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Optimization of carbon dioxide concentration in the didactic rooms by the regulation of ventilation 通过调节通风来优化教学室的二氧化碳浓度
Q4 Environmental Science Pub Date : 2016-01-01 DOI: 10.2428/ECEA.2016.23(3)27
E. Słodczyk, D. Suszanowicz
Poor ventilation of didactic rooms can interfere with students’ ability to concentrate and even cause them to suffer headaches. This is a significant issue as the ventilation systems of most lecture buildings in Poland do not provide proper air exchange. This paper presents findings of research on air parameters research in the didactic rooms of various sizes. Rooms for classes should ensure climatic comfort i.e. proper humidity and air temperature, physical and biological air quality, and low concentration of carbon dioxide. The research suggested that natural ventilation should not be used, and further research was done after the upgrading of ventilation systems and installation of exhaust fans. The coefficients of carbon dioxide emissions by one student depend on the number of people and size of the room were calculated. Designated coefficients will be used in the algorithm for determining the parameters of the fans in the ventilation system of the classrooms and lecture halls.
教学教室通风不良会影响学生集中注意力,甚至导致他们头痛。这是一个重要的问题,因为波兰大多数教学楼的通风系统不能提供适当的空气交换。本文介绍了不同规模教学教室空气参数研究的研究结果。教室应确保气候舒适,即适当的湿度和空气温度,物理和生物空气质量,以及低浓度的二氧化碳。研究建议不宜采用自然通风,待通风系统升级、安装排风机后再作进一步研究。每个学生的二氧化碳排放系数取决于人数和房间的大小。算法将使用指定的系数来确定教室和报告厅通风系统中风扇的参数。
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引用次数: 6
Changes in activity of acid hydrolases in tissues of wild pheasants induced by heavy metals 重金属对野鸡组织酸性水解酶活性的影响
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)09
S. Zielińska, M. Pieniążek, M. Dżugan
The aim of the study was to determinate the activity of chosen acid hydrolases in tissues of pheasants (Phasianus colchicus L.) and first attempts to use these enzymes as biomarkers of the effect of birds exposure to heavy metals in the environment. The samples of liver, kidneys and testes were collected from wild pheasants shot in the Podkarapacie region in contaminated (n = 5) and clear (n = 5) areas. Tissues were examined for the cadmium and lead concentrations by AAS method, as well as the activity of five hydrolases. The major site of cadmium accumulation were kidneys, the levels of Cd found in liver and testes were by 5-fold and 30-fold lower (P < 0.05), respectively. Similarly, Pb concentrations observed in the liver and testes were lower than in kidney, by 1.5-fold and 6-fold, respectively. The presence of four glycosidases and arylsulphatase in all examined tissues was demonstrated and N-acetyl-D-glucosaminiadase (NAG) was identified as the most active enzyme in all studied tissues. Significant differences (P < 0.05) were observed only in the level of NAG activity in liver of pheasants inhabiting the contaminated area as compared to the birds from the clear region (control group). We conclude that the determination of NAG in birds organs can be used as biomarker of environmental exposure to cadmium.
本研究的目的是测定野鸡(Phasianus colchicus L.)组织中选定的酸水解酶的活性,并首次尝试将这些酶作为鸟类暴露于环境中重金属影响的生物标志物。在Podkarapacie地区污染区(n = 5)和干净区(n = 5)射击野鸡的肝脏、肾脏和睾丸标本。用原子吸收光谱法测定了组织中镉、铅的浓度,并测定了5种水解酶的活性。镉的主要积聚部位为肾脏,肝脏和睾丸的镉含量分别降低了5倍和30倍(P < 0.05)。同样,在肝脏和睾丸中观察到的铅浓度比肾脏低,分别为1.5倍和6倍。四种糖苷酶和芳基硫酸酶在所有检测组织中均被证实存在,n -乙酰- d -氨基葡萄糖酶(NAG)被确定为所有研究组织中最活跃的酶。只有污染区的野鸡肝脏NAG活性水平与未污染区的野鸡(对照组)有显著差异(P < 0.05)。因此,鸟类器官中NAG的测定可作为环境镉暴露的生物标志物。
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引用次数: 0
Comparison of the effectiveness of different types of extractants for recovery of iron from mineral wool waste 不同萃取剂回收矿棉废铁的效果比较
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(2)18
M. Huculak-Mączka, E. Klem, E. Ogonowska, A. Justyniarski, J. Hoffmann
The paper presents the results of iron extraction from wool waste. In studies as extractant was used: water, EDTA, acetic acid, formic acid, DTPA, ammonium lactate and calcium lactate. For analysis has been taken wool after one year cultivation of tomato and cucumber and wool after two years of mixed cultivation. The main aim of the analysis was to determine which extractant allows the greatest recovery of the iron from waste mineral wool. Current trends in the agriculture development and the fertilizer industry are aimed at maximizing the recovery of nutrients from waste for re-use. Demonstration of the effectiveness of the recycling of valuable trace elements contained in the mineral wool can make develop a method of wool utilization profitable. In addition, the high cost of fertilizer components makes a new type of medium containing nutrients obtained by extraction from mineral wool waste, can be an interesting option in the future. Implementation of this type of process is consistent with the objectives of Sustainable Development, as well as the environmental policy of the European Union. The proposed way to get iron from mineral waste wool consists of following steps: drying at 30 C for 24 hours, grinding to particles with a sieve size of 0.40 nm, extraction and phase separation. The studies included the effect of time, temperature and type of extractants on the efficiency of the process. The iron content in the samples was determined by spectrophotometric method based on the ferric ion complex of 2,2-pyridyl in a solution at pH of 3.1.
本文介绍了从羊毛废料中提取铁的试验结果。研究中使用的萃取剂有:水、EDTA、乙酸、甲酸、DTPA、乳酸铵和乳酸钙。对番茄和黄瓜栽培1年后的羊毛和混作2年后的羊毛进行了分析。分析的主要目的是确定哪种萃取剂可以最大限度地从废矿棉中回收铁。目前农业发展和肥料工业的趋势旨在最大限度地从废物中回收营养物质进行再利用。论证了矿棉中有价微量元素回收利用的有效性,为开发一种有益的矿棉利用方法奠定了基础。此外,肥料成分的高成本使得从矿棉废料中提取含有营养物质的新型培养基在未来可能是一个有趣的选择。这类进程的实施符合可持续发展的目标,也符合欧洲联盟的环境政策。本文提出的从废羊毛中提取铁的方法包括:在30℃下干燥24小时,磨成0.40 nm粒度的颗粒,萃取和相分离。研究了萃取时间、萃取温度和萃取剂种类对萃取效率的影响。以2,2-吡啶的铁离子配合物为基础,在pH为3.1的溶液中分光光度法测定样品中的铁含量。
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引用次数: 0
Ammonia as a sustainable fuel 氨是一种可持续燃料
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)32
D. Grzesiak, R. Kędzior, D. Popławski, A. Hałat, P. Falewicz
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引用次数: 3
Metal pollution of surface water from Wielkopolska region 大波兰地区地表水的金属污染
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)23
Adam Perczak, A. Waśkiewicz, P. Goliński
Abstract: Polish water resources in comparison to other European countries are small. It is one of the factors leading to increased interest in monitoring tests for their quality. Heavy metals are major water pollutants in Poland. The aim of this study was to determine seasonal variability in concentrations of cadmium, lead, zinc and copper in various reservoirs and water courses in the Wielkopolska region. Water samples were collected from lakes, large and small rivers and drainage ditches. These water bodies differ in land use in the surrounding. These were mostly rural. The study was conducted during the growing season from May to December 2012. Quantitative analysis of heavy metals was performed on the AA spectrometer Agilent 280Z. The results showed high seasonal variation in heavy metal contents in different water bodies. The concentrations of cadmium and zinc mainly depend on the date of discharge to water. Lead concentrations were caused by emissions and depended mainly on cultivation measures in fields. The highest concentration of copper was observed in the lakes, which could be due to the use of compounds that eliminate algal blooms. Under Polish law, all water bodies are classified into water quality classes I or II intended for drinking. Living conditions for cyprinids and salmonids were satisfactory in all the locations.
摘要:波兰的水资源相对于其他欧洲国家来说是很少的。这是导致人们对监测测试质量越来越感兴趣的因素之一。重金属是波兰主要的水污染物。这项研究的目的是确定大波兰地区各水库和水道中镉、铅、锌和铜浓度的季节性变化。从湖泊、大小河流和排水沟中采集水样。这些水体在周围的土地利用上有所不同。这些大多是农村地区。研究在2012年5月至12月的生长季节进行。采用Agilent 280Z AA谱仪进行重金属定量分析。结果表明,不同水体重金属含量的季节变化较大。镉和锌的浓度主要取决于排放到水中的日期。铅浓度主要由排放引起,主要取决于田间栽培措施。在湖泊中观察到的铜浓度最高,这可能是由于使用了消除藻华的化合物。根据波兰法律,所有的水体都被划分为供饮用的I级或II级水质。所有地点的鲤科和鲑科鱼的生存条件都令人满意。
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引用次数: 2
Living organisms in water quality biomonitoring system 水质生物监测系统中的生物
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(1)01
E. Tomczak, A. Dominiak
The typical living organisms used for biological monitoring of surface waters and their use in applications are presented in the paper. The main focus is on the characterisation and use of freshwater mussels. The paper discusses the role of biomonitoring in surface water supply systems. Three-stage biomonitoring system which has been functioning for 20 years in Water and Wastewater Company (ZWiK Sp. z o.o.) in Lodz is presented as an example. The system employs living organisms such as mussels, perch and luminescent bacteria.
本文介绍了地表水生物监测中常用的典型生物及其应用。主要的重点是淡水贻贝的特性和使用。本文讨论了生物监测在地表水供应系统中的作用。以罗兹自来水公司(ZWiK Sp. z .o.)运行20年的三级生物监测系统为例。该系统采用了贻贝、鲈鱼和发光细菌等生物体。
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引用次数: 0
Assessment of air contamination with selected radioisotopes nearby cement plant using moss bag method 用苔藓袋法评价水泥厂附近选定放射性同位素的空气污染
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)35
D. Modzelewska, A. Dołhańczuk-Śródka, Z. Ziembik
: Mining and processing industry represents a potential source of radioisotopes contaminating the nearest environment. In order to estimate conditions of the environment in the vicinity of cement plant moss bag biomonitoring method was used. The aim of the study was to assess the relationship between the extent of air pollution with 40 K, 137 Cs, 210 Pb and the distance from the cement plant. The share of various radiation sources in the total 210 Pb activity concentration in mosses after exposure was also analyzed. Sampling sites were located in the forest near Opole (PL), in a line and at different distances from the cement plant. In test two types of moss bags, exposed simultaneously in the same places, were used. In the studies, activity concentrations of gamma-radioactive isotopes were determined in samples of moss before and after the exposure. In investigations the gamma-spectrometer with a germanium detector was used. From the obtained results the Relative Accumulation Factors ( RAF ) were calculated. In order to assess the extent to which radionuclides activity depends on the distance from the cement plant, correlation coefficients were calculated. It is hard to estimate the trends of radionuclides activity concentration changes with distance from the cement plant due to substantial discrepancies in the results. No significant relationship of radionuclides deposition on the distance from the cement plant was noticed.
采矿和加工业是污染最近环境的放射性同位素的潜在来源。为了对水泥厂附近的环境状况进行评价,采用了苔藓袋生物监测方法。该研究的目的是评估40 K, 137 Cs, 210 Pb的空气污染程度与水泥厂距离之间的关系。分析了不同辐射源在暴露后苔藓中210 Pb活性浓度的占比。采样点位于Opole (PL)附近的森林中,与水泥厂成一条直线,距离不同。在试验中,使用两种类型的苔藓袋,在同一地点同时暴露。在这些研究中,测定了暴露前后苔藓样品中伽马放射性同位素的活性浓度。在研究中使用了带锗探测器的伽马谱仪。根据所得结果计算了相对积累因子(RAF)。为了评估放射性核素活性与水泥厂距离的依赖程度,计算了相关系数。由于结果存在很大差异,因此很难估计放射性核素活性浓度随水泥厂距离的变化趋势。放射性核素的沉降与水泥厂的距离没有显著的关系。
{"title":"Assessment of air contamination with selected radioisotopes nearby cement plant using moss bag method","authors":"D. Modzelewska, A. Dołhańczuk-Śródka, Z. Ziembik","doi":"10.2428/ECEA.2015.22(4)35","DOIUrl":"https://doi.org/10.2428/ECEA.2015.22(4)35","url":null,"abstract":": Mining and processing industry represents a potential source of radioisotopes contaminating the nearest environment. In order to estimate conditions of the environment in the vicinity of cement plant moss bag biomonitoring method was used. The aim of the study was to assess the relationship between the extent of air pollution with 40 K, 137 Cs, 210 Pb and the distance from the cement plant. The share of various radiation sources in the total 210 Pb activity concentration in mosses after exposure was also analyzed. Sampling sites were located in the forest near Opole (PL), in a line and at different distances from the cement plant. In test two types of moss bags, exposed simultaneously in the same places, were used. In the studies, activity concentrations of gamma-radioactive isotopes were determined in samples of moss before and after the exposure. In investigations the gamma-spectrometer with a germanium detector was used. From the obtained results the Relative Accumulation Factors ( RAF ) were calculated. In order to assess the extent to which radionuclides activity depends on the distance from the cement plant, correlation coefficients were calculated. It is hard to estimate the trends of radionuclides activity concentration changes with distance from the cement plant due to substantial discrepancies in the results. No significant relationship of radionuclides deposition on the distance from the cement plant was noticed.","PeriodicalId":44472,"journal":{"name":"ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68905360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Comparative studies on decomposition of selected estrogens and xenoestrogens by photocatalysis processes 光催化过程中选定雌激素和异种雌激素分解的比较研究
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)36
Edyta Burdzik-Niemiec, M. Dudziak
This study addressed the degradation efficiency of three different compounds belonging to the group of endocrine disrupting compounds (EDCs), namely 17 -estradiol (E2), 17 -ethinyl estradiol (EE2), and bisphenol A (BPA) in the photocatalysis process (UV/TiO2). The subject of the study was a synthetic municipal waste water treatment plant effluent containing inorganic and optionally organic substances and to which the investigated micropollutants were added at a concentration of 500 g/dm. The obtained results were compared in terms of the degradation of the selected compounds in deionized water. It was found that the efficiency of the photocatalysis depends significantly both on the environmental matrix and physico-chemical properties of the compounds present in the treated waste water. The highest degradation efficiency was observed for the synthetic effluent that contained only inorganic substances. The degradation of bisphenol A and 17 -ethinyl estradiol exceeded 90 % (after 60-minute irradiation) and 17 -estradiol was decomposed completely. The observed phenomenon can be attributed to the process termed as sensitized photocatalysis, which was enabled by inorganic substances present in the synthetic waste water. This phenomenon was not observed for the synthetic effluent that contained both inorganic and organic substances, and moreover the degradation efficiency of the micropollutans was lower. These observations were also confirmed by the results regarding the decomposition of the compounds in deionized water. In order to describe the course of photocatalytic oxidation reaction rate constants were determined as well as degradation half-lives using the Langmuir-Hinshelwood kinetic model.
本研究研究了三种不同的内分泌干扰化合物(EDCs),即17 -雌二醇(E2), 17 -乙基雌二醇(EE2)和双酚A (BPA)在光催化过程(UV/TiO2)中的降解效率。该研究的主题是一个含有无机和任选有机物质的合成城市污水处理厂流出物,所研究的微污染物以500 g/dm的浓度加入其中。对所选化合物在去离子水中的降解效果进行了比较。研究发现,光催化的效率在很大程度上取决于环境基质和处理后废水中化合物的物理化学性质。仅含无机物的合成出水的降解效率最高。辐照60分钟后,双酚A和17 -乙基雌二醇的降解率超过90%,17 -雌二醇被完全分解。观察到的现象可归因于称为敏化光催化的过程,这是由合成废水中存在的无机物实现的。同时含有无机物和有机物的合成出水没有出现这种现象,而且对微污染物的降解效率较低。有关化合物在去离子水中分解的结果也证实了这些观察结果。为了描述光催化氧化过程,采用Langmuir-Hinshelwood动力学模型确定了光催化氧化反应的速率常数和降解半衰期。
{"title":"Comparative studies on decomposition of selected estrogens and xenoestrogens by photocatalysis processes","authors":"Edyta Burdzik-Niemiec, M. Dudziak","doi":"10.2428/ECEA.2015.22(4)36","DOIUrl":"https://doi.org/10.2428/ECEA.2015.22(4)36","url":null,"abstract":"This study addressed the degradation efficiency of three different compounds belonging to the group of endocrine disrupting compounds (EDCs), namely 17 -estradiol (E2), 17 -ethinyl estradiol (EE2), and bisphenol A (BPA) in the photocatalysis process (UV/TiO2). The subject of the study was a synthetic municipal waste water treatment plant effluent containing inorganic and optionally organic substances and to which the investigated micropollutants were added at a concentration of 500 g/dm. The obtained results were compared in terms of the degradation of the selected compounds in deionized water. It was found that the efficiency of the photocatalysis depends significantly both on the environmental matrix and physico-chemical properties of the compounds present in the treated waste water. The highest degradation efficiency was observed for the synthetic effluent that contained only inorganic substances. The degradation of bisphenol A and 17 -ethinyl estradiol exceeded 90 % (after 60-minute irradiation) and 17 -estradiol was decomposed completely. The observed phenomenon can be attributed to the process termed as sensitized photocatalysis, which was enabled by inorganic substances present in the synthetic waste water. This phenomenon was not observed for the synthetic effluent that contained both inorganic and organic substances, and moreover the degradation efficiency of the micropollutans was lower. These observations were also confirmed by the results regarding the decomposition of the compounds in deionized water. In order to describe the course of photocatalytic oxidation reaction rate constants were determined as well as degradation half-lives using the Langmuir-Hinshelwood kinetic model.","PeriodicalId":44472,"journal":{"name":"ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68905371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of water matrix on the retention of pharmaceuticals by high-pressure membrane filtration 高压膜过滤中水基质对药物滞留的影响
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)37
E. Kudlek, J. Bohdziewicz, M. Dudziak
{"title":"Influence of water matrix on the retention of pharmaceuticals by high-pressure membrane filtration","authors":"E. Kudlek, J. Bohdziewicz, M. Dudziak","doi":"10.2428/ECEA.2015.22(4)37","DOIUrl":"https://doi.org/10.2428/ECEA.2015.22(4)37","url":null,"abstract":"","PeriodicalId":44472,"journal":{"name":"ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68905380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
The influence of coconut fibre and salts composite used for eliminating slipperiness and on roads on soils 椰子纤维和盐复合材料对路面和土壤防滑的影响
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)38
K. Łuczak, G. Kusza
The subject of the study is analyzing the impact of coconut fibre and salt mixture used for eliminating slipperiness on roads on roadside soil. The tests were done on the soil samples taken from the fixed areas twice: in the autumn before applying the composite and in the following spring. Laboratory tests indicated decrease of conduciveness in soil after using the composite in wintertime. This can cause decreasing saltiness of roadside soil. In contrast to commonly used methods of eliminating slipperiness on roads with salts only applying the composite could diminish the negative effects of roadside soil saltiness.
该研究的主题是分析椰子纤维和盐混合物用于消除道路对路边土壤的滑溜的影响。对固定区域的土壤样本进行了两次测试:在施用复合材料之前的秋季和次年的春季。室内试验表明,冬季使用复合材料后,土壤电导率下降。这会导致路边土壤的盐分减少。与常用的用盐消除道路滑滑的方法相比,只使用复合材料可以减少路边土壤盐分的负面影响。
{"title":"The influence of coconut fibre and salts composite used for eliminating slipperiness and on roads on soils","authors":"K. Łuczak, G. Kusza","doi":"10.2428/ECEA.2015.22(4)38","DOIUrl":"https://doi.org/10.2428/ECEA.2015.22(4)38","url":null,"abstract":"The subject of the study is analyzing the impact of coconut fibre and salt mixture used for eliminating slipperiness on roads on roadside soil. The tests were done on the soil samples taken from the fixed areas twice: in the autumn before applying the composite and in the following spring. Laboratory tests indicated decrease of conduciveness in soil after using the composite in wintertime. This can cause decreasing saltiness of roadside soil. In contrast to commonly used methods of eliminating slipperiness on roads with salts only applying the composite could diminish the negative effects of roadside soil saltiness.","PeriodicalId":44472,"journal":{"name":"ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68905427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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