Monitoring of respirable dust concentration in high-humidity coal mine environments is subject to severe distortion due to interference from spray droplets. We propose a spectral angle differential decoupling method to suppress spray droplet interference by exploiting the differences in scattering characteristics at dual wavelengths (650 and 940 nm) and dual angles (20° and 90°). Experiments revealed that the dual-wavelength scattering intensity ratios for spray droplets at fixed angles were close to each other (αw,20°≈0.844,αw,90°≈0.864), whereas a significant disparity arose for respirable dust due to its wavelength-dependent scattering properties. A differential cancellation model was established, using the wavelength dimension to eliminate spray scattering interference and employing the angular dimension to decouple the dust concentration. This led to the derivation of an explicit dust concentration inversion model. We designed a time-division multiplexed circuit control system (trigger period < 14 ms), employing alternating laser triggering to ensure spatiotemporal signal consistency. Experimental results demonstrated that under spray interference, conventional single-light-source monitoring methods exhibited a peak error of 50%, while the proposed model reduced this error to 14%. Furthermore, within a concentration range of 35–100 mg/m³, the average relative error remained stable between 10% and 15%.
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