首页 > 最新文献

Plant\/operations Progress最新文献

英文 中文
Ultimate capacity of blast loaded structures common to chemical plants 化工厂常用爆炸荷载结构的极限承载力
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110407
M. Whitney, D. Barker, K. H. Spivey
There has been a great deal of investment in development of design criteria and design and construction of heavily reinforced, blast-resistant control rooms. This remains the best option for protective construction against severe blast loading experienced close in to a vapor cloud or other explosion hazard. However, most structures encountered at chemical plants and contemplated for future construction are conventional steel frame, metal clad buildings. In this paper we look closely at the response of such buildings to explosion loads and their ability to undergo large deformations without structural failure. The types of structural elements evaluated include metal decking of various gauge and shape along with a variety of girt and purlin sections. Building frames or bents are also evaluated, although the date base for these is much more limited. The work is based on observations made during investigations of large explosion accidents along with analytical predictions and test measurements. To conclude, we offer specific design criteria and connection recommendations for enhancing the overall strength of a building through the use of conventional components in unconventional construction.
在设计标准的制定以及重加固、防爆控制室的设计和施工方面投入了大量资金。这仍然是保护建筑免受严重爆炸载荷的最佳选择,经历靠近蒸汽云或其他爆炸危险。然而,在化工厂遇到的大多数结构和未来的建设都是传统的钢框架,金属包层建筑。在本文中,我们仔细研究了这类建筑物对爆炸荷载的反应及其承受大变形而不破坏结构的能力。所评估的结构元素类型包括各种规格和形状的金属甲板以及各种围梁和檩条。构建框架或弯曲也会被评估,尽管它们的数据基础要有限得多。这项工作是基于对大型爆炸事故的调查以及分析预测和试验测量所作的观察。最后,我们提供了具体的设计标准和连接建议,通过在非常规建筑中使用传统组件来提高建筑物的整体强度。
{"title":"Ultimate capacity of blast loaded structures common to chemical plants","authors":"M. Whitney, D. Barker, K. H. Spivey","doi":"10.1002/PRSB.720110407","DOIUrl":"https://doi.org/10.1002/PRSB.720110407","url":null,"abstract":"There has been a great deal of investment in development of design criteria and design and construction of heavily reinforced, blast-resistant control rooms. This remains the best option for protective construction against severe blast loading experienced close in to a vapor cloud or other explosion hazard. However, most structures encountered at chemical plants and contemplated for future construction are conventional steel frame, metal clad buildings. In this paper we look closely at the response of such buildings to explosion loads and their ability to undergo large deformations without structural failure. The types of structural elements evaluated include metal decking of various gauge and shape along with a variety of girt and purlin sections. Building frames or bents are also evaluated, although the date base for these is much more limited. The work is based on observations made during investigations of large explosion accidents along with analytical predictions and test measurements. To conclude, we offer specific design criteria and connection recommendations for enhancing the overall strength of a building through the use of conventional components in unconventional construction.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123900628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Documentation and utilization of the results of hazard evaluation studies 记录和利用危害评价研究的结果
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110414
D. Hendershot
A Hazard Evaluation (HE) study is not finished until the study documentation is complete and all of the issues and recommendations from the HE study have been resolved. While the extent and detail of the HE documentation will vary depending on the HE technique used, and on the stage in the process life cycle at which the study is performed, all studies should include documentation in three categories: 1 Process documentation, defining the design and intended operation of the facility at the time the HE study was performed. 2 HE study documentation, recording the actual performance of the HE study and including, for example, meeting notes or worksheets, logic models, hazard index calculations, etc. 3 Action documentation, summarizing all recommendations, perhaps with prioritization, and listing actions taken in response to the recommendations. Thorough and complete documentation of HE studies is essential for understanding the concerns which give rise to each recommendation, tracking action taken on recommendations to insure that all are resolved, using the HE study as a basis for subsequent HE or quantitative risk analysis studies, using the HE study to assist in the management of change, and periodic updating of the HE study. Modern computer based information storage and retrieval technology also opens the potential for use of HE study documentation as a tool for training and for process troubleshooting.
在研究文件完成并且HE研究的所有问题和建议得到解决之前,危害评估(HE)研究尚未完成。虽然HE文件的范围和细节将根据所使用的HE技术和进行研究的过程生命周期阶段而有所不同,但所有研究都应包括三类文件:1过程文件,在进行HE研究时定义设施的设计和预期操作。2 . HE研究文件,记录HE研究的实际表现,包括会议记录或工作表、逻辑模型、危险指数计算等。3 .行动文件,总结所有建议,可能有优先顺序,并列出针对建议采取的行动。全面完整的高等教育研究文件对于理解产生每项建议的问题,跟踪建议所采取的行动以确保所有问题都得到解决,将高等教育研究作为后续高等教育或定量风险分析研究的基础,使用高等教育研究协助管理变更,以及定期更新高等教育研究至关重要。现代以计算机为基础的信息存储和检索技术也开辟了利用高等教育研究文件作为培训和过程故障排除工具的潜力。
{"title":"Documentation and utilization of the results of hazard evaluation studies","authors":"D. Hendershot","doi":"10.1002/PRSB.720110414","DOIUrl":"https://doi.org/10.1002/PRSB.720110414","url":null,"abstract":"A Hazard Evaluation (HE) study is not finished until the study documentation is complete and all of the issues and recommendations from the HE study have been resolved. While the extent and detail of the HE documentation will vary depending on the HE technique used, and on the stage in the process life cycle at which the study is performed, all studies should include documentation in three categories: \u0000 \u0000 \u0000 \u00001 \u0000Process documentation, defining the design and intended operation of the facility at the time the HE study was performed. \u0000 \u00002 \u0000HE study documentation, recording the actual performance of the HE study and including, for example, meeting notes or worksheets, logic models, hazard index calculations, etc. \u0000 \u00003 \u0000Action documentation, summarizing all recommendations, perhaps with prioritization, and listing actions taken in response to the recommendations. \u0000 \u0000 \u0000 \u0000 \u0000 \u0000Thorough and complete documentation of HE studies is essential for understanding the concerns which give rise to each recommendation, tracking action taken on recommendations to insure that all are resolved, using the HE study as a basis for subsequent HE or quantitative risk analysis studies, using the HE study to assist in the management of change, and periodic updating of the HE study. Modern computer based information storage and retrieval technology also opens the potential for use of HE study documentation as a tool for training and for process troubleshooting.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133373825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Process safety testing program for reducing risks associated with large scale chemical manufacturing operations 过程安全测试程序,以减少与大规模化学生产操作相关的风险
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110412
J. Sharkey, R. Cutro, W. J. Fraser, G. Wildman
The reduction of risks associated with chemical processing operations is essential for the safe operation of chemical plants. The reduction of these risks is accomplished through a comprehensive process safety management program. Key elements of this program include Hazard and Operability Studies, Emergency Relief Venting, Process Automation, Management of Change Control Procedures, Process Specific Training, and so forth. Central to many of these elements is a thorough, in-depth understanding of the reactive nature of chemical processing operations. This understanding can only be obtained through intensive laboratory evalutions using “leading edge” process safety testing technologies. To accomplish this goal, a systematic process safety testing program has been established aimed at characterizing the reactive nature of both the desired and undesired chemistry. The information obtained is directly applicable to the development of intrinsically safe processes and for the safe design/operation of chemical processing facilities.
减少与化学加工操作有关的风险对化工厂的安全运行至关重要。减少这些风险是通过一个全面的过程安全管理程序来完成的。该计划的关键要素包括危害和可操作性研究、紧急救援排气、过程自动化、变更控制程序管理、过程特定培训等等。许多这些要素的核心是对化学处理操作的反应性质的透彻、深入的理解。这种理解只能通过使用“前沿”过程安全测试技术进行密集的实验室评估来获得。为了实现这一目标,已经建立了一个系统的过程安全测试程序,旨在描述所需和不需要的化学反应性质。所获得的信息直接适用于本质安全工艺的发展和化学处理设施的安全设计/操作。
{"title":"Process safety testing program for reducing risks associated with large scale chemical manufacturing operations","authors":"J. Sharkey, R. Cutro, W. J. Fraser, G. Wildman","doi":"10.1002/PRSB.720110412","DOIUrl":"https://doi.org/10.1002/PRSB.720110412","url":null,"abstract":"The reduction of risks associated with chemical processing operations is essential for the safe operation of chemical plants. The reduction of these risks is accomplished through a comprehensive process safety management program. Key elements of this program include Hazard and Operability Studies, Emergency Relief Venting, Process Automation, Management of Change Control Procedures, Process Specific Training, and so forth. Central to many of these elements is a thorough, in-depth understanding of the reactive nature of chemical processing operations. This understanding can only be obtained through intensive laboratory evalutions using “leading edge” process safety testing technologies. To accomplish this goal, a systematic process safety testing program has been established aimed at characterizing the reactive nature of both the desired and undesired chemistry. The information obtained is directly applicable to the development of intrinsically safe processes and for the safe design/operation of chemical processing facilities.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115018542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Acceptable risk—an overview 可接受的风险—概述
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110409
J. Philley
This paper offers an overview of the concept of acceptable risk. Variations in the definition of risk are addressed as well as criteria for measuring and evaluating risk. Risk acceptance depends on many factors, some of which are highlighted. The myth of zero risk is addressed with relevant examples such as dioxin and the U.S. space program. Practical applications of acceptable risk concepts are discussed, featuring the RISK MATRIX from system safety MIL-STD-882. Some sample guidelines and benchmarks are offered.
本文概述了可接受风险的概念。讨论了风险定义的变化,以及衡量和评价风险的标准。风险接受取决于许多因素,其中一些是重点强调的。零风险的神话是通过二恶英和美国太空计划等相关例子来解决的。讨论了可接受风险概念的实际应用,并以系统安全MIL-STD-882中的风险矩阵为特征。提供了一些示例指南和基准。
{"title":"Acceptable risk—an overview","authors":"J. Philley","doi":"10.1002/PRSB.720110409","DOIUrl":"https://doi.org/10.1002/PRSB.720110409","url":null,"abstract":"This paper offers an overview of the concept of acceptable risk. Variations in the definition of risk are addressed as well as criteria for measuring and evaluating risk. Risk acceptance depends on many factors, some of which are highlighted. The myth of zero risk is addressed with relevant examples such as dioxin and the U.S. space program. Practical applications of acceptable risk concepts are discussed, featuring the RISK MATRIX from system safety MIL-STD-882. Some sample guidelines and benchmarks are offered.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129618305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Predicting and controlling flammability of multiple fuel and multiple inert mixtures 预测和控制多种燃料和多种惰性混合物的可燃性
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110408
J. G. Hansel, J. Mitchell, H. Klotz
Le Chatelier's Rule is in wide use for predicting the flammability of mixtures with multiple fuels present. The rule does not conveniently handle multiple inerts or elevated temperatures and pressures. This paper describes an alternate method, developed at Air Products, called FLAMCHEKTM, which conveniently handles these variables. This method for predicting flammability is based upon the commonality of the adiabatic flame temperature of a wide variety of fuels at their upper and lower flammable limits. The method, if PC based, can be extended to automatically control the addition of inerts, fuels, or oxidizers in order to avoid flammable conditions. The concept may be extended to more involved applications, such as within an oil well with fuel gas mixtures containing oxygen. In this case, the location from which a gas sample is obtained for analysis (wellhead) may have a different fuel analysis and flammability condition than the location where an explosion is likely to initiate (bottom of well). Hence a correction of the fuels analysis is required.
勒夏特列规则被广泛用于预测含有多种燃料的混合物的可燃性。该规则不能方便地处理多重惰性或高温高压。本文介绍了空气产品公司开发的一种替代方法,称为FLAMCHEKTM,它可以方便地处理这些变量。这种预测可燃性的方法是基于各种燃料在其可燃性上限和下限的绝热火焰温度的共性。该方法,如果基于PC,可以扩展到自动控制添加的惰性,燃料,或氧化剂,以避免易燃条件。这个概念可以扩展到更复杂的应用中,例如在油井中使用含有氧气的燃料气体混合物。在这种情况下,获得气体样本进行分析的位置(井口)可能与可能发生爆炸的位置(井底)具有不同的燃料分析和可燃性条件。因此,需要对燃料分析进行修正。
{"title":"Predicting and controlling flammability of multiple fuel and multiple inert mixtures","authors":"J. G. Hansel, J. Mitchell, H. Klotz","doi":"10.1002/PRSB.720110408","DOIUrl":"https://doi.org/10.1002/PRSB.720110408","url":null,"abstract":"Le Chatelier's Rule is in wide use for predicting the flammability of mixtures with multiple fuels present. The rule does not conveniently handle multiple inerts or elevated temperatures and pressures. This paper describes an alternate method, developed at Air Products, called FLAMCHEKTM, which conveniently handles these variables. This method for predicting flammability is based upon the commonality of the adiabatic flame temperature of a wide variety of fuels at their upper and lower flammable limits. The method, if PC based, can be extended to automatically control the addition of inerts, fuels, or oxidizers in order to avoid flammable conditions. The concept may be extended to more involved applications, such as within an oil well with fuel gas mixtures containing oxygen. In this case, the location from which a gas sample is obtained for analysis (wellhead) may have a different fuel analysis and flammability condition than the location where an explosion is likely to initiate (bottom of well). Hence a correction of the fuels analysis is required.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121495113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 22
Disengagement predictions via drift flux correlation vertical, horizontal and spherical vessels 通过垂直、水平和球形容器的漂移通量相关进行脱离预测
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110411
C. Sheppard
The behavior of an open system is modeled. Thus, for special cases, the void fraction is predicted as a function of location and time. The open system may be an open vessel or a vessel with an open relief device. A single governing equation is derived based on combining the material and energy balances with the churn-turbulent drift flux relationship and assuming no radial gradients. This partial differential equation is not solved. It is, however, bounded by homogeneous and all vapor venting. These special cases are solved. In homogeneous venting the key variable is time. In all vapor venting under pseudo-steady-state conditions the key variable is location. The solution of the partial differential equation is also discussed. Under pseudo-steady-state and churn-turbulent conditions, the open system is modeled. The minimum void fractions (corresponding to a maximum liquid inventory) with all vapor venting, for vertical, horizontal, and spherical vessels are predicted and compared. Analytical expressions for the local and average void fractions in a vertical vessel and non-unity distribution parameters are presented. Void fraction profiles are compared for three cases: 1. vertical cylinders with distribution parameters (Co values) of unity and 1.5, 2. horizontal and vertical cylinders with varying L/D ratios, and 3. spheres with inscribed vertical cylinders having constant gas production to bubble rise ratio (Ψ′ value). The vertical cylinder average void fraction for non-unity distribution parameters can now be calculated analytically. The horizontal cylinder average void fraction predicted by turning it upright results in an over prediction of at most 4%. The sphere average void fraction predicted via an inscribed vertical cylinder, with the same Ψ′ value, is consistenly high by at most 8%.
对开放系统的行为进行了建模。因此,在特殊情况下,孔隙率被预测为位置和时间的函数。所述开式系统可以是开式容器或具有开式减压装置的容器。将物质和能量平衡与搅拌-湍流漂移通量关系结合起来,并假设没有径向梯度,推导出单一的控制方程。这个偏微分方程没有解。然而,它是由均匀的和所有的蒸汽排气。这些特殊情况都解决了。在均质排气中,关键变量是时间。在拟稳态条件下的所有蒸汽排气中,关键变量是位置。讨论了偏微分方程的解。在伪稳态和搅拌-湍流条件下,对开放系统进行了建模。预测并比较了垂直、水平和球形容器中所有蒸汽排气的最小空隙分数(对应于最大液体存量)。给出了垂直容器内局部和平均空隙分数的解析表达式以及非统一分布参数。对比了三种情况下的孔隙率分布:1。分布参数(Co值)为1、1.5、2的垂直圆柱体。2 .具有不同L/D比的水平和垂直气缸;带有垂直柱体的球体,产气量与气泡上升比恒定(Ψ’值)。对于非单位分布参数,现在可以解析计算垂直柱体平均空隙率。水平柱平均孔隙率通过将其倒置来预测,结果最多超过预测4%。通过内切垂直圆柱体预测的球体平均孔隙率,具有相同的Ψ '值,始终最高可达8%。
{"title":"Disengagement predictions via drift flux correlation vertical, horizontal and spherical vessels","authors":"C. Sheppard","doi":"10.1002/PRSB.720110411","DOIUrl":"https://doi.org/10.1002/PRSB.720110411","url":null,"abstract":"The behavior of an open system is modeled. Thus, for special cases, the void fraction is predicted as a function of location and time. The open system may be an open vessel or a vessel with an open relief device. A single governing equation is derived based on combining the material and energy balances with the churn-turbulent drift flux relationship and assuming no radial gradients. This partial differential equation is not solved. It is, however, bounded by homogeneous and all vapor venting. These special cases are solved. In homogeneous venting the key variable is time. In all vapor venting under pseudo-steady-state conditions the key variable is location. The solution of the partial differential equation is also discussed. \u0000 \u0000Under pseudo-steady-state and churn-turbulent conditions, the open system is modeled. The minimum void fractions (corresponding to a maximum liquid inventory) with all vapor venting, for vertical, horizontal, and spherical vessels are predicted and compared. Analytical expressions for the local and average void fractions in a vertical vessel and non-unity distribution parameters are presented. Void fraction profiles are compared for three cases: 1. vertical cylinders with distribution parameters (Co values) of unity and 1.5, 2. horizontal and vertical cylinders with varying L/D ratios, and 3. spheres with inscribed vertical cylinders having constant gas production to bubble rise ratio (Ψ′ value). The vertical cylinder average void fraction for non-unity distribution parameters can now be calculated analytically. The horizontal cylinder average void fraction predicted by turning it upright results in an over prediction of at most 4%. The sphere average void fraction predicted via an inscribed vertical cylinder, with the same Ψ′ value, is consistenly high by at most 8%.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128241348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Laboratory and large-scale dust explosion research 实验室及大型粉尘爆炸研究
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110413
K. Cashdollar, E. S. Weiss, N. Greninger, K. Chatrathi
This paper describes dust explosibility research in full-scale experimental mines and a 20-L laboratory chamber at the U.S. Bureau of Mines and in a 1-m[sup +3] laboratory chamber at Fike Corporation. The purpose of this research is to improve safety in mining and other industries that manufacture, process, or use combustible dusts. As part of this work, carbonaceous dusts with a wide range of volatilities and various particle size distributions were studied. Laboratory data on the minimum explosible concentrations of predispersed dusts were comparable to mine data for nominal dust loadings that were dispersed by the aerodynamic disturbance from a gas ignition zone. Recommendations are given on the limitations of small-scale testing such as [open quotes]overdriving[close quotes] by too strong an ignitor. The effect of dust particle size on explosibility data is illustrated for coal and aluminum dusts. For both dusts, the finest sizes were the most hazardous. The inerting requirements for preventing explosions were also measured in both laboratory and large-scale systems. All the data show relatively good agreement between the laboratory and the large-scale tests. 50 refs., 14 figs.
本文介绍了在全尺寸试验矿山和美国矿产局20-L实验室室以及菲克公司1-m[sup +3]实验室室进行的粉尘爆炸研究。这项研究的目的是提高采矿和其他制造、加工或使用可燃粉尘的行业的安全性。作为这项工作的一部分,研究了具有广泛挥发性和不同粒径分布的含碳粉尘。预分散粉尘的最低爆炸浓度的实验室数据与由气体点火区的空气动力扰动分散的标称粉尘负荷的矿井数据相当。对小规模测试的局限性给出了建议,例如[开引号]过度驱动[闭引号],因为点火器太强。说明了粉尘粒径对煤粉和铝粉爆炸数据的影响。对于这两种粉尘,最细的尺寸是最危险的。在实验室和大型系统中,还测量了防止爆炸的惯性要求。实验数据与大规模试验结果吻合较好。参50。, 14个无花果。
{"title":"Laboratory and large-scale dust explosion research","authors":"K. Cashdollar, E. S. Weiss, N. Greninger, K. Chatrathi","doi":"10.1002/PRSB.720110413","DOIUrl":"https://doi.org/10.1002/PRSB.720110413","url":null,"abstract":"This paper describes dust explosibility research in full-scale experimental mines and a 20-L laboratory chamber at the U.S. Bureau of Mines and in a 1-m[sup +3] laboratory chamber at Fike Corporation. The purpose of this research is to improve safety in mining and other industries that manufacture, process, or use combustible dusts. As part of this work, carbonaceous dusts with a wide range of volatilities and various particle size distributions were studied. Laboratory data on the minimum explosible concentrations of predispersed dusts were comparable to mine data for nominal dust loadings that were dispersed by the aerodynamic disturbance from a gas ignition zone. Recommendations are given on the limitations of small-scale testing such as [open quotes]overdriving[close quotes] by too strong an ignitor. The effect of dust particle size on explosibility data is illustrated for coal and aluminum dusts. For both dusts, the finest sizes were the most hazardous. The inerting requirements for preventing explosions were also measured in both laboratory and large-scale systems. All the data show relatively good agreement between the laboratory and the large-scale tests. 50 refs., 14 figs.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131344000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Using the ASTM CHETAH program in chemical process hazard evaluation 在化学过程危害评估中使用ASTM CHETAH程序
Pub Date : 1992-10-01 DOI: 10.1002/PRSB.720110410
D. Frurip
The CHETAH program has proven to be of great utility in the assessment of reactive chemicals hazards associated with the development of new chemicals and chemical processes. At the Dow Chemical Company, the most frequent use of the program is for the estimation of heats of reaction. Reaction heats are often the single most important parameter in reactive chemicals evaluation since most “worst case” scenarios involve the instantaneous liberation of the reaction energy. Another common use of the program is using CHETAH's unique capability to predict the “explosive” behavior of a material or mixture solely from a knowledge of its molecular structure. Several examples of day-to-day use of the program are presented. Current development activity in the ASTM subcommittee which supports CHETAH are discussed. These include new hazard evaluation criteria, better thermodynamic property estimation techniques, and user friendly versions of the program.
CHETAH计划已被证明在评估与新化学品和化学工艺开发相关的反应性化学品危害方面具有很大的实用性。在陶氏化学公司,最常用的程序是估算反应热。反应热通常是反应性化学品评价中最重要的参数,因为大多数“最坏情况”都涉及到反应能量的瞬时释放。该程序的另一个常见用途是利用CHETAH的独特能力,仅从其分子结构的知识来预测材料或混合物的“爆炸”行为。介绍了该程序日常使用的几个例子。讨论了支持CHETAH的ASTM小组委员会的当前开发活动。其中包括新的危害评估标准,更好的热力学性质估计技术,以及用户友好的程序版本。
{"title":"Using the ASTM CHETAH program in chemical process hazard evaluation","authors":"D. Frurip","doi":"10.1002/PRSB.720110410","DOIUrl":"https://doi.org/10.1002/PRSB.720110410","url":null,"abstract":"The CHETAH program has proven to be of great utility in the assessment of reactive chemicals hazards associated with the development of new chemicals and chemical processes. At the Dow Chemical Company, the most frequent use of the program is for the estimation of heats of reaction. Reaction heats are often the single most important parameter in reactive chemicals evaluation since most “worst case” scenarios involve the instantaneous liberation of the reaction energy. Another common use of the program is using CHETAH's unique capability to predict the “explosive” behavior of a material or mixture solely from a knowledge of its molecular structure. Several examples of day-to-day use of the program are presented. Current development activity in the ASTM subcommittee which supports CHETAH are discussed. These include new hazard evaluation criteria, better thermodynamic property estimation techniques, and user friendly versions of the program.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"113939315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Halon replacement: The law and the options 哈龙替代:法律和选择
Pub Date : 1992-07-01 DOI: 10.1002/PRSB.720110315
J. Senecal
Halons 1301 and 1211 have been employed widely for over 20 years in a broad array of fire and explosion protection applications. These chemicals, however, have been determined to be environmentally unfriendly due to their high ozone depleting potentials. International treaty, national laws and local ordinances have severely limited the future use of these chemicals. Production in the United States will likely come to an effective halt by 1994. A number of alternative chemicals have been suggested as potential replacements for the halons both in total flooding and streaming agent applications. A comparison of the several viable halon alternatives is made including performance, cost and availability. Areas where new applications data are required are noted.
哈龙1301和1211已被广泛应用超过20年,在广泛的防火和防爆应用。然而,这些化学物质已被确定为对环境不友好,因为它们具有很高的消耗臭氧的潜力。国际条约、国家法律和地方条例严格限制了这些化学品的未来使用。美国的生产很可能在1994年实际上停止。许多替代化学品被建议作为哈龙的潜在替代品,无论是在总驱油剂还是流剂应用中。对几种可行的哈龙替代品进行了比较,包括性能、成本和可用性。注意需要新应用程序数据的区域。
{"title":"Halon replacement: The law and the options","authors":"J. Senecal","doi":"10.1002/PRSB.720110315","DOIUrl":"https://doi.org/10.1002/PRSB.720110315","url":null,"abstract":"Halons 1301 and 1211 have been employed widely for over 20 years in a broad array of fire and explosion protection applications. These chemicals, however, have been determined to be environmentally unfriendly due to their high ozone depleting potentials. International treaty, national laws and local ordinances have severely limited the future use of these chemicals. Production in the United States will likely come to an effective halt by 1994. A number of alternative chemicals have been suggested as potential replacements for the halons both in total flooding and streaming agent applications. A comparison of the several viable halon alternatives is made including performance, cost and availability. Areas where new applications data are required are noted.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129201093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Dust entrainability and its effect on explosion propagation in elongated structures 细长结构中粉尘携带性及其对爆炸传播的影响
Pub Date : 1992-07-01 DOI: 10.1002/PRSB.720110314
E. A. Ural
Two apparatuses have been developed to characterize the entrainability of dust deposits. The minimum aerodynamic wall shear stress required for dust removal (Critical Shear Stress), measured by the first apparatus, is an indicator of the ease with which dust particles can be removed from a layer. The second apparatus measures the settling velocity distribution of dust clouds, which is an important factor controlling the extent of dispersion as well as the time period during which the entrained dust cloud can remain suspended. Testing has shown that the critical shear stress depends not only on the nature of the dust, but on the way the dust deposit is formed. Therefore, a portable version of this apparatus was developed to allow field testing of dust deposits. This methodology has also been used to evaluate the effect of oil treatment sometimes used in the grain handling industry to reduce dust emission. Simulated explosion tests have demonstrated the importance of critical shear stress on dust entrainability. A simple model calculating unsteady dust concentration in elongated structures has been developed. The model shows that flammable dust concentrations induced in a gallery by a primary explosion exist over a finite length and time period. Therefore, the probability of a secondary explosion depends not only on the dust and layer properties, but on the details of the primary explosion and of the enclosure geometry. A simple criterion for transmission of a primary explosion into an adjoining elongated structure is discussed in the paper.
已经研制出两种仪器来表征粉尘沉积物的可携性。由第一个仪器测量的除尘所需的最小空气动力壁面剪切应力(临界剪切应力)是粉尘颗粒从一层中去除的难易程度的指标。第二个装置测量尘埃云的沉降速度分布,这是控制扩散程度和夹带尘埃云保持悬浮时间的重要因素。试验表明,临界剪应力不仅与粉尘的性质有关,而且与粉尘沉积的形成方式有关。因此,该仪器的便携式版本被开发出来,以便对粉尘沉积物进行现场测试。该方法也被用于评价粮食加工工业中有时用于减少粉尘排放的油处理的效果。模拟爆炸试验证明了临界剪应力对粉尘可携性的重要性。本文提出了一种计算细长结构中非定常粉尘浓度的简单模型。该模型表明,一次爆炸引起的走廊内可燃粉尘浓度存在有限的长度和时间。因此,二次爆炸的概率不仅取决于粉尘和粉尘层的性质,而且取决于初次爆炸的细节和外壳的几何形状。本文讨论了一次爆炸在相邻细长结构中传播的一个简单判据。
{"title":"Dust entrainability and its effect on explosion propagation in elongated structures","authors":"E. A. Ural","doi":"10.1002/PRSB.720110314","DOIUrl":"https://doi.org/10.1002/PRSB.720110314","url":null,"abstract":"Two apparatuses have been developed to characterize the entrainability of dust deposits. The minimum aerodynamic wall shear stress required for dust removal (Critical Shear Stress), measured by the first apparatus, is an indicator of the ease with which dust particles can be removed from a layer. The second apparatus measures the settling velocity distribution of dust clouds, which is an important factor controlling the extent of dispersion as well as the time period during which the entrained dust cloud can remain suspended. \u0000 \u0000 \u0000 \u0000Testing has shown that the critical shear stress depends not only on the nature of the dust, but on the way the dust deposit is formed. Therefore, a portable version of this apparatus was developed to allow field testing of dust deposits. This methodology has also been used to evaluate the effect of oil treatment sometimes used in the grain handling industry to reduce dust emission. \u0000 \u0000 \u0000 \u0000Simulated explosion tests have demonstrated the importance of critical shear stress on dust entrainability. A simple model calculating unsteady dust concentration in elongated structures has been developed. The model shows that flammable dust concentrations induced in a gallery by a primary explosion exist over a finite length and time period. Therefore, the probability of a secondary explosion depends not only on the dust and layer properties, but on the details of the primary explosion and of the enclosure geometry. A simple criterion for transmission of a primary explosion into an adjoining elongated structure is discussed in the paper.","PeriodicalId":364732,"journal":{"name":"Plant\\/operations Progress","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129998934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
期刊
Plant\/operations Progress
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1