
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引用次数: 15
Effect of CdS annealing in (CdCl/sub 2/+CdS) atmosphere on CdTe cells (CdCl/sub 2/+CdS)气氛下CdS退火对CdTe电池性能的影响
Sung Chan Park, B. Han, J. Ahn, B. Ahn, Donghwan Kim
To increase grain size, solution-grown CdS films were annealed at 560/spl deg/C in a (CdCl/sub 2/+CdS) atmosphere, instead of CdCl/sub 2/ only environment. CdS was used to prevent the evaporation of CdS from the films. After 5 min annealing, the grain size increased from 10 nm to 100 nm and the surface morphology was very smooth and densely packed. The optical transmittance was greatly improved near E/sub g/, compared to that of CdS films annealed at 400/spl deg/C for 30 min in H/sub 2/. The efficiency of the CdTe solar cell was improved by fabricating with the CdS layer annealed in a (CdCl/sub 2/+CdS) atmosphere. The increase of the efficiency was mainly due to the increase of fill factor, which might be due to the decrease of defects at CdTe bulk and the CdS/CdTe interface.
为了增加晶粒尺寸,将溶液生长的CdS薄膜在(CdCl/sub 2/+CdS)气氛下(560/spl℃)退火,而不是只在CdCl/sub 2/环境下退火。cd被用来防止cd从胶片上蒸发。退火5 min后,晶粒尺寸由10 nm增大到100 nm,表面形貌光滑致密。在E/sub - g/附近,CdS薄膜的透光率比在H/sub - 2/下,在400/spl℃下退火30 min的薄膜有了很大的提高。在(CdCl/sub 2/+CdS)气氛中退火的CdS层可以提高CdTe太阳能电池的效率。效率的提高主要是由于填充因子的增加,这可能是由于CdTe本体和cd /CdTe界面缺陷的减少。
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引用次数: 1
Surface texturing using reactive ion etching for multicrystalline silicon solar cells 多晶硅太阳能电池的反应离子蚀刻表面纹理
K. Fukui, Y. Inomata, K. Shirasawa
We have developed a new surface texturing technique using a reactive ion etching (RIE) method for multicrystalline silicon (mc-Si) solar cells, which is expected to form a low reflectance surface on grains of various crystalline orientations. This surface texture has a cone shape, and aspect ratio and size of which can be easily controlled. We have optimized surface shape and emitter sheet resistance. The optimum emitter sheet resistance for RIE textured cell is higher than that for the usual cell. The high aspect ratio of the cone shape makes surface reflectance low, but the cell efficiency is not so good. There is an optimum aspect ratio because the emitter of cell with high aspect ratio surface has large saturation current and cell performance is decreased with aspect ratio. We have fabricated over 17% efficient large area (225 cm/sup 2/) mc-Si solar cell using this surface texturing technique and passivation schemes which is based on the silicon nitride film deposited by the plasma CVD method and hydrogen annealing at a high temperature.
我们开发了一种新的表面纹理技术,使用反应离子蚀刻(RIE)方法用于多晶硅(mc-Si)太阳能电池,该技术有望在各种晶体取向的颗粒上形成低反射率表面。这种表面纹理具有锥体形状,其纵横比和大小可以很容易地控制。我们优化了表面形状和射极片电阻。RIE纹理电池的最佳射极片电阻高于普通电池。锥形的高长宽比使得表面反射率较低,但电池效率不高。高长宽比表面的电池发射极具有较大的饱和电流,且电池性能随长宽比的增大而降低,因此存在最佳长宽比。采用等离子体CVD法沉积氮化硅薄膜,并在高温下进行氢退火,采用表面织构技术和钝化方案制备了效率超过17%的大面积(225 cm/sup 2/) mc-Si太阳能电池。
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引用次数: 27
Multiinterface Si solar cells with active substructures and active interfaces 具有活性子结构和活性界面的多界面硅太阳能电池
Z. T. Kuzinicki
The multiinterface concept seems allow a considerable increase of the present efficiency limit of Si solar cells. An experimental investigation of several types of multiinterface Si structures obtained, for example, by impurity implantation and adequate thermal treatment has been carried out. The most characteristic feature of the devices investigated concerns a buried amorphized substructure which is delimited at its front and back edges by a-Si/c-Si heterointerfaces. Electron microscope and X-ray studies show that these two phases are separated by a very sharp interface and a very thin c-Si transition zone with new crystalline properties. In this way, active substructures and active interfaces can be well-controlled by bandgap, defect and stress engineering. The results obtained indicate one of the possible ways towards the practical realization of improvements postulated by theory and simulations.
多界面的概念似乎允许相当大的提高目前的效率限制硅太阳能电池。实验研究了几种类型的多界面Si结构,例如通过杂质注入和适当的热处理获得的Si结构。所研究的器件最具特色的特征是埋置的非晶化子结构,其前后边缘由a- si /c-Si异质界面划分。电子显微镜和x射线研究表明,这两个相被一个非常锋利的界面和一个非常薄的c-Si过渡区分开,具有新的晶体性质。这样就可以通过带隙、缺陷和应力工程很好地控制活性子结构和活性界面。所得结果为实际实现理论和仿真所假定的改进提供了可能的途径之一。
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引用次数: 1
Thin film CdS/CdTe solar cells prepared by electrodeposition using low cost materials 采用低成本材料电沉积法制备薄膜CdS/CdTe太阳能电池
F. Álvarez, N. Di Lalla, A. Lamagna
This article describes the elaboration process of thin films for CdS/CdTe solar cells using low cost materials and a very simple process. The device structure (SnO/sub 2/:F/CdS/CdTe/Cu/Au) is deposited on coverglass substrates. The crystal structure of the films were determined by X-ray diffraction analysis. The surface morphology and microstructure of both films were subsequently characterized using a conventional scanning electron microscopy (SEM) and an atomic force microscopy (AFM). An enlargement of the grain size structure is observed after the thermal annealing. Finally, the solar cells prepared using this process exhibited a short circuit current density of J/sub sc/=18 mA/cm/sup 2/, open circuit voltage of V/sub oc/=600 mV and efficiencies above 5% under AM 1 simulated solar illumination.
本文描述了采用低成本材料和非常简单的工艺制备CdS/CdTe太阳能电池薄膜的过程。器件结构(SnO/sub 2/:F/CdS/CdTe/Cu/Au)沉积在覆盖玻璃衬底上。通过x射线衍射分析确定了薄膜的晶体结构。随后使用常规扫描电子显微镜(SEM)和原子力显微镜(AFM)对两种薄膜的表面形貌和微观结构进行了表征。热退火后晶粒尺寸结构增大。最后,该工艺制备的太阳能电池在AM 1模拟太阳光照下,短路电流密度为J/sub sc/=18 mA/cm/sup 2/,开路电压为V/sub oc/=600 mV,效率在5%以上。
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引用次数: 8
Monolithic two-junction AlGaAs/GaAs solar cells 单片双结AlGaAs/GaAs太阳能电池
V. Andreev, V. Khvostikov, V. Rumyantsev, E. V. Paleeva, M. Shvarts
Monolithic two-junction two-terminal AlGaAs/GaAs solar cells were grown during two-stage liquid phase epitaxy. At the first stage the GaAs-based bottom subcell with a tunnel junction was grown on n-GaAs(Sn) substrate. Test samples of such a cell without layers of the tunnel junction and with thin enough p-Al/sub 0.9/Ga/sub 0.1/As window layer demonstrated the efficiencies of 27.5% (AM1.5D, 140 Suns) and of about 25% (AM1.5D, 1000-1500 Suns). At the second stage, the top AlGaAs subcell was grown. The following parameters have been measured in tandems: V/sub OC/=2.53 V, FF=0.80 at 50 Suns (AM0). An efficiency of 20.3% (AM0) has been achieved.
采用两级液相外延法生长了单片双结双端AlGaAs/GaAs太阳能电池。第一阶段在n-GaAs(Sn)衬底上生长具有隧道结的gaas基底亚电池。这种电池的测试样品没有隧道结层,有足够薄的p-Al/sub 0.9/Ga/sub 0.1/As窗口层,效率为27.5% (AM1.5D, 140个太阳),约为25% (AM1.5D, 1000-1500个太阳)。第二阶段,生长顶端AlGaAs亚细胞。以下参数已被串联测量:V/sub OC/=2.53 V, FF=0.80在50太阳(AM0)。效率达到20.3% (AM0)。
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引用次数: 4
期刊
Conference Record of the Twenty Sixth IEEE Photovoltaic Specialists Conference - 1997
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