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Driving Zn-MnO_2 grid-scale batteries: A roadmap to cost-effective energy storage 驱动Zn-MnO_2电网级电池:经济高效的能源存储路线图
IF 4.3 Q2 Engineering Pub Date : 2022-03-01 DOI: 10.1557/s43581-021-00018-4
E. Spoerke, H. Passell, Gabriel Cowles, T. Lambert, Gautam G. Yadav, Jinchao Huang, Sanjoy Banerjee, B. Chalamala
Highlights Zn-MnO_2 batteries promise safe, reliable energy storage, and this roadmap outlines a combination of manufacturing strategies and technical innovations that could make this goal achievable. Approaches such as improved efficiency of manufacturing and increasing active material utilization will be important to getting costs as low as $100/kWh, but key materials innovations that facilitate the full 2-electron capacity utilization of MnO_2, the use of high energy density 3D electrodes, and the promise of a separator-free battery with greater than 2V potential offer a route to batteries at $50/kWh or less. Abstract Large-scale energy storage is certain to play a significant, enabling role in the evolution of the emerging electrical grid. Battery-based storage, while not a dominant form of storage today, has opportunity to expand its utility through safe, reliable, and cost-effective technologies. Here, secondary Zn–MnO_2 batteries are highlighted as a promising extension of ubiquitous primary alkaline batteries, offering a safe, environmentally friendly chemistry in a scalable and practical energy dense technology. Importantly, there is a very realistic pathway to also making such batteries cost-effective at price points of $50/kWh or lower. By examining manufacturing examples at the Zn–MnO_2 battery manufacturer Urban Electric Power, a roadmap has been created to realize such low-cost systems. By focusing on manufacturing optimization through reduced materials waste, scalable manufacturing, and effective materials selection, costs can be significantly reduced. Ultimately, though, coupling these approaches with emerging research and development advances to enable full capacity active materials utilization and battery voltages greater than 2V are likely needed to drive costs below a target of $50/kWh. Reaching this commercially important goal, especially with a chemistry that is safe, well-known, and reliably effective stands to inject Zn–MnO_2 batteries in the storage landscape at a critical time in energy storage development and deployment. Graphical abstract
锌- mno_2电池承诺安全、可靠的能量存储,这一路线图概述了制造战略和技术创新的结合,可以使这一目标实现。提高制造效率和增加活性材料利用率等方法对于降低成本到100美元/千瓦时很重要,但关键的材料创新,促进MnO_2的完全2电子容量利用,高能量密度3D电极的使用,以及具有大于2V电位的无分离器电池的承诺,为50美元/千瓦时或更低的电池提供了一条途径。大规模储能系统必将在新兴电网的发展中发挥重要的推动作用。基于电池的存储,虽然不是目前的主要存储形式,但有机会通过安全、可靠和经济高效的技术扩大其用途。在这里,锌- mno_2二次电池被强调为普遍存在的碱性电池的有前途的延伸,在可扩展和实用的能量密度技术中提供安全,环保的化学物质。重要的是,有一个非常现实的途径可以使这种电池在50美元/千瓦时或更低的价格点具有成本效益。通过对锌- mno_2电池制造商城市电力公司的生产实例的考察,为实现这种低成本系统制定了路线图。通过减少材料浪费、可扩展制造和有效的材料选择,专注于制造优化,可以显着降低成本。然而,最终,将这些方法与新兴的研究和开发进展相结合,以实现活性材料的全容量利用和电池电压大于2V,可能需要将成本降至50美元/千瓦时以下的目标。实现这一重要的商业目标,特别是通过一种安全、知名、可靠有效的化学方法,可以在储能开发和部署的关键时刻将锌- mno_2电池注入储能领域。图形抽象
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引用次数: 5
Design strategies and recent advances in utilisation of solar energy for pasteurisation 巴氏灭菌中太阳能利用的设计策略和最新进展
IF 4.3 Q2 Engineering Pub Date : 2022-03-01 DOI: 10.1557/s43581-021-00017-5
Fazia Taj, A. Dar, M. Dwivedi, H. Naik, Wasiya Farzana, S. Khan
Use of sustainable sources of energy is on the rise due to depletable nature of the conventional sources of energy generation. Renewable sources of energy such as wind, biomass, solar energy etc. are some of the most extensively available non-conventional source of energy. Pasteurisation refers to the phenomenon of mild thermal treatment to liquids or foods to eliminate the most resistant pathogenic bacteria. As such, the primary aim of this paper is to discuss about solar pasteurisation as an alternative to conventional pasteurisation and examine various research works on solar pasteurisation to achieve a solution for sustainable development. Various coatings’ materials and components used in the manufacturing of solar pasteurisation setup have been discussed with emphasis on increasing efficiency. Results reveal that use of PV/T support and certain design modifications leads to the reduction in the total pasteurisation time of raw milk.
由于传统能源的耗竭性质,可持续能源的使用正在增加。可再生能源,如风能、生物质能、太阳能等,是一些最广泛使用的非常规能源。巴氏杀菌是指对液体或食物进行温和的热处理,以消除最具抗性的致病菌的现象。因此,本文的主要目的是讨论太阳能巴氏杀菌作为传统巴氏杀菌的替代方案,并检查太阳能巴氏杀菌的各种研究工作,以实现可持续发展的解决方案。讨论了太阳能巴氏杀菌装置制造中使用的各种涂层材料和组件,重点是提高效率。结果表明,使用PV/T支持和某些设计修改导致原料奶的总巴氏灭菌时间的减少。
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引用次数: 0
Drivers of ethanol fuel development in Brazil: A sociotechnical review 巴西乙醇燃料发展的驱动因素:社会技术综述
IF 4.3 Q2 Engineering Pub Date : 2022-03-01 DOI: 10.1557/s43581-021-00016-6
Julio N. Campos, J. E. Viglio
The development of ethanol as a vehicle fuel in Brazil is the result of a historical trajectory shaped by the interaction of several societal and technological elements. This article addresses this relationship from the perspective of sociotechnical systems, by framing how each sociotechnical element (actors, exogenous shocks, infrastructure, knowledge, social institutions and technologies) enabled the consolidation of ethanol as a fuel alternative to gasoline in Brazil. The section dedicated to institutional change provides a historical overview emphasizing institutional arrangements aimed toward ethanol fuel specifically, as well as an updated review of formal incentive mechanisms. To discuss the expertise system, we analyze the role of private and public actors of research and development (R&D) related with ethanol fuel. We also provide a summary table of the associated sociotechnical elements for researchers interested in applying the sociotechnical transitions framework in the context of biofuels. This article suggests that the strengthening of the sociotechnical system has enabled flexible-fuel vehicles to reach over 70% of the Brazilian light vehicle fleet since their introduction in 2003, a threshold that may indicate an energy transition if changes in fleets, instead of new vehicle sales, are accounted for as an energy transition by itself. Graphical abstract
乙醇作为汽车燃料在巴西的发展是由几个社会和技术因素相互作用形成的历史轨迹的结果。本文从社会技术系统的角度阐述了这种关系,通过构建每个社会技术元素(参与者、外生冲击、基础设施、知识、社会制度和技术)如何在巴西巩固乙醇作为汽油替代品的地位。制度变革部分提供了一个历史概述,强调了针对乙醇燃料的制度安排,以及对正式激励机制的最新审查。为了讨论专家系统,我们分析了与乙醇燃料相关的研究与开发(R&D)的私人和公共行为者的作用。我们还为有兴趣在生物燃料背景下应用社会技术转型框架的研究人员提供了相关社会技术要素的汇总表。本文认为,自2003年引入以来,社会技术系统的加强已经使灵活燃料汽车达到巴西轻型汽车车队的70%以上,如果车队的变化而不是新车销售本身被视为能源转型,则这一阈值可能表明能源转型。图形抽象
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引用次数: 1
Low-cost fluorinated diatomaceous earth polyurethane foam for the absorption of oil 低成本的含氟硅藻土聚氨酯吸油泡沫
IF 4.3 Q2 Engineering Pub Date : 2022-03-01 DOI: 10.1557/s43581-022-00022-2
Helanka J. Perera, Anjali Goyal, Hussaina Banu, S. Alhassan
In the present work, we intend to focus on the synthesis, characterization, and application of a high-performing hydrophobic and oleophilic polyurethane foam functionalized with diatomaceous earth and fluorosilane, which are eco-friendly and low-cost materials for their potential use as absorbents for hydrophobic materials. The scanning electron microscopic studies and thermogravimetric analysis showed that the surface-modified polyurethane has a significant micro–nano-structure and surface functionalization, and the water contact angle measurement showed an increase in hydrophobicity due to the fluorosilane-functionalized diatomaceous earth particles anchoring onto the polyurethane foam. Also, the thermogravimetric analysis revealed an increased thermal stability due to the surface functionalization. The novel fluorosilane—diatomaceous earth—polyurethane foam exhibited a silver mirror-like effect when immersed into water due to inherent hydrophobicity and had an enhanced absorption of oil and organic solvents compared to the unmodified polyurethane. This research presents the successful synthesis of surface-modified polyurethane for its suitability for oil absorption capacity for cleaning the oil pollutants from water and for organic solvents clean-up purposes. Graphical abstract Overview of the research approach, which represents stepwise synthesis of the polyurethane (PU) foam surface modified with diatomaceous earth (DE) and fluorosilane (FS) to form low-density and high-absorbing surface-functionalized PU foam exhibiting enhanced oil absorption making this novel composite as a potential candidate for crude oil clean-up and recovery process.
在本研究中,我们将重点研究硅藻土和氟硅烷功能化的高性能疏水亲油聚氨酯泡沫的合成、表征和应用。硅藻土和氟硅烷功能化是一种环保、低成本的材料,具有作为疏水材料吸附剂的潜力。扫描电镜研究和热重分析表明,表面改性聚氨酯具有明显的微纳米结构和表面功能化,水接触角测量表明,由于氟硅烷功能化硅藻土颗粒锚定在聚氨酯泡沫上,疏水性增加。此外,热重分析显示,由于表面功能化,热稳定性增加。新型氟硅烷-硅藻土-聚氨酯泡沫由于其固有的疏水性,在浸入水中时表现出银镜般的效果,并且与未改性的聚氨酯相比,对油和有机溶剂的吸收能力增强。本研究成功合成了表面改性聚氨酯,它具有吸油能力,可以清洗水中的油类污染物,也可以清洗有机溶剂。研究方法概述:采用硅藻土(DE)和氟硅烷(FS)对聚氨酯(PU)泡沫表面进行改性,逐步合成低密度、高吸油率的表面功能化PU泡沫,具有较强的吸油性,使这种新型复合材料成为原油清理和回收工艺的潜在候选材料。
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引用次数: 3
Active learning as enabler of sustainability learning outcomes: Capturing the perceptions of learners during a materials education workshop 主动学习作为可持续性学习成果的推动者:在材料教育研讨会期间捕捉学习者的感知
IF 4.3 Q2 Engineering Pub Date : 2021-12-06 DOI: 10.1557/s43581-021-00019-3
V. Kioupi, T. Vakhitova, K. Whalen
Active learning is a promising teaching approach that can develop sustainability competences in learners. In this paper, we investigate the potential of active-learning pedagogies such as serious games and active-learning toolkits to deliver sustainability knowledge and skills in materials education. We organised a workshop for 20 participants from UK Universities where they played the serious game In the Loop around critical materials and circular economy and engaged in the Active-Learning ToolKit Sustainable Development (Granta Design/now Ansys UK Ltd.) to assess the sustainability of a proposed policy intervention around the use of electric cars. We used a self-assessment questionnaire and reflection sessions to deduce the level of sustainability skill developed by the participants as well as importance and performance analysis (IPA) to help the educators understand crucial components they should concentrate their teaching and learning efforts on in the future. Finally, we provide recommendations for educators on how to implement active learning in materials education in order to empower students with skills for sustainability.
主动学习是一种很有前途的教学方法,可以培养学习者的可持续能力。在本文中,我们研究了主动学习教学法(如严肃游戏和主动学习工具包)在材料教育中提供可持续性知识和技能的潜力。我们为来自英国大学的20名参与者组织了一次研讨会,他们围绕关键材料和循环经济玩了一场严肃的游戏,并参与了Active-Learning工具包可持续发展(Granta Design/now Ansys UK有限公司),以评估围绕电动汽车使用的拟议政策干预的可持续性。我们使用自我评估问卷和反思会来推断参与者发展的可持续性技能水平,以及重要性和绩效分析(IPA)来帮助教育工作者了解他们未来应该集中教学努力的关键组成部分。最后,我们为教育工作者提供了如何在材料教育中实施积极学习的建议,以增强学生的可持续发展技能。
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引用次数: 0
Elaboration of bio-based building materials made from recycled olive core 由回收橄榄核制成的生物基建筑材料
IF 4.3 Q2 Engineering Pub Date : 2021-09-01 DOI: 10.1557/s43581-021-00006-8
Djamila Boukhelkhal, Mohamed Guendouz, Alexandra Bourdot, Hanane Cheriet, Kaouther Messaoudi
Highlights Use of olive core wastes as sand in self-compacting mortar (SCM). The behavior of SCM with olive core waste is evaluated by the physico-mechanical and thermal properties of different mixes. The bulk density and thermal conductivity are improved by using of olive core wastes. Abstract The recycling of organic wastes in the field of civil engineering is a very important process as long as the products to be obtained are not subjected to stringent quality standards. This research is a part of the general policy of saving energy and protecting the environment. Its aim is to study the possibility of developing a new insulating building material by recycling vegetable waste from the olive processing industry (olive core) that discarded in nature. After having been sorted, dried and then extruded in the form of grains, these wastes are incorporated as fine aggregate (sand) in the manufacturing of self-compacting mortar (SCM) by substituting the mass of sand with different percentages (10, 20, 30 40 and 50%). The physico-mechanical and thermal properties of the obtained SCMs are analyzed and compared to the control. The results of this study show a decrease in density and compressive strength of SCM by increasing the content of olive core wastes. However, the thermal properties of SCM are improved through replacing sand by such wastes, which could allow using olive waste core based SCM in various types of nonstructural components with intriguing insulating properties. Graphic abstract
利用橄榄核废料作为砂在自密实砂浆(SCM)。通过不同混合料的物理力学性能和热性能来评价橄榄核废弃物的SCM性能。利用橄榄核废渣可以提高堆密度和导热系数。在土木工程领域,有机废物的回收利用是一个非常重要的过程,只要所获得的产品没有严格的质量标准。这项研究是节能环保总方针的一部分。其目的是研究通过回收自然界中丢弃的橄榄加工业(橄榄核)的蔬菜废料来开发一种新的绝缘建筑材料的可能性。这些废弃物经过分选、干燥后以颗粒的形式挤压,通过不同比例(10%、20%、30%、40%和50%)的沙子代替质量,作为细骨料(砂)掺入自密实砂浆(SCM)的制造中。分析了所获得的SCMs的物理力学和热性能,并与对照进行了比较。研究结果表明,随着橄榄核废弃物含量的增加,SCM的密度和抗压强度降低。然而,通过用这些废物代替沙子,SCM的热性能得到了改善,这可以使基于橄榄废物芯的SCM在各种具有有趣绝缘性能的非结构部件中使用。图形抽象
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引用次数: 12
Correction to: Elaboration of bio-based building materials made from recycled olive core 更正:由回收橄榄核制成的生物基建筑材料
IF 4.3 Q2 Engineering Pub Date : 2021-09-01 DOI: 10.1557/s43581-021-00010-y
Djamila Boukhelkhal, Mohamed Guendouz, Alexandra Bourdot, Hanane Cheriet, Kaouther Messaoudi
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引用次数: 0
Public trust in science: Climate, energy and public health 公众对科学的信任:气候、能源和公共卫生
IF 4.3 Q2 Engineering Pub Date : 2021-09-01 DOI: 10.1557/s43581-021-00014-8
Yue Meng
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引用次数: 2
Experimental development of a hybrid solar-gas heating system 混合太阳能-燃气加热系统的实验开发
IF 4.3 Q2 Engineering Pub Date : 2021-09-01 DOI: 10.1557/s43581-021-00007-7
M. D. Sarmouk, A. Smaili, A. Merabtine, H. Fellouah
Highlights The hybrid solar heating systems help in increasing energy savings. However, an optimal configuration along with suitable control strategies will be required to enhance the thermal performance of the system. Abstract In the present work, a hybrid solar-gas heating system is built up in Algiers, Algeria, to investigate its thermal performances and thus highlight the annual solar coverage rate. The system consists essentially of two flat plate solar collectors, a gas boiler, and a hot water storage tank. The operation of the installation is controlled by data acquisition card through LabVIEW software. For this purpose, experiment tests have been conducted for different weather conditions on which the hybrid system was operating under three different scenarios simulating working days and weekends. It has been found that temperatures of the storage tank water can reach 36, 34 and 27 °C for days with a global horizontal irradiation of 390, 400 and 533 W/m^2, respectively. These preliminary results showed that temperatures of the tank under the steady state operating modes might contribute to the reduction of energy consumption for a given space heating application. Graphic abstract
混合太阳能加热系统有助于增加能源节约。然而,优化配置以及合适的控制策略将需要提高系统的热性能。在本工作中,在阿尔及利亚阿尔及尔建立了一个混合太阳能-燃气供暖系统,以研究其热性能,从而突出年太阳能覆盖率。该系统主要由两个平板太阳能集热器、一个燃气锅炉和一个热水储存罐组成。通过LabVIEW软件控制数据采集卡的安装操作。为此,在模拟工作日和周末的三种不同情况下,对混合系统运行的不同天气条件进行了实验测试。研究发现,在全球水平辐照量分别为390、400和533 W/m^2的情况下,储罐水的温度可达36、34和27℃。这些初步结果表明,在稳态运行模式下的储罐温度可能有助于减少给定空间加热应用的能耗。图形抽象
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引用次数: 0
Solar energy and the circular economy: An introduction 太阳能与循环经济:导论
IF 4.3 Q2 Engineering Pub Date : 2021-03-01 DOI: 10.1557/s43581-021-00003-x
A. Braun, R. Toth, S. Erat
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引用次数: 1
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