The life cycle carbon dioxide equivalent (CO2e) intensity of Power-to-Liquid (PtL) sustainable aviation fuel (SAF) scenarios in Spain are evaluated using a specific, granular, and transparent modelling approach. Post combustion CO2 capture and direct air CO2 capture are considered, in addition to grid and renewable electricity sources. The mass and energy requirements of the PtL system are determined from a mass and energy conserved reaction mechanism and a comprehensive literature review. The SAF yield is constrained by its molecular composition, formulated to meet the physical property specifications for Fischer-Tropsch synthetic paraffinic kerosene (FT-SPK) in ASTM D7566 Annex 1. The results of the life cycle assessment (LCA) show large ranges in CO2e intensity of PtL SAF scenarios, from 11 to 101 gCO2e/MJ. The electricity emission factors at which the CO2e intensity of PtL SAFs meet the 70% reduction required under the ReFuelEU Aviation legislation are 112 – 168 gCO2e/kWh for direct air capture and post combustion capture of biogenic CO2. As the average EU grid is approximately 300 gCO2e/kWh, the use of renewable electricity (onsite or power purchase agreement) is therefore essential to achieve the 70% reduction. The carbon intensity of the Madrid to Dublin commercial flight route is analysed, per revenue-passenger-kilometre (RPK), as a specific use case with actual data of Ryanair Boeing 737-800 and 737 MAX 8 aircraft. Compared to the Science Based Targets 1.5°C limit of 3.3 gCO2/RPK, it is shown that sustainable aviation is challenging using PtL SAF, with a best case of 9 gCO2/RPK.
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