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Ignition delay time measurements and kinetic modeling for n-dodecane and methane blends at low-to-intermediate temperature conditions 正十二烷和甲烷混合物在中低温条件下的点火延迟时间测量和动力学建模
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-31 DOI: 10.1016/j.combustflame.2024.113527
Zhaoming Mai , Yingtao Wu , Chenglong Tang , Haibao Mu , Wei Wang , Zuohua Huang

In this study, novel ignition delay times (IDTs) were experimentally measured for the n-dodecane/methane binary mixture with various n-dodecane content at the range of 5–20 bar and 600–1000 K, utilizing a heated rapid compression machine (RCM). Subsequently, a chemical kinetic model was developed for n-dodecane/methane binary mixture and widely validated by the experimental data including ignition delay times, laminar flame speeds, and speciation evolution in this study and the literature. The present model shows good predictive performance and was further applied in the kinetic analysis of the n-dodecane/methane binary mixture ignition characteristic. The results highlight a significant reactivity-promoting effect on the IDTs with the addition of n-dodecane through the low-temperature oxidation processes. This promoting effect is nonlinear and particularly notable in the NTC region. Additionally, the dilution gas component significantly influences the total IDTs at low-to-intermediate temperature conditions but shows less impact on the first-stage IDTs. The chemical effect of the dilution gas is minor at low-temperature conditions, while the thermodynamic effect plays a more important role in influencing the IDTs of the binary mixture.

本研究利用加热快速压缩机(RCM),在 5-20 巴和 600-1000 K 的温度范围内,对不同正十二烷含量的正十二烷/甲烷二元混合物进行了新的点火延迟时间(IDT)实验测量。随后,针对正十二烷/甲烷二元混合物建立了化学动力学模型,并通过本研究和文献中的实验数据(包括点火延迟时间、层流火焰速度和物种演变)进行了广泛验证。本模型显示出良好的预测性能,并被进一步应用于正十二烷/甲烷二元混合物点火特性的动力学分析。结果表明,通过低温氧化过程,正十二烷的加入对 IDTs 的反应活性有明显的促进作用。这种促进作用是非线性的,在 NTC 区域尤为明显。此外,稀释气体成分对中低温条件下的总 IDT 有显著影响,但对第一阶段 IDT 的影响较小。在低温条件下,稀释气体的化学效应较小,而热力学效应在影响二元混合物的 IDT 方面发挥着更重要的作用。
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引用次数: 0
Laminar flame speeds of supercritical CO2 diluted oxy-syngas and oxy-methane flames under direct-fired power cycle relevant conditions 直接燃烧发电循环相关条件下超临界二氧化碳稀释富氧合成气和富氧甲烷火焰的层流速度
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-31 DOI: 10.1016/j.combustflame.2024.113526
Yakun Zhang, Zifeng Weng, Rémy Mével

The propagation of laminar oxy-syngas and oxy-methane flames diluted by supercritical carbon dioxide was numerically simulated for the planar flame configuration under the conditions related to the operation of oxy-combustor in the direct-fired power cycle. Because of the extremely high pressure typically used for such an application, real fluid models were considered for the equation of state, thermodynamic functions, transport properties, as well as the mass action law. Numerical results show that the relative uncertainty on the flame speed caused by real gas effects and by different chemical mechanisms can be on the same order of magnitude for oxy-syngas combustion. For oxy-methane combustion, the deviation of the flame speed between the predictions of different mechanisms is much more significant than that caused by real gas effects. The effects of various non-ideal effects were explored progressively. Including the real gas equation of state and thermodynamic functions reduces the adiabatic flame temperature, and thus the flame speed is decreased. Adopting transport properties of real gas and including revisions on the mass action law and equilibrium constant would both increase the flame speed. Inhibition and promotion of flame propagation resulting from the effects of inter-molecular attraction and finite molecular volume were also identified and analyzed.

Novelty and Significance Statement

1. Supercritical laminar flame speed was systematically simulated with complete real gas model to quantify the non-ideal effects under direct-fired power cycle relevant conditions.

2. The individual impact of components in the real gas model on the flame speed were determined and represented with key parameters.

3. The uncertainties on laminar flame speed caused by reaction mechanism and real gas effects were compared and found to be on the same order of magnitude under certain conditions.

在直燃发电循环中氧燃烧器运行的相关条件下,对平面火焰配置中被超临界二氧化碳稀释的层状全氧-合成气和全氧-甲烷火焰的传播进行了数值模拟。由于此类应用通常使用极高的压力,因此考虑了真实流体模型的状态方程、热力学函数、传输特性以及质量作用定律。数值结果表明,对于全氧ngas 燃烧,真实气体效应和不同化学机制对火焰速度造成的相对不确定性在数量级上是相同的。对于甲烷全氧燃烧,不同机理预测的火焰速度偏差比实际气体效应造成的偏差要大得多。我们逐步探索了各种非理想效应的影响。加入真实气体状态方程和热力学函数会降低绝热火焰温度,从而降低火焰速度。采用真实气体的输运特性以及对质量作用定律和平衡常数的修正都会提高火焰速度。此外,还确定并分析了分子间吸引力和有限分子体积效应对火焰传播的抑制和促进作用。
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引用次数: 0
A parsimonious system of ordinary differential equations for the response modeling of turbulent swirled flames 用于湍流漩涡火焰响应建模的常微分方程解析系统
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-30 DOI: 10.1016/j.combustflame.2024.113408
Gregor Doehner, Alexander J. Eder, Camilo F. Silva

In this work, we present a parsimonious set of ordinary differential equations (ODEs), describing with good precision and over a wide range of frequencies the linear and nonlinear dynamics of different types of fully premixed, turbulent, swirl-stabilized flames. This phenomenological model comprises eight ODEs and can physically be interpreted as a superposition of two mass–spring–damper systems.

The model is characterized by 11 parameters and one nonlinear term of structure βx2ẋ in particular, with position x and rate of displacement ẋ of a given oscillator mass. The model can be optimized in frequency domain or in time domain. The former is suitable for situations where experimental data of the flame transfer function (FTF) and flame describing function (FDF) are available. The latter is suitable for situations where time series (input and output) from numerical simulations or experiments are available. In the present work, large eddy simulation (LES) data is used.

Choosing a model comprising ODEs enables us to describe the dynamics of the flame using linear and nonlinear input-to-output transformations via the states. This is a sharp contrast to commonly applied finite impulse response (FIR) models, which can only directly employ nonlinear functions acting on the input or output — not on derivatives or other states of the underlying dynamical system. We demonstrate the simplicity of implementing our model by investigating the coupling of a time-domain acoustic solver with the set of ODEs proposed, all within the graphical interface of Simulink. The x2ẋ nonlinearity plays a crucial role in achieving good agreement in the nonlinear regime, as observed in the FDF, as well as in both the amplitude and frequency of the investigated limit cycle, which exhibits a simple period-one oscillation. However, there is still room for improvement in the nonlinear model if more complex dynamics need to be modeled, thanks to the flexible ODE structure proposed in this work.

Novelty and significance

A phenomenological model, characterized by a parsimonious set of ordinary differential equations is presented. This model is able to describe the dynamic flame response of typical turbulent, swirl-stabilized flames to acoustic disturbances in their linear and nonlinear regime. The model can be calibrated from broadband time series data or reference frequency domain data. After calibration, the model can be coupled to an acoustic network to predict the occurrence of limit cycle

在这项工作中,我们提出了一套简明的常微分方程(ODEs),在很宽的频率范围内精确地描述了不同类型的完全预混、湍流、漩涡稳定火焰的线性和非线性动力学。这一现象学模型由八个 ODE 组成,在物理上可以解释为两个质量-弹簧-阻尼系统的叠加。
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引用次数: 0
Plasma-assisted NH3/air flame: Simultaneous LIF measurements of O and OH 等离子体辅助 NH3/空气火焰:同时测量 O 和 OH 的 LIF
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-30 DOI: 10.1016/j.combustflame.2024.113529
Jinguo Sun, Yupan Bao, Jonas Ravelid, Alexander A. Konnov, Andreas Ehn

In the emerging field of plasma-assisted ammonia (NH3) combustion, the evolution of key intermediate species has rarely been reported. This work establishes a simultaneous measurement system of laser-induced fluorescence (LIF) for hydroxyl (OH) and quantitative two-photon-absorption LIF for atomic oxygen (O), to explore the OH and O dynamics in an NH3/air flame affected by a nanosecond (ns) pulsed plasma discharge. Firstly, with the plasma on, the molar fraction of O is quantified to reach 8.7 × 10–3 in the burnt zone, about two orders of magnitude higher than that without plasma. In addition, the OH LIF signal intensity is four times higher, indicating a significant kinetic enhancement. Then, the spatial characteristics of OH and O are discussed and compared, showing remarkable discrepancy. The discrepancy between them indicates that O production is dominated by plasma kinetics, however, the OH production, primarily stemming from reactions between O and NH3/H2O, still depends on parameters associated with combustion kinetics. We further study the temporal dynamics of O and OH. It is concluded that O and OH peaks at 1.75 μs are mainly attributed to the pathway of quenching of the excited species. After that, O and OH start to decay but show significant differences between unburnt and burnt zones, which are characterized by a single-exponential decay and a bi-exponential decay, respectively. In the unburnt zone, the OH decay is much slower than the O decay due to the diverse pathways for OH production. In the burnt zone, the bi-exponential decay of O and OH can essentially be regarded as a process in which the NH3/air reactive system reaches chemical equilibrium. At this stage, the impacts of the excited species from the plasma gradually diminish and combustion kinetics dominates alone.

在等离子体辅助氨(NH)燃烧这一新兴领域,很少有关于关键中间物种演变的报道。这项研究建立了一个同时测量羟基(OH)激光诱导荧光(LIF)和原子氧(O)定量双光子吸收 LIF 的系统,以探索纳秒(ns)脉冲等离子体放电影响的 NH/ 空气火焰中羟基和 O 的动态。首先,在等离子体开启的情况下,灼烧区中 O 的摩尔分数达到 8.7 × 10,比未开启等离子体时高两个数量级。此外,OH LIF 信号强度高出四倍,表明动力学增强效果显著。然后,对 OH 和 O 的空间特征进行了讨论和比较,结果显示两者之间存在显著差异。它们之间的差异表明,O 的产生主要受等离子体动力学的支配,而主要来自 O 和 NH/HO 反应的 OH 的产生仍然取决于与燃烧动力学相关的参数。我们进一步研究了 O 和 OH 的时间动态。结论是,1.75 μs 时的 O 和 OH 峰值主要归因于激发物种的淬火途径。此后,O 和 OH 开始衰减,但在未燃烧区和燃烧区之间存在显著差异,分别表现为单指数衰减和双指数衰减。在未燃烧区,由于产生 OH 的途径不同,OH 的衰减比 O 的衰减慢得多。在燃烧区,O 和 OH 的双指数衰减基本上可以看作是 NH/空气反应系统达到化学平衡的过程。在这个阶段,来自等离子体的激发物种的影响逐渐减弱,燃烧动力学单独占据主导地位。
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引用次数: 0
Numerical determination of iron dust laminar flame speeds with the counter-flow twin-flame technique 利用逆流双火焰技术对铁屑层流火焰速度进行数值测定
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-29 DOI: 10.1016/j.combustflame.2024.113524
C.E.A.G van Gool, T. Hazenberg, J.A. van Oijen, L.P.H. de Goey

Iron dust counter-flow flames have been studied with the low-Mach-number combustion approximation. The model considers full coupling between the two phases, including particle/droplet drag. The dispersed phase flow strain relations are derived in the Stokes regime (Reynolds number much smaller than unity). The importance of solving a particle flow strain model is demonstrated by comparing three different cases: a free unstrained flame, a counter-flow flame where slip effects are neglected and a counter-flow flame where slip effects are included. All three cases show preferential diffusion effects, due to the lack of diffusion of iron in the fuel mixture, e.g. DFe,m= 0. The preferential diffusion effect causes a peak in the fuel equivalence ratio in the preheat zone. On the burned side, the combined effect of strain and preferential diffusion shows a decrease in fuel equivalence ratio. Inertia effects, which are only at play in the counter-flow case with slip, counteract this effect and result in an increase of the fuel equivalence ratio on the burned side. A laminar flame speed analysis is performed and a recommendation is given on how to experimentally determine the flame speed in a counter-flow set-up.

Novelty & Significance

We introduce a novel model to include particle flow strain in a dispersed counter-flow set-up. For the first time, the impact of particle flow strain on the flame structure of iron dust is studied with a one-dimensional (1D) model. Two major effects that modify the flame structure and burning velocity are identified: preferential diffusion and inertia of the particles. Preferential diffusion effects are found to be always present in (iron) dust flames. Inertia effects play a role in the counter-flow case with slip. Due to the inertia of the particles, the particle flow strain is lower than the gas flow strain. As a consequence, higher particle concentrations are reached compared to the other cases. Furthermore, it is shown that each particle size experiences a different particle flow strain rate, which is important when doing experiments as it implies that the PSD at the flame front will be different than at the inlet.

采用低马赫数燃烧近似法研究了铁屑逆流火焰。该模型考虑了两相之间的完全耦合,包括颗粒/液滴阻力。在斯托克斯体系(雷诺数远小于一)中推导出了分散相流动应变关系。通过比较以下三种不同情况,证明了求解粒子流应变模型的重要性:自由无约束火焰、忽略滑移效应的逆流火焰和包含滑移效应的逆流火焰。由于燃料混合物(如 0)中缺乏铁的扩散,所有三种情况都显示出优先扩散效应。在燃烧侧,应变和优先扩散的综合效应导致燃料等价比下降。只有在有滑移的逆流情况下才会产生的惯性效应抵消了这一效应,并导致燃烧侧的燃料等价比增加。对层流火焰速度进行了分析,并就如何通过实验确定逆流装置中的火焰速度提出了建议。
{"title":"Numerical determination of iron dust laminar flame speeds with the counter-flow twin-flame technique","authors":"C.E.A.G van Gool,&nbsp;T. Hazenberg,&nbsp;J.A. van Oijen,&nbsp;L.P.H. de Goey","doi":"10.1016/j.combustflame.2024.113524","DOIUrl":"10.1016/j.combustflame.2024.113524","url":null,"abstract":"<div><p>Iron dust counter-flow flames have been studied with the low-Mach-number combustion approximation. The model considers full coupling between the two phases, including particle/droplet drag. The dispersed phase flow strain relations are derived in the Stokes regime (Reynolds number much smaller than unity). The importance of solving a particle flow strain model is demonstrated by comparing three different cases: a free unstrained flame, a counter-flow flame where slip effects are neglected and a counter-flow flame where slip effects are included. All three cases show preferential diffusion effects, due to the lack of diffusion of iron in the fuel mixture, e.g. <span><math><mrow><msub><mrow><mi>D</mi></mrow><mrow><mi>Fe</mi><mo>,</mo><mi>m</mi></mrow></msub><mo>=</mo></mrow></math></span> 0. The preferential diffusion effect causes a peak in the fuel equivalence ratio in the preheat zone. On the burned side, the combined effect of strain and preferential diffusion shows a decrease in fuel equivalence ratio. Inertia effects, which are only at play in the counter-flow case with slip, counteract this effect and result in an increase of the fuel equivalence ratio on the burned side. A laminar flame speed analysis is performed and a recommendation is given on how to experimentally determine the flame speed in a counter-flow set-up.</p><p><strong>Novelty &amp; Significance</strong></p><p>We introduce a novel model to include particle flow strain in a dispersed counter-flow set-up. For the first time, the impact of particle flow strain on the flame structure of iron dust is studied with a one-dimensional (1D) model. Two major effects that modify the flame structure and burning velocity are identified: preferential diffusion and inertia of the particles. Preferential diffusion effects are found to be always present in (iron) dust flames. Inertia effects play a role in the counter-flow case with slip. Due to the inertia of the particles, the particle flow strain is lower than the gas flow strain. As a consequence, higher particle concentrations are reached compared to the other cases. Furthermore, it is shown that each particle size experiences a different particle flow strain rate, which is important when doing experiments as it implies that the PSD at the flame front will be different than at the inlet.</p></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0010218024002335/pdfft?md5=58e1345c91405220bb1beaa13456d8c6&pid=1-s2.0-S0010218024002335-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141194245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Ignition delay time measurements of diesel and gasoline blends” [Combust. Flame 222 (2020) 460-475] 柴油和汽油混合燃料的点火延迟时间测量"[Combust. Flame 222 (2020) 460-475] 更正
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-25 DOI: 10.1016/j.combustflame.2024.113523
Mohammed Alabbad , Yang Li , Khalid Aljohani , Gavin Kenny , Khaiyom Hakimov , Moaz Al-lehaibi , Abdul-Hamid Emwas , Patrick Meier , Jihad Badra , Henry Curran , Aamir Farooq
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引用次数: 0
Corrigendum to “A comprehensive experimental and modeling study of n-propylcyclohexane oxidation” [Combust. Flame 238 (2022) 111944] 正丙基环己烷氧化的综合实验和模型研究"[Combust. Flame 238 (2022) 111944]更正
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-25 DOI: 10.1016/j.combustflame.2024.113521
Mingxia Liu , Ruozhou Fang , Chih-Jen Sung , Khalid Aljohani , Aamir Farooq , Yousef Almarzooq , Olivier Mathieu , Eric L. Petersen , Philippe Dagaut , Jie Zhao , Zhiping Tao , Lijun Yang , Chong-Wen Zhou
{"title":"Corrigendum to “A comprehensive experimental and modeling study of n-propylcyclohexane oxidation” [Combust. Flame 238 (2022) 111944]","authors":"Mingxia Liu ,&nbsp;Ruozhou Fang ,&nbsp;Chih-Jen Sung ,&nbsp;Khalid Aljohani ,&nbsp;Aamir Farooq ,&nbsp;Yousef Almarzooq ,&nbsp;Olivier Mathieu ,&nbsp;Eric L. Petersen ,&nbsp;Philippe Dagaut ,&nbsp;Jie Zhao ,&nbsp;Zhiping Tao ,&nbsp;Lijun Yang ,&nbsp;Chong-Wen Zhou","doi":"10.1016/j.combustflame.2024.113521","DOIUrl":"https://doi.org/10.1016/j.combustflame.2024.113521","url":null,"abstract":"","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S001021802400230X/pdfft?md5=f5e402eb04b5a1ef9474e9e9b1d67513&pid=1-s2.0-S001021802400230X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141094919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Reaction kinetics for high pressure hydrogen oxy-combustion in the presence of high levels of H2O and CO2” [Combust. Flame 247 (2023) 112498] 对 "高压氢氧燃烧在高浓度 H2O 和 CO2 存在下的反应动力学"[Combust. Flame 247 (2023) 112498]的更正
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-25 DOI: 10.1016/j.combustflame.2024.113520
Ashkan Beigzadeh , Mohammed Alabbad , Dapeng Liu , Khalid Aljohani , Khaiyom Hakimov , Touqeer Anwar Kashif , Kourosh Zanganeh , Eric Croiset , Aamir Farooq
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引用次数: 0
Experimental study on flame height and radiation characteristics in jet flames with ammonia/hydrocarbon mixture fuels 氨/烃混合燃料喷射火焰的火焰高度和辐射特性实验研究
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-24 DOI: 10.1016/j.combustflame.2024.113517
Jingru Zheng , Xiaolei Zhang , Suk Ho Chung , Longhua Hu

Ammonia is considered as a renewable fuel and expected to play an essential role in coping with the energy crisis and climate change. Because of low combustion rate and high NO emission of ammonia, many studies focused on the characteristics of ammonia/hydrocarbon mixture fuels. However, the flame height and radiation characteristics of jet flames of ammonia and hydrocarbon mixture fuels have not been systematically studied yet. In this work, hydrocarbon fuels of methane and ethylene are mixed with ammonia for the fuel mixing ratio in the range of 0 to 50 %. Results show that the flame height increases with heat release rate (HRR) but changes little with the concentration of ammonia. The previous physical models for turbulent jet flames based on an integral approach can basically predict the flame height for heat release rate larger than 2.7 kW and a semi empirical formula based on dimensional analysis is verified well in predicting the flame height with the flame Froude number for Frf > 0.05. For laminar flame heights, a model is proposed here considering the buoyancy effect which predicts well for CH4/NH3 flame with total flow rate smaller than 5 L/min. For thermal radiation characteristics, the radiation fraction decreases with the ammonia mixing ratio increases. A consistent transitional value in predicting the radiation fraction is observed, irrespective of fuel type, which is mainly due to the reduction of soot during the transition from laminar to turbulent flames. The influence of ammonia on the flame radiation fraction of CH4/NH3 flames normalized by that of pure hydrocarbon fuel (χR/χR0) can be correlated by the mixing ratio. For C2H4/NH3 flames, the influence of ammonia on the dimensionless radiation fraction is the result of the coupling effect of mixing fraction and strain rate. A correlation is proposed considering the effects of ammonia addition on radiation fraction in relation to Reynolds number, which is shown to correlate well the experimental results.

Novelty and significance statement

As ammonia/hydrocarbon fuel mixtures can reduce the emission of carbon dioxide, it can play an essential role during the transition to a non-carbonization society. Considering a fundamental importance of jet flames and a fire hazard scenario in case of fuel leakage, the present study investigates the effect of ammonia addition on the flame height and flame radiation fraction for ammonia/hydrocarbon fuel mixtures. We test the physical model of Quintiere and a semi empirical formula of Delichatsios in predicting the turbulent flame height of ammonia/hydrocarbon mixture fuels. A normalized model is proposed to describe the effect of adding ammonia on radiation fraction in relation to the Reynolds

氨被认为是一种可再生燃料,有望在应对能源危机和气候变化方面发挥重要作用。由于氨的燃烧率低、氮氧化物排放量高,许多研究都集中在氨/烃混合燃料的特性上。然而,氨和碳氢化合物混合燃料喷射火焰的火焰高度和辐射特性尚未得到系统研究。在这项研究中,甲烷和乙烯等碳氢化合物燃料与氨混合,燃料混合比范围为 0% 至 50%。结果表明,火焰高度随热释放率(HRR)的增加而增加,但随氨浓度的增加而变化不大。之前基于积分法的湍流喷射火焰物理模型基本上可以预测热释放率大于 2.7 kW 时的火焰高度,而基于尺寸分析的半经验公式在预测 Frf > 0.05 时火焰高度与火焰 Froude 数的关系时得到了很好的验证。对于层流火焰高度,本文提出了一个考虑浮力效应的模型,该模型能很好地预测总流量小于 5 L/min 的 CH4/NH3 火焰。在热辐射特性方面,随着氨气混合比的增加,辐射分数也在减少。无论燃料类型如何,在预测辐射分数时都观察到一个一致的过渡值,这主要是由于从层流火焰过渡到湍流火焰时烟尘的减少。氨对 CH4/NH3 火焰辐射率的影响(χR/χR0)与纯碳氢化合物燃料的火焰辐射率(χR/χR0)归一化,可以用混合比来表示。对于 C2H4/NH3 火焰,氨对无量纲辐射分数的影响是混合分数和应变率耦合效应的结果。由于氨/烃燃料混合物可以减少二氧化碳的排放,因此在向非碳化社会过渡的过程中可以发挥重要作用。考虑到喷射火焰的基本重要性和燃料泄漏时的火灾危险情景,本研究调查了氨添加量对氨/烃燃料混合物火焰高度和火焰辐射率的影响。我们测试了 Quintiere 的物理模型和 Delichatsios 的半经验公式在预测氨/烃混合物燃料湍流火焰高度方面的作用。我们提出了一个归一化模型来描述添加氨对辐射率的影响与雷诺数的关系。我们的研究结果为进一步研究氨/烃混合燃料火焰提供了必要的实验数据和模型。
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引用次数: 0
Corrigendum to “Ignition delay time and speciation of dibutyl ether at high pressures” [Combust. Flame 223 (2021) 98-109] 对 "高压下二丁基醚的点火延迟时间和标本 "的更正[Combust. Flame 223 (2021) 98-109]
IF 4.4 2区 工程技术 Q1 Physics and Astronomy Pub Date : 2024-05-24 DOI: 10.1016/j.combustflame.2024.113522
Khaiyom Hakimov , Farhan Arafin , Khalid Aljohani , Khalil Djebbi , Erik Ninnemann , Subith S. Vasu , Aamir Farooq
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引用次数: 0
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Combustion and Flame
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