The production of incomplete combustion products from the burning of wood, medium density fiberboard (MDF), and nylon in an under-ventilated compartment fire was investigated using a reduced-scale compartment. Species measurements of carbon monoxide (CO) and carbon dioxide (CO2) were performed using Fourier Transform Infrared Spectroscopy (FTIR) and methane (CH4), hydrogen cyanide (HCN), benzene (C6H6), ethylene (C2H4) and acetylene (C2H2) were measured with Laser Absorption Spectroscopy (LAS) with three different interband cascade lasers. The fuels were burned in three different crib configurations; only wood, only MDF, and a mixture of wood and nylon, to examine the production of different toxicants. During the experiments, measurements were collected of CO, CO2, CH4, HCN, C2H2, and C6H6 species from the gas exiting the compartment, gas temperature from inside the compartment, and the flow into and out of the compartment. Consistent with under-ventilated combustion, the temperature inside the compartment typically exceeded 600 °C. CO was measured during all experiments and was two orders of magnitude less than the measured CO2 concentration. Significant amounts of unburned hydrocarbons were measured during all of the experiments, while HCN was only detected during the wood-nylon tests. Higher toxicant yields were measured for wood-nylon compared to pure wood and MDF.
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