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Content of nickel in maize and soil fertilized with organic materials derived from waste 玉米和土壤中镍的含量
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)07
B. Filipek-Mazur, M. Tabak
The research was conducted to determine the influence of fertilization with waste organic materials on the content and uptake of lead by maize as well as on the total content of lead in soil. The three-year field experiment comprised 7 treatments: a non-fertilized soil (control treatment) as well as a soil fertilized with mineral fertilizers, cattle manure, green waste compost, sewage sludge, compost from sewage sludge and straw as well as with a mixture of sewage sludge and hard coal ash. Maize cultivated for silage was the test plant. The lead content in the above-ground parts of plants and in the soil was determined using ICP-AES method. During the research, no lead pollution of the soil or the above-ground parts of the maize was found. No statistically significant effect of fertilization on the lead content in the maize was found or the fertilized plants contained considerably less of the element than the control plants. The lowest weighted mean content of lead was found in the maize fertilized with the green waste compost, sewage sludge as well as with the compost from sludge and straw. Soil with the lowest lead content was the soil of the treatment fertilized with organic materials. The soil fertilized with the green waste compost (all the years), sewage sludge (2 year) as well as with the mixture of sludge and ash (1 and 2 year) contained significantly more lead than the soil fertilized with mineral fertilizers.
本试验旨在研究有机废弃物施肥对玉米对铅的含量、吸收及土壤中铅总含量的影响。为期三年的田间试验包括7个处理:不施肥的土壤(对照处理),以及用矿物肥料、牛粪、绿色废物堆肥、污水污泥、污水污泥和秸秆堆肥以及污水污泥和硬煤灰混合施肥的土壤。青贮玉米为试验作物。采用电感耦合等离子体发射光谱法测定了植物地上部分和土壤中的铅含量。在研究过程中,土壤和玉米地上部分均未发现铅污染。未发现施肥对玉米铅含量的显著影响,或施肥植株的铅含量明显低于对照植株。玉米中铅的加权平均含量以绿色废弃物堆肥、污水污泥以及污泥和秸秆堆肥施肥的玉米最低。有机肥处理的土壤铅含量最低。施用绿色废弃物堆肥(所有年份)、污水污泥(2年)以及污泥灰分混合物(1年和2年)的土壤含铅量明显高于施用无机肥料的土壤。
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引用次数: 1
Steam gasification of multiwire LiYCY type electrical cable 多线LiYCY型电缆的蒸汽气化
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)10
W. Szczepaniak, M. Zabłocka-Malicka, Amelia. Zielińska, P. Rutkowski
Original, non-separated pieces of the LiYCY cable (with multilayer metal/plastic (copper/PVC) structure) were gasified by steam in an excess at atmospheric pressure. Conversion of the gaseous stream was enhanced by catalytic bed of original granulated material, prepared from aluminosilicate (local clay) and calcium carbonate. In the process metal (Cu) preserved unchanged form of cords and braids and was quantitatively separated (49 % of original mass of the cable). Non-metal components (51 % of original mass of the cable) were converted to a slightly sintered non-metallic powder (3.3 % of original mass of the cable) and gaseous phase. Condensation of steam facilitated elimination of tars and oils as well as hydrochloride from the gas. It was estimated that only 5 % of carbon (from the cable components) was retained in the cooling/condensing line, mostly as water non-soluble phases. Efficiency of absorption of hydrochloride by catalytic bed and aqueous condensate was almost the same (but only 50 % of estimated total chlorine quantity was finally balanced).
原始的、未分离的LiYCY电缆(多层金属/塑料(铜/PVC)结构)在大气压下被过量的蒸汽气化。以硅酸铝(当地粘土)和碳酸钙为原料制备的原始颗粒物料为催化床,提高了气体的转化率。在此过程中,金属(Cu)保持了绳状和辫状的不变形式,并被定量分离(电缆原始质量的49%)。非金属成分(电缆原始质量的51%)被转化为稍微烧结的非金属粉末(电缆原始质量的3.3%)和气相。蒸汽的冷凝有助于从气体中除去焦油和油以及盐酸盐。据估计,只有5%的碳(来自电缆组件)保留在冷却/冷凝管道中,主要是水不溶相。催化床和冷凝水对盐酸的吸附效率几乎相同(但最终平衡的氯只占估计总氯量的50%)。
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引用次数: 0
Toxicological and ecotoxicological properties of an iron based combustion modifier for liquid fuels 液体燃料铁基燃烧改进剂的毒理学和生态毒理学特性
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(2)13
J. Guziałowska-Tic, W. Tic
It is necessary to use specific modifiers in order to reduce harmful emissions arising in the combustion of liquid fuels into the atmosphere. Such modifiers include organic metal salts which are soluble in fuels and tend to form metal oxides under combustion process conditions, improving the oxidizing properties of fuels. The modifier, described in this paper was used in liquid fuel combustion tests, showing a desirable effect of reducing CO, NOx and hydrocarbon emissions. For such modifiers to be approved for use, examination of their physico-chemical, toxicological and ecotoxicological properties is required according to REACH Regulation. REACH is intended, first of all, to provide appropriate protection to the environment and human health, while striving to maintain competitiveness of European enterprises in the global market. Discussed in this paper are the results of selected tests of the effect of an iron-based modifier for liquid fuels on human health and on the land and air and the aquatic environment. The modifier was subjected to physico-chemical analyses, and toxicological and ecotoxicological tests in accordance with good laboratory practice and OECD guidelines. The test results indicate that the modifier is a safe substance, posing no hazard to human health or the environment.
为了减少液体燃料向大气中燃烧时产生的有害排放物,有必要使用特定的改性剂。这些改性剂包括可溶于燃料的有机金属盐,在燃烧过程条件下易于形成金属氧化物,从而改善燃料的氧化性能。将该改性剂用于液体燃料燃烧试验,取得了降低CO、NOx和碳氢化合物排放的良好效果。对于批准使用的此类改性剂,需要根据REACH法规对其物理化学,毒理学和生态毒理学特性进行检查。REACH的目的首先是为环境和人类健康提供适当的保护,同时努力保持欧洲企业在全球市场上的竞争力。本文讨论了液体燃料铁基改性剂对人体健康以及对陆地、空气和水生环境的影响的选定试验结果。根据良好实验室规范和经合组织准则,对改性剂进行了理化分析、毒理学和生态毒理学测试。试验结果表明,该改性剂是一种安全物质,对人体健康和环境没有危害。
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引用次数: 2
Thermal stability of polypropylene composite reinforced with glass fibre in the oxidising atmosphere 氧化气氛中玻璃纤维增强聚丙烯复合材料的热稳定性
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ecea.2015.22(3)33
A. Hałat, R. Kędzior, D. Grzesiak, J. Głowiński
Stability of the polypropylene composite with fiber glass (45/55) in the form of low density mat was tested experimentally at increased temperature. It was examined by analyzing the influence of the atmosphere with various oxygen content on the decomposition rate of the polypropylene composite. It has been found that in the air atmosphere, the initial decomposition temperature is close to 200 C. Lowering the oxygen concentration in the atmosphere to 2 % results in increase of composite decomposition temperature to almost 240 C. Decomposition components were identified in the methylene chloride extract from composite and in the condensed reaction products. Rate of decomposition conversion at initial stage below 0.2 was estimated as a system of equations: zero order path r = k1 for polypropylene degradation and first order path r = k2[O2] for oxidative decomposition. A brief safety analysis is performed identifying the possibility of exceeding an explosion limit under certain conditions. The best way of mitigating the fire/explosion hazard is lowering the oxygen content below 2 % vol., especially for processing of recycled polypropylene.
对低密度玻纤(45/55)聚丙烯复合材料在高温下的稳定性进行了实验研究。通过分析不同含氧量的气氛对聚丙烯复合材料分解速率的影响,对其进行了验证。在空气气氛中,初始分解温度接近200℃,当大气中氧气浓度降至2%时,复合材料的分解温度升高至240℃左右,在复合材料的二氯甲烷萃取物和缩合反应产物中发现了分解成分。在初始阶段分解转化率低于0.2时,用方程组来估计:聚丙烯降解的零阶路径r = k1,氧化分解的一阶路径r = k2[O2]。进行了简要的安全分析,确定了在某些条件下超过爆炸极限的可能性。减少火灾/爆炸危险的最佳方法是将氧含量降低到2% vol.以下,特别是对于再生聚丙烯的加工。
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引用次数: 0
Characteristics of grey water filtration on polypropylene filters 聚丙烯过滤器过滤灰水的特点
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)04
J. Mucha
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引用次数: 1
Granulometric analysis to estimate influence of anionic surfactant on activated sludge structure 阴离子表面活性剂对活性污泥结构影响的粒度分析
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)05
A. Dereszewska, A. Tuszyńska, S. Cytawa
The work concerns the evaluation of the possibility of using laser diffraction analyzer to determine changes in the distribution of sludge floc size in the presence of anionic surfactant. As a model of surfactant linear alkylbenzene sulphonate (LAS) was used. Different concentrations: 10, 100 and 200 mg/dm of LAS was applied. The granulometric analysis showed that the pure activated sludge was composed of particles with a size of 1 m to 2 mm. The largest and fastest changes in the distribution of sludge floc size after the addition of a surfactant at a concentration of 100 mg/dm were observed. The flocs with a diameter above 0.8 mm disappear and the average diameter over volume of particles decrease from 0.29 to 0.19 mm. Doubling the dose of surfactant causes the flocs aggregation. The sludge flocs capability for break-up and aggregation is not proportional to the concentration of LAS. Addition of LAS to the sludge results in decrease of the sludge volume index. This study showed that granulometric measurement may help to estimate an impact of chemical substances contained in wastewater on activated sludge.
研究了用激光衍射分析仪测定阴离子表面活性剂存在下污泥絮团粒径分布变化的可能性。以线性烷基苯磺酸盐(LAS)为表面活性剂。不同浓度:10、100、200 mg/dm。粒度分析表明,纯活性污泥由粒径为1 ~ 2 mm的颗粒组成。在添加浓度为100 mg/dm的表面活性剂后,污泥絮团粒径分布变化最大,变化最快。粒径在0.8 mm以上的絮凝体消失,平均粒径比体积由0.29 mm降至0.19 mm。表面活性剂用量加倍可引起絮凝体聚集。污泥絮凝体的破碎和聚集能力与LAS浓度不成正比。在污泥中加入LAS,污泥体积指数降低。本研究表明,颗粒法测量可以帮助估计废水中所含化学物质对活性污泥的影响。
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引用次数: 0
Invasiveness and reproduction of the Steinernema feltiae from selected agrocoenose located in Wielun 威伦某农田飞蛾的入侵与繁殖
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)26
J. Matuska-Łyżwa
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引用次数: 1
Assessment of the effect of environmental variables on health status of Tilia cordata Mill. in parks 环境变量对天麻健康状况影响的评价。在公园里
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)29
D. Świerk, M. Krzyżaniak, Miłosz T. Walerzak, P. Urbański
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引用次数: 0
Effect of “Hajdow” wastewater treatment plant modernization on wastewater purification process “Hajdow”污水处理厂现代化改造对污水净化工艺的影响
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)24
K. Jaromin-Gleń, E. Kurek, M. Bis, A. Kopertowska, M. Jaczyński, M. Jaworska
The study presents the effect of modernization of selected elements of the technological line in the ‘Hajdów’ municipal wastewater treatment plant (WWTP) on the course of the process of wastewater treatment. The researchers paid special attention to the changes in the amount of emerging waste (rake bar screens, sand, excess sludge) due to modernization, and the elimination of odour nuisance from the plant. Technological changes in the system of activated sludge bioreactor contributed to a considerable increase in the amount of excess sludge. This caused problems with its effective management with the use of previously applied methods and devices; therefore, facilities were introduced supporting the dehydration of excess sludge. Therefore, the article also presents the description of solutions concerning the processing of sludge introduced to-date in the ‘Hajdów’ WWTP and further modernizations implemented.
本文研究了“Hajdów”城市污水处理厂(WWTP)工艺线选定要素的现代化对污水处理过程的影响。研究人员特别关注了由于现代化而产生的废物(耙杆筛网、沙子、多余污泥)数量的变化,以及工厂异味的消除。活性污泥生物反应器系统的技术变化导致了剩余污泥量的大幅增加。这对使用以前应用的方法和设备进行有效管理造成了问题;为此,介绍了配套的多余污泥脱水设备。因此,本文还介绍了迄今为止在“Hajdów”污水处理厂引入的污泥处理解决方案和进一步现代化实施的描述。
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引用次数: 4
Assessment of the microbiological contamination of air in a municipal solid waste treatment company 某城市生活垃圾处理公司空气微生物污染评价
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(2)14
K. Wolny-Koładka, M. Malinowski
The subject of the study is the analysis of the number of microorganisms forming a microbiological aerosol in a municipal solid waste treatment plant in Krakow. The storage time of mixed municipal solid waste in the plant hall is 6–48 hours and the storage time of the produced alternative fuel is within the range of 12–96 hours. 18 employees work in the three shift system in the sorting facility. The air for research was sampled using a MAS-100 impactor (Merck, Switzerland) in three locations within the plant, four times within a year to assess the effect of meteorological conditions (temperature, humidity and dustiness) on the number of selected groups of microorganisms. It was found that the number of microorganisms changes with seasons and depends on the meteorological conditions as well as the air sampling location. Since the border values of bioaerosol concentration were exceeded, further research is required to assess the changes in the number of microorganisms with potential negative impact on human health.
本研究的主题是分析克拉科夫城市固体废物处理厂形成微生物气溶胶的微生物数量。混合城市生活垃圾在工厂大厅的储存时间为6-48小时,生产的替代燃料的储存时间在12-96小时范围内。18名员工在分拣工厂实行三班倒制。用于研究的空气是使用MAS-100冲击器(瑞士默克公司)在工厂内的三个地点取样的,一年内取样四次,以评估气象条件(温度、湿度和粉尘)对选定微生物群数量的影响。结果表明,微生物数量随季节、气象条件和采样地点的不同而变化。由于生物气溶胶浓度已超过边界值,因此需要进一步研究评估对人类健康有潜在负面影响的微生物数量的变化。
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引用次数: 5
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ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A
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