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Effect of sulfur impurity on the nucleation of α-Cr precipitates in nickel-based alloys 硫杂质对镍基合金中 α-Cr 沉淀成核的影响
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-04 DOI: 10.1016/j.mtla.2024.102220
Yusuke Kohigashi , Takafumi Amino , Tomoaki Hamaguchi , Daichi Akahoshi , Koji Moriguchi , Hiroyuki Semba , Kazuma Ito

Sulfur is considered an unfavorable element in metallic materials because of its potential to cause embrittlement, thereby prompting its removal. However, trace amounts of S impurities can influence the precipitation of the primary α-Cr strengthening phase in the heat-resistant 50Ni–30Cr–0.8Ti–6W–Fe alloy, and thus affect its creep strength. In this study, fine Ti2S particles were observed in heat-treated 50Ni–30Cr–0.8Ti–6W–Fe alloys through high-sensitivity, high-resolution, and wide-field element analysis using aberration-corrected scanning transmission electron microscopy. The Ti2S particles were distributed linearly with the adjacent α-Cr precipitates. The Ti2S precipitates functioned as nucleation sites for α-Cr, thereby refining and increasing the hardness of the alloy. The findings of this work challenge conventional approaches to material design and emphasize the significance of design based on fundamental principles.

硫被认为是金属材料中的不利元素,因为它可能导致脆化,从而促使将其去除。然而,微量的 S 杂质会影响耐热 50Ni-30Cr-0.8Ti-6W-Fe 合金中初级 α-Cr 强化相的析出,从而影响其蠕变强度。本研究利用像差校正扫描透射电子显微镜,通过高灵敏度、高分辨率和宽视场元素分析,在热处理 50Ni-30Cr-0.8Ti-6W-Fe 合金中观察到细小的 Ti2S 颗粒。Ti2S 颗粒与相邻的 α-Cr 沉淀呈线性分布。Ti2S 沉淀是 α-Cr 的成核点,从而细化并提高了合金的硬度。这项工作的发现对材料设计的传统方法提出了挑战,并强调了基于基本原理进行设计的重要性。
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引用次数: 0
Effect of cryogenic milling on the mechanical and corrosion properties of ODS Hastelloy-N 低温研磨对 ODS 哈斯特洛伊-N 的机械和腐蚀特性的影响
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.mtla.2024.102215
Minsung Hong , Jeffrey E. Bickel , Ertugrul Demir , D. Kaoumi , Peter Hosemann

This study entails the fabrication of two oxide-dispersion strengthened (ODS) Hastelloy-N (HN) alloys utilizing divergent methods. The first alloy was synthesized using cryogenic attritor milling coupled with spark plasma sintering (SPS), while the second was produced via room temperature attritor milling and SPS. The ODS HN alloy derived from cryogenic milling demonstrated superior strength relative to its commercial-grade counterpart. Conversely, the alloy produced through room temperature milling exhibited lower ultimate tensile strength (UTS), attributed to manufacturing defects and the precipitation of Zr at grain boundaries. Corrosion resistance in molten FLiNaK for both ODS samples was found to be inferior compared to commercial HN. Particularly, in the room temperature-milled ODS HN, Zr present at grain boundaries appeared to dissolve more readily than in cryogenic or commercial samples, facilitating enhanced penetration by molten salt. The cryogenically-milled ODS HN contained Zr, yet it was not segregated to grain boundaries. Although the homogeneously dispersed Mo-based compound in the cryogenically-milled ODS HN augmented mechanical properties, it also accelerated corrosion propagation beyond that of the commercial-grade alloy.

本研究采用不同的方法制造了两种氧化物弥散强化(ODS)哈氏-N(HN)合金。第一种合金是通过低温磨料研磨和火花等离子烧结(SPS)合成的,而第二种合金则是通过室温磨料研磨和 SPS 制成的。通过低温研磨制得的 ODS HN 合金的强度优于商用级合金。相反,通过室温研磨生产的合金显示出较低的极限拉伸强度(UTS),这归因于制造缺陷和晶界处的锆析出。与商用 HN 相比,两种 ODS 样品在熔融 FLiNaK 中的耐腐蚀性都较差。特别是在室温研磨的 ODS HN 中,晶界上的 Zr 似乎比低温或商用样品更容易溶解,从而促进了熔盐的渗透。低温研磨的 ODS HN 中含有锆,但它并没有在晶界上分离。虽然低温研磨 ODS HN 中均匀分散的 Mo 基化合物提高了机械性能,但它也加速了腐蚀的扩展,超过了商用级合金。
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引用次数: 0
Kinetics-controlled reaction pathway and microstructure development of Ti3SiC2-TiC composite processed through reactive spark plasma sintering 通过反应火花等离子烧结工艺加工的 Ti3SiC2-TiC 复合材料的动力学控制反应路径和微观结构发展
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.mtla.2024.102213
Nisha Verma , Sandip Bysakh , Soupitak Pal

Reactive spark plasma sintering of ternary Ti-Si-C system was performed using three different powder precursors systems 3Ti/Si/2C, 3Ti/SiC/C and 2Ti/TiC/Si, to explore the fundamental physics behind Ti3SiC2 MAX phase formation, its stability and microstructure development, and, finally linked with its hardening and contact induced damage tolerance. Phase evolution in Ti-Si-C system is a complex phenomenon, and, present experimental conditions never yield a phase pure Ti3SiC2 MAX phase, rather results in varying volume fractions of Ti3SiC2-(Tix,Si1-x)C solid solution due to non-equilibrium processing conditions exerted by SPS processing which restricts coherent site specific diffusional jumps and promotes the formation of (Ti, Si)C solid-solution instead of well reported non-stoichiometric TiCx. 3Ti/SiC/C precursor was the best candidate for processing composite with highest yields of Ti3SiC2. Phase evolution is guided by the free energy of formation of different phases and chemical affinity amongst the constituent elements rather than the equilibrium phase diagram of the Ti-Si-C system. Presence of free carbon, low temperature liquid phase and slow heating rate are the key requirements for forming phase pure Ti3SiC2, where excess free carbon reduces the stability of Ti3SiC2 via decarburization. Non-equilibrium processing conditions impart nano-precipitation of coherent hexagonal Ti3SiC2 precipitates within a cubic (Ti, Si)C matrix with a distinct orientation relation of (220)matrix ║(0004)precipitate and <114>matrix ║<2–1–10>precipitate that has never been reported, instead of growing highest density plane of hcp-on-fcc matrix. Coherency strain and fine interlocking microstructure of the as-processed composite experiences ≈36 % of enhancement in hardness followed by an improved contact damage for the as-processed composite.

使用三种不同的粉末前驱体系统 3Ti/Si/2C、3Ti/SiC/C 和 2Ti/TiC/Si,对三元 Ti-Si-C 系统进行了反应火花等离子烧结,以探索 Ti3SiC2 MAX 相形成、其稳定性和微观结构发展背后的基本物理学原理,并最终将其与硬化和接触诱导损伤耐受性联系起来。Ti-Si-C 体系中的相演化是一种复杂的现象,目前的实验条件从未产生纯相 Ti3SiC2 MAX 相,相反,由于 SPS 加工所施加的非平衡加工条件限制了相干的特定位点扩散跃迁,促进了(Ti、Si)C 固溶体的形成,而不是已报道的非化学计量 TiCx,从而导致了不同体积分数的 Ti3SiC2-(Tix、Si1-x)C 固溶体。3Ti/SiC/C 前驱体是加工 Ti3SiC2 产率最高的复合材料的最佳候选材料。相演化是由不同相形成的自由能和组成元素之间的化学亲和力引导的,而不是由 Ti-Si-C 系统的平衡相图引导的。游离碳的存在、低温液相和缓慢的加热速度是形成纯相 Ti3SiC2 的关键条件,而过量的游离碳会通过脱碳作用降低 Ti3SiC2 的稳定性。在非平衡加工条件下,立方(Ti、Si)C 基体中会产生纳米沉淀物,即相干的六方 Ti3SiC2 沉淀物,这种沉淀物与 (220)matrix ║(0004)precipitate 和 <114>matrix║<2-1-10>沉淀物之间的取向关系是从未报道过的,而不是在 hcp-on-fcc 基体的最高密度面上生长。加工后复合材料的相干应变和细微交错微观结构使其硬度提高了≈36%,加工后复合材料的接触损伤也得到了改善。
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引用次数: 0
Effect of TiN coating on suppressing Ce-Fe interaction under irradiation TiN 涂层对抑制辐照下 Ce-Fe 相互作用的影响
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.mtla.2024.102221
Jian Gan , Chao Jiang , Yizhi Zhang , Yifan Zhang , Jiawei Song , Ke Xu , Benson Kunhung Tsai , Xuanyu Sheng , Haiyan Wang , Yinbin Miao , Peter Mouche , Kun Mo , Bei Ye

Advanced cladding is critical for fast reactors with the adequate thermal conductivity, mechanical stability and radiation tolerance of the cladding base material, corrosion resistance and high temperature coolant compatibility of the cladding surface, and chemical stability of the cladding inner wall against fuel cladding chemical interaction (FCCI). The preliminary results of recent ion irradiation studies of two diffusion-couple samples of cerium (Ce)/oxide-dispersion strengthened steel (ODS) and Ce/TiN/ODS, irradiated with 80 MeV xenon (Xe) ions to 100 displacements per atom (dpa) at 500°C, are summarized. Significant Ce-Fe interaction occurred in the Ce/ODS sample, and no noticeable Ce-Fe interaction was found in the Ce/TiN/ODS sample. It shows the effectiveness of 1-µm TiN diffusion barrier coated by the pulsed laser deposition on suppressing Ce-Fe interaction, a major contributor to FCCI in cladding. Density function theory (DFT) calculations of the impurity diffusivities of Ce and Fe within the Ti sublattice of TiN were performed to assist a mechanistic understanding of the experimental results.

先进的堆芯对于快堆至关重要,它需要堆芯基体材料具有足够的导热性、机械稳定性和耐辐射性,堆芯表面具有耐腐蚀性和高温冷却剂兼容性,堆芯内壁具有抗燃料堆芯化学作用(FCCI)的化学稳定性。本文总结了最近对铈(Ce)/氧化物弥散强化钢(ODS)和Ce/TiN/ODS 两种扩散耦合样品进行离子辐照研究的初步结果,这些样品在 500°C 下被 80 MeV 氙(Xe)离子辐照到每原子 100 位移(dpa)。在 Ce/ODS 样品中发生了显著的 Ce-Fe 相互作用,而在 Ce/TiN/ODS 样品中没有发现明显的 Ce-Fe 相互作用。这表明脉冲激光沉积所镀上的 1 微米 TiN 扩散屏障能有效抑制 Ce-Fe 相互作用,而 Ce-Fe 相互作用是造成包层中 FCCI 的主要因素。对 TiN 的 Ti 亚晶格内 Ce 和 Fe 的杂质扩散率进行了密度函数理论 (DFT) 计算,以帮助从机理上理解实验结果。
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引用次数: 0
Grain refinement of Fe4N compound layer in nitrided steel 氮化钢中 Fe4N 化合物层的晶粒细化
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.mtla.2024.102217
Norimitsu Koga , Atsushi Yamashita , Ryusei Kato , Ryosuke Kanebu , Kenta Miyake , Yohei Hashimoto

This study elucidated the microstructure of the Fe4N (γ’) compound layer in specimens subjected to the nitriding to the specimens with various finished surfaces. Gyrofinishing produces a specimen surface with an ultra-fine-grained (UFGed) structure and a rough surface, whereas the buff-finished specimen exhibited a coarse grain but smooth surface. The γ’ grains formed on the gyrofinished specimens after nitriding were considerably finer and more equiaxial compared with those on the buff-finished specimen. The γ’ nucleated from the grain boundary in the matrix, indicating that the grain boundaries act as a nucleation site. Therefore, the UFGed structure promotes the nucleation of γ’ during the nitriding, resulting in fine grains. Numerous pores were formed in the γ’ layer of the gyrofinished specimen owing to the rough surface. The UFGed structure and surface roughness before nitriding are key factors for controlling the microstructure in the γ’ compound layer.

本研究阐明了氮化试样中 Fe4N (γ') 化合物层的微观结构,以及试样的各种加工表面。陀螺抛光产生的试样表面具有超细晶粒(UFGed)结构和粗糙的表面,而抛光试样则表现出粗晶粒但光滑的表面。氮化处理后,回火处理试样上形成的γ'晶粒比抛光处理试样上的γ'晶粒要细得多,而且更加等轴。γ'晶粒从基体中的晶界成核,表明晶界是成核部位。因此,UFGed 结构在氮化过程中促进了 γ' 的成核,从而产生了细小的晶粒。由于表面粗糙,回火试样的γ'层中形成了许多气孔。氮化前的 UFGed 结构和表面粗糙度是控制 γ'复合层微观结构的关键因素。
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引用次数: 0
Editors for Materialia 材料学》编辑
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/S2589-1529(24)00220-5
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引用次数: 0
High strain-rate strength response of single crystal tantalum through in-situ hole closure imaging experiments 通过原位孔闭合成像实验获得单晶钽的高应变速率强度响应
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.mtla.2024.102219
J. Lind, R.A. Carson, N. Bertin, M. Nelms

The properties of crystalline materials often depend on directionality and operating conditions. Specifically, the strength of materials can depend anisotropically on crystal direction and the loading condition. To probe these effects, a preliminary series of high strain-rate (>105/s) strength plate-impact hole closure experiments were performed on high purity single crystal tantalum cubes. The orientation of the single crystals with respect to impact/loading were varied to provide data to inform crystal plasticity modeling efforts. The experiments consist of in-situ high-resolution X-ray radiographic imaging of the hole collapse under dynamic compression conditions to infer the material strength via its resistance to closure at increasing levels of plastic strain. The experiments are compared against hydrocode simulation predictions. A comparison with simple elastic perfectly plastic strength model predictions is presented to elucidate the response of the different crystal orientations at high strain-rate and large plastic strains.

晶体材料的特性通常取决于方向性和操作条件。具体地说,材料的强度会随晶体方向和加载条件而各向异性。为了探究这些影响,我们在高纯度单晶钽立方体上进行了一系列初步的高应变速率(105/s)强度平板冲击孔闭合实验。单晶体相对于冲击/加载的取向发生了变化,以便为晶体塑性建模工作提供数据。实验包括在动态压缩条件下对孔洞塌陷进行原位高分辨率 X 射线射线成像,以推断材料在塑性应变不断增加时的抗闭合强度。实验结果与水文编码模拟预测结果进行了比较。与简单弹性完全塑性强度模型预测进行比较,以阐明不同晶体取向在高应变速率和大塑性应变下的反应。
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引用次数: 0
Effect of gadolinia–stabilized zirconia nanoparticles manufactured from Mist CVD on the mechanical properties of ceramics sintered by SPS 雾状 CVD 制造的钆稳定氧化锆纳米粒子对 SPS 烧结陶瓷机械性能的影响
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-24 DOI: 10.1016/j.mtla.2024.102216
Rong Tu , Xiangyu Chen , Yingqiu Zheng , Chao Song , Xiaoping Guo , Meijun Yang , Guoqiang Luo , Song Zhang , Takashi Goto

Zirconia is an engineering ceramic material with excellent comprehensive properties. However, it suffers from the inherent disadvantage of low fracture toughness. To improve its fracture toughness, Gd2O3 is an effective stabilizer. In the present study, Gd2O3–ZrO2 composite powders were synthesized using the Mist CVD method. Following synthesis, these powders were pressed through spark plasma sintering. The crystallinity of the Gd2O3–ZrO2 powders improved as the deposition temperature increased from 600°C to 900°C. The tetragonality (c/2a) of the Gd–TZP composites increased from 0.99941 to 1.01571 as the Gd2O3 content increased from 2 mol% to 4 mol%, but it decreased when the content reached 5 mol%. The Gd2O3–ZrO2 nanoparticles produced via the Mist CVD approach presented a unique hollow spherical structure. Under moist chemical vapor deposition (CVD) conditions with 4 mol% Gd2O3 at 1400°C, the Gd–TZP composites exhibited fracture toughness and hardness values of approximately 12.03 ± 0.15 MPa·m1/2 and 12.16 ± 0.17 GPa, respectively.

氧化锆是一种工程陶瓷材料,具有优异的综合性能。然而,它也存在断裂韧性低的固有缺点。为了提高其断裂韧性,Gd2O3 是一种有效的稳定剂。本研究采用喷雾 CVD 法合成了 Gd2O3-ZrO2 复合粉末。合成后,这些粉末通过火花等离子烧结进行压制。随着沉积温度从 600°C 升至 900°C,Gd2O3-ZrO2 粉末的结晶度有所提高。随着 Gd2O3 含量从 2 摩尔%增加到 4 摩尔%,Gd-TZP 复合材料的四方性(c/2a)从 0.99941 增加到 1.01571,但当含量达到 5 摩尔%时,四方性有所下降。通过雾化化学气相沉积法制备的 Gd2O3-ZrO2 纳米粒子呈现出独特的中空球形结构。在湿化学气相沉积(CVD)条件下,Gd2O3 的含量为 4 mol%,温度为 1400°C,Gd-TZP 复合材料的断裂韧性和硬度值分别约为 12.03 ± 0.15 MPa-m1/2 和 12.16 ± 0.17 GPa。
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引用次数: 0
Effect of hyaluronic acid-based viscosupplementation on cartilage material properties 基于透明质酸的粘度补充剂对软骨材料特性的影响
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-23 DOI: 10.1016/j.mtla.2024.102218
Emilie Patois , Marie Gaumet , Isabelle Badoud , Ivo Dellavia , Patrick Ammann

Viscosupplementation by intra-articular injections of hyaluronic acid (HA) is used to treat symptomatic osteoarthritis. Exogenous HA remains in the joint cavity for a short period of time (days) while claimed pain relief period lasts over months. There is a clear lack of understanding of viscosupplementation mechanism of action. Here, we hypothesize that HA penetrates the cartilage and contributes to the restoration of its mechanical quality.

Confocal microscopy and bio-indentation were used to confirm HA penetration into cartilage and modulation of cartilage quality. Bio-indentation was performed on rat distal femurs incubated overnight in HA solutions, using phosphate buffered saline (PBS) as control. For this proof-of-concept evaluation, measurements of elastic modulus (MPa) and of maximal force (µN) were recorded before and immediately after exposure with HA, as well as after an additional washout with PBS. Cartilage thickness at the site of indentation was evaluated by contrast enhanced computed tomography with an ionic contrast agent. Indentation depths were located in the upper part of hyaline cartilage. Ostenil®, commercial product containing 1 % HA, induced a decrease in indentation depth in the range of forces influencing the whole cartilage thickness, together with an increase of the elastic modulus. Then, bio-indentation and size distribution of HA chains via SEC-SLS were assessed for a range of commercially available products. The results showed higher modulation of cartilage quality in the presence of 0.25–1 MDa HA chains.

The present in vitro study suggests that HA modulates cartilage quality and might thus explain the long-term beneficial effect of viscosupplementation.

通过关节内注射透明质酸(HA)来补充粘液,可用于治疗症状性骨关节炎。外源性透明质酸在关节腔内停留的时间很短(数天),而声称的疼痛缓解期却长达数月。人们对粘度补充剂的作用机制显然缺乏了解。在此,我们假设 HA 可渗透软骨,并有助于恢复软骨的机械质量。共聚焦显微镜和生物压痕法用于确认 HA 对软骨的渗透和对软骨质量的调节。以磷酸盐缓冲盐水(PBS)为对照,对在 HA 溶液中培养过夜的大鼠股骨远端进行生物压痕测试。在这一概念验证评估中,分别记录了暴露于 HA 溶液之前和之后的弹性模量(兆帕)和最大力(微牛)的测量值,以及用磷酸盐缓冲盐水(PBS)冲洗后的测量值。通过使用离子造影剂的对比增强计算机断层扫描评估了压痕部位的软骨厚度。压痕深度位于透明软骨的上部。含有 1% HA 的商业产品 Ostenil® 能在影响整个软骨厚度的作用力范围内降低压痕深度,同时提高弹性模量。然后,通过 SEC-SLS 对一系列市售产品的生物压痕和 HA 链的尺寸分布进行了评估。结果显示,0.25-1 MDa 的 HA 链对软骨质量的调节作用更大。本体外研究表明,HA 可调节软骨质量,从而解释了粘度补充剂的长期有益效果。
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引用次数: 0
Superlubricity in solid lubricated sliding and rolling contacts 固体润滑滑动和滚动接触的超润滑性
IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-18 DOI: 10.1016/j.mtla.2024.102212
Ali Zayaan Macknojia , Mohammad Eskandari , Khalil Omotosho , Maria Cinta Lorenzo Martin , Aditya Ayyagari , Diana Berman

Superlubricity, or near zero friction is a highly desired lubrication state for a wide range of practical applications. Although such application scenarios often involve complex contact geometries, solid lubricant technologies, including previous efforts on achieving superlubricity, are almost entirely in linear sliding test conditions. This report demonstrates an experimental pathway to yield superlubricity in rolling-sliding contact conditions using solid-lubricant materials. Ti3C2X based solid lubricant was tested under complex sliding-rolling conditions at engineering-significant contact pressures. The material's compression and inter-layer shearing result in material reconstruction to pose superlubricity. High-resolution transmission electron microscopy analysis, complemented by multi-scan Raman spectroscopy showed the formation of a robust amorphous tribolayer. This demonstration is expected to not only advance the applied aspects in the development of oil-free solid lubricants but also push the boundaries of fundamental understanding of materials’ structure-property relations across physical states.

超润滑或接近零摩擦是各种实际应用中非常理想的润滑状态。虽然此类应用场景通常涉及复杂的接触几何形状,但固体润滑剂技术,包括之前为实现超润滑所做的努力,几乎都是在线性滑动测试条件下实现的。本报告展示了利用固体润滑剂材料在滚动滑动接触条件下获得超润滑性的实验途径。以 Ti3C2X 为基础的固体润滑剂在复杂的滑动-滚动条件下进行了测试,接触压力达到了工程上的显著水平。材料的压缩和层间剪切导致材料重构,从而形成超润滑性。高分辨率透射电子显微镜分析和多扫描拉曼光谱分析表明,形成了坚固的无定形摩擦层。这一成果不仅有望推动无油固体润滑剂的应用发展,还将推动对材料跨物理状态的结构-性能关系的基本认识。
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引用次数: 0
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