Ultrasonics Sonochemistry最新文献

英文中文

Dual-functional ultrasound-activated sonosensitizer for microbial inactivation and sprouts quality enhancement 用于微生物灭活和芽菜品质提高的双功能超声激活超声敏化剂

IF 8.4 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-13 DOI: 10.1016/j.ultsonch.2026.107818

Zifei Liu, Wendi Chen, Lingdai Liu, Cliff An Ting Tham, Dan Li

引用次数: 0

Corrigendum to "Optimization of sonication for preserving the biochemical and physicochemical attributes of pomegranate arils during storage" [Ultrason. Sonochem. 126 (2026) 107763]. “保存石榴皮储存期间生化和物理化学属性的超声优化”的勘误表[超声]。声学化学，26(2026):107763]。

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-11 DOI: 10.1016/j.ultsonch.2026.107790

Isa Hazbawi, Hamed Etezadi

引用次数: 0

Editorial on the special issue "How do intrabubble conditions influence sonochemical reactivity?" 专题社论“泡内条件如何影响声化学反应性？”

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-06 DOI: 10.1016/j.ultsonch.2026.107798

Glyus Sharipov, Sergey I Nikitenko, Rachel Pflieger

引用次数: 0

Corrigendum to “Mechanism of deep removal of iron impurities from zinc sulfate solutions via ultrasonic-enhanced goethite process”. [Ultrason. Sonochemistry 124 (2026) 107708 超声强化针铁矿法深度去除硫酸锌溶液中铁杂质的机理的勘误。[Ultrason。声学化学124 (2026)107708

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-02-07 DOI: 10.1016/j.ultsonch.2026.107759

Heng Zhang , Shuxuan Hu , Shixing Wang , Rong Zhu , Yadong Li , Libo Zhang

引用次数: 0

Corrigendum to “Sonocatalytic degradation of bisphenol A in aqueous solution: A review”. [Ultrason. Sonochemistry 125 (2026) 107745] “水溶液中双酚A的声催化降解：综述”的勘误表。[Ultrason。声波化学125 (2026)107745]

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-02-06 DOI: 10.1016/j.ultsonch.2026.107762

Hyunjin Shin , Hak-Hyeon Kim , Sujin An , Narae Yang , Chang Min Park , Min Jang , Byung-Moon Jun , Yeomin Yoon

引用次数: 0

Molecular dynamics and energy analysis of ultrasonic cavitation effects on aged asphalt 老化沥青超声空化效应的分子动力学及能量分析

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-02-07 DOI: 10.1016/j.ultsonch.2026.107765

Jinwei Zhang, Ruien Yu, Jie Ren, Xueliang Cui, Linzheng Ye, Xijing Zhu

The physicochemical degradation of asphalt during long-term service leads to pronounced aging, characterized by increased molecular aggregation, elevated viscosity, and degraded mechanical performance. Ultrasonic treatment has shown potential for reducing the viscosity of heavy oils and asphaltic materials; however, the underlying rejuvenation mechanism of aged asphalt at the molecular scale remains insufficiently understood. In this study, the interaction between ultrasonic cavitation and aged asphalt is investigated from an energy-based and molecular-level perspective using molecular dynamics (MD) simulations combined with cavitation energy analysis. A representative aged asphalt model consisting of twelve molecular species was constructed based on the SARA fraction composition of JingBo 70# asphalt, incorporating oxidation-induced functional groups (CO and SO). Intermolecular cohesion within the aged asphalt system was quantified, revealing that π-π stacking and hydrogen bonding dominate the electrostatic interaction energy that stabilizes molecular aggregates. An order-of-magnitude comparison indicates that the energy released during the collapse of a single ultrasonic cavitation bubble is sufficient to overcome the characteristic intermolecular cohesive energy within the affected volume. To examine the molecular response under ultrasonic excitation, a time-dependent ultrasonic-like external force was introduced in MD simulations at 20 kHz and 453 K. The results show that ultrasonic excitation induces periodic energy and temperature oscillations and leads to rapid bond scission at the early stage of loading. Bond rupture occurs preferentially at weaker C–C and C–S single bonds, particularly at side-chain positions and C–C bonds adjacent to carbonyl groups, resulting in molecular fragmentation and reduced aggregation stability. Complementary experimental results, including viscosity measurements and SARA fraction analysis, exhibit trends consistent with the simulated molecular disruption behavior. These findings provide an energy-based and molecular-scale mechanistic interpretation of ultrasonic treatment of aged asphalt and offer theoretical support for its potential application in asphalt rejuvenation and recycling.

沥青在长期使用过程中的物理化学降解导致明显的老化，其特征是分子聚集增加，粘度升高，机械性能下降。超声波处理已显示出降低重油和沥青材料粘度的潜力；然而，在分子尺度上，老化沥青的潜在再生机制仍未得到充分的了解。本研究采用分子动力学（MD）模拟和空化能分析相结合的方法，从能量和分子水平的角度研究了超声空化与老化沥青的相互作用。以京博70#沥青SARA馏分组成为基础，建立了具有代表性的老化沥青模型，包含氧化诱导的官能团（CO和SO）。对老化沥青体系中的分子间内聚力进行了定量分析，发现π-π堆积和氢键在稳定分子聚集体的静电相互作用能中占主导地位。一个数量级的比较表明，在单个超声空化泡崩溃过程中释放的能量足以克服受影响体积内的特征分子间内聚能。为了研究分子在超声激励下的响应，在20 kHz和453 K下引入了时间相关的超声类外力。结果表明：在加载初期，超声激发会引起周期性的能量和温度振荡，导致键的快速断裂；键断裂优先发生在较弱的C-C和C-S单键，特别是在侧链位置和靠近羰基的C-C键，导致分子断裂和聚集稳定性降低。补充实验结果，包括粘度测量和SARA分数分析，显示出与模拟的分子破坏行为一致的趋势。这些发现为超声处理老化沥青提供了基于能量和分子尺度的机理解释，并为其在沥青再生和回收中的潜在应用提供了理论支持。

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引用次数: 0

Optimization of sonication for preserving the biochemical and physicochemical attributes of pomegranate arils during storage 超声波保鲜石榴果皮生化及理化特性的优化

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-02-07 DOI: 10.1016/j.ultsonch.2026.107763

Isa Hazbawi , Hamed Etezadi

Pomegranate arils rapidly experience quality deterioration and a decline in bioactive compounds during storage. This study aimed to develop and optimize an effective non-thermal technology by evaluating the efficacy of ultrasound treatment in preserving the biochemical and physicochemical attributes of pomegranate arils using response surface methodology (RSM). The effects of ultrasound time (4–14 min) and storage duration (0–16 days) on key quality indicators, including total phenol content (TPC), antioxidant activity (AOA), total anthocyanin content (TAC), titratable acidity (TA), and weight loss (WL), were assessed. Results indicated that controlled increases in ultrasound exposure helped maintain bioactive compounds, whereas quality loss was primarily dependent on storage duration. The optimal conditions were determined as 12.3 min of ultrasound and 7.1 days of storage, under which AOA of 71.58%, TA of 2.3%, TAC of 155.16 mg 100 g⁻¹, and TPC of 133.82 mg 100 g⁻¹ were predicted, along with minimal WL of 1.32%. Experimental validation confirmed the accuracy of the model and demonstrated that ultrasound can effectively mitigate quality decline in pomegranate arils. The findings suggest that this non-thermal technology provides a sustainable and practical approach for postharvest quality management and the development of advanced storage systems, particularly within cold chains for sensitive products.

石榴皮在储存过程中迅速经历质量恶化和生物活性化合物的下降。本研究旨在利用响应面法（response surface methodology， RSM）评价超声处理对石榴皮生化和理化特性的保存效果，开发并优化一种有效的非热处理技术。研究了超声处理时间（4 ~ 14 min）和贮藏时间（0 ~ 16 d）对甜菜总酚含量（TPC）、抗氧化活性（AOA）、总花青素含量（TAC）、可滴定酸度（TA）和失重（WL）等关键品质指标的影响。结果表明，超声暴露的控制增加有助于维持生物活性化合物，而质量损失主要取决于储存时间。最佳条件为超声时间12.3 min，贮藏时间7.1 d， AOA为71.58%，TA为2.3%，TAC为155.16 mg 100 g−1，TPC为133.82 mg 100 g−1，WL最小值为1.32%。实验验证了该模型的准确性，表明超声能有效缓解石榴皮质量下降。研究结果表明，这种非热技术为采后质量管理和先进存储系统的开发提供了一种可持续和实用的方法，特别是在敏感产品的冷链中。

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引用次数: 0

Ultrasound-assisted preparation of nanoemulsions co-stabilized by immature nectarine polysaccharide and soy protein isolate 未成熟油桃多糖与大豆分离蛋白共稳定纳米乳的超声辅助制备

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-02-08 DOI: 10.1016/j.ultsonch.2026.107771

Yalong Liang, Xiangke Jin, Sheng Geng, Benguo Liu

This study isolated and characterized polysaccharides from immature nectarines (INP) and constructed nanoemulsions co-stabilized with soy protein isolate (SPI). The results showed that arabinose and galactose were the main monosaccharides in INP, which was identified as a pectic heteropolysaccharide with a high molecular weight (M_w = 9.26 × 10⁵ Da) and high polydispersity (PDI = 11.42). INP exhibited a compact random coil conformation and a loose, porous morphology. The incorporation of SPI effectively reduced the interfacial tension of the SPI-INP composite system, significantly enhancing the stability of the resulting nanoemulsions. The concentration of the INP-SPI mixture, the SPI/INP mass ratio, and ultrasonic conditions significantly influenced the formation of the nanoemulsions. Based on the results of single-factor experiments and response surface analysis, the optimal process parameters for nanoemulsion preparation were determined as follows: INP-SPI concentration 1.6%, SPI/INP mass ratio 2.1:1, ultrasonic power 500 W, and ultrasonic time 5.3 min. Validation experiments confirmed that under these conditions, the average droplet size of the obtained nanoemulsion was 214.10 ± 1.74 nm, which closely aligned with the model-predicted value (216.33 nm). The superior stability of the INP-SPI nanoemulsion under various pH (6.0–9.0) and salt (0–100 mM NaCl) conditions was attributed to the formation of a robust interfacial layer providing steric stabilization, as validated through droplet size analysis and environmental stress testing. This research promotes the in-depth utilization of immature nectarine resources and provides a reference for the construction of food-grade nanoemulsions.

本研究从未成熟油桃（INP）中分离和表征了多糖，并构建了与大豆分离蛋白（SPI）共稳定的纳米乳液。结果表明，INP中以阿拉伯糖和半乳糖为主要单糖，是一种分子量高（Mw = 9.26 × 105 Da）、多分散性高（PDI = 11.42）的果胶杂多糖。INP表现出紧凑的随机线圈结构和松散的多孔形态。SPI的加入有效降低了SPI- inp复合体系的界面张力，显著提高了纳米乳液的稳定性。INP-SPI混合物的浓度、SPI/INP的质量比和超声条件对纳米乳的形成有显著影响。通过单因素实验和响应面分析，确定了制备纳米乳的最佳工艺参数为：INP-SPI浓度1.6%，SPI/INP质量比2.1:1，超声功率500 W，超声时间5.3 min。验证实验证实，在此条件下，所得纳米乳的平均粒径为214.10 ± 1.74 nm，与模型预测值（216.33 nm）接近。在不同pH值（6.0-9.0）和盐（0-100 mM NaCl）条件下，INP-SPI纳米乳具有优异的稳定性，这是由于形成了坚固的界面层，提供了空间稳定性，这一点通过液滴尺寸分析和环境应力测试得到了验证。本研究促进了未成熟油桃资源的深度利用，为食品级纳米乳的构建提供参考。

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引用次数: 0

Ultrasonic-assisted chemical milling: surface roughness characterization and material removal enhancement of Al 6061 超声辅助化学铣削：al6061表面粗糙度表征及增强材料去除率

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-01-25 DOI: 10.1016/j.ultsonch.2026.107753

Shamim Mohammadi, Amir Rasti

Chemical milling (CHM) is widely used for thinning and pocketing components, especially in aerospace applications, but its low material removal rate (MRR) requires high etchant consumption and often leads to poor surface integrity. This study introduces a novel method, direct ultrasonic-assisted chemical milling (UACM), as an efficient and sustainable alternative to CHM. A full-factorial design examined three ultrasonic powers (50, 150, 250 W) across acidic and alkaline etchants at three concentration levels. MRR and roughness parameters (Ra, Rz, Sa) were experimentally quantified and modeled using ANOVA-based regression, while multi-region SEM/EDS elucidated oxide disruption, pit formation, and surface evolution on Al 6061. In 10 % HCl at 250 W, UACM increased MRR by 591 % through cavitation-enhanced agitation and rapid renewal of reactive species, enabling≈85.5 % reduction in acid use. Moreover, at matched MRR, UACM yielded 15–30 % lower Sa than CHM, producing uniform microporosity beneficial for bonding and coating applications. The best acidic condition was 15 % HCl at 250 W, where MRR increased from 0.70 to 1.30 mm/m/s and produced a clean, crack-free, homogeneous surface with optimal integrity. The optimal alkaline condition was 50 % NaOH at 250 W, where MRR increased from 0.08 to 0.23 mm/m/s (≈65.2 % time reduction), and the disruption of hydrogen-bubble shielding generated a uniform and stable morphology. Key experimental challenges included maintaining thermal stability under high acoustic power, controlling bubble adhesion in alkaline media, and achieving a reproducible initial surface. Overall, UACM substantially enhances removal efficiency, improves surface integrity, and reduces chemical consumption, offering a practical pathway toward high-precision and greener manufacturing.

化学铣削（CHM）广泛用于减薄和装袋部件，特别是在航空航天应用中，但其低材料去除率（MRR）需要高蚀刻剂消耗，并且往往导致表面完整性差。本研究介绍了一种新的方法，直接超声辅助化学磨粉（UACM），作为一种高效和可持续的替代中药。全因子设计检测了酸性和碱性腐蚀剂在三种浓度水平下的三种超声波功率（50、150、250 W）。MRR和粗糙度参数（Ra, Rz, Sa）通过实验量化和基于方差分析的回归建模，而多区域SEM/EDS阐明了Al 6061的氧化物破坏，坑形成和表面演化。在250 W、10 % HCl条件下，UACM通过空化强化搅拌和反应物质的快速更新，使MRR提高了591 %，使酸用量减少了约85.5 %。此外，在匹配的MRR下，UACM的Sa比CHM低15-30 %，产生均匀的微孔隙，有利于粘接和涂层应用。最佳酸性条件为15 % HCl， 250 W， MRR从0.70增加到1.30 mm/m/s，可获得干净、无裂纹、均匀且完整性最佳的表面。在250 W下，NaOH浓度为50 %，MRR从0.08提高到0.23 mm/m/s（时间减少约65.2 %），破坏氢泡屏蔽后形貌均匀稳定。关键的实验挑战包括在高声功率下保持热稳定性，控制碱性介质中的气泡粘附，以及实现可复制的初始表面。总的来说，UACM大大提高了去除效率，改善了表面完整性，减少了化学品消耗，为高精度和绿色制造提供了切实可行的途径。

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Effects of ultrasound-assisted Maillard reaction on the emulsifying and flavor properties of brewer’s spent grain protein–gum arabic conjugates 超声辅助美拉德反应对啤酒废谷物蛋白-阿拉伯胶偶联物乳化及风味特性的影响

IF 9.7 1区化学 Q1 ACOUSTICS

Ultrasonics Sonochemistry

Pub Date : 2026-03-01 Epub Date: 2026-01-29 DOI: 10.1016/j.ultsonch.2026.107755

Mingyu Kim, Hyunwoo Ahn, Yujin Wang, Beomkyung Cho, Woojin Na, Kwang-Geun Lee

This study explores the effects of ultrasound-assisted heating compared to conventional wet heating on the Maillard reaction (MR) between brewer’s spent grain (BSG) protein and gum arabic (GA), focusing on various factors like reaction kinetics, structural changes, emulsifying performance, and volatile formation. Ultrasound process markedly accelerated glycation, with a 45 min sonicated sample glycation to a similar degree to that induced by traditional 3 h treatment, such that cavitation facilitates early MR pathways. Both approaches enhanced solubility and remodeled secondary structures, although in different manners: conventional heating promoted a gradual increase in β-sheet content and a decrease in α-helix content, while ultrasound induced rapid unfolding and structural reorganization. All MRPs enhanced the emulsifying properties, but the conventional sample after 3 h obtained the highest emulsifying activity index (EAI) and emulsion stability index (ESI) values. Samples treated with ultrasound showed moderate improvement, however, at considerably reduced reaction times. Dynamic light scattering (DLS) and fluorescence microscopy have also confirmed that conventionally heated MRPs form smaller and more uniform droplets. Volatile profiling indicated that conventional heating produced a broader spectrum of aldehydes, ketones, and furans associated with off-flavors, whereas ultrasound greatly reduced compounds such as (E,E)-2,4-decadienal and 2-pentylfuran, indicating a flavor-protective potential. In general, the reaction efficiencies and flavor quality of ultrasound-assisted heating are higher, and emulsifying performance is optimized by the conventional heating technology. This work shows that BSG protein–GA conjugates are versatile enough to achieve clean-label, plant-based emulsifier applications and its desired functional/sensory properties.

本研究探讨了超声辅助加热与传统湿法加热相比对啤酒废谷物（BSG）蛋白与阿拉伯胶（GA）之间美拉德反应（MR）的影响，重点研究了反应动力学、结构变化、乳化性能和挥发性形成等各种因素。超声处理显著加速糖基化，45分钟超声处理的糖基化程度与传统3小时处理的糖基化程度相似，因此空化有利于早期MR通路。两种方法都能提高溶解度，重塑二级结构，但方式不同：常规加热促进β-片含量逐渐增加，α-螺旋含量逐渐减少，而超声诱导快速展开和结构重组。所有MRPs均增强了乳化性能，但常规样品在3 h后获得最高的乳化活性指数（EAI）和乳液稳定性指数（ESI）值。然而，用超声波处理的样品在相当短的反应时间内显示出适度的改善。动态光散射（DLS）和荧光显微镜也证实了常规加热的MRPs形成更小更均匀的液滴。挥发性分析表明，传统加热会产生与异味相关的更广泛的醛、酮和呋喃，而超声波则会大大减少（E，E）-2,4-十烯醛和2-戊基呋喃等化合物，表明其具有保护风味的潜力。总的来说，超声辅助加热的反应效率和风味品质较高，并通过常规加热技术优化乳化性能。这项工作表明，BSG蛋白- ga偶联物是通用的，足以实现清洁标签，植物为基础的乳化剂应用及其所需的功能/感官特性。

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