Green hydrogen is increasingly recognized as a critical energy carrier for global decarbonization. Sub-Saharan Africa possesses abundant biomass resources that could support decentralized hydrogen systems; however, spatially explicit assessments remain limited. This study conducts a geospatial evaluation of forestry residues, crop wastes, and livestock manure across Kenya's 47 counties. Biomass availability was estimated using land cover and productivity datasets. Three biomass-to‑hydrogen pathways—gasification, pyrolysis, and fermentation—were compared using a decision matrix based on yield, efficiency, feedstock compatibility, cost, and technology readiness. Gasification emerged as the most suitable option for Kenya, achieving ~60 kg H₂ per tonne of biomass and 60–70 % conversion efficiency, and was therefore selected for detailed modeling. Hydrogen yields were estimated through a stoichiometric gasification model, while Sankey flow diagrams were used to trace mass and energy balances. Scenario analysis considered both technical maximum and realistic utilization potentials. Croplands and forest residues were identified as higher-quality feedstocks than shrublands. Under technical maximum conditions, hydrogen production potential reaches ~400,000 t per year. A moderate 20 % utilization scenario projects ~70,000 t annually by 2035. Environmental co-benefits include up to 0.9 MtCO₂e in emission offsets via biochar application and fossil fuel substitution. Overall, Kenya's biomass resources can sustain decentralized hydrogen pathways that advance both energy transition and rural development goals. Geospatially targeted feedstock mapping provides a replicable framework for policy, infrastructure planning, and climate co-benefit integration in emerging economies.
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