首页 > 最新文献

Fuel最新文献

英文 中文
Performance and mechanism of a novel electro-magnetic treatment for improving the cold flowability of waxy crude oil 用于改善含蜡原油冷流动性的新型电磁处理方法的性能和机理
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-23 DOI: 10.1016/j.fuel.2024.133803
Yiwei Xie , Hongying Li , Bing Liang , Quande Li , Yang Su , Chaoyue Zhang , Jiabao Kang , Zhaoming Yang , Huai Su , Zhongli Ji , Jinjun Zhang
Under the framework of achieving carbon neutrality, the transformation of pipeline transportation modes, coupled with the poor flowability of crude oil, has raised the standards for ensuring the flow assurance of oil pipelines. Improving the cold flowability of waxy crude oil is crucial for flow assurance. Previous studies have demonstrated that electric or magnetic treatment could have such efficacy. However, the combined treatment of electric and magnetic fields has never been investigated. This paper introduces such a novel exploration, revealing a quite encouraging synergistic effect on cold flowability improvement. Specifically, the crude oil was first exposed to a magnetic field above its WAT, followed by an electric field below the WAT. For the studied crude oil, the synergistic treatment achieved a 50 % reduction in viscosity, compared to 24 % and 30 % reductions for magnetic and electric treatment alone, respectively. Although magnetic treatment showed limited effect on weakening the structural strength of the oil gel, it significantly enhanced the effectiveness of the electric field, increasing the yield stress reduction from 77 % to 84 %. Attention must be paid to the non-monotonic influences of magnetic field strength, treatment duration, and temperature. Mechanistically, magnetic treatment reduced the crude oil’s impedance, indicating an enhanced dispersion of resins and asphaltenes. This improved dispersion allowed for greater adsorption of resins and asphaltenes onto wax particles during subsequent electric treatment, thus making the electric treatment much more effective. These new findings reveal the electro-magnetorheological effects of crude oil, guiding advanced flowability improvement technologies.
在实现碳中和的框架下,管道运输模式的转变,加上原油流动性差,提高了确保石油管道流动性的标准。改善含蜡原油的低温流动性是保证流动性的关键。以往的研究表明,电处理或磁处理可以达到这种效果。然而,电场和磁场的组合处理方法还从未被研究过。本文介绍了这一新颖的探索,揭示了在改善冷流动性方面令人鼓舞的协同效应。具体来说,原油首先暴露在高于其加权平均值的磁场中,然后再暴露在低于加权平均值的电场中。对于所研究的原油,协同处理使粘度降低了 50%,而单独使用磁场和电场处理则分别降低了 24% 和 30%。虽然磁处理对削弱油凝胶结构强度的作用有限,但它显著增强了电场的效果,将屈服应力降低率从 77% 提高到 84%。必须注意磁场强度、处理时间和温度的非单调影响。从机理上讲,磁处理降低了原油的阻抗,表明树脂和沥青质的分散性得到了提高。这种分散性的提高使树脂和沥青质在随后的电处理过程中更容易吸附在蜡颗粒上,从而使电处理更加有效。这些新发现揭示了原油的电磁流变效应,为先进的流动性改进技术提供了指导。
{"title":"Performance and mechanism of a novel electro-magnetic treatment for improving the cold flowability of waxy crude oil","authors":"Yiwei Xie ,&nbsp;Hongying Li ,&nbsp;Bing Liang ,&nbsp;Quande Li ,&nbsp;Yang Su ,&nbsp;Chaoyue Zhang ,&nbsp;Jiabao Kang ,&nbsp;Zhaoming Yang ,&nbsp;Huai Su ,&nbsp;Zhongli Ji ,&nbsp;Jinjun Zhang","doi":"10.1016/j.fuel.2024.133803","DOIUrl":"10.1016/j.fuel.2024.133803","url":null,"abstract":"<div><div>Under the framework of achieving carbon neutrality, the transformation of pipeline transportation modes, coupled with the poor flowability of crude oil, has raised the standards for ensuring the flow assurance of oil pipelines. Improving the cold flowability of waxy crude oil is crucial for flow assurance. Previous studies have demonstrated that electric or magnetic treatment could have such efficacy. However, the combined treatment of electric and magnetic fields has never been investigated. This paper introduces such a novel exploration, revealing a quite encouraging synergistic effect on cold flowability improvement. Specifically, the crude oil was first exposed to a magnetic field above its WAT, followed by an electric field below the WAT. For the studied crude oil, the synergistic treatment achieved a 50 % reduction in viscosity, compared to 24 % and 30 % reductions for magnetic and electric treatment alone, respectively. Although magnetic treatment showed limited effect on weakening the structural strength of the oil gel, it significantly enhanced the effectiveness of the electric field, increasing the yield stress reduction from 77 % to 84 %. Attention must be paid to the non-monotonic influences of magnetic field strength, treatment duration, and temperature. Mechanistically, magnetic treatment reduced the crude oil’s impedance, indicating an enhanced dispersion of resins and asphaltenes. This improved dispersion allowed for greater adsorption of resins and asphaltenes onto wax particles during subsequent electric treatment, thus making the electric treatment much more effective. These new findings reveal the electro-magnetorheological effects of crude oil, guiding advanced flowability improvement technologies.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133803"},"PeriodicalIF":6.7,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing biodiesel production and tribocorrosion resistance with MWCNT–COOH @TiO2 nanocatalysts 利用 MWCNT-COOH @TiO2 纳米催化剂提高生物柴油生产和耐摩擦腐蚀性能
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-23 DOI: 10.1016/j.fuel.2024.133811
Younis Muhsin Younis Al-Ani, Majid Ahmadlouydarab
This study marks a significant advancement in sustainable energy by demonstrating the potential of novel nanocatalysts to efficiently transesterify used cooking oils into biodiesel. A nanocatalyst consisting of titanium dioxide and functionalized multiwalled carbon nanotubes (MWCNTs) was selected for its large specific surface area and high catalytic efficiency in biodiesel production. Prepared through impregnation followed by calcination, the nanocatalyst was thoroughly characterized using advanced techniques such as Brunauer–Emmett–Teller (BET) surface area analysis, X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), High-Resolution Field Emission Scanning Electron Microscopy (HR–FESEM), and Atomic Force Microscopy (AFM). The optimum parameters of the transesterification process were determined by Taguchi method as 30 min of reaction at a temperature of 50 °C a stirrer speed of 600 rpm with a nanocatalyst concentration of 400 mg and the oil-to-methanol ratio 1:6. Under these conditions, this nanocatalyst afforded a 98.4 % biodiesel yield, effectively converting waste oil into renewable energy. The biodiesel, with a flash point of 148 °C and a viscosity of 4.2 mm2/s, met the required specifications according to American Society for Testing and Materials (ASTM) standards for applications. Furthermore, the nanocatalyst reusability 91.2 % efficiency after three cycles.
The nanocatalyst was reported to reduce wear rates by 9.46%, 10%, and 14.3% compared to functionalized multi-walled carbon nanotubes, according to ASTM G99 standards on a wear test. The wear resistance is enhanced by the formation of a protective oxide layer, which provides smoothness to the surface with solid protection against wear. Combining a high biodiesel yield and low wear provides a route to increase the efficiency and sustainability of energy processes. This highly efficient and durable nanocatalyst can be applied in the transesterification of waste cooking oil as an economical and eco-friendly procedure to produce biodiesel.
这项研究展示了新型纳米催化剂高效地将废食用油酯交换成生物柴油的潜力,标志着可持续能源领域取得了重大进展。研究人员选择了一种由二氧化钛和功能化多壁碳纳米管(MWCNTs)组成的纳米催化剂,因为这种催化剂的比表面积大,在生物柴油生产中的催化效率高。通过浸渍和煅烧制备出的纳米催化剂采用了先进的技术,如布鲁纳-埃美特-泰勒(BET)表面积分析、X 射线衍射(XRD)、傅立叶变换红外光谱(FTIR)、高分辨率场发射扫描电子显微镜(HR-FESEM)和原子力显微镜(AFM),对其进行了全面的表征。通过田口方法确定了酯交换过程的最佳参数:反应 30 分钟,温度 50 ℃,搅拌器转速 600 转/分钟,纳米催化剂浓度 400 毫克,油甲醇比 1:6。在这些条件下,这种纳米催化剂的生物柴油产量达到 98.4%,有效地将废油转化为可再生能源。生物柴油的闪点为 148 °C,粘度为 4.2 mm2/s,符合美国材料试验协会(ASTM)的应用标准。此外,根据 ASTM G99 标准的磨损测试,与功能化多壁碳纳米管相比,纳米催化剂的磨损率分别降低了 9.46%、10% 和 14.3%。保护性氧化层的形成增强了耐磨性,使表面更加光滑,并提供了坚实的耐磨保护。将生物柴油的高产率和低磨损结合起来,为提高能源工艺的效率和可持续性提供了一条途径。这种高效耐用的纳米催化剂可用于废食用油的酯交换反应,是生产生物柴油的经济环保型工艺。
{"title":"Enhancing biodiesel production and tribocorrosion resistance with MWCNT–COOH @TiO2 nanocatalysts","authors":"Younis Muhsin Younis Al-Ani,&nbsp;Majid Ahmadlouydarab","doi":"10.1016/j.fuel.2024.133811","DOIUrl":"10.1016/j.fuel.2024.133811","url":null,"abstract":"<div><div>This study marks a significant advancement in sustainable energy by demonstrating the potential of novel nanocatalysts to efficiently transesterify used cooking oils into biodiesel. A nanocatalyst consisting of titanium dioxide and functionalized multiwalled carbon nanotubes (MWCNTs) was selected for its large specific surface area and high catalytic efficiency in biodiesel production. Prepared through impregnation followed by calcination, the nanocatalyst was thoroughly characterized using advanced techniques such as Brunauer–Emmett–Teller (BET) surface area analysis, X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), High-Resolution Field Emission Scanning Electron Microscopy (HR–FESEM), and Atomic Force Microscopy (AFM). The optimum parameters of the transesterification process were determined by Taguchi method as 30 min of reaction at a temperature of 50 °C a stirrer speed of 600 rpm with a nanocatalyst concentration of 400 mg and the oil-to-methanol ratio 1:6. Under these conditions, this nanocatalyst afforded a 98.4 % biodiesel yield, effectively converting waste oil into renewable energy. The biodiesel, with a flash point of 148 °C and a viscosity of 4.2 mm<sup>2</sup>/s, met the required specifications according to American Society for Testing and Materials (ASTM) standards for applications. Furthermore, the nanocatalyst reusability 91.2 % efficiency after three cycles.</div><div>The nanocatalyst was reported to reduce wear rates by 9.46%, 10%, and 14.3% compared to functionalized multi-walled carbon nanotubes, according to ASTM G99 standards on a wear test. The wear resistance is enhanced by the formation of a protective oxide layer, which provides smoothness to the surface with solid protection against wear. Combining a high biodiesel yield and low wear provides a route to increase the efficiency and sustainability of energy processes. This highly efficient and durable nanocatalyst can be applied in the transesterification of waste cooking oil as an economical and eco-friendly procedure to produce biodiesel.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133811"},"PeriodicalIF":6.7,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High organic loading rate treatment of palm oil mill effluent using a pilot-scale integrated anaerobic-aerobic bioreactor: A comprehensive performance study 利用中试规模的厌氧-好氧一体化生物反应器对棕榈油厂污水进行高有机负荷率处理:综合性能研究
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-23 DOI: 10.1016/j.fuel.2024.133727
Cheau Chin Yap , Abu Danish Aiman Bin Abu Sofian , Yi Jing Chan , Soh Kheang Loh , Mei Fong Chong , Lian Keong Lim
This study evaluates a pilot-plant Integrated Anaerobic-Aerobic Bioreactor (IAAB) for treating Palm Oil Mill Effluent (POME) at a high Organic Loading Rate (OLR) of 30.0 gCOD/L.day. Conducted over 118 days, the research aimed to optimise operational parameters to meet discharge standards. The system’s effectiveness was measured by its ability to reduce Biochemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD), and Total Suspended Solids (TSS) alongside methane production and process stability. Results showed high removal efficiencies: BOD (99.95 %), COD (99.58 %), and TSS (99.24 %), with a consistent methane yield of 0.218 ± 0.032 LCH4/gCODremoved. These outcomes confirm the IAAB’s capability to maintain effluent quality with BOD under 20 mg/L, complying with the Department of Environment (DOE) Malaysia standards without pH adjustment. The study supports the IAAB’s efficiency in handling significant pollutant loads with stable performance and substantial biogas production, presenting it as a viable solution for sustainable energy management in the palm oil industry. Future research will investigate co-digestion processes to enhance methane yield and economic viability.
本研究评估了一个试验性厌氧-好氧生物反应器(IAAB),用于处理有机负荷率(OLR)高达 30.0 gCOD/L.day的棕榈油厂废水(POME)。这项研究历时 118 天,旨在优化运行参数,以达到排放标准。该系统的有效性通过其降低生化需氧量 (BOD)、化学需氧量 (COD) 和总悬浮固体 (TSS) 的能力以及甲烷产量和工艺稳定性来衡量。结果显示去除率很高:BOD (99.95 %)、COD (99.58 %)和 TSS (99.24 %),甲烷产量始终为 0.218 ± 0.032 LCH4/gCODremoved。这些结果证实,IAAB 有能力将出水水质保持在 BOD 低于 20 mg/L 的水平,符合马来西亚环境部 (DOE) 的标准,而无需调节 pH 值。这项研究证明,IAAB 能以稳定的性能和可观的沼气产量高效处理大量污染物负荷,是棕榈油行业可持续能源管理的可行解决方案。未来的研究将对联合消化工艺进行调查,以提高甲烷产量和经济可行性。
{"title":"High organic loading rate treatment of palm oil mill effluent using a pilot-scale integrated anaerobic-aerobic bioreactor: A comprehensive performance study","authors":"Cheau Chin Yap ,&nbsp;Abu Danish Aiman Bin Abu Sofian ,&nbsp;Yi Jing Chan ,&nbsp;Soh Kheang Loh ,&nbsp;Mei Fong Chong ,&nbsp;Lian Keong Lim","doi":"10.1016/j.fuel.2024.133727","DOIUrl":"10.1016/j.fuel.2024.133727","url":null,"abstract":"<div><div>This study evaluates a pilot-plant Integrated Anaerobic-Aerobic Bioreactor (IAAB) for treating Palm Oil Mill Effluent (POME) at a high Organic Loading Rate (OLR) of 30.0 gCOD/L.day. Conducted over 118 days, the research aimed to optimise operational parameters to meet discharge standards. The system’s effectiveness was measured by its ability to reduce Biochemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD), and Total Suspended Solids (TSS) alongside methane production and process stability. Results showed high removal efficiencies: BOD (99.95 %), COD (99.58 %), and TSS (99.24 %), with a consistent methane yield of 0.218 ± 0.032 LCH<sub>4</sub>/gCOD<sub>removed</sub>. These outcomes confirm the IAAB’s capability to maintain effluent quality with BOD under 20 mg/L, complying with the Department of Environment (DOE) Malaysia standards without pH adjustment. The study supports the IAAB’s efficiency in handling significant pollutant loads with stable performance and substantial biogas production, presenting it as a viable solution for sustainable energy management in the palm oil industry. Future research will investigate co-digestion processes to enhance methane yield and economic viability.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133727"},"PeriodicalIF":6.7,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First field application of functionalized nanoparticles-based nanofluids in thermal enhanced oil recovery: From laboratory experiments to cyclic steam stimulation process 基于功能化纳米粒子的纳米流体在热力强化采油中的首次实地应用:从实验室实验到循环蒸汽激发工艺
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-22 DOI: 10.1016/j.fuel.2024.133736
Carlos A. Franco , Camilo A. Franco , Lina M. Salinas , Luis G. Alzate , Daniela Molina , Gabriel J. Rendón , Cristian C. Obregón , Sergio H. Lopera , Oscar E. Medina , Farid B. Cortés
The increasing global demand for fossil fuels and the depletion of light crude oil reserves have driven the petroleum industry to focus on exploiting heavy crude oils, which present significant challenges in recovery and processing. To address these challenges, enhanced oil recovery (EOR) technologies are being developed, with a strong emphasis on advances in catalysis and nanomaterials science. This research significantly contributes to developing new technologies for petroleum exploitation by introducing a novel nanofluid designed to facilitate in-situ upgrading of heavy oil, improving its quality for downstream refining and fuel production. The nanofluid, engineered to enhance the productivity of a heavy oil reservoir under cyclic steam stimulation, targets improvements in oil recovery and fuel-quality indicators such as API gravity and viscosity. Laboratory tests demonstrated the nanofluid’s capability to reduce oil viscosity, improve oil mobility, and selectively interact with heavy oil fractions like resins and asphaltenes. Displacement tests simulating steam injection conditions showed an improvement in oil recovery, increasing from 56 % to 76 % after nanofluid application. The treatment also led to a notable increase in API gravity, from 11.6° to 29.2°, and a significant reduction in viscosity, from 39,987 cP to 104 cP, indicating enhanced crude oil quality, critical for refining and fuel production. Field trials in two wells in Colombia demonstrated the nanofluid’s practical effectiveness, with production increases averaging 97 % and incremental yields of 11,966 barrels in well A and 3213 barrels in well B. Post-treatment, the crude oil exhibited sustained improvements in quality, with API gravity increasing from 11.6° to 13.4° and viscosity decreasing from 39,987 cP to 11,734 cP. These results confirm the long-term durability of the nanofluid’s effects and its potential to enhance fuel production from heavy oil reservoirs. Additionally, the field trial indicated a 48 % reduction in operational costs, primarily due to decreased steam generation and lower CO2 emissions, highlighting the environmental and economic benefits of nanofluid technology for petroleum exploitation.
全球对化石燃料日益增长的需求和轻质原油储量的枯竭促使石油工业将重点放在重质原油的开采上,而重质原油的开采和加工面临着巨大的挑战。为应对这些挑战,正在开发提高石油采收率(EOR)技术,重点是催化和纳米材料科学的进步。这项研究引入了一种新型纳米流体,旨在促进重油的原位升级,提高重油质量,以利于下游精炼和燃料生产,从而为开发石油开采新技术做出重大贡献。这种纳米流体的设计目的是在循环蒸汽刺激下提高重油储层的生产率,从而提高石油采收率和燃料质量指标(如 API 重力和粘度)。实验室测试表明,纳米流体能够降低石油粘度、提高石油流动性,并有选择地与树脂和沥青质等重油馏分相互作用。模拟蒸汽注入条件的置换测试表明,使用纳米流体后,石油采收率从 56% 提高到 76%。这种处理方法还显著提高了 API 重力,从 11.6° 提高到 29.2°,并显著降低了粘度,从 39,987 cP 降至 104 cP,表明原油质量得到提高,这对炼油和燃料生产至关重要。在哥伦比亚两口油井中进行的现场试验证明了纳米流体的实际效果,A 井的平均产量提高了 97%,增产 11966 桶,B 井增产 3213 桶。处理后,原油的质量得到持续改善,API 重力从 11.6° 上升到 13.4°,粘度从 39987 cP 下降到 11734 cP。这些结果证实了纳米流体效果的长期持久性及其提高重油储层燃料产量的潜力。此外,现场试验表明,主要由于蒸汽产生量减少和二氧化碳排放量降低,运营成本降低了 48%,这突出表明了纳米流体技术在石油开采方面的环境和经济效益。
{"title":"First field application of functionalized nanoparticles-based nanofluids in thermal enhanced oil recovery: From laboratory experiments to cyclic steam stimulation process","authors":"Carlos A. Franco ,&nbsp;Camilo A. Franco ,&nbsp;Lina M. Salinas ,&nbsp;Luis G. Alzate ,&nbsp;Daniela Molina ,&nbsp;Gabriel J. Rendón ,&nbsp;Cristian C. Obregón ,&nbsp;Sergio H. Lopera ,&nbsp;Oscar E. Medina ,&nbsp;Farid B. Cortés","doi":"10.1016/j.fuel.2024.133736","DOIUrl":"10.1016/j.fuel.2024.133736","url":null,"abstract":"<div><div>The increasing global demand for fossil fuels and the depletion of light crude oil reserves have driven the petroleum industry to focus on exploiting heavy crude oils, which present significant challenges in recovery and processing. To address these challenges, enhanced oil recovery (EOR) technologies are being developed, with a strong emphasis on advances in catalysis and nanomaterials science. This research significantly contributes to developing new technologies for petroleum exploitation by introducing a novel nanofluid designed to facilitate in-situ upgrading of heavy oil, improving its quality for downstream refining and fuel production. The nanofluid, engineered to enhance the productivity of a heavy oil reservoir under cyclic steam stimulation, targets improvements in oil recovery and fuel-quality indicators such as API gravity and viscosity. Laboratory tests demonstrated the nanofluid’s capability to reduce oil viscosity, improve oil mobility, and selectively interact with heavy oil fractions like resins and asphaltenes. Displacement tests simulating steam injection conditions showed an improvement in oil recovery, increasing from 56 % to 76 % after nanofluid application. The treatment also led to a notable increase in API gravity, from 11.6° to 29.2°, and a significant reduction in viscosity, from 39,987 cP to 104 cP, indicating enhanced crude oil quality, critical for refining and fuel production. Field trials in two wells in Colombia demonstrated the nanofluid’s practical effectiveness, with production increases averaging 97 % and incremental yields of 11,966 barrels in well A and 3213 barrels in well B. Post-treatment, the crude oil exhibited sustained improvements in quality, with API gravity increasing from 11.6° to 13.4° and viscosity decreasing from 39,987 cP to 11,734 cP. These results confirm the long-term durability of the nanofluid’s effects and its potential to enhance fuel production from heavy oil reservoirs. Additionally, the field trial indicated a 48 % reduction in operational costs, primarily due to decreased steam generation and lower CO<sub>2</sub> emissions, highlighting the environmental and economic benefits of nanofluid technology for petroleum exploitation.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133736"},"PeriodicalIF":6.7,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mutual promotion of CoP/CNT/Ni2P by heterojunction structural design and intrinsic activity coupling for water splitting 通过异质结结构设计和内在活性耦合实现 CoP/CNT/Ni2P 相互促进,从而实现水分离
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-22 DOI: 10.1016/j.fuel.2024.133761
Guo Yu , Jiaxiang Zhao , Songjia Hou , Haoyang Han , Qing Zhou , Zuoyi Yan , Jie Liu , Haohong Li , Huidong Zheng , Meiqing Zheng
The design of highly stable and active bifunctional catalysts for electrolytic water remains a significant challenge. In this study, self-supported CoP/CNT/Ni2P bifunctional catalysts with three-phase heterojunction nanostructures were constructed by a multi-step electrodeposition and phosphorylation strategy. X-ray diffraction analysis and transmission electron microscope showed that CoP/CNT/Ni2P was a three-phase heterojunction nanostructure, and scanning electron microscope results of CoP/CNT/Ni2P suggested the successful introduction of carbon nanotube (CNT). The X-ray photoelectron spectroscopy results indicate a shift in the elemental binding energy in CoP/CNT/Ni2P, which is believed to contribute to the electrocatalytic reaction. The incorporation of CNT enhances charge transfer within the multiphase catalyst and maximizes the exposure of catalytically active sites, achieving an increase in catalyst performance. As anticipated, the CoP/CNT/Ni2P catalyst displays high catalytic activity for both the hydrogen evolution reaction (61 mV at 10 mA cm−2) and the oxygen evolution reaction (342 mV at 100 mA cm−2), in addition to exhibiting long-term stability at a current density of 10 mA cm−2 over 40 h. The electrolyzer comprising CoP/CNT/Ni2P(+,−) necessitates a modest operating voltage of 1.52 V to attain 10 mA cm−2 during alkaline water splitting, thereby outperforming the commercial catalyst Pt/C||IrO2 and earlier reports. This study provides guidance for the development of ultra-high activity and durability catalysts for water splitting.
设计用于电解水的高稳定性和高活性双功能催化剂仍然是一项重大挑战。本研究通过多步电沉积和磷化策略,构建了具有三相异质结纳米结构的自支撑 CoP/CNT/Ni2P 双功能催化剂。X 射线衍射分析和透射电子显微镜显示 CoP/CNT/Ni2P 为三相异质结纳米结构,CoP/CNT/Ni2P 的扫描电子显微镜结果表明成功引入了碳纳米管(CNT)。X 射线光电子能谱结果表明,CoP/CNT/Ni2P 中的元素结合能发生了变化,这被认为有助于电催化反应。CNT 的加入增强了多相催化剂内部的电荷转移,最大限度地暴露了催化活性位点,从而提高了催化剂的性能。正如预期的那样,CoP/CNT/Ni2P 催化剂在氢气进化反应(10 mA cm-2 时为 61 mV)和氧气进化反应(100 mA cm-2 时为 342 mV)中都表现出很高的催化活性,此外,在 10 mA cm-2 的电流密度下还能长期稳定地工作 40 小时。由 CoP/CNT/Ni2P(+,-) 组成的电解槽只需 1.52 V 的适度工作电压就能在碱性水分离过程中达到 10 mA cm-2,因此性能优于商业催化剂 Pt/C||IrO2 和之前的报告。这项研究为开发超高活性和耐久性的水分离催化剂提供了指导。
{"title":"Mutual promotion of CoP/CNT/Ni2P by heterojunction structural design and intrinsic activity coupling for water splitting","authors":"Guo Yu ,&nbsp;Jiaxiang Zhao ,&nbsp;Songjia Hou ,&nbsp;Haoyang Han ,&nbsp;Qing Zhou ,&nbsp;Zuoyi Yan ,&nbsp;Jie Liu ,&nbsp;Haohong Li ,&nbsp;Huidong Zheng ,&nbsp;Meiqing Zheng","doi":"10.1016/j.fuel.2024.133761","DOIUrl":"10.1016/j.fuel.2024.133761","url":null,"abstract":"<div><div>The design of highly stable and active bifunctional catalysts for electrolytic water remains a significant challenge. In this study, self-supported CoP/CNT/Ni<sub>2</sub>P bifunctional catalysts with three-phase heterojunction nanostructures were constructed by a multi-step electrodeposition and phosphorylation strategy. X-ray diffraction analysis and transmission electron microscope showed that CoP/CNT/Ni<sub>2</sub>P was a three-phase heterojunction nanostructure, and scanning electron microscope results of CoP/CNT/Ni<sub>2</sub>P suggested the successful introduction of carbon nanotube (CNT). The X-ray photoelectron spectroscopy results indicate a shift in the elemental binding energy in CoP/CNT/Ni<sub>2</sub>P, which is believed to contribute to the electrocatalytic reaction. The incorporation of CNT enhances charge transfer within the multiphase catalyst and maximizes the exposure of catalytically active sites, achieving an increase in catalyst performance. As anticipated, the CoP/CNT/Ni<sub>2</sub>P catalyst displays high catalytic activity for both the hydrogen evolution reaction (61 mV at 10 mA cm<sup>−2</sup>) and the oxygen evolution reaction (342 mV at 100 mA cm<sup>−2</sup>), in addition to exhibiting long-term stability at a current density of 10 mA cm<sup>−2</sup> over 40 h. The electrolyzer comprising CoP/CNT/Ni<sub>2</sub>P<sub>(+,−)</sub> necessitates a modest operating voltage of 1.52 V to attain 10 mA cm<sup>−2</sup> during alkaline water splitting, thereby outperforming the commercial catalyst Pt/C||IrO<sub>2</sub> and earlier reports. This study provides guidance for the development of ultra-high activity and durability catalysts for water splitting.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133761"},"PeriodicalIF":6.7,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ thermite combustion of micro magnesium fuel and lunar regolith simulant nanoparticles 微镁燃料和月球碎屑模拟纳米颗粒的原位热火燃烧
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-22 DOI: 10.1016/j.fuel.2024.133722
Connor J. MacRobbie, Anqi Wang, Jean-Pierre Hickey, John Z. Wen
Significant heat generation will be required for humans and equipment to the lunar night. In this work, we investigate the use of a sustainable in-situ thermite material as a fuel to provide the thermal energy required to keep components in working conditions. Magnesium is used as a reactive metal fuel, with lunar regolith simulant ball milled to sub-micron sizes as a solid oxidizer producing exothermic reactions. Enhanced combustion is achieved by controlling particle size and composition of the thermite mixture. Simulant particles ranging from hundreds of nanometers to tens of microns in diameter are tested, as well as the magnesium fuel compositions of 20% to 40% by weight. Small pellets of 3 mm in diameter and 3 mm in height are ignited by laser in both air and vacuum to quantify the combustion properties in different environments. High speed video, infrared camera and pyrometry techniques are taken to quantify the sample combustion properties. These pellets demonstrate the burning rates between 2.3 and 5.9 mm/s and temperatures ranging from 1100 to 1480 °C in vacuum and in air conditions, respectively. The samples composed of 20% magnesium and 80% regolith simulant release around 400 J/g, and sustain elevated temperatures for 15 s after combustion, making them suitable for in-situ lunar heating. Novel 2D temperature mapping allows greater understanding of the simulant thermite combustion. Based on the results, we discuss the design considerations that would need to be made in the creation of an in-situ metal fuel heating lunar system.
人类和设备在月夜需要大量的热量。在这项工作中,我们研究了使用一种可持续的原地热敏材料作为燃料,以提供使组件保持工作状态所需的热能。镁被用作反应性金属燃料,月球碎屑模拟物被球磨成亚微米大小,作为固体氧化剂产生放热反应。通过控制热敏混合物的颗粒大小和成分,可以增强燃烧效果。测试了直径从数百纳米到数十微米的模拟颗粒,以及重量百分比为 20% 到 40% 的镁燃料成分。直径 3 毫米、高 3 毫米的小颗粒在空气和真空中用激光点燃,以量化不同环境下的燃烧特性。采用高速视频、红外摄像和高温测量技术来量化样品的燃烧特性。这些颗粒在真空和空气条件下的燃烧速率分别为 2.3 至 5.9 mm/s,温度范围为 1100 至 1480 ℃。由20%的镁和80%的流石模拟物组成的样品释放出约400焦耳/克的热量,并在燃烧后保持15秒的高温,使其适用于原位月球加热。新颖的二维温度分布图让我们对模拟热剂燃烧有了更深入的了解。基于这些结果,我们讨论了在创建原位金属燃料加热月球系统时需要考虑的设计因素。
{"title":"In-situ thermite combustion of micro magnesium fuel and lunar regolith simulant nanoparticles","authors":"Connor J. MacRobbie,&nbsp;Anqi Wang,&nbsp;Jean-Pierre Hickey,&nbsp;John Z. Wen","doi":"10.1016/j.fuel.2024.133722","DOIUrl":"10.1016/j.fuel.2024.133722","url":null,"abstract":"<div><div>Significant heat generation will be required for humans and equipment to the lunar night. In this work, we investigate the use of a sustainable in-situ thermite material as a fuel to provide the thermal energy required to keep components in working conditions. Magnesium is used as a reactive metal fuel, with lunar regolith simulant ball milled to sub-micron sizes as a solid oxidizer producing exothermic reactions. Enhanced combustion is achieved by controlling particle size and composition of the thermite mixture. Simulant particles ranging from hundreds of nanometers to tens of microns in diameter are tested, as well as the magnesium fuel compositions of 20% to 40% by weight. Small pellets of 3 mm in diameter and 3 mm in height are ignited by laser in both air and vacuum to quantify the combustion properties in different environments. High speed video, infrared camera and pyrometry techniques are taken to quantify the sample combustion properties. These pellets demonstrate the burning rates between 2.3 and 5.9 mm/s and temperatures ranging from 1100 to 1480 °C in vacuum and in air conditions, respectively. The samples composed of 20% magnesium and 80% regolith simulant release around 400 J/g, and sustain elevated temperatures for 15 s after combustion, making them suitable for in-situ lunar heating. Novel 2D temperature mapping allows greater understanding of the simulant thermite combustion. Based on the results, we discuss the design considerations that would need to be made in the creation of an in-situ metal fuel heating lunar system.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133722"},"PeriodicalIF":6.7,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142700991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study of combustion and emissions characteristics of low blend ratio of 2-methylfuran/ 2-methyltetrahyrofuran with gasoline in a DISI engine DISI 发动机中 2-甲基呋喃/2-甲基四氢呋喃与汽油低混合比燃烧和排放特性的实验研究
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-22 DOI: 10.1016/j.fuel.2024.133799
Rafiu K. Olalere , Gengxin Zhang , Haoye Liu , Xiao Ma , Hongming Xu
The nearing depletion of fossil fuels and the possible consequences of its emissions on the global climate has prompted a worldwide probe for their alternatives. 2-methylfuran and 2-methyltetrahydrofuran are considered promising alternative fuels for spark ignition engines. In this study, the combustion and emission characteristics of low blending ratio MF20 (2-methylfuran 20 %, gasoline 80 % by volume) and MTHF20 (2-methyltetrahydrofuran 20 %, gasoline 80 % by volume) were first implemented and compared to neat gasoline in a single-cylinder direct injection spark ignition engine. The combustion performance of the test fuels was analyzed across a range of loads from 3.5 to 8.5 bar indicated mean effective pressure and fuel injection timings between 180 and 280 crank angle degrees before top dead center. Meanwhile, the compositions of the hydrocarbon emissions were experimentally investigated using the Fourier Transform Infrared Spectroscopy technique. Results show that MF20 exhibits advanced spark timing flexibility of 8 and 7 crank angle degrees before top dead center compared to the unleaded gasoline and MTHF20 respectively at the peak load. MTHF20 exhibits the highest maximum cylinder pressure at medium load compared to other fuels but drops sharply at peak load accompany with the audible knock. Additionally, MTHF20 exhibits specific fuel consumption advantage over MF20 across the entire load range. The unburned furan of the total hydrocarbon emissions was recorded to be 3 % of total hydrocarbon emissions. The concept of low blending ratio furan-based fuel proposed could provide a solution for the transition period of carbon neutrality.
化石燃料即将枯竭,其排放物可能对全球气候造成影响,这促使全世界都在探索其替代品。2-甲基呋喃和 2-甲基四氢呋喃被认为是火花点火发动机的理想替代燃料。本研究首次在单缸直喷式火花点火发动机中使用了低混合比 MF20(2-甲基呋喃 20%,汽油 80%(体积比))和 MTHF20(2-甲基四氢呋喃 20%,汽油 80%(体积比)),并将其与纯汽油进行了燃烧和排放特性比较。在 3.5 至 8.5 巴的负载范围内,分析了测试燃料的燃烧性能,显示了平均有效压力和顶死中心前 180 至 280 曲柄角之间的喷油时间。同时,使用傅立叶变换红外光谱技术对碳氢化合物排放的成分进行了实验研究。结果表明,与无铅汽油和 MTHF20 相比,在峰值负荷下,MF20 的火花定时灵活性分别比顶死点提前了 8 和 7 曲柄角度。与其他燃料相比,MTHF20 在中等负荷时表现出最高的最大气缸压力,但在峰值负荷时急剧下降,并伴有明显的敲击声。此外,与 MF20 相比,MTHF20 在整个负荷范围内都表现出比油耗优势。据记录,未燃烧的呋喃占碳氢化合物排放总量的 3%。所提出的低混合比呋喃基燃料概念可为碳中和过渡时期提供解决方案。
{"title":"Experimental study of combustion and emissions characteristics of low blend ratio of 2-methylfuran/ 2-methyltetrahyrofuran with gasoline in a DISI engine","authors":"Rafiu K. Olalere ,&nbsp;Gengxin Zhang ,&nbsp;Haoye Liu ,&nbsp;Xiao Ma ,&nbsp;Hongming Xu","doi":"10.1016/j.fuel.2024.133799","DOIUrl":"10.1016/j.fuel.2024.133799","url":null,"abstract":"<div><div>The nearing depletion of fossil fuels and the possible consequences of its emissions on the global climate has prompted a worldwide probe for their alternatives. 2-methylfuran and 2-methyltetrahydrofuran are considered promising alternative fuels for spark ignition engines. In this study, the combustion and emission characteristics of low blending ratio MF20 (2-methylfuran 20 %, gasoline 80 % by volume) and MTHF20 (2-methyltetrahydrofuran 20 %, gasoline 80 % by volume) were first implemented and compared to neat gasoline in a single-cylinder direct injection spark ignition engine. The combustion performance of the test fuels was analyzed across a range of loads from 3.5 to 8.5 bar indicated mean effective pressure and fuel injection timings between 180 and 280 crank angle degrees before top dead center. Meanwhile, the compositions of the hydrocarbon emissions were experimentally investigated using the Fourier Transform Infrared Spectroscopy technique. Results show that MF20 exhibits advanced spark timing flexibility of 8 and 7 crank angle degrees before top dead center compared to the unleaded gasoline and MTHF20 respectively at the peak load. MTHF20 exhibits the highest maximum cylinder pressure at medium load compared to other fuels but drops sharply at peak load accompany with the audible knock. Additionally, MTHF20 exhibits specific fuel consumption advantage over MF20 across the entire load range. The unburned furan of the total hydrocarbon emissions was recorded to be 3 % of total hydrocarbon emissions. The concept of low blending ratio furan-based fuel proposed could provide a solution for the transition period of carbon neutrality.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133799"},"PeriodicalIF":6.7,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142701034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of methanol energy substitution ratio and diesel injection timing on a methanol/diesel dual-fuel direct injection engine 甲醇能量替代率和柴油喷射时间对甲醇/柴油双燃料直喷发动机的影响
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-21 DOI: 10.1016/j.fuel.2024.133773
Xiaojun Yin , Yu Yan , Xianfeng Ren , Lixin Yu , Hao Duan , Erjiang Hu , Ke Zeng
Dual-direct injection technology is a very promising method to improve the mixture organization and combustion process of dual-fuel engines. In this paper, the performance of a modified dual-fuel engine fueled with methanol and diesel has been explored experimentally at various methanol energy substitution ratios (ESRMs) and diesel injection timings (SOIDs). Independent injection of methanol and diesel is realized in real time and accurately through a dual-direct injection system with by two different in-cylinder injectors based on engine operating status. The results show that the dual-direct injection technology has great potential to expand the operating range of the engine, with the improvement of indicated thermal efficiency (ITE) and the reduction of pollutant emissions. It is noted that ESRM and SOID are both very significant factors to influence the combustion phasing and exothermic process. As the SOID advances, the combustion process is enhanced and the HC, CO and soot emissions are limited, while the NOx emissions are sacrificed to some extent. By optimizing of ESRM, synchronous optimization of ITE and NOx has been realized. As the ESRM increases, the ITE increases first, achieving a maximum value of 41.5% at 50% ESRM, and then decreases quickly, which is opposite to the HC and CO emissions. However, NOx and soot emissions are consistently reduced as the ESRM increases. Compared with SOID, the ITE is highly sensitive to the ESRM. Moreover, the combustion stability can be enhanced effectively through the collaborative optimization of SOID and ESRM.
双直接喷射技术是改善双燃料发动机混合气组织和燃烧过程的一种非常有前途的方法。本文通过实验探讨了在不同的甲醇能量替代比(ESRMs)和柴油喷射时间(SOIDs)条件下,以甲醇和柴油为燃料的改进型双燃料发动机的性能。甲醇和柴油的独立喷射是通过一个双直喷系统实时、准确地实现的,该系统根据发动机的工作状态由两个不同的缸内喷射器进行喷射。结果表明,双直喷技术在扩大发动机工作范围、提高指示热效率(ITE)和减少污染物排放方面具有巨大潜力。值得注意的是,ESRM 和 SOID 都是影响燃烧相位和放热过程的重要因素。随着 SOID 的增加,燃烧过程得到加强,HC、CO 和烟尘排放受到限制,而 NOx 排放则会在一定程度上受到影响。通过优化 ESRM,实现了 ITE 和 NOx 的同步优化。随着 ESRM 的增加,ITE 首先增加,在 50% ESRM 时达到最大值 41.5%,然后迅速减少,这与 HC 和 CO 的排放正好相反。然而,随着 ESRM 的增加,NOx 和烟尘排放量持续减少。与 SOID 相比,ITE 对 ESRM 非常敏感。此外,通过协同优化 SOID 和 ESRM,可以有效提高燃烧稳定性。
{"title":"Effects of methanol energy substitution ratio and diesel injection timing on a methanol/diesel dual-fuel direct injection engine","authors":"Xiaojun Yin ,&nbsp;Yu Yan ,&nbsp;Xianfeng Ren ,&nbsp;Lixin Yu ,&nbsp;Hao Duan ,&nbsp;Erjiang Hu ,&nbsp;Ke Zeng","doi":"10.1016/j.fuel.2024.133773","DOIUrl":"10.1016/j.fuel.2024.133773","url":null,"abstract":"<div><div>Dual-direct injection technology is a very promising method to improve the mixture organization and combustion process of dual-fuel engines. In this paper, the performance of a modified dual-fuel engine fueled with methanol and diesel has been explored experimentally at various methanol energy substitution ratios (ESR<sub>M</sub>s) and diesel injection timings (SOI<sub>D</sub>s). Independent injection of methanol and diesel is realized in real time and accurately through a dual-direct injection system with by two different in-cylinder injectors based on engine operating status. The results show that the dual-direct injection technology has great potential to expand the operating range of the engine, with the improvement of indicated thermal efficiency (ITE) and the reduction of pollutant emissions. It is noted that ESR<sub>M</sub> and SOI<sub>D</sub> are both very significant factors to influence the combustion phasing and exothermic process. As the SOI<sub>D</sub> advances, the combustion process is enhanced and the HC, CO and soot emissions are limited, while the NO<em><sub>x</sub></em> emissions are sacrificed to some extent. By optimizing of ESR<sub>M</sub>, synchronous optimization of ITE and NO<em><sub>x</sub></em> has been realized. As the ESR<sub>M</sub> increases, the ITE increases first, achieving a maximum value of 41.5% at 50% ESR<sub>M</sub>, and then decreases quickly, which is opposite to the HC and CO emissions. However, NO<em><sub>x</sub></em> and soot emissions are consistently reduced as the ESR<sub>M</sub> increases. Compared with SOI<sub>D</sub>, the ITE is highly sensitive to the ESR<sub>M</sub>. Moreover, the combustion stability can be enhanced effectively through the collaborative optimization of SOI<sub>D</sub> and ESR<sub>M</sub>.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133773"},"PeriodicalIF":6.7,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142701855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Vesicle-Shaped Co-Ni-S designed by first principles screening and d-Band center control for active hydrogen evolution 通过第一原理筛选和 d 波段中心控制设计的囊泡状 Co-Ni-S 可用于主动氢气进化
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-21 DOI: 10.1016/j.fuel.2024.133743
Youbin Zheng , Ze Li , Hao Guo , Cunyin Liu , Yuefeng Chen , Xiumei Han , Liang Dong , Jianbing Zang
Hydrogen evolution reaction (HER) is considered as an effective pathway for hydrogen production. Herein, to obtain efficient HER catalyst, density functional theory is employed to figure out the optimal candidate for nickel sulfide. Guided by the mechanistic screening, the highly active HER electrocatalyst, Co-substituted Ni3S4, is synthesized by one-step hydrothermal method, resembling a vesicle composed of a broken spherical membrane and encapsulated clusters of nanospheres. Cracks on membrane provide a rational entry for reactant molecules to be enclosed in the vesicle. Additionally, the enhanced intrinsic activity also attributes to the upward shift of the d-band center. From the reaction energy diagrams, the decomposition of H2O* is confirmed as the rate-determining step (RDS) and the energy required for the RDS is efficiently lowered by the elevated d-band center, which made the catalyst achieves 185 mV overpotential at 100 mA·cm−2 and 38 mV at 20 mA·cm−2 lower than utmost Co-Ni-S relative electrocatalyst.
氢进化反应(HER)被认为是制氢的有效途径。为了获得高效的 HER 催化剂,本文采用密度泛函理论找出硫化镍的最佳候选物。在机理筛选的指导下,一步水热法合成了高活性 HER 电催化剂 Co 取代 Ni3S4。膜上的裂缝为反应物分子进入囊泡提供了合理的入口。此外,内在活性的增强还归因于 d 波段中心的上移。从反应能量图来看,H2O* 的分解被确认为速率决定步骤(RDS),而 RDS 所需的能量因 d 带中心的升高而有效降低,这使得催化剂在 100 mA-cm-2 时的过电位达到 185 mV,在 20 mA-cm-2 时的过电位比最大 Co-Ni-S 相对电催化剂低 38 mV。
{"title":"Vesicle-Shaped Co-Ni-S designed by first principles screening and d-Band center control for active hydrogen evolution","authors":"Youbin Zheng ,&nbsp;Ze Li ,&nbsp;Hao Guo ,&nbsp;Cunyin Liu ,&nbsp;Yuefeng Chen ,&nbsp;Xiumei Han ,&nbsp;Liang Dong ,&nbsp;Jianbing Zang","doi":"10.1016/j.fuel.2024.133743","DOIUrl":"10.1016/j.fuel.2024.133743","url":null,"abstract":"<div><div>Hydrogen evolution reaction (HER) is considered as an effective pathway for hydrogen production. Herein, to obtain efficient HER catalyst, density functional theory is employed to figure out the optimal candidate for nickel sulfide. Guided by the mechanistic screening, the highly active HER electrocatalyst, Co-substituted Ni<sub>3</sub>S<sub>4</sub>, is synthesized by one-step hydrothermal method, resembling a vesicle composed of a broken spherical membrane and encapsulated clusters of nanospheres. Cracks on membrane provide a rational entry for reactant molecules to be enclosed in the vesicle. Additionally, the enhanced intrinsic activity also attributes to the upward shift of the d-band center. From the reaction energy diagrams, the decomposition of H<sub>2</sub>O* is confirmed as the rate-determining step (RDS) and the energy required for the RDS is efficiently lowered by the elevated d-band center, which made the catalyst achieves 185 mV overpotential at 100 mA·cm<sup>−2</sup> and 38 mV at 20 mA·cm<sup>−2</sup> lower than utmost Co-Ni-S relative electrocatalyst.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133743"},"PeriodicalIF":6.7,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142701856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction and thermal characterizes of ventilation-controlled fire in coal mine dead-end roadway: An experimental investigation 煤矿巷道通风控制火灾的预测和热特性:实验研究
IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-21 DOI: 10.1016/j.fuel.2024.133765
Jingxin Wang , Baolin Qu , Yu Meng , Chenguang Zhao , Bing Wu
Ventilation conditions can significantly affect the fire behavior of dead-end roadway fires. Due to the unique characteristics of coal mine dead-end roadways, fires in such environments are prone to transition into ventilation-controlled fires, presenting a significant threat to mine production and personnel safety. In this study, several small-scale experiments were used to investigate the thermal characteristics and critical conditions for ventilation-controlled combustion in dead-end roadway fires. The findings show that the flame range, flame length, smoke temperature, and fuel mass loss rate are significantly higher in ventilation-controlled fires than in fuel-controlled fires. Lower ventilation velocities lead to an earlier transition to ventilation-controlled combustion and higher mass loss rates. Besides, a prediction model for dead-end roadway fires based on fuel-to-air equivalent ratio is proposed to forecast the combustion type. The critical fuel-to-air equivalence ratio for the occurrence of ventilation-controlled fires is 0.08–0.11. In addition, the oxygen volume fraction in the downstream smoke of the fire source will stabilize at about 2 % and 15 % in ventilation-controlled fires and fuel-controlled fires, respectively. When the combustion changes from fuel-controlled to ventilation-controlled combustion, the CO yield will rise rapidly. Moreover, when the ventilation velocity is lower than the critical ventilation velocity, combustion often transitions to ventilation-controlled combustion. The outcomes of this research offer a novel perspective into the fire behavior of dead-end roadways, offering valuable guidance for firefighting and rescue operations in similar structures.
通风条件会严重影响巷道死角火灾的起火行为。由于煤矿巷道死角的特殊性,这种环境下的火灾很容易转变为通风控制型火灾,对煤矿生产和人员安全构成重大威胁。在这项研究中,使用了几个小规模实验来研究巷道死角火灾中通风控制燃烧的热特性和关键条件。研究结果表明,通风控制燃烧的火焰范围、火焰长度、烟雾温度和燃料质量损失率明显高于燃料控制燃烧。较低的通风速度会导致更早地过渡到通风控制燃烧和更高的质量损失率。此外,还提出了一种基于燃料与空气当量比的巷道死角火灾预测模型,用于预测燃烧类型。发生通风控制型火灾的临界燃料空气当量比为 0.08-0.11。此外,在通风控制型火灾和燃料控制型火灾中,火源下游烟雾中的氧气体积分数将分别稳定在 2% 和 15% 左右。当燃烧从燃料控制转变为通风控制燃烧时,一氧化碳产量会迅速上升。此外,当通风速度低于临界通风速度时,燃烧往往会过渡到通风控制燃烧。这项研究成果为研究死巷的火灾行为提供了一个新的视角,为类似结构中的灭火和救援行动提供了宝贵的指导。
{"title":"Prediction and thermal characterizes of ventilation-controlled fire in coal mine dead-end roadway: An experimental investigation","authors":"Jingxin Wang ,&nbsp;Baolin Qu ,&nbsp;Yu Meng ,&nbsp;Chenguang Zhao ,&nbsp;Bing Wu","doi":"10.1016/j.fuel.2024.133765","DOIUrl":"10.1016/j.fuel.2024.133765","url":null,"abstract":"<div><div>Ventilation conditions can significantly affect the fire behavior of dead-end roadway fires. Due to the unique characteristics of coal mine dead-end roadways, fires in such environments are prone to transition into ventilation-controlled fires, presenting a significant threat to mine production and personnel safety. In this study, several small-scale experiments were used to investigate the thermal characteristics and critical conditions for ventilation-controlled combustion in dead-end roadway fires. The findings show that the flame range, flame length, smoke temperature, and fuel mass loss rate are significantly higher in ventilation-controlled fires than in fuel-controlled fires. Lower ventilation velocities lead to an earlier transition to ventilation-controlled combustion and higher mass loss rates. Besides, a prediction model for dead-end roadway fires based on fuel-to-air equivalent ratio is proposed to forecast the combustion type. The critical fuel-to-air equivalence ratio for the occurrence of ventilation-controlled fires is 0.08–0.11. In addition, the oxygen volume fraction in the downstream smoke of the fire source will stabilize at about 2 % and 15 % in ventilation-controlled fires and fuel-controlled fires, respectively. When the combustion changes from fuel-controlled to ventilation-controlled combustion, the CO yield will rise rapidly. Moreover, when the ventilation velocity is lower than the critical ventilation velocity, combustion often transitions to ventilation-controlled combustion. The outcomes of this research offer a novel perspective into the fire behavior of dead-end roadways, offering valuable guidance for firefighting and rescue operations in similar structures.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"382 ","pages":"Article 133765"},"PeriodicalIF":6.7,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142701033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Fuel
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1