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Multi-trigger resist for electron beam lithography 电子束光刻用多触发抗蚀剂
Pub Date : 2017-09-28 DOI: 10.1117/12.2279767
C. Popescu, A. McClelland, G. Dawson, J. Roth, D. Kazazis, Y. Ekinci, W. Theis, A. Robinson
Irresistible Materials is developing a new molecular resist system that demonstrates high-resolution capability based on the Multi-trigger concept. In a Multi-Trigger resist, multiple distinct chemical reactions in chemical amplification process must take place in close proximity simultaneously during resist exposure. Thus, at the edge of a pattern feature, where the density of photo-initiators that drive the chemical reactions is low, the amplification process ceases. This significantly reduces blurring effects and enables much improved resolution and line edge roughness while maintaining the sensitivity advantages of chemical amplification. A series of studies such as enhanced resist crosslinking, elimination of the nucleophilic quencher and the addition of high-Z additives to e-beam resist (as a means to increase sensitivity and modify secondary electron blur) were conducted in order to optimize the performance of this material. The optimized conditions allowed patterning down to 28 nm pitch lines with a dose of 248 μC/cm2 using 100kV e-beam lithography, demonstrating the potential of the concept. Furthermore, it was possible to pattern 26 nm diameter pillars on a 60 nm pitch with dose of 221μC/cm2 with a line edge roughness of 2.3 nm.
不可抗拒材料公司正在开发一种基于多触发器概念的新型分子抗蚀剂系统,该系统具有高分辨率能力。在多触发抗蚀剂中,化学放大过程中的多个不同化学反应必须在抗蚀剂暴露过程中近距离同时发生。因此,在图案特征的边缘,驱动化学反应的光引发剂密度较低,放大过程停止。这大大减少了模糊效果,并使分辨率和线边缘粗糙度大大提高,同时保持了化学放大的灵敏度优势。为了优化该材料的性能,进行了增强抗蚀剂交联、消除亲核猝灭剂以及在电子束抗蚀剂中添加高z添加剂(作为提高灵敏度和修正二次电子模糊的手段)等一系列研究。在优化的条件下,使用100kV电子束光刻技术,在248 μC/cm2的剂量下,可以绘制到28 nm间距的线,证明了该概念的潜力。此外,在剂量为221μC/cm2、线边缘粗糙度为2.3 nm的条件下,可以在60 nm的间距上绘制直径为26 nm的柱。
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引用次数: 2
Characterizing electron beam induced damage in metrology and inspection of advance devices 电子束损伤在先进设备计量和检测中的表征
Pub Date : 2017-09-28 DOI: 10.1117/12.2279707
A. Mohtashami, V. Navarro, H. Sadeghian, I. Englard, D. Shemesh, N. S. Malik
Using the electron beam (e-beam) as an advanced metrology tool in semiconductor manufacturing technologies has attracted many interests in the recent years. Owing to its high resolution and transparency to a wide range of materials including the metals, the e-beam shows a great promise to be used individually or in combination with the current optical metrology techniques in semiconductor industries. However, the e-beam can cause damages to the materials under inspection due to its relatively high energy. Therefore, determining the amount and type of damage as a result of the e-beam exposure is critical. Here, we present scanning probe microscopy techniques with the capability of measuring the e-beam induced damages on various materials. The experimental results of the e-beam induced damages on 300 mm silicon wafers covered by 1) patterned low-k material and 2) patterned low-k material filled with copper metal after chemical-mechanical polishing treatment are discussed. This method can be considered as a complementary approach to e-beam to ensure minimizing damage to the features.
近年来,电子束作为一种先进的计量工具在半导体制造技术中引起了人们的广泛关注。由于其高分辨率和对包括金属在内的各种材料的透明度,电子束显示出单独使用或与半导体行业当前光学计量技术结合使用的巨大前景。然而,电子束由于其相对较高的能量,会对被测材料造成损伤。因此,确定电子束暴露造成的损伤的数量和类型至关重要。在这里,我们提出了扫描探针显微镜技术,具有测量各种材料的电子束损伤的能力。讨论了化学机械抛光处理后300 mm硅片(1)图案化低钾材料覆盖层和(2)图案化低钾金属铜填充材料)的电子束损伤实验结果。这种方法可以被认为是电子束的一种补充方法,以确保对特征的损害最小。
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引用次数: 0
Pattern sampling for etch model calibration 蚀刻模型校准的模式采样
Pub Date : 2017-09-28 DOI: 10.1117/12.2279700
F. Weisbuch, A. Lutich, Jirka Schatz
Successful patterning requires good control of the photolithography and etch processes. While compact litho models, mainly based on rigorous physics, can predict very well the contours printed in photoresist, pure empirical etch models are less accurate and more unstable. Compact etch models are based on geometrical kernels to compute the litho-etch biases that measure the distance between litho and etch contours. The definition of the kernels as well as the choice of calibration patterns is critical to get a robust etch model. This work proposes to define a set of independent and anisotropic etch kernels –“internal, external, curvature, Gaussian, z_profile” – designed to capture the finest details of the resist contours and represent precisely any etch bias. By evaluating the etch kernels on various structures it is possible to map their etch signatures in a multi-dimensional space and analyze them to find an optimal sampling of structures to train an etch model. The method was specifically applied to a contact layer containing many different geometries and was used to successfully select appropriate calibration structures. The proposed kernels evaluated on these structures were combined to train an etch model significantly better than the standard one. We also illustrate the usage of the specific kernel “z_profile” which adds a third dimension to the description of the resist profile.
成功的图案化需要良好的光刻和蚀刻工艺控制。而紧凑的光刻模型,主要基于严格的物理,可以很好地预测光刻胶印刷的轮廓,纯经验蚀刻模型不太准确,更不稳定。紧凑型蚀刻模型基于几何核来计算蚀刻偏差,测量蚀刻和蚀刻轮廓之间的距离。核的定义以及校正模式的选择是获得鲁棒腐蚀模型的关键。这项工作建议定义一组独立的各向异性蚀刻核——“内部、外部、曲率、高斯、z_profile”——旨在捕捉抗蚀胶轮廓的最精细细节,并精确地表示任何蚀刻偏差。通过评估不同结构上的蚀刻核,可以在多维空间中映射它们的蚀刻特征,并对它们进行分析,以找到最优的结构采样来训练蚀刻模型。该方法特别应用于包含许多不同几何形状的接触层,并成功地选择了合适的校准结构。在这些结构上评估的所提出的核结合起来训练的蚀刻模型明显优于标准模型。我们还说明了特定内核“z_profile”的用法,它为抗阻配置文件的描述增加了第三个维度。
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引用次数: 2
Splendidly blended: a machine learning set up for CDU control 完美融合:为CDU控制设置的机器学习
Pub Date : 2017-09-28 DOI: 10.1117/12.2279430
C. Utzny
As the concepts of machine learning and artificial intelligence continue to grow in importance in the context of internet related applications it is still in its infancy when it comes to process control within the semiconductor industry. Especially the branch of mask manufacturing presents a challenge to the concepts of machine learning since the business process intrinsically induces pronounced product variability on the background of small plate numbers. In this paper we present the architectural set up of a machine learning algorithm which successfully deals with the demands and pitfalls of mask manufacturing. A detailed motivation of this basic set up followed by an analysis of its statistical properties is given. The machine learning set up for mask manufacturing involves two learning steps: an initial step which identifies and classifies the basic global CD patterns of a process. These results form the basis for the extraction of an optimized training set via balanced sampling. A second learning step uses this training set to obtain the local as well as global CD relationships induced by the manufacturing process. Using two production motivated examples we show how this approach is flexible and powerful enough to deal with the exacting demands of mask manufacturing. In one example we show how dedicated covariates can be used in conjunction with increased spatial resolution of the CD map model in order to deal with pathological CD effects at the mask boundary. The other example shows how the model set up enables strategies for dealing tool specific CD signature differences. In this case the balanced sampling enables a process control scheme which allows usage of the full tool park within the specified tight tolerance budget. Overall, this paper shows that the current rapid developments off the machine learning algorithms can be successfully used within the context of semiconductor manufacturing.
随着机器学习和人工智能的概念在互联网相关应用的背景下变得越来越重要,它在半导体行业的过程控制方面仍处于起步阶段。特别是掩模制造的分支对机器学习的概念提出了挑战,因为业务流程本质上在小号牌的背景下诱发了明显的产品可变性。在本文中,我们提出了一种机器学习算法的架构设置,该算法成功地处理了掩模制造的需求和缺陷。详细介绍了这种基本设置的动机,并对其统计性质进行了分析。为掩模制造设置的机器学习包括两个学习步骤:初始步骤识别和分类过程的基本全局CD模式。这些结果构成了通过平衡采样提取优化训练集的基础。第二个学习步骤使用这个训练集来获得由制造过程引起的局部和全局CD关系。使用两个生产动机的例子,我们展示了这种方法如何灵活和强大到足以处理口罩制造的严格要求。在一个示例中,我们展示了如何将专用协变量与CD地图模型的空间分辨率增加结合使用,以处理掩膜边界的病理CD效应。另一个示例显示了如何设置模型以启用处理特定于工具的CD签名差异的策略。在这种情况下,平衡取样实现了一个过程控制方案,该方案允许在指定的严格公差预算内使用整个刀具库。总体而言,本文表明,当前机器学习算法的快速发展可以成功地应用于半导体制造。
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引用次数: 8
Function follows form: combining nanoimprint and inkjet printing 功能遵循形式:结合纳米压印和喷墨印刷
Pub Date : 2017-09-28 DOI: 10.1117/12.2282503
Michael J. Haslinger, Michael M. Mühlberger, Kurzmann Julia, Markus Ikeda, Anita Fuchsbauer, Thomas Faury, T. Köpplmayr, H. Außerhuber, Julia Kastner, Christian Wögerer, Daniel Fechtig
We are investigating the possibilities and the technical requirements to do nanopatterning on arbitrary curved surfaces. This is done considering the opportunities and possibilities of additive manufacturing. One of the key elements is the necessity to deposit material in well-defined areas of various complex 3D objects. In order to achieve this we are developing a robot-based inkjet printing. We report on our progress with this respect and also on our efforts to perform nanoimprinting on curved, possibly 3D-printed objects using materials that can be deposited by inkjet printing. In the framework of this article, we provide an overview over our current status, the challenges and an outlook.
我们正在研究在任意曲面上制作纳米图案的可能性和技术要求。这是考虑到增材制造的机会和可能性。其中一个关键要素是必须将材料沉积在各种复杂3D物体的明确区域。为了实现这一目标,我们正在开发一种基于机器人的喷墨打印。我们报告了我们在这方面的进展,也报告了我们在曲面上进行纳米压印的努力,可能是3d打印的物体,使用的材料可以通过喷墨打印沉积。在本文的框架内,我们概述了我们的现状、挑战和展望。
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引用次数: 3
Challenges for scanning electron microscopy and inspection on the nanometer scale for non-IC application: and how to tackle them using computational techniques 非集成电路应用中扫描电子显微镜和纳米尺度检测的挑战:以及如何使用计算技术解决它们
Pub Date : 2017-09-28 DOI: 10.1117/12.2279564
J. Bolten, K. Arat, N. Ünal, C. Porschatis, T. Wahlbrink, M. Lemme
In this paper key challenges posed on metrology by feature dimensions of 20nm and below are discussed. In detail, the need for software-based tools for SEM image acquisition and image analysis in environments where CD-SEMs are not available and/or not flexible enough to cover all inspection tasks is outlined. These environments include research at universities as well as industrial R and D environments focused on non-IC applications. The benefits of combining automated image acquisition and analysis with computational techniques to simulate image generation in a conventional analytical SEM with respect to the overall reliability, precision and speed of inspection will be demonstrated using real-life inspection tasks as demonstrators.
本文讨论了20nm及以下特征尺寸测量所面临的主要挑战。详细地说,在没有cd -SEM和/或不够灵活以覆盖所有检查任务的环境中,需要基于软件的SEM图像采集和图像分析工具。这些环境包括大学的研究以及专注于非集成电路应用的工业研发环境。将自动图像采集和分析与计算技术相结合,以模拟传统分析SEM中图像生成的整体可靠性,精度和检查速度的好处将通过现实生活中的检查任务作为演示。
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引用次数: 0
Experimental verification of sub-wavelength holographic lithography physical concept for single exposure fabrication of complex structures on planar and nonplanar surfaces 亚波长全息光刻物理概念在平面和非平面表面单曝光加工中的实验验证
Pub Date : 2017-09-28 DOI: 10.1117/12.2279736
Mike Borisov, D. Chelyubeev, V. Chernik, Peter A. Miheev, Vadim I. Rakhovskiі, A. Shamaev
Authors of the report have been developing Sub-Wavelength Holographic Lithography (SWHL) methods of aerial image creation for IC layer topologies for the last several years. Sub-wavelength holographic masks (SWHM) have a number of substantial advantages in comparison with the traditional masks, which are used in projection photo-microlithography. The main advantages: there is no one-to-one correspondence between mask and image elements thus the effect of local mask defects almost completely eliminated [1]; holographic mask may consist of single-tipe elements with typical size many times bigger than projection mask elements [2]; technological methods of image quality optimization can be replaced by virtual routines in the process of the holographic mask calculating, that simplifies mask manufacturing and dramatically reduces the mask cost [3]; imaging via holographic mask does not need the projection lens, that significantly simplifies photolithographic tool and reduces ones cost. Our group developed effective methods of holographic mask synthesis and of aerial images modelling and created software package. This methods and calculation results were verified and reported many times [1-3].
该报告的作者在过去几年中一直在开发用于IC层拓扑的亚波长全息光刻(SWHL)航空图像创建方法。与传统掩模相比,亚波长全息掩模(SWHM)在投影显微光刻中具有许多实质性的优势。主要优点:蒙版与图像元素之间不存在一一对应关系,几乎完全消除了局部蒙版缺陷的影响[1];全息掩模可以由典型尺寸比投影掩模大许多倍的单类元件组成[2];在全息掩模计算过程中,可以用虚拟例程代替图像质量优化的技术方法,简化了掩模的制造,大大降低了掩模的成本[3];通过全息掩模成像不需要投影透镜,大大简化了光刻工具,降低了成本。我们小组开发了全息掩模合成和航拍图像建模的有效方法,并开发了软件包。该方法和计算结果被多次验证和报道[1-3]。
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引用次数: 1
A thick photoresist process for high aspect ratio MEMS applications 用于高纵横比MEMS应用的厚光刻胶工艺
Pub Date : 2016-10-20 DOI: 10.1117/12.2247899
E. Laforge, R. Anthony, P. McCloskey, C. O'Mathúna
In recent years, increased demand for high aspect ratio MEMS structures has driven the need for thick photoresist fabrication processes. In this work, the optimization of a thick photoresist process using a negative tone resist (THB-151N) is described. A thickness of 85 μm is obtained with an aspect ratio of 17:1 in a single coating process, with a 5 μm pitch. Conventional UV lithography is used and its parameters are optimized in order to achieve straight and near vertical sidewall profiles. The developed patterns are used as a mold to electroplate high aspect ratio copper windings of micro-inductors and micro-transformers. A high aspect ratio yields a copper track with a large cross sectional area resulting in a lower DC resistance. This enables a further reduction in the footprint area allowing for a more efficient manufacturing process and smaller device size. Unlike other high aspect ratio resist such as SU-8, this resist does not need a post exposure bake and can be readily removed after metal electroplating.
近年来,对高纵横比MEMS结构的需求增加,推动了对厚光刻胶制造工艺的需求。在这项工作中,描述了使用负色调抗蚀剂(THB-151N)的厚光刻胶工艺的优化。单次涂覆可获得厚度为85 μm、宽高比为17:1、间距为5 μm的涂层。采用传统的UV光刻技术,并对其参数进行优化,以获得直的和接近垂直的侧壁轮廓。所开发的图案用于微电感器和微变压器的高纵横比铜绕组的电镀。高纵横比产生具有大横截面积的铜轨道,从而产生较低的直流电阻。这可以进一步减少占地面积,从而实现更高效的制造工艺和更小的设备尺寸。与其他高纵横比抗蚀剂(如SU-8)不同,这种抗蚀剂不需要曝光后烘烤,并且在金属电镀后可以很容易地去除。
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引用次数: 2
The future of 2D metrology for display manufacturing 显示器制造业二维计量的未来
Pub Date : 2016-10-20 DOI: 10.1117/12.2248951
T. Sandstrom, M. Wahlsten, Youngjin Park
The race to 800 PPI and higher in mobile devices and the transition to OLED displays are driving a dramatic development of mask quality: resolution, CDU, registration, and complexity. 2D metrology for large area masks is necessary and must follow the roadmap. Driving forces in the market place point to continued development of even more dense displays. State-of-the-art metrology has proven itself capable of overlay below 40 nm and registration below 65 nm for G6 masks. Future developments include incoming and recurrent measurements of pellicalized masks at the panel maker’s factory site. Standardization of coordinate systems across supplier networks is feasible. This will enable better yield and production economy for both mask and panel maker. Better distortion correction methods will give better registration on the panels and relax the flatness requirements of the mask blanks. If panels are measured together with masks and the results are used to characterize the aligners, further quality and yield improvements are possible. Possible future developments include in-cell metrology and integration with other instruments in the same platform.
移动设备向800 PPI及更高水平的竞争,以及向OLED显示器的过渡,正在推动掩膜质量的戏剧性发展:分辨率、CDU、注册和复杂性。大面积口罩的二维计量是必要的,必须遵循路线图。市场的驱动力指向了更密集显示器的持续发展。最先进的计量技术已经证明自己能够覆盖低于40纳米的G6掩模和低于65纳米的注册。未来的发展包括在面板制造商的工厂现场对隔离口罩进行传入和周期性测量。跨供应商网络的坐标系统标准化是可行的。这将为掩膜和面板制造商带来更好的产量和生产经济性。更好的畸变校正方法将使面板上的配准更好,并放宽掩模坯的平面度要求。如果面板与掩模一起测量,并使用结果来表征对准器,则可能进一步提高质量和良率。未来可能的发展包括单元内计量和与同一平台上的其他仪器的集成。
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引用次数: 1
Mask manufacturing of advanced technology designs using multi-beam lithography (Part 1) 利用多光束光刻技术制造先进的掩模设计(第一部分)
Pub Date : 2016-10-20 DOI: 10.1117/12.2247941
Michael Green, Y. Ham, Brian Dillon, B. Kasprowicz, Ikboum Hur, Joong Hee Park, Yohan Choi, J. McMurran, Henry H. Kamberian, D. Chalom, J. Klikovits, Michal Jurkovič, P. Hudek
As optical lithography is extended into 10nm and below nodes, advanced designs are becoming a key challenge for mask manufacturers. Techniques including advanced Optical Proximity Correction (OPC) and Inverse Lithography Technology (ILT) result in structures that pose a range of issues across the mask manufacturing process. Among the new challenges are continued shrinking Sub-Resolution Assist Features (SRAFs), curvilinear SRAFs, and other complex mask geometries that are counter-intuitive relative to the desired wafer pattern. Considerable capability improvements over current mask making methods are necessary to meet the new requirements particularly regarding minimum feature resolution and pattern fidelity. Advanced processes using the IMS Multi-beam Mask Writer (MBMW) are feasible solutions to these coming challenges. In this paper, we study one such process, characterizing mask manufacturing capability of 10nm and below structures with particular focus on minimum resolution and pattern fidelity.
随着光刻技术扩展到10nm及以下节点,先进的设计正成为掩模制造商面临的关键挑战。包括先进的光学接近校正(OPC)和逆光刻技术(ILT)在内的技术导致在整个掩模制造过程中产生一系列问题的结构。新的挑战包括不断缩小的亚分辨率辅助特征(SRAFs)、曲线SRAFs和其他复杂的掩模几何形状,这些几何形状与期望的晶圆图案相反。为了满足新的要求,特别是在最小特征分辨率和模式保真度方面,需要对当前掩模制作方法进行相当大的能力改进。采用IMS多波束掩码编写器(MBMW)的先进工艺是应对这些即将到来的挑战的可行解决方案。在本文中,我们研究了一种这样的工艺,表征了10nm及以下结构的掩模制造能力,特别关注最小分辨率和图案保真度。
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引用次数: 4
期刊
European Mask and Lithography Conference
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