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Acta Biomaterialia Silver Medal 2026 生物材料学报银牌2026
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102569
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引用次数: 0
Mary Fortune Award 2026 - Natasha Vermaak 玛丽财富奖2026 -娜塔莎维尔马克
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102571
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引用次数: 0
Design of strong and ductile Ni-rich high entropy alloy for cryogenic temperature application 低温强韧性富镍高熵合金的设计
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102618
K.R. Ramkumar , Hyojin Park , Eun Seong Kim , Kali Prasad , Sougata Roy , Qingfeng Wu , Jungwan Lee , Hyoung Seop Kim
This study explores the correlation between microstructural features and the mechanical properties of innovatively developed Ni30Co20Cr20Fe20Al6Ti2Ta2 high entropy alloy. A high density of ɣʹ-L12 nanoprecipitates was observed within the grains and along grain boundaries. The alloy achieved a yield strength (YS) of 761.05 MPa, an ultimate tensile strength (UTS) of 1062.1 MPa, and a total elongation (TE) of 55.7 % at 298 K. At 77 K, the YS increased to 991.8 MPa, the UTS to 1511.2 MPa, with an appreciable TE of 47.4 %. The properties improved significantly with the decrease in temperature from 298 K to 77 K. The alloy exhibited strong temperature dependency, progression of a planar-slip deformation mechanism at 298 K to dense dislocation array or Taylor lattice at 77 K. The interaction of dislocation arrays with ɣʹ precipitates enhanced the strain-hardening ability, delaying necking and preserving TE at cryogenic temperature. The present research lays the foundation for the development of advanced alloys with superior properties for cryogenic applications.
本研究探讨了创新研制的Ni30Co20Cr20Fe20Al6Ti2Ta2高熵合金的显微组织特征与力学性能之间的关系。在晶粒内和沿晶界观察到高密度的α α -L12纳米沉淀。该合金在298 K时的屈服强度(YS)为761.05 MPa,极限抗拉强度(UTS)为1062.1 MPa,总伸长率(TE)为55.7%。当温度为77 K时,风压为991.8 MPa,风压为1511.2 MPa, TE值为47.4%。当温度从298 K降低到77 K时,材料的性能显著改善。合金表现出强烈的温度依赖性,在298 K时由平面滑移变形机制发展到77 K时的密集位错阵列或泰勒晶格。位错阵列与析出相的相互作用增强了材料的应变硬化能力,延缓了颈缩,并在低温下保持了TE。本研究为开发具有优异低温应用性能的先进合金奠定了基础。
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引用次数: 0
Unlocking the synergy: How tip-radius and crystal orientation govern indentation in ferrous FCC alloys 解锁协同作用:尖端半径和晶体取向如何控制铁FCC合金中的压痕
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102621
Arka Mandal , Sankalp Biswal , Shiv Brat Singh, Debalay Chakrabarti
The present study investigates the synergistic effects of indenter tip-radius and crystallographic orientation on the nanoindentation response of a ferrous FCC alloy, i.e. 304 austenitic stainless steel, combining experimental nanoindentation and molecular dynamics (MD) simulations. Although considerable research attention has been paid to the individual effects of crystal orientation and tip-radius, their combined influence on the indentation response of these alloys is still not well explored. This investigation concentrates on grains having different crystallographic orientations for various indenter geometries (tip-radii), which is of primary importance to relate mechanical response with microstructural features as well as identify where such differences in micro-mechanics originate. Grain 1, i.e., (111), having poor slip plane alignment, is the stiffest, while Grain 2, i.e., (100) with favorable slip plane orientations, is found to pose the least resistance to deformation. MD simulations provide insight into the details of occurring dislocation dynamics, such as Shockley partials, Stair-rod, and Hirth dislocations, with respect to their role in accommodating strains and the load-dip phenomenon. Distinct deformation mechanisms between sharp Berkovich (by the formation of prismatic dislocation loop) and spherical (by the formation of perfect stacking fault tetrahedron) indenters emphasize the influence of tip geometry on the development of dislocation substructure. This study bridges the gap between the fundamental mechanics of deformation and the application-oriented design of materials for developing these alloys with enhanced strength, reliability, and resistance to complex modes of loading.
结合实验纳米压痕和分子动力学模拟,研究了压痕尖端半径和晶体取向对304奥氏体不锈钢的纳米压痕响应的协同效应。虽然晶体取向和尖端半径的单独影响已经引起了相当多的研究,但它们对这些合金的压痕响应的综合影响尚未得到很好的探讨。本研究集中在不同压头几何形状(尖端半径)具有不同晶体取向的晶粒上,这对于将力学响应与微观结构特征联系起来以及确定微观力学差异的来源至关重要。滑移面取向较差的晶粒1(111)是最硬的,而滑移面取向良好的晶粒2(100)对变形的阻力最小。MD模拟提供了对发生的位错动力学细节的深入了解,例如肖克利偏位、阶梯位错和Hirth位错,以及它们在适应应变和负载倾斜现象中的作用。尖锐的Berkovich压头(通过形成棱柱形位错环)和球形压头(通过形成完美的层错四面体)之间不同的变形机制强调了尖端几何形状对位错子结构发展的影响。这项研究弥合了变形的基本力学和面向材料的应用设计之间的差距,以开发这些具有增强强度,可靠性和抵抗复杂加载模式的合金。
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引用次数: 0
Investigating the effect of phosphorus on L10 ordering in melt-solidified Fe-Ni alloys 研究了磷对熔体凝固铁镍合金L10有序度的影响
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102617
Samantha R. Maness , Samuel M. Pennell , David C. Dunand
Recently, bulk synthesis of the hard-magnetic, chemically-ordered FeNi L10-tetrataenite phase has been reported in phosphorus-containing Fe-Ni alloys processed via conventional melt solidification. Low-temperature ordering was hypothesized to occur in these alloys due to the presence of phosphorus accelerating vacancy-based diffusion in the Fe-Ni solid solution. Here, we investigated two Fe-Ni-P alloys previously reported to form high volume fractions of L10-tetrataenite following melt solidification as well as two new alloys representing stoichiometric variations. Additionally, a phosphorus-free Fe-33.3Ni alloy was produced via low-temperature, solid-state hydrogen reduction of NiFe2O4 powders, an alternative approach previously reported for forming L10-tetrataenite, which was used as a control to compare the efficacy of the melt-solidification approach. Vibrating-sample magnetometry was used to investigate all alloys’ magnetic characteristics, with further compositional and phase analysis performed for melt-solidified alloys via scanning-electron microscopy, energy-dispersive X-ray spectroscopy, electron backscattered diffraction, and X-ray diffraction. While the Fe-33.3Ni control alloy demonstrates evident magnetic hysteresis, no hysteresis is observed for any melt-solidified alloy; furthermore, no tetragonal phase character is detected for these alloys. Thus, though these melt-solidified alloys exhibit good Fe-Ni compositional homogeneity, none are found to possess the hard-magnetic properties or chemical ordering indicative of L10-tetrataenite. These findings indicate that melt solidification is not a suitable method for the production of bulk quantities of hard-magnetic L10-tetrataenite, contrasting prior literature.
最近,在常规熔体凝固法制备的含磷铁镍合金中,大量合成了硬磁性、化学有序的FeNi l10 -四ataenite相。假设在这些合金中发生低温有序是由于在Fe-Ni固溶体中存在磷加速空位基扩散。在这里,我们研究了先前报道的两种Fe-Ni-P合金在熔体凝固后形成高体积分数的l10 -四轴体,以及两种代表化学计量变化的新合金。此外,通过低温固态氢还原NiFe2O4粉末制备了无磷Fe-33.3Ni合金,这是先前报道的形成l10 -四ataenite的另一种方法,并将其作为对照来比较熔融凝固方法的效果。采用振动样品磁强计研究了所有合金的磁性特征,并通过扫描电子显微镜、能量色散x射线能谱、电子背散射衍射和x射线衍射对熔融凝固合金进行了进一步的成分和物相分析。Fe-33.3Ni对照合金表现出明显的磁滞现象,而熔体凝固合金无磁滞现象;此外,没有检测到这些合金的四方相特征。因此,尽管这些熔融凝固合金表现出良好的Fe-Ni成分均匀性,但没有一种合金具有l10 -四ataenite的硬磁性能或化学有序性。这些发现表明,与先前的文献相比,熔体凝固不是生产大量硬磁性l10 -四长石的合适方法。
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引用次数: 0
Acta Biomaterialia Gold Medal 2026 生物材料学报金牌2026
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102567
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引用次数: 0
Nanoscale grain formation at crack initiation region under very-high-cycle fatigue for Ti-6Al-4 V manufactured by selective laser melting 选择性激光熔化制备ti - 6al - 4v高周疲劳裂纹萌生区纳米级晶粒的形成
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102619
Hang Su , Yanfeng Li , Xiangnan Pan , Punit Kumar , Xu Long
The very-high-cycle fatigue (VHCF) behavior of Ti-6Al-4 V alloy produced by selective laser melting (SLM) was systematically investigated, with particular emphasis on the microstructural features at crack initiation sites. Fatigue cracks predominantly originated from internal pores, accompanied by the formation of a fine granular area (FGA) and characteristic fisheye (FiE) morphologies. For the first time in the selectively laser melted (SLMed) Ti-6Al-4 V, a nanocrystalline layer at the immediate crack surface within the FGA was characterized in detail, providing direct experimental evidence in support of the numerous cyclic pressing (NCP) model for crack initiation and early-stage propagation. The interrelation among pore size, applied stress amplitude, and the degree of microstructural refinement within the FGA was clarified. These findings offer new insights into the fatigue behavior of additively manufactured (AM) alloys and underscore the critical influence of process-induced defects and post-processing treatments on VHCF performance.
系统地研究了选择性激光熔化ti - 6al - 4v合金的高周疲劳行为,重点研究了裂纹起裂部位的显微组织特征。疲劳裂纹主要产生于内部孔隙,并伴有细小颗粒区(FGA)和典型的鱼眼(FiE)形貌的形成。在选择性激光熔化(SLMed) ti - 6al - 4v中,首次对FGA内直接裂纹表面的纳米晶层进行了详细表征,为裂纹萌生和早期扩展的多次循环挤压(NCP)模型提供了直接的实验证据。阐明了FGA内孔径、外加应力幅值与微观组织细化程度之间的相互关系。这些发现为增材制造(AM)合金的疲劳行为提供了新的见解,并强调了工艺诱导缺陷和后处理对VHCF性能的关键影响。
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引用次数: 0
Erratum to “On the nature of variant selection along build direction in additively manufactured Ti-6Al-4V walls” [Materialia 42 (2025) 102500] “关于增材制造Ti-6Al-4V壁沿构建方向的变异选择的性质”的勘误[材料42 (2025)102500]
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102522
Vikrant Saumitra , Avinash Gonnabattula , V. Anil Kumar , Anand K Kanjarla
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引用次数: 0
Designing robust Y2O3 based multilayer coatings for mitigating fuel-cladding chemical interactions in fast nuclear reactors: Materials and engineering insights 设计坚固的基于Y2O3的多层涂层,以减轻快核反应堆中燃料包层的化学相互作用:材料和工程见解
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102609
Sumit Bhattacharya, Abdellatif M. Yacout
Pure Y2O3 barriers have long been favored to prevent molten uranium interaction with crucibles during fuel fabrication, the question remains about feasibility of Y2O3 as a robust and resilient barrier against fuel and fission product attack in an in-reactor nuclear environment? This work explores that very question, detailing both the advantages and limitations of standalone Y2O3, as well as potential mitigation through a multilayer approach under simulated extreme reactor conditions. We present an innovative multilayer thin-film metal–ceramic coating (Y2O3/CrY), engineered to provide robust FCCI mitigation. The coating architecture evolved through systematic mechanical testing, radiation tolerance assessments, and high-temperature diffusion studies from a preliminary multilayer concept to an optimized high-performance design. The optimized structure leverages stoichiometric Y2O3 for its radiation stability, chemical inertness, and ultra-low fission product diffusivity. This is paired with ductile chromium-rich interlayers (Cr₉₅Y₅), which significantly enhance fracture toughness and mechanical resilience. Design refinements, including increased ceramic layer thickness and optimized Cr–Y interlayer composition, eliminated fracture propagation and preserved coating integrity under extreme mechanical stress (>10 × typical reactor conditions) and prolonged radiation exposure (∼300 dpa). These studies provide a foundation for addressing the feasibility of Y₂O₃ as an FCCI barrier. Based on our preliminary findings, dense, stoichiometric Y₂O₃, when integrated within a metal–ceramic multilayer architecture, appears to be capable of resisting fission-product diffusion at elevated temperatures and high doses of irradiation. Meanwhile, extensive testing, including integral in-reactor irradiation, are expected in the future to confirm the barrier’s performance under prototypic conditions as a potential solution against FCCI.
在燃料制造过程中,纯Y2O3屏障一直被用于防止熔融铀与坩埚的相互作用,但在反应堆核环境中,Y2O3作为一种坚固而有弹性的屏障来抵御燃料和裂变产物攻击的可行性仍然是一个问题。这项工作探讨了这个问题,详细介绍了独立Y2O3的优点和局限性,以及在模拟极端反应堆条件下通过多层方法的潜在缓解。我们提出了一种创新的多层薄膜金属陶瓷涂层(Y2O3/CrY),旨在提供强大的FCCI缓解。涂层结构经过系统的机械测试、辐射耐受性评估和高温扩散研究,从初步的多层概念发展到优化的高性能设计。优化后的结构利用了化学计量学Y2O3的辐射稳定性、化学惰性和超低的裂变产物扩散系数。这与延展性富铬夹层(Cr₉₅Y₅)相匹配,可显着提高断裂韧性和机械弹性。设计改进,包括增加陶瓷层厚度和优化Cr-Y层间成分,在极端机械应力(>;10倍典型反应堆条件)和长时间辐射暴露(~ 300 dpa)下消除了断裂扩展并保持了涂层的完整性。这些研究为解决Y₂O₃作为FCCI屏障的可行性提供了基础。根据我们的初步发现,致密的、化学计量的Y₂O₃,当集成在金属-陶瓷多层结构中时,似乎能够抵抗高温和高剂量辐射下的裂变产物扩散。同时,未来将进行广泛的测试,包括反应堆内整体辐照,以确认该屏障在原型条件下的性能,作为对抗FCCI的潜在解决方案。
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引用次数: 0
Coupled in situ monitoring and nonlinear thermomechanical modeling of stress evolution in glass-to-metal seals 玻璃-金属密封应力演化的耦合原位监测和非线性热力学建模
IF 2.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.mtla.2025.102615
Zifeng Song , Keqian Gong , Zhangjing Shi , Zheng Liu , Chao Zhou , Siyue Nie , Yanfei Sun , Cheng Ren , Yong Zhang
Understanding the dynamic development of residual stress in glass-to-metal (GTM) seals is essential for ensuring long-term performance in harsh environments. In this study, a combined experimental and numerical approach was adopted to investigate the transient thermomechanical behavior during the sealing process. Real-time temperature and strain data were acquired using embedded thermocouples and fibre Bragg grating (FBG) sensors, while a temperature-dependent transient finite element analysis (FEA) model was developed to simulate the spatiotemporal evolution of thermal and mechanical fields. The analysis reveals that the nonuniform heat conduction gives rise to a strongly heterogeneous temperature distribution within the sealing glass, which is called the "soft-boiled egg" temperature distribution. This nonuniformity, together with mismatch in thermal expansion between the glass and metal, generates complex stress profiles. The residual stress was found to be closely linked to the integrated difference in coefficients of thermal expansion of sealing materials over the temperature range, with peak values localized at the glass-metal interface. Additionally, axial tensile stress emerges in the core region due to Poisson effect deformation. The validated simulation results not only reproduce the measured stress trends but also uncover stress rebound phenomena below 200 °C. The coupling research method of experiment and modeling provides a new idea for studying the stress evolution of cylindrical sealing. These insights enhance the predictive ability of GTM stress hotspots and offer valuable design implications for applications involving thermal cycling and pressure loading.
了解玻璃-金属(GTM)密封件残余应力的动态发展对于确保恶劣环境下的长期性能至关重要。本文采用实验与数值相结合的方法对密封过程中的瞬态热力学行为进行了研究。利用嵌入式热电偶和光纤布拉格光栅(FBG)传感器获取实时温度和应变数据,同时建立了温度相关的瞬态有限元分析(FEA)模型来模拟热场和力学场的时空演变。分析表明,非均匀热传导导致密封玻璃内部温度分布极不均匀,称为“半熟蛋”温度分布。这种不均匀性,加上玻璃和金属之间热膨胀的不匹配,产生了复杂的应力分布。残余应力与密封材料热膨胀系数在温度范围内的积分差密切相关,峰值集中在玻璃-金属界面处。此外,由于泊松效应变形,在核心区出现轴向拉应力。经过验证的模拟结果不仅再现了实测应力趋势,而且揭示了200℃以下的应力反弹现象。实验与建模耦合的研究方法为研究圆柱密封的应力演化提供了新的思路。这些见解增强了GTM应力热点的预测能力,并为涉及热循环和压力加载的应用提供了有价值的设计指导。
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