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Extraction of salt and base metals from geothermal water: Kinetic modeling and mechanism 从地热水中提取盐和贱金属:动力学模型和机理
IF 4.3 Q2 Engineering Pub Date : 2023-07-10 DOI: 10.1557/s43581-023-00066-y
Rohit Pawar, Sourav Santara, A. Sircar, R. Kumari, N. Bist, K. Yadav
Geothermal fluids have the potential as important sources of precious minerals and metals. There are several hydrometallurgical techniques by which geothermal fluid solutions can be processed to extract and purify metals and minerals such as potassium, manganese, zinc, and lithium. The primary methods for extraction of salt and base metals from geothermal water include precipitation, electrodialysis, reverse osmosis, adsorption, electrochemical intercalation, and ion exchange. Among several methods discussed so far membrane and adsorption methods can be one of the suitable methods for extraction of salt and base metals, respectively. The article also summarizes various mathematical modeling used to study dynamic behavior and kinetics of column adsorption. The three most widely used column models, i.e., Thomas, BDST, and Yoon–Nelson are discussed herein, that help to estimate the adsorption capacity and intensity giving an overview of mechanism and forces responsible for column sorption process. The elaborate discussion on mechanistic forces and factors responsible for metal extraction by sorption makes this review significant and preferable. Therefore, the article aims to provide deep insights and a quick overview of salt and base metal sources, their extraction processes, column sorption dynamics, kinetic modeling, and mechanisms in one sight. Work flow for Base metal Extraction from geothermal water.
地热流体具有作为珍贵矿物和金属的重要来源的潜力。有几种湿法冶金技术可以处理地热流体溶液来提取和纯化金属和矿物,如钾、锰、锌和锂。从地热水中提取盐和贱金属的主要方法包括沉淀、电渗析、反渗透、吸附、电化学插层和离子交换。在迄今为止讨论的几种方法中,膜法和吸附法分别是提取盐和碱金属的合适方法之一。文章还总结了用于研究柱吸附动力学行为和动力学的各种数学模型。本文讨论了三种最广泛使用的柱模型,即Thomas、BDST和Yoon–Nelson,它们有助于估计吸附容量和强度,从而概述了柱吸附过程的机理和力。对通过吸附提取金属的机制力和因素的详细讨论使这篇综述具有重要意义和可取性。因此,本文旨在对盐和贱金属来源、它们的提取过程、柱吸附动力学、动力学建模和机理提供深入的见解和快速的概述。从地热水中提取贱金属的工作流程。
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引用次数: 0
Pumped hydro storage for intermittent renewable energy: Present status and future potential in India 间歇性可再生能源的抽水蓄能:印度的现状和未来潜力
IF 4.3 Q2 Engineering Pub Date : 2023-05-10 DOI: 10.1557/s43581-023-00064-0
V. Pandey, A. Sircar, K. Yadav, N. Bist
Globally, communities are converting to renewable energy because of the negative effects of fossil fuels. In 2020, renewable energy sources provided about 29% of the world's primary energy. However, the intermittent nature of renewable power, calls for substantial energy storage. Pumped storage hydropower is the most dependable and widely used option for large-scale energy storage. This study discusses working, types, advantages and drawbacks, and global and national scenarios of pumped storage schemes. It discusses global leaders in pumped hydropower storage such as China and the USA and the current status of India in Pumped storage capacity. The study also highlights major pumped storage schemes of India and their contribution to total hydropower generation capacity. The study also discusses the possibilities for high-capacity pumped storage schemes (> 1000 MW) in India going forward with Agencies like the New & Renewable Energy Development Corporation of Andhra Pradesh and the Water Resource Department. Graphical Abstract
在全球范围内,由于化石燃料的负面影响,社区正在转向可再生能源。2020年,可再生能源提供了全球约29%的一次能源。然而,可再生能源的间歇性要求大量的能源储存。抽水蓄能水电是大规模储能中最可靠、应用最广泛的选择。本研究讨论了抽水蓄能方案的工作方式、类型、优缺点以及全球和国家情景。讨论了中国和美国等抽水蓄能领域的全球领导者以及印度抽水蓄能能力的现状。该研究还强调了印度的主要抽水蓄能计划及其对水力发电总容量的贡献。该研究还讨论了大容量抽水蓄能方案的可能性(> 1000MW)与安得拉邦新能源和可再生能源开发公司和水利部等机构合作。图形摘要
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引用次数: 1
Efficiency enhancement of photovoltaic solar system by integrating multi-pipe copper frame filled with ZnO-doped phase change material 掺杂zno相变材料集成多管铜框架提高光伏太阳能系统效率
IF 4.3 Q2 Engineering Pub Date : 2023-05-03 DOI: 10.1557/s43581-023-00063-1
S. Rubaiee, M. Fazal
The increase of module temperature during operation adversely affect the power conversion efficiency (PCE) of a photovoltaic (PV) solar system. In an attempt to improve the PCE of the PV solar system, multi-pipe copper cooling frames integrated with phase change material (PCM) and ZnO-doped PCM have been developed and examined. Monocrystalline silicon modules (50 W each), solar meter, temperature sensor, digital anemometer and multi-meter are employed to conduct the tests. The I–V curves are plotted for the PV systems tested. The outcomes unveiled that the module temperature and electrical efficiency of conventional PV system at noon were 52.8 °C and 12.29% respectively. Integrating PCM/ZnO with PV system has reduced 5.68% of the module temperature and increased the 5.04% of electrical efficiency. The multi-pipe copper cooling frame filled with ZnO-doped PCM shows better cooling performance owing to the role of natural convection and conduction heat transfer inside the frame. Graphical abstract
在操作期间模块温度的升高不利地影响光伏(PV)太阳能系统的功率转换效率(PCE)。为了提高光伏太阳能系统的PCE,开发并测试了与相变材料(PCM)和ZnO掺杂PCM集成的多管铜冷却框架。测试采用单晶硅模块(每个50W)、太阳能表、温度传感器、数字风速计和万用表。绘制了测试光伏系统的I–V曲线。结果表明,传统光伏系统中午的组件温度和电效率分别为52.8°C和12.29%。将PCM/ZnO与光伏系统集成,降低了5.68%的模块温度,提高了5.04%的电效率。ZnO掺杂PCM填充的多管铜冷却框架由于框架内部的自然对流和传导传热作用,显示出更好的冷却性能。图形摘要
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引用次数: 3
Environmental costs of green hydrogen production as energy storage for renewable energies 绿色制氢作为可再生能源储能的环境成本
IF 4.3 Q2 Engineering Pub Date : 2023-03-21 DOI: 10.1557/s43581-023-00062-2
Niklas Gerloff
Green hydrogen can play an important role in the energy transition because it can be used to store renewable energies in the long term, especially if the gas infrastructure is already in place. Furthermore, environmental costs are becoming increasingly important for companies and society, so that this study examines the environmental costs of green hydrogen production and compares them with the environmental costs of steam reforming, the conventional process that produces more than 90% of the world's hydrogen. For the green hydrogen production, the renewable energy sources solar, wind, and hydro energy are taken into account. The study shows that hydrogen production from hydro energy causes less environmental costs than the production from wind and solar energy. Moreover, the environmental costs of steam reforming are in part more than twice as high as the environmental costs of hydrogen produced from wind and hydro energy, whereby only the impact category climate change could be considered for steam reforming due to a lack of information. Graphical abstract
绿氢可以在能源转型中发挥重要作用,因为它可以用于长期储存可再生能源,特别是在天然气基础设施已经到位的情况下。此外,环境成本对公司和社会来说越来越重要,因此本研究考察了绿色氢气生产的环境成本,并将其与蒸汽重整的环境成本进行了比较,蒸汽重整是一种生产世界90%以上氢气的传统工艺。对于绿色氢气生产,考虑了可再生能源太阳能、风能和水能。研究表明,水力发电产生的氢气比风能和太阳能产生的氢气产生的环境成本更低。此外,蒸汽重整的环境成本在一定程度上是风能和水能生产氢气的环境成本的两倍多,因此,由于缺乏信息,蒸汽重整只能考虑气候变化的影响类别。图形摘要
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引用次数: 0
Opportunities for the materials research community to support the development of the H_2 economy 材料研究界支持H_2经济发展的机遇
IF 4.3 Q2 Engineering Pub Date : 2023-03-20 DOI: 10.1557/s43581-023-00061-3
A. Ku, Elizabeth A. Kócs, Shaik Afzal, M. Ewan, Jennifer R. Glenn, F. Toma, James W. Vickers, B. Weeks, Ashley A. White
The goal of decarbonizing global energy systems by 2050 is a challenge of unprecedented scope and ambition. Hydrogen has been identified as an important enabler for this effort, but its precise role in the energy transition and future energy system remains unclear. The MRS Focus on Sustainability subcommittee sponsored a panel discussion on the roles of and materials needs associated with hydrogen in the energy transition. This commentary summarizes key elements from the panel discussion and addresses how the materials research community can engage more deeply with the H_2 energy transition. The topics include inventing new materials with improved properties for advanced technologies, but also supporting the growth of a robust manufacturing base, improving materials corrosion mitigation, helping to de-risk supply chains, and training qualified workers across the industrial ecosystem to reinforce a culture of safety and support the evolution of commercial processes and business models. Graphical abstract
到2050年实现全球能源系统脱碳的目标是一项规模和雄心前所未有的挑战。氢已被确定为这一努力的重要推动者,但其在能源转型和未来能源系统中的确切作用尚不清楚。MRS关注可持续性小组委员会发起了一场关于氢在能源转型中的作用和相关材料需求的小组讨论。这篇评论总结了小组讨论中的关键元素,并阐述了材料研究界如何更深入地参与H_2能量跃迁。这些主题包括为先进技术发明具有改进性能的新材料,但也支持强大的制造基地的发展,改善材料腐蚀缓解,帮助降低供应链风险,以及在整个工业生态系统中培训合格的工人,以加强安全文化,支持商业流程和商业模式的发展。图形摘要
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引用次数: 1
Determination of optimally feasible operating parameters for gasification of high-ash-content coal 高灰分煤气化最佳可行操作参数的确定
IF 4.3 Q2 Engineering Pub Date : 2023-02-06 DOI: 10.1557/s43581-022-00056-6
Priyank P. Dave, Parth D. Shah, Taha Poonawala, S. Channiwala, J. Parikh
The use of the coal in power generation poses serious issues of particulate emissions and efficiency limitations. Power generation through a gasification route is a potential eco-friendly method. However, the gasification of high-ash-content coal itself is a major challenge, as the presence of high ash content (> 40%) limits the rate of reaction and leads to flow resistance, significantly affecting the gas quality. To overcome this limitation, one has to determine the optimal feasible operating parameters for its gasification. In the present investigation, a two-phase equilibrium model is used to determine the optimally feasible range of the equivalence ratio for gasification of five different types of coals whose ash content varies from 41.08 to 52.56% on a dry weight percentage basis. A parametric study is also carried out with respect to enriched O_2 air and steam addition to find the optimal process configuration. Moreover, response surface methodology is used to optimize the operating variables. From the analysis, it is finally observed that for high-ash-content coals, the most optimally feasible operating parameters are the use of 26.5% O_2-enriched air with 10% mass addition by steam. Graphical abstract
在发电中使用煤炭造成了严重的颗粒物排放和效率限制问题。通过气化路线发电是一种潜在的环保方法。然而,高灰分含量煤的气化本身是一个主要挑战,因为高灰分含量(> 40%)限制反应速率并导致流动阻力从而显著影响气体质量。为了克服这一限制,必须确定其气化的最佳可行操作参数。在本研究中,使用两相平衡模型来确定五种不同类型煤的气化当量比的最佳可行范围,这些煤的灰分含量在干重百分比的基础上从41.08%变化到52.56%。还对富氧空气和蒸汽的添加进行了参数研究,以找到最佳的工艺配置。此外,使用响应面方法来优化操作变量。通过分析,最终观察到,对于高灰分煤,最佳可行的操作参数是使用26.5%O_2-富集空气,通过蒸汽添加10%的质量。图形摘要
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引用次数: 1
Optimal scheduling of distributed generators for efficient microgrid system operation for different electricity market pricing and grid participation 不同电力市场价格和电网参与下的分布式发电机组优化调度
IF 4.3 Q2 Engineering Pub Date : 2023-01-03 DOI: 10.1557/s43581-022-00059-3
S. Misra, P. K. Panigrahi, B. Dey, Saradindu Ghosh
A microgrid comprising several distributed energy resources (DERs) may include both conventional and non-conventional energy sources. Based on its mode of operation, a microgrid is classified as an islanded or grid-connected type. This paper studies five scenarios of optimal scheduling operations for DERs to achieve an economical low-voltage microgrid system. These scenarios are based on different types of grid participation and electricity market pricing strategies. The study's optimization tool was a freshly built, rapid and popular crow search algorithm (CSA). The findings imply that the most economical scenario of microgrid operation was when the grid was actively involved in the purchasing and selling of power with a time-of-usage-based dynamic pricing strategy. Considering scenario 1 as the ideal case, there was a 60% increase in the generation cost when a fixed-price grid was chosen in case 2 and an 80% increase in generation cost when the grid was contributing passively. Numerical findings support the statements that were made, with the CSA technique consistently producing superior-quality solutions with minimal execution time, independent of the problem's dimensions, therefore exceeding other similarly constructed algorithms used in the research. Graphical abstract
包括若干分布式能源(DER)的微电网可以包括传统能源和非传统能源。根据其运行模式,微电网可分为孤岛型或并网型。本文研究了DER的五种优化调度操作场景,以实现经济的低压微电网系统。这些场景基于不同类型的电网参与和电力市场定价策略。该研究的优化工具是一种新构建的、快速且流行的乌鸦搜索算法(CSA)。研究结果表明,微电网运行最经济的情况是电网通过基于使用时间的动态定价策略积极参与电力购销。将情景1视为理想情况,当在情景2中选择固定价格电网时,发电成本增加了60%,而当电网被动贡献时,发电费用增加了80%。数值结果支持了所做的陈述,CSA技术始终以最小的执行时间产生高质量的解决方案,与问题的维度无关,因此超过了研究中使用的其他类似构造的算法。图形摘要
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引用次数: 0
Wind turbines with aramid fiber composite wind blades for smart cities like urban environments: Numerical simulation study 用于城市环境等智能城市的芳纶纤维复合风叶片风力涡轮机:数值模拟研究
IF 4.3 Q2 Engineering Pub Date : 2023-01-03 DOI: 10.1557/s43581-022-00060-w
E. Fantin Irudaya Raj, Appadurai M, T. Lurthu Pushparaj, M. Chithambara Thanu
A smart city is an efficient and resilient urban center that, by leveraging its resources, provides its inhabitants with a good standard of living. Many countries worldwide have it as a mission to create citizen-friendly, eco-friendly, and sustainable smart cities. Power generation and power management are also integral parts of this mission. Power generation through renewable energy sources will be a crucial factor in a smart city environment. Renewable energy sources like solar and winds are the most used renewable energy and are more suited for urban applications. The present manuscript focuses on wind power generation using wind turbines in urban environments like smart cities. Most of the urban applications use Vertical axis Wind Turbine (VWT) for power generation. Compared with the Horizontal axis Wind Turbine (HWT), the low efficiency and dynamic instability problems are the main drawbacks of VWT. But the HWT does not have any such issues. Instead, it has its own disadvantages when it is used in smart cities like urban environments. The main shortfalls of conventional HWT are weighing heavily and creating more vibration and acoustic noise. An aramid fiber-based wind blade is proposed in this work to solve the shortcomings of conventional HWT and make it more suited for smart cities such as the urban environment. The CATIA modeling software suite is used to model and design wind blades. To examine the behaviour of the proposed wind turbine, structural, modal, and harmonic analyses are performed using ANSYS. The numerical results indicated that the proposed aramid fiber-based wind turbine is light in weight, creates low acoustic noises, free from vibration, and has a lower chance of resonance occurrence. Thus, it is better suited for urban environments such as smart cities. Graphical abstract
智慧城市是一个高效、有弹性的城市中心,通过充分利用其资源,为居民提供良好的生活水平。世界上许多国家都把创建市民友好型、生态友好型和可持续发展的智慧城市作为使命。发电和电源管理也是这一使命的组成部分。通过可再生能源发电将成为智慧城市环境的关键因素。太阳能和风能等可再生能源是使用最多的可再生能源,更适合城市应用。目前的手稿侧重于在智能城市等城市环境中使用风力涡轮机进行风力发电。大多数城市应用使用垂直轴风力涡轮机(VWT)发电。与水平轴风力机相比,低效率和动力不稳定问题是其主要缺点。但高铁不存在这样的问题。相反,当它在城市环境等智能城市中使用时,它有自己的缺点。传统HWT的主要缺点是重量大,产生更多的振动和噪音。本文提出了一种基于芳纶纤维的风叶片,以解决传统HWT的缺点,使其更适合城市环境等智慧城市。采用CATIA建模软件对风叶片进行建模和设计。为了检查所提出的风力涡轮机的性能,使用ANSYS进行了结构、模态和谐波分析。数值计算结果表明,所设计的芳纶基风力机具有重量轻、噪声低、无振动、共振发生几率低等特点。因此,它更适合智慧城市等城市环境。图形抽象
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引用次数: 3
A study on various sources and technologies for production of biodiesel and its efficiency 生物柴油生产的各种来源、技术及其效率研究
IF 4.3 Q2 Engineering Pub Date : 2022-12-27 DOI: 10.1557/s43581-022-00058-4
Pulkit Kharia, R. Saini, Vamsi Krishna Kudapa
Energy from renewable sources is steadily expanding, even if fossil fuels remain the primary source of energy. Numerous advantages to biodiesel over other biofuels and fossil fuels make it a promising alternative fuel. It was the goal of this research project to distinguish between conventional and new technologies used throughout the biodiesel production and consumption life cycle. Biodiesel generation from micro-algal lipids and enhanced homogeneous and enzymatic transesterification, as well as non-catalytic supercritical transesterification using microwave and ultrasound as helping technologies, are all discussed in detail in the study. Our examination of biodiesel environmental assessment principles and current accomplishments takes into account all the variables that can affect the process efficiency and safety. Scientific research and development on biodiesel have increased over the past few decades. Alternative fuels are high in demand due to dwindling petroleum hydrocarbon supplies worldwide. Biodiesel, a type of biofuel, is now being hailed as a breakthrough commodity that will eventually replace petroleum-based diesel. Biodiesel is a crucial advantage over conventional diesel in biodegradability, reduced exhaust emissions, more outstanding flash points, good lubricity, and other characteristics. Feedstock for biodiesel production includes various edible oils, non-edible oils, animal fats, microalgal oils, waste oils, and advanced solar oil. Biodiesel is prepared by breaking down the fats and oils into their corresponding alkyl esters by heating them. Processes such as transesterification, dilution, pyrolysis, and microemulsion are used to synthesize biodiesel. Microwave-assisted transesterification, reactive distillation, membrane separation, reactive extraction, and ultrasound are all recent developments in biodiesel manufacturing. The present works compare the ongoing research in the area of various biodiesel production processes in terms of their effectiveness. Graphical abstract
即使化石燃料仍然是主要能源,可再生能源的能源仍在稳步增长。与其他生物燃料和化石燃料相比,生物柴油有许多优点,使其成为一种有前景的替代燃料。该研究项目的目标是区分生物柴油生产和消费生命周期中使用的传统技术和新技术。本研究详细讨论了由微藻脂质产生生物柴油、增强的均相和酶促酯交换以及使用微波和超声波作为辅助技术的非催化超临界酯交换。我们对生物柴油环境评估原则和当前成就的审查考虑了可能影响工艺效率和安全性的所有变量。在过去的几十年里,生物柴油的科学研究和开发有所增加。由于全球石油碳氢化合物供应的减少,替代燃料的需求量很大。生物柴油是一种生物燃料,现在被誉为一种突破性商品,最终将取代石油柴油。生物柴油在生物降解性、减少废气排放、更突出的闪点、良好的润滑性和其他特性方面比传统柴油具有关键优势。生物柴油生产的原料包括各种食用油、非食用油、动物脂肪、微藻油、废油和高级太阳能油。生物柴油是通过加热将脂肪和油分解成相应的烷基酯来制备的。采用酯交换、稀释、热解和微乳液等工艺合成生物柴油。微波辅助酯交换、反应蒸馏、膜分离、反应萃取和超声波都是生物柴油生产的最新进展。目前的工作比较了在各种生物柴油生产工艺领域正在进行的研究的有效性。图形摘要
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引用次数: 3
Microgrid system allocation using a bi-level intelligent approach and demand-side management 微电网系统配置采用双层智能方法和需求侧管理
IF 4.3 Q2 Engineering Pub Date : 2022-12-15 DOI: 10.1557/s43581-022-00057-5
B. Dey, S. Basak, B. Bhattacharyya
Abstract Demand-side management (DSM) segregates the elastic and inelastic loads and restructures the load demand model of a distribution system by minimizing the operational cost of the entire process. This is done by optimally transferring the flexible loads to hours when the per-unit cost of utility is lower. This paper performs a bi-level optimization strategy to lower the operating expense of a low-voltage microgrid (LV MG) system operating in grid-connected mode, comprising battery energy storage (BES), renewable energy sources (RES), and fossil fuel-powered generators. In the first level of optimization, the load model is restructured as per the DSM participation level. Thereafter, the restructured load demand model is considered, and optimal allocation for distributed generators (DGs) is percolated for minimizing the generation cost of the microgrid system in the second level. A recently developed hybrid swarm intelligence algorithm that has already been used in solving diverse power system optimization problems was used as the optimization tool for the study. The generation cost was minimized for different grid participation types and grid pricing strategies with and without consideration of DSM. The numerical results show a 55–75% reduction in generation cost when 20–30% DSM participation was considered. Graphical abstract Highlights i. The generation cost of an LV microgrid (MG) system was evaluated for diverse grid-dependent scenarios. ii. The impact of demand-side management on the performance of the MG system and generation costs was studied. Discussion The work described in this paper initially restructured the forecasted load demand for different DSM participation levels to reduce the peak demand and improve the load factor of the MG system. Thereafter, the generation costs were evaluated for diverse grid-dependent scenarios and compared for various load demand models obtained after DSM implementation.
需求侧管理(demand -side management, DSM)将弹性负荷和非弹性负荷分离开来,以使整个过程的运行成本最小化为目标,重构配电系统的负荷需求模型。这是通过将灵活负载最佳地转移到单位效用成本较低的小时来实现的。为了降低由电池储能(BES)、可再生能源(RES)和化石燃料发电机组成的并网模式低压微电网(LV MG)系统的运行费用,本文采用了双级优化策略。在第一级优化中,根据电力需求侧管理的参与水平对负荷模型进行重构。在此基础上,考虑重构的负荷需求模型,对分布式发电机组进行优化配置,使微电网二级发电成本最小。本文采用近年来发展起来的混合群智能算法作为优化工具进行研究,该算法已被用于解决各种电力系统优化问题。在考虑和不考虑电力需求侧管理的情况下,对不同的电网参与类型和电网定价策略进行了发电成本最小化。数值结果表明,当考虑20-30%的DSM参与时,发电成本降低了55-75%。1 .在不同电网依赖情景下,对低压微电网(MG)系统的发电成本进行了评估。2研究了需求侧管理对自动发电系统性能和发电成本的影响。本文所描述的工作初步重构了不同DSM参与水平下的预测负荷需求,以降低峰值需求,提高MG系统的负荷系数。然后,对不同电网依赖情景下的发电成本进行了评估,并对实施DSM后获得的各种负荷需求模型进行了比较。
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引用次数: 0
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