Accurate evaluation of the performance of Intumescent fire-retardant coating (IFRC) is critical for predicting fire behavior in protected construction. In this work, the pyrolysis performance of IFRC is characterized in both N2 and air. Comprehensive models based on ThermaKin are developed. A seven-step inert reaction and eight-step oxidative reaction schemes are proposed to describe the pyrolysis of IFRC in N2 and air. The corresponding kinetic and thermodynamic model parameters are obtained by inversely analyzing the measurements. The obtained comprehensive models are used to simulate the experimental results of cone calorimeter. Both model simulations capture the trend of mass loss rate (MLR) curves. However, the simulation with oxidative reaction scheme presents a faster initial MLR increase rate, higher MLR peak (MLRpeak) and earlier time to MLRpeak with higher R2 of 0.91, 0.95 and 0.85 (for the dry film thickness of 1.00 mm, 2.00 mm and 3.00 mm). This is due to the exothermic reactions in air accelerating the IFRC pyrolysis, while the endothermic reactions in N2 decelerating the IFRC pyrolysis. The model with an oxidative reaction scheme can better predict the performance of IFRC in real-fire scenarios, which may contribute to the evaluation of IFRC in the construction fire design.
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