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The growth of Si overlayers on Er2O3(111)/Si (111) by solid phase epitaxy 用固相外延法在Er2O3(111)/Si(111)表面生长Si覆盖层
Pub Date : 2010-10-11 DOI: 10.1117/12.888362
R. Xu, Jiaming Xie, Minyan Tang, Y. Zhu, Linjun Wang
The Si overlayers were grown by solid phase epitaxy on the atomically smooth Er2O3 (111) films, which is prepared on the Si (111) substrate in optimum conditions. The twin structure was observed in the spot-like reflective high energy electron diffraction (RHEED) patterns. The rough surface of Si overlayer, as identified by both RHEED results and Atomic force microscopy (AFM) images, indicated a three dimensional growth mode in contrast to the two dimensional growth mode of Er2O3 on the Si (111) substrate. The physical origin of three dimensional grow is given based on the interfacial energy argument.
采用固相外延的方法,在硅(111)衬底上制备了原子光滑的Er2O3(111)薄膜。在点状反射高能电子衍射(RHEED)图中观察到孪晶结构。与Er2O3在Si(111)衬底上的二维生长模式相比,通过RHEED结果和原子力显微镜(AFM)图像识别的Si(111)衬底上的粗糙表面显示出三维生长模式。基于界面能理论,给出了三维生长的物理根源。
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引用次数: 1
Preparation and characterization of free-standing Zr, PI and Zr/PI filter 独立式Zr、PI及Zr/PI滤波器的制备与表征
Pub Date : 2010-10-11 DOI: 10.1117/12.887562
Heyun Wu, Yonggang Wu, G. Lv, Zhenhua Wang, Leijie Ling, Zihuan Xia, N. Chen
A thin PI film equal to or less than 200nm was fabricated on a Zr film to improve the mechanical characteristics of the latter. The PI film was prepared by two-step process. Througth fully reaction between Pyromellitic Dianhydride (PMDA) and Oxydianiline (ODA) in Dimethylacetamide (DMAC), polyamic acid (PAA) was produced. After the deposition of Zr film on floating glass using direct-current magnetron sputtering, PAA was prepared on the Zr film through dip-coating and then thermally imidized to form the PI film. The transmission spectrum obtained by using synchrotron radiation fits with calculation result fairly well. Although the combination of the PI film with Zr film results in the decline of the transmission, the mechanical strength of the composite film is improved, and the transmittances of the Zr(300nm)/PI(200nm) and Zr(400nm)/PI(200nm) films reach 14.9% and 7.5% respectively at 13.9 nm, still satisfying the actual requirement.
为了改善Zr薄膜的力学性能,在Zr薄膜上制备了小于200nm的PI薄膜。采用两步法制备了PI薄膜。邻苯二甲酸(PMDA)与氧化二胺(ODA)在二甲基乙酰胺(DMAC)中充分反应,制得聚酰胺(PAA)。采用直流磁控溅射法在浮法玻璃上沉积Zr膜后,通过浸涂在Zr膜上制备PAA,然后热亚氮化形成PI膜。用同步辐射得到的透射谱与计算结果吻合较好。虽然PI膜与Zr膜的结合导致透光率下降,但复合膜的机械强度得到提高,Zr(300nm)/PI(200nm)和Zr(400nm)/PI(200nm)膜在13.9 nm处的透光率分别达到14.9%和7.5%,仍然满足实际要求。
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引用次数: 1
Preparation and characterization of (110) diamond films used for field-effect transistors 场效应晶体管用金刚石薄膜的制备与表征
Pub Date : 2010-10-11 DOI: 10.1117/12.888210
Fengjuan Zhang, Qinkai Zeng, Xiaoyu Pan, Mei Bi, Xingmao Yan, Jian Huang, K. Tang, Jijun Zhang, Linjun Wang
In this work, H-terminated (110) diamond film, a novel active material for high-frequency and high-power field-effect transistors (FETs), was successfully prepared by hot filament chemical vapor deposition (HFCVD) method using acetone as carbon source. X-ray diffraction (XRD) measurements showed that at a lower pressure of 2 KPa and a C/H ratio of 40/200, a higher intensity of (110) diffraction peak with a narrower full width at half maximum (FWHM) was detected which meant highly (110) preferential orientation of diamond films. H-terminated films were achieved by the hydrogen gas pressure of 5KPa and a microwave power of 2.4KW. The H-terminated (110) diamond films obtained were suitable for FETs. Hall Effect measurement indicated that the sheet carrier density of (110)-oriented films was 2.2x1013cm-2, and 2.3 times higher than that of the randomly-oriented films.
本文以丙酮为碳源,采用热丝化学气相沉积(HFCVD)法制备了一种新型高频大功率场效应晶体管(fet)的活性材料——端氢(110)金刚石薄膜。x射线衍射(XRD)测试结果表明,在较低压力为2 KPa、C/H比为40/200的条件下,金刚石薄膜的(110)衍射峰强度较高,半峰全宽较窄,表明金刚石薄膜具有高度的(110)择优取向。氢气压力为5KPa,微波功率为2.4KW,可获得h端膜。所得到的h端(110)金刚石薄膜适合用于fet。霍尔效应测量表明,(110)取向薄膜的载流子密度为2.2x1013cm-2,是随机取向薄膜载流子密度的2.3倍。
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引用次数: 0
Natural dye -sensitized mesoporous ZnO solar cell 天然染料敏化介孔ZnO太阳能电池
Pub Date : 2010-10-11 DOI: 10.1117/12.888318
Qishuang Wu, Guizhi Wu, M. Cao
Natural dye-sensitized solar cells (N-DSSCs) were assembled using chlorophyll sensitized mesoporous ZnO (based on FTO) as the photoanode and platinum plate as the cathode. The natural dyes (chlorophyll) were extracted from spinach by simple procedure. The absorption spectrum and fluorescence spectrum of chlorophyll were studied. Mesoporous ZnO (m-ZnO) applied to the N-DSSCs was synthesized through hydrothermal method. The structures and morphologies were characterized by X-ray Diffraction (XRD) and diffuse reflection. The results indicated that the samples had an average pore size of 17 nm and the m-ZnO was hexagonal wurtzite structure. The performances of the N-DSSCs were investigated under AM 1.5G illumination. The Voc of the N-DSSCs was about 480mv, and the Isc was about 470μA. The performance of the N-DSSCs could be further improved by adjusting its structure.
以叶绿素敏化的介孔ZnO(基于FTO)为光阳极,铂板为阴极,组装了天然染料敏化太阳能电池(N-DSSCs)。采用简单的方法从菠菜中提取天然色素叶绿素。研究了叶绿素的吸收光谱和荧光光谱。采用水热法合成了用于N-DSSCs的介孔ZnO (m-ZnO)。通过x射线衍射(XRD)和漫反射对其结构和形貌进行了表征。结果表明,样品的平均孔径为17 nm, m-ZnO为六方纤锌矿结构。在AM 1.5G光照下研究了N-DSSCs的性能。N-DSSCs的Voc约为480mv, Isc约为470μA。通过调整结构可以进一步提高N-DSSCs的性能。
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引用次数: 2
Wideband reflector and bandpass filter by using a Ge subwavelength periodic membrane 宽带反射器和带通滤波器,采用Ge亚波长周期膜
Pub Date : 2010-10-11 DOI: 10.1117/12.888278
Tian Sang, Tuo Cai, Xiaowei Zhang, Sanhong Ding, Shaohong Cai, Zhanshan Wang
Wideband reflector and bandpass filter are obtained by using a Ge subwavelength periodic membrane with the thickness kept constant at 3.20 μm. The strong refractive-index modulation of the Ge subwavelength periodic membrane yields increased bandwidth of the leaky mode resonances, thus the excitation of the leaky mode resonances TE1,1, TE2,1, and TE3,0 may interact to form a broad reflection band or a transmission passband near λ=10.60 μm.
采用厚度为3.20 μm的Ge亚波长周期膜制备了宽带反射器和带通滤波器。Ge亚波长周期膜的强折射率调制使漏模共振的带宽增加,从而在λ=10.60 μm附近激发漏模共振TE1、1、TE2、1和TE3、0可能相互作用形成宽反射带或透射通带。
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引用次数: 0
Nanometer gap detection method using GMR grating GMR光栅纳米缝隙检测方法
Pub Date : 2010-10-11 DOI: 10.1117/12.887554
Zihuan Xia, Yonggang Wu, Leijie Ling, G. Lv, Heyun Wu
In this paper the displacement of the reflection resonant peak resulting from the change of the gap between the guided-mode resonance (GMR) grating and substrate is used to measure the nanometer gap. The paper calculates double layer model and metal substrate model using rigorous coupled-wave analysis (RCWA). It is revealed that nano-gap detection using GMR grating is feasible for both dielectric and metal substrate. The detection range of resonant wavelength and gap is tunable. The detect sensitivity is investigated by varying the parameters of grating (thickness, period and refractive index), the thickness of films, and polarization. Tolerance of grating implies an advantage for manufacture. An optimized result presents an 18nm resonant shift for 100nm gap with the max sensitivity achieving 0.85.
本文利用导模谐振光栅与衬底之间的间隙变化引起的反射谐振峰位移来测量纳米间隙。本文采用严格耦合波分析(RCWA)计算了双层模型和金属基板模型。结果表明,利用GMR光栅对介质和金属衬底进行纳米间隙检测是可行的。谐振波长和间隙的探测范围是可调的。通过改变光栅的厚度、周期和折射率等参数、薄膜厚度和偏振度来研究探测灵敏度。光栅的公差意味着制造的优势。优化后的结果显示,在100nm的间隙内,共振位移为18nm,最大灵敏度达到0.85。
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引用次数: 0
Polymer films as planarization and sacrificial layers for uncooled infrared focal plane arrays 聚合物薄膜作为非冷却红外焦平面阵列的平面化和牺牲层
Pub Date : 2010-10-11 DOI: 10.1117/12.888597
Huan Liu, Weiguo Liu, Chang-long Cai, Shun Zhou
This paper presents a planarization procedure using polymer films to achieve a flat CMOS surface of Readout Integrated Circuit (ROIC) for the integration between uncooled infrared focal plane arrays and ROIC. At the same time, the polymer film is also used as the sacrificial layers. After amorphous Silicon (a-Si) film was deposited using plasma enhanced chemical vapor deposition (PECVD), and patterned using inductively coupled plasma (ICP), the polymer sacrificial layer should be removed to form a-Si self-supporting micro-bridge structure. So the thickness of polymer film determine the height of the micro-bridge; the soft curing temperature determines if the contact hole can be etched by developer during the first photolithography; and the rate of dry etching determines whether the sacrificial layers of the structure can be released successfully. In this paper, the curing temperature, surface roughness, etching process of polymer films are systematically researched. On this basis, polymer film as planarization successfully reduces the 2μm height of the bumps on ROIC to less than 83 nm, over the planarized polymer mesas, bolometer arrays are fabricated. Then the polymer film as sacrificial are removed by ICP and 160x120 self-supporting micro-bridge structure arrays are successfully fabricated.
本文提出了一种利用聚合物薄膜将读出集成电路(ROIC)表面平面化的方法,用于非冷却红外焦平面阵列与ROIC之间的集成。同时,聚合物薄膜也被用作牺牲层。采用等离子体增强化学气相沉积(PECVD)技术沉积非晶硅(a-Si)薄膜,并采用电感耦合等离子体(ICP)技术进行图图化后,需要去除聚合物牺牲层以形成自支撑的a-Si微桥结构。所以聚合物膜的厚度决定了微桥的高度;软固化温度决定了接触孔能否在第一次光刻时被显影剂蚀刻;干刻蚀速率决定了结构牺牲层能否成功释放。本文对聚合物薄膜的固化温度、表面粗糙度、蚀刻工艺进行了系统的研究。在此基础上,将聚合物薄膜平面化,成功地将ROIC上凸起的2μm高度减小到小于83 nm,在平面化的聚合物平台上,制备了测热计阵列。然后用ICP除去作为牺牲物的聚合物薄膜,成功制备了160x120自支撑微桥结构阵列。
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引用次数: 0
Study of high temperature piezoelectric scandium aluminum nitride thin films 高温压电氮化钪铝薄膜的研究
Pub Date : 2010-10-11 DOI: 10.1117/12.888228
Xiaolei Shi, Yigang Chen, W. Shi, Linjun Wang
AlN has weak piezoelectric property (piezoelectric coefficient d33=5.5pCN-1) and a high Curie temperature (>1150°C). By Sc-doping in AlN thin films, it is possible to synthesize ScxAl1-xN alloy with high piezoelectric coefficient and high temperature stability. In this study, c-axis oriented AlN thin films have been successfully grown on Si (100) substrates by DC magnetron reactive sputtering method. First-principles calculations are also performed to investigate the structure of ScxAl1-xN.
AlN具有弱压电特性(压电系数d33=5.5pCN-1)和高居里温度(>1150℃)。通过在AlN薄膜中掺杂sc,可以合成具有高压电系数和高温稳定性的ScxAl1-xN合金。在本研究中,采用直流磁控反应溅射法在Si(100)衬底上成功生长了c轴取向AlN薄膜。还进行了第一性原理计算来研究ScxAl1-xN的结构。
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引用次数: 1
Innovations in structured thin film design and fabrication for optical applications 光学应用中结构薄膜设计和制造的创新
Pub Date : 2010-10-11 DOI: 10.1117/12.888231
H. Qi, Jianpeng Wang, A. Erdmann, Yunxia Jin, J. Shao, Z. Fan
This paper presents the design and fabrication of several versions of structured thin films (STF). One kind of STF is a sculptured thin film, generally deposited with a glancing angle deposition technique. Several optical components were designed and fabricated using this technique. This includes a TiO2 based wave-plate for an operating wavelength of 550 nm, a multilayer based beam splitter with a transmittance of 75.0% for TM light and 38.6% for TE light at 632 nm, and a multilayer based polarization neutral transmission filter for an incidence angle of 45°. Multilayer dielectric gratings (MDG) present another type of STF. To obtain a broad diffraction bandwidth, a novel MDG structure with three materials is proposed. Using multi-parameter optimization, a broadband spectrum with an efficiency >97.5% and a bandwidth >100 nm centered at 800 nm was obtained. For the first time, a new type of two-dimensional (2D) MDG is proposed to obtain higher efficiency (>98%) and broader bandwidth (>110 nm). Finally, the designs of pulse compression gratings and of broadband polarizers, which can be fabricated with a single material, are presented.
本文介绍了几种结构薄膜(STF)的设计和制造。一种STF是一种雕刻薄膜,通常用掠角沉积技术沉积。利用该技术设计和制造了几种光学元件。这包括一个工作波长为550 nm的TiO2基波片,一个在632 nm处TM光透射率为75.0%、TE光透射率为38.6%的多层分束器,以及一个入射角为45°的多层偏振中性透射滤光片。多层介质光栅(MDG)是另一种类型的STF。为了获得较宽的衍射带宽,提出了一种由三种材料组成的新型MDG结构。通过多参数优化,获得了效率>97.5%、带宽>100 nm、以800 nm为中心的宽带光谱。首次提出了一种新型二维MDG,该MDG具有更高的效率(>98%)和更宽的带宽(>110 nm)。最后,介绍了脉冲压缩光栅和宽带偏振器的设计,它们可以用一种材料制作。
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引用次数: 1
Growth and UV detectors application of ZnMgO films ZnMgO薄膜的生长及紫外探测器的应用
Pub Date : 2010-10-11 DOI: 10.1117/12.888372
K. Tang, Jian Huang, Qinkai Zeng, Jijun Zhang, Wei-min Shi, Yiben Xia, Linjun Wang
ZnMgO films were prepared at room temperature on freestanding diamond (FSD) substrates by co-sputtering with different sputtering power of MgO target. The effect of sputtering power of MgO target on the property of ZnMgO films was investigated. The PL spetra of ZnMgO films revealed that the bandgap of ZnMgO was approximately linear related to the sputtering power of MgO target. The ZnMgO film was also applied to be fabricating UV detectors. Finally, we studied the photoelectric property of the UV detector.
采用不同溅射功率的MgO靶材在独立金刚石(FSD)衬底上共溅射制备了ZnMgO薄膜。研究了MgO靶材溅射功率对ZnMgO薄膜性能的影响。ZnMgO薄膜的PL谱显示,ZnMgO的带隙与靶材的溅射功率近似成线性关系。ZnMgO薄膜也被用于制作紫外探测器。最后,对紫外探测器的光电性能进行了研究。
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引用次数: 0
期刊
International Conference on Thin Film Physics and Applications
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