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Environmental assessment of industrial aquaponics in arid zones using an integrated dynamic model 基于综合动态模型的干旱区工业水培环境评价
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-19 DOI: 10.1016/j.inpa.2024.09.005
Ze Zhu , Uri Yogev , Amit Gross , Karel J. Keesman
Land desertification, water scarcity, and food security challenges in arid zones are intensifying, driving the need for sustainable agricultural solutions like aquaponics. This study investigated innovative water and energy-saving strategies using an integrated dynamic model for an on-demand industrial aquaponics system in Israel. The model evaluated the performance of a recirculating aquaculture system (RAS), hydroponics system (HPS), and desalination unit (DU) by adjusting physical and operational parameters to optimize water and nutrient use efficiency, energy consumption, and yield. Optimizing the system design resulted in an aquaponics system with approximately 420 m3 RAS, 6.85 ha HPS and 40 m3/d DU, achieving phosphorus use efficiency of 96 %, a water use efficiency of 97 %, freshwater input of 1.5 L/day/m2, and energy consumption of 0.56 kWh/day/m2. To mitigate the challenges of extreme arid climates, evaporative cooling combined with outdoor shading and mechanical cooling was found to be a feasible option to control temperature and humidity in the greenhouse. Dehumidification technologies further improved system performance by recovering 22 % freshwater from seawater and increasing nitrogen use efficiency by 18 %. Achieving daily energy self-sufficiency required 4500 m2 photovoltaic panels and 5000 m2 solar heating system. While the system model was initially devised with a specific focus on conditions in Israel, it has been designed with scalability, allowing it to be adapted and applied extensively across diverse peri-urban regions and arid zones globally.
干旱地区的土地荒漠化、水资源短缺和粮食安全挑战正在加剧,推动了对水培等可持续农业解决方案的需求。本研究利用以色列按需工业水培系统的综合动态模型调查了创新的水和节能策略。该模型通过调整物理和操作参数,对循环水养殖系统(RAS)、水培系统(HPS)和海水淡化装置(DU)的性能进行评估,以优化水和养分利用效率、能耗和产量。优化后的水培系统RAS为420 m3, HPS为6.85 ha, DU为40 m3/d,磷利用效率为96%,水利用效率为97%,淡水输入量为1.5 L/d /m2,能耗为0.56 kWh/d /m2。为了缓解极端干旱气候的挑战,蒸发冷却结合室外遮阳和机械冷却被认为是控制温室温度和湿度的可行选择。除湿技术进一步提高了系统性能,从海水中回收22%的淡水,提高了18%的氮利用效率。实现每日能源自给需要4500平方米的光伏板和5000平方米的太阳能供暖系统。虽然该系统模型最初是专门针对以色列的情况设计的,但它的设计具有可扩展性,可以在全球不同的城市周边地区和干旱地区进行调整和广泛应用。
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引用次数: 0
Classification and identification of pest, diseases and nutrient deficiency in paddy using layer based EMD phase features with decision tree 基于分层EMD阶段特征的决策树方法对水稻病虫害和营养缺乏症进行分类鉴定
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-10 DOI: 10.1016/j.inpa.2024.09.003
A. Pushpa Athisaya Sakila Rani , N. Suresh Singh
Pest attack, disease incidence, and nutrient deficiency are the major factors limiting the yield of paddy. Therefore, the paper proposes a classification system for the identification of pest, disease, and nutrient deficiency classes. This approach initially preprocesses leaf images using entropy filtering followed by a leaf segmentation process. Multiple layers are then constructed on the leaf image through which features are extracted. The Gray Level Co-occurrence Matrix (GLCM) algorithm and Principal Component Analysis (PCA) are used to extract the global texture features of the leaf image. A 1D-signal sequence is constructed on each layer, which is decomposed by the Empirical Mode Decomposition algorithm from which the phase features are estimated. The features are trained/classified using the decision tree classifiers that classify the pest attack, disease incidence, and nutrient deficiency categories. The proposed approach provides a precision, accuracy, specificity, sensitivity, and F1-score of 97 %, 97.88 %, 96.52 %, 96.7 %, and 96.7 % respectively.
病虫害、病害和营养缺乏是制约水稻产量的主要因素。因此,本文提出了一种鉴定病虫害和营养缺乏症的分类体系。该方法首先使用熵滤波对叶片图像进行预处理,然后进行叶片分割处理。然后在叶子图像上构建多层,通过多层提取特征。采用灰度共生矩阵(GLCM)算法和主成分分析(PCA)方法提取叶片图像的全局纹理特征。在每一层上构造一维信号序列,通过经验模态分解算法对其进行分解,并从中估计相位特征。使用决策树分类器对特征进行训练/分类,决策树分类器对害虫攻击、疾病发病率和营养缺乏类别进行分类。该方法的精密度、准确度、特异性、敏感性和f1评分分别为97%、97.88%、96.52%、96.7%和96.7%。
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引用次数: 0
Maintaining environmental context and geoprivacy protection in agriculture 维护农业的环境背景和地理隐私保护
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-07 DOI: 10.1016/j.inpa.2024.09.001
Parvaneh Nowbakht , Lilian O’Sullivan , David P. Wall , Paul Holloway
To achieve sustainable agriculture and food security there is an urgent need to share agricultural data with a range of relevant stakeholders; however, to reduce the risk of identification, spatial data must be obfuscated prior to sharing. To-date, most obfuscation methods that have been developed do not consider a) the areal nature of field-level data and b) the differing environmental conditions at the original and obfuscated sites. To address these issues, we developed the Polygon-based Environmental Similarity Obfuscation Method (PESOM) to provide geoprivacy protection and guarantee that obfuscated data will retain the same environmental conditions as the original data. PESOM was developed using an unsupervised clustering algorithm and seasonal climate data, before being applied to the Nutrient Management Plan (NMP) online in Ireland. PESOM satisfied high level of geoprivacy protection and absolute environmental clustering preservation, with no false-identification and non-unique obfuscation risk. It provided a low level of distribution preservation and correlation preservation, large location displacement and subsequently low local analytical accuracy. PESOM is a significant advance on existing obfuscation techniques in agriculture data and will allow the sharing of data to be used widely for agri-environmental purposes, a current limitation of existing methods. The results of this research should be of wide interest to those working in agri-environmental research and computer science, and be of relevance to researchers, data managers, and practitioners.
为实现可持续农业和粮食安全,迫切需要与一系列相关利益攸关方共享农业数据;然而,为了减少被识别的风险,空间数据必须在共享之前进行混淆处理。迄今为止,大多数已开发的混淆方法都没有考虑到a)现场级数据的地域性和b)原始和混淆地点的不同环境条件。为了解决这些问题,我们开发了基于多边形的环境相似性混淆方法(PESOM),以提供地理隐私保护,并保证混淆后的数据将保留与原始数据相同的环境条件。PESOM是使用无监督聚类算法和季节性气候数据开发的,然后应用于爱尔兰的在线营养管理计划(NMP)。PESOM满足高水平的地理隐私保护和绝对环境聚类保护,无虚假识别和非唯一混淆风险。它提供了低水平的分布保存和相关性保存,大的位置位移,从而降低了局部分析精度。PESOM是对现有农业数据混淆技术的重大进步,将允许数据共享广泛用于农业环境目的,这是目前现有方法的限制。这项研究的结果应该引起那些从事农业环境研究和计算机科学的人的广泛兴趣,并与研究人员、数据管理人员和实践者相关。
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引用次数: 0
A novel random forest-based approach for the non-destructive and explainable estimation of ammonia and chlorophyll in fresh-cut rocket leaves 一种基于随机森林的新方法,用于无损和可解释地估计鲜切火箭叶片中氨和叶绿素
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-03 DOI: 10.1016/j.inpa.2024.09.002
Stefano Polimena , Gianvito Pio , Maria Cefola , Michela Palumbo , Michelangelo Ceci , Giovanni Attolico
The perceived visual quality of fruits and vegetables plays a central role in the choices made by retail customers. Machine learning (ML) approaches based on image analysis have been recently proposed to overcome the poor efficiency and subjectivity of human visual evaluation as well as the expensiveness and destructiveness of physical and chemical methods that measure internal indicators. In this paper, we propose a ML method based on Random Forests for estimating the chlorophyll and ammonia contents (considered, in the literature, reliable indicators of product freshness) from images of fresh-cut rocket leaves. Our approach copes with specific issues raised by (i) the non-uniform distributions of ammonia and chlorophyll values and (ii) the need to provide insights into the features that produce a particular model outcome, aiming to enhance its trustworthiness. Our experiments, performed on real images of fresh-cut rocket leaves, proved that the proposed approach significantly outperforms 7 competitor methods, obtaining an improvement of the RSE results of 6.6% for the prediction of the ammonia and of 10.4% for the prediction of the chlorophyll over its best competitor. Moreover, a specific analysis of the explainability of the predictions showed that the learned models are based on reasonable features, empowering their acceptance in real-world applications.
水果和蔬菜的视觉感知质量在零售顾客的选择中起着核心作用。最近提出了基于图像分析的机器学习(ML)方法,以克服人类视觉评估的低效率和主观性,以及测量内部指标的物理和化学方法的昂贵和破坏性。在本文中,我们提出了一种基于随机森林的机器学习方法,用于从新鲜切割的火箭叶片图像中估计叶绿素和氨含量(在文献中被认为是产品新鲜度的可靠指标)。我们的方法处理了以下方面提出的具体问题:(i)氨和叶绿素值的不均匀分布以及(ii)需要提供对产生特定模型结果的特征的见解,旨在提高其可信度。我们在鲜切火箭叶片的真实图像上进行的实验证明,该方法显著优于7种竞争对手的方法,在预测氨的RSE结果上比最佳竞争对手提高了6.6%,在预测叶绿素的RSE结果上比最佳竞争对手提高了10.4%。此外,对预测的可解释性的具体分析表明,学习模型基于合理的特征,使其能够在现实世界的应用中被接受。
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引用次数: 0
Artificial intelligence solutions to reduce information asymmetry for Colombian cocoa small-scale farmers 减少哥伦比亚可可小农户信息不对称的人工智能解决方案
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2023.03.001

The lack of information creates problems for Colombian small-scale farmers, as it impedes them from selling at fair prices and knowing efficient production techniques. Around the world, many technological interventions have proven helpful in reducing information asymmetries. Therefore, we proposed a technological scheme based on a genetic algorithm and a natural language processor (NLP) that enables producers to obtain knowledge through information processing. Also, we ran fieldwork in twenty municipalities and a survey among 500 Colombian cocoa small-scale farmers in different regions in Colombia. This fieldwork helps us determine small-scale farmers' necessities, market conditions, and the relevance of an Artificial Intelligence (AI) tool. The results have shown that AI methodologies could improve the economic conditions of small farmers by providing access to information on prices, weather, and production techniques. The fieldwork evidence that a technological tool is a good option only if there are dynamic trade cycles. AI tools could transmit and process information to become producers' knowledge and help them evolve into collective strategies. The methodology, which combines genetic algorithms, NLP, and fieldwork for cocoa farming, is a novelty that contributes to information asymmetry reduction. We contributed to the literature about adopting AI tools to develop cocoa small-scale farming better.

信息的缺乏给哥伦比亚的小规模农户带来了问题,因为这阻碍了他们以公平的价格销售和了解高效的生产技术。在世界各地,许多技术干预措施已被证明有助于减少信息不对称。因此,我们提出了一种基于遗传算法和自然语言处理器(NLP)的技术方案,使生产者能够通过信息处理获得知识。此外,我们还在哥伦比亚不同地区的 20 个城市进行了实地考察,并对 500 名哥伦比亚可可小农进行了调查。这项实地调查有助于我们确定小规模农户的需求、市场条件以及人工智能(AI)工具的相关性。结果表明,人工智能方法可以通过提供有关价格、天气和生产技术的信息,改善小农户的经济状况。实地工作证明,只有在动态贸易周期的情况下,技术工具才是一个好的选择。人工智能工具可以传输和处理信息,使之成为生产者的知识,帮助他们发展成集体战略。该方法结合了遗传算法、NLP 和可可种植的实地调查,是一种有助于减少信息不对称的新方法。我们为有关采用人工智能工具更好地发展可可小规模种植业的文献做出了贡献。
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引用次数: 0
Detection and counting method of juvenile abalones based on improved SSD network 基于改进SSD网络的鲍鱼幼鱼检测计数方法
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2023.03.002

Detection and counting of abalones is one of key technologies of abalones breeding density estimation. The abalones in the breeding stage are small in size, densely distributed, and occluded between individuals, so the existing object detection algorithms have low precision for detecting the abalones in the breeding stage. To solve this problem, a detection and counting method of juvenile abalones based on improved SSD network is proposed in this research. The innovation points of this method are: Firstly, the multi-layer feature dynamic fusion method is proposed to obtain more color and texture information and improve detection precision of juvenile abalones with small size; secondly, the multi-scale attention feature extraction method is proposed to highlight shape and edge feature information of juvenile abalones and increase detection precision of juvenile abalones with dense distribution and individual coverage; finally, the loss feedback training method is used to increase the diversity of data and the pixels of juvenile abalones in the images to get the even higher detection precision of juvenile abalones with small size. The experimental results show that the [email protected] value, [email protected] value and [email protected] value of the detection results of the proposed method are 91.14%, 89.90% and 80.14%, respectively. The precision and recall rates of the counting results are 99.59% and 97.74%, respectively, which are superior to the counting results of SSD, FSSD, MutualGuide, EfficientDet and VarifocalNet models. The proposed method can provide support for real-time monitoring of aquaculture density for juvenile abalones.

鲍鱼的检测和计数是鲍鱼繁殖密度估计的关键技术之一。繁殖期的鲍鱼个体较小,分布密集,且个体之间存在遮挡,因此现有的物体检测算法对繁殖期鲍鱼的检测精度较低。为解决这一问题,本研究提出了一种基于改进的 SSD 网络的幼鲍检测与计数方法。该方法的创新点在于首先,提出了多层特征动态融合方法,以获取更多的颜色和纹理信息,提高对小体型幼鲍的检测精度;其次,提出了多尺度注意力特征提取方法,以突出幼鲍的形状和边缘特征信息,提高对密集分布和个体覆盖的幼鲍的检测精度;最后,采用损失反馈训练方法,增加图像中数据和幼鲍像素的多样性,以获得更高的小体型幼鲍的检测精度。实验结果表明,所提方法检测结果的[email protected]值、[email protected]值和[email protected]值分别为 91.14%、89.90%和 80.14%。计数结果的精确率和召回率分别为 99.59% 和 97.74%,优于 SSD、FSSD、MutualGuide、EfficientDet 和 VarifocalNet 模型的计数结果。所提出的方法可为实时监测鲍鱼幼体的养殖密度提供支持。
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引用次数: 0
A low-cost digital 3D insect scanner 一种低成本的数字3D昆虫扫描仪
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2023.03.003

Collections of biological specimens are essential in entomology laboratories for scientific knowledge and the characterization of natural varieties. It is vital to liberate useful information from physical collections by digitizing specimens, allowing them to be shared, examined, annotated, and compared more readily. As a result, current research has concentrated on developing 3D modeling machine systems to digitize insect specimens. Despite many great outcomes, these systems have certain drawbacks. In this research, a new scanning machine is proposed for creating 3D virtual models of insects. Our method has overcome certain previous constraints by aiding in the automation of the entire imaging process at a low cost, lowering shooting time, and generating 3D models with accurate color, high resolution, and high accuracy of insect samples with small sizes and complicated structures. Because of its ease of installation and modification, our system may be expanded and utilized in a variety of settings and areas.

在昆虫学实验室中,收集生物标本对于获取科学知识和描述自然物种特征至关重要。通过对标本进行数字化处理,使其更易于共享、检查、注释和比较,从而从实物收藏中获取有用信息至关重要。因此,目前的研究主要集中在开发三维建模机器系统,以实现昆虫标本的数字化。尽管这些系统取得了很多成果,但也存在一些缺点。本研究提出了一种新的扫描机器,用于创建昆虫的三维虚拟模型。我们的方法克服了以往的一些限制,以较低的成本实现了整个成像过程的自动化,缩短了拍摄时间,并能生成色彩准确、分辨率高、精度高的三维模型,适用于体积小、结构复杂的昆虫样本。由于其易于安装和修改,我们的系统可在各种环境和领域进行扩展和使用。
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引用次数: 0
Key technologies and applications of rural energy internet in China 中国农村能源互联网的关键技术及应用
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2022.03.001

Rural energy plays an important role in realizing the goals of “carbon peak” and “carbon neutrality” in China. In this paper, the countryside was regarded as the research object, and the rural energy internet was constructed to study the impact of rural energy development on rural carbon emissions. The most advanced energy and informative technologies in the development of rural energy were introduced from three perspectives, including rural living, rural planting and rural breeding. The benefits of rural energy internet in practical application, including energy and carbon benefits, were presented through three application cases. In general, a low-carbon, digital and intelligent rural energy will be developed, and the goals of “carbon peak” and “carbon neutrality” will be achieved by constructing and applying of rural energy internet in China.

农村能源对我国实现 "碳峰值 "和 "碳中和 "目标具有重要作用。本文以农村为研究对象,构建农村能源互联网,研究农村能源发展对农村碳排放的影响。从农村生活、农村种植和农村养殖三个方面介绍了农村能源发展中最先进的能源技术和信息化技术。通过三个应用案例介绍了农村能源互联网在实际应用中的效益,包括能源效益和碳效益。总体而言,中国将通过农村能源互联网的建设和应用,发展低碳、数字、智能的农村能源,实现 "碳峰值 "和 "碳中和 "的目标。
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引用次数: 0
Pig face recognition based on improved YOLOv4 lightweight neural network 基于改进的YOLOv4轻量级神经网络的猪人脸识别
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2023.03.004

With the vigorous development of intelligence agriculture, the progress of automated large-scale and intensive pig farming has accelerated significantly. As a biological feature, the pig face has important research significance for precise breeding of pigs and traceability of health. In the management of live pigs, many managers adopt traditional methods, including color marking and RFID identification, but there will be problems such as off-label, mixed-label and waste of manpower. This work proposes a non-invasive way to study the identification of multiple individuals in pigs. The model was to first replace the original backbone network of YOLOv4 with MobileNet-v3, a popular lightweight network. Then depth-wise separable convolution was adopted in YOLOv4′s feature extraction network SPP and PANet to further reduce network parameters. Moreover, CBAM attention mechanism formed by the concatenation of CAM and SAM was added to PANet to ensure the network accuracy while reducing the model weight. The introduction of multi-attention mechanism selectively strengthened key areas of pig face and filtered out weak correlation features, so as to improve the overall model effect. Finally, an improved MobileNetv3-YOLOv4-PACNet (M-YOLOv4-C) network model was proposed to identify individual sows. The mAP were 98.15 %, the detection speed FPS were 106.3frames/s, and the model parameter size was only 44.74 MB, which can be well implanted into the small-volume pig house management sensors and applied to the pig management system in a lightweight, fast and accurate manner. This model will provide model support for subsequent pig behavior recognition and posture analysis.

随着智慧农业的蓬勃发展,生猪养殖自动化规模化、集约化进程明显加快。猪脸作为一种生物特征,对生猪精准育种和健康追溯具有重要的研究意义。在生猪管理中,很多管理者采用传统方法,包括色标、RFID识别等,但会存在脱标、混标、浪费人力等问题。这项工作提出了一种非侵入式的方法来研究猪的多个体识别。该模型首先用流行的轻量级网络 MobileNet-v3 代替 YOLOv4 的原始主干网络。然后在 YOLOv4 的特征提取网络 SPP 和 PANet 中采用深度可分离卷积,进一步降低网络参数。此外,还在 PANet 中加入了由 CAM 和 SAM 组合而成的 CBAM 注意机制,以在降低模型权重的同时确保网络精度。多重关注机制的引入选择性地强化了猪脸的关键区域,过滤掉了弱相关特征,从而提高了整体模型效果。最后,提出了一种改进的 MobileNetv3-YOLOv4-PACNet (M-YOLOv4-C) 网络模型来识别母猪个体。该模型的mAP为98.15%,检测速度FPS为106.3帧/秒,模型参数大小仅为44.74 MB,可以很好地植入到小体积猪舍管理传感器中,轻便、快速、准确地应用到猪场管理系统中。该模型将为后续的猪只行为识别和姿态分析提供模型支持。
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引用次数: 0
Spectroscopic measurement and dielectric relaxation study of vegetable oils 植物油的光谱测量和介电弛豫研究
IF 7.7 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.inpa.2023.04.002

The purpose of the current study is to investigate the qualitative characterization of nine different pure vegetable oil samples using dielectric spectroscopy which is a vastly resourceful and reasoned technique in the temperature range 0 ℃ to 25 ℃. Time-domain reflectometry technique is applied up to the microwave frequencies of 50 GHz for the first time for qualitative characterization of the selected vegetable oil samples with a special focus on the variances of dielectric properties like dielectric permittivity (ε′), dielectric loss (ε″), relaxation time concerning temperature and other physiochemical properties of the vegetable oil specimens.

The experimental methodology involves the use of time-domain reflectometry (TDR) measurements up to the scale of 50 GHz done to analyse the aspects like lower and higher scales of values towards the static dielectric permittivity (εs) and relaxation time (τ) (ps) to further meaningfully compare and correlate this values with the fatty acid profiles of each of the nine vegetable oil samples to reason and draw comparative inferences about the quality aspects of vegetable oils. Microwave TDR studies provide an effective, alternate, simple, rapid, and viable way to exercise quality control and actuate data regarding the quality status of vegetable oils. Variances of dielectric permittivity (ε′) concerning dielectric loss (ε″) are graphically interpreted using the Cole Davidson model. The static dielectric permittivity (εs) was further recertified and measured accurately by using a precision LCR meter. Thermodynamic properties of all the nine vegetable oil samples like enthalpy (ΔH) (kJ/mol) and entropy of activation (ΔS) (J/mol ∙ K) are also calculated to further insight the dependence of dielectric properties of these oil samples concerning temperature.

This dielectric spectroscopic study affirms the association of the quality aspects of these nine vegetable oil samples with their dielectric properties by providing meaningful correlations, comparatives and concurrencies of dielectric properties concerning the physiochemical properties which are a part of fatty acid profiles of these samples, which is a novel aspect of this study. The Cole-Cole plot underlines the tendency of realignment of dipoles as per the applied field. The complex permittivity spectra indicate the dwindling nature of molecular alignment including a slow decline to average coinciding values depending on the molecular bonding pattern of vegetable oil samples. The activation energy (ΔH) in (kJ/mol) is calculated for all the samples which are indicative of endothermic nature which experimentally proves that high energy is required for rotation of unsaturated oil sample molecules with low relaxation times.

The highlight of the current dielectric spectroscopic study is that it conclusively divides the nine vegetable oil samples into

本研究的目的是在 0 ℃ 至 25 ℃ 的温度范围内,利用介电光谱技术研究九种不同纯植物油样品的定性特征。时域反射仪技术首次被应用到 50 GHz 的微波频率上,对所选植物油样品进行定性表征,特别关注介电性质的变化,如介电常数 (ε′)、介电损耗 (ε″)、温度弛豫时间以及植物油样品的其他理化性质。实验方法包括使用高达 50 GHz 的时域反射仪 (TDR) 测量来分析静态介电介电常数 (εs)和弛豫时间 (τ) (ps) 等方面的较低和较高数值,进一步将这些数值与九种植物油样本中每种样本的脂肪酸概况进行有意义的比较和关联,从而推理和得出有关植物油质量方面的比较推论。微波 TDR 研究提供了一种有效、替代、简单、快速和可行的方法来进行质量控制和获取有关植物油质量状况的数据。介电常数(ε′)与介电损耗(ε″)的差异是利用科尔-戴维森模型用图形解释的。静态介电介电常数(εs)通过使用精密 LCR 表进行了进一步的重新认证和精确测量。还计算了所有九种植物油样品的热力学性质,如焓(ΔH)(kJ/mol)和活化熵(ΔS)(J/mol ∙ K),以进一步了解这些油样品的介电性质与温度的关系。这项介电光谱研究证实了这九种植物油样品的质量与其介电性质之间的联系,提供了介电性质与理化性质之间有意义的相关性、可比性和一致性,而理化性质是这些样品脂肪酸特征的一部分,这是本研究的一个新方面。科尔-科尔图强调了偶极子随外加磁场重新排列的趋势。复介电常数频谱表明分子排列逐渐减弱,包括根据植物油样品的分子键模式缓慢下降到平均重合值。计算出的所有样品的活化能(ΔH)单位为(kJ/mol),表明其具有内热性质,实验证明,低弛豫时间的不饱和油样品分子旋转需要高能量。本次介电波谱研究的亮点在于,它根据弛豫时间将九种植物油样品明确分为两组,分别测量了ps弛豫时间较高的植物油样品[大豆油(398.5)、落花生油(412.5)、亚麻籽油(318.4)和蓖麻油(305.3)]和ps弛豫时间较低的油类样品[红花油(37.91)、葵花籽油(30.6)、核桃油(22.4)和芝麻油(38.4)],并将这一介电特性与油酸存在的程度相关联:C18H34O2, linoleic acid:C18H32O2, linolenic acid:C18H30O2 和蓖麻油酸 C18H34O3,以及每个样本脂肪酸图谱中存在的不饱和百分比。椰子油饱和脂肪图谱(饱和度百分比为 82.5)的弛豫时间(41.8)ps 较低,其与月桂酸 C12H24O2(52 ps)、肉豆蔻酸 C14H28O2(21 ps)、亚麻酸 C18H30O2 和蓖麻油酸 C18H34O3 的百分比存在程度有关:C14H28O2 (21 ps) 也有关联。目前的介电光谱研究进一步强调和比较了九种植物油样品介电常数的差异与不饱和/饱和度的百分比,以推断与这些油样品脂肪酸概况的相关性。
{"title":"Spectroscopic measurement and dielectric relaxation study of vegetable oils","authors":"","doi":"10.1016/j.inpa.2023.04.002","DOIUrl":"10.1016/j.inpa.2023.04.002","url":null,"abstract":"<div><p>The purpose of the current study is to investigate the qualitative characterization of nine different pure vegetable oil samples using dielectric spectroscopy which is a vastly resourceful and reasoned technique in the temperature range 0 ℃ to 25 ℃. Time-domain reflectometry technique is applied up to the microwave frequencies of 50 GHz for the first time for qualitative characterization of the selected vegetable oil samples with a special focus on the variances of dielectric properties like dielectric permittivity (<em>ε</em>′), dielectric loss (<em>ε″</em>), relaxation time concerning temperature and other physiochemical properties of the vegetable oil specimens.</p><p>The experimental methodology involves the use of time-domain reflectometry (TDR) measurements up to the scale of 50 GHz done to analyse the aspects like lower and higher scales of values towards the static dielectric permittivity (<em>ε<sub>s</sub></em>) and relaxation time (<em>τ</em>) (ps) to further meaningfully compare and correlate this values with the fatty acid profiles of each of the nine vegetable oil samples to reason and draw comparative inferences about the quality aspects of vegetable oils. Microwave TDR studies provide an effective, alternate, simple, rapid, and viable way to exercise quality control and actuate data regarding the quality status of vegetable oils. Variances of dielectric permittivity (<em>ε′</em>) concerning dielectric loss (<em>ε″</em>) are graphically interpreted using the Cole Davidson model. The static dielectric permittivity (<em>ε<sub>s</sub></em>) was further recertified and measured accurately by using a precision LCR meter. Thermodynamic properties of all the nine vegetable oil samples like enthalpy (ΔH) (kJ/mol) and entropy of activation (ΔS) (J/mol ∙ K) are also calculated to further insight the dependence of dielectric properties of these oil samples concerning temperature.</p><p>This dielectric spectroscopic study affirms the association of the quality aspects of these nine vegetable oil samples with their dielectric properties by providing meaningful correlations, comparatives and concurrencies of dielectric properties concerning the physiochemical properties which are a part of fatty acid profiles of these samples, which is a novel aspect of this study. The Cole-Cole plot underlines the tendency of realignment of dipoles as per the applied field. The complex permittivity spectra indicate the dwindling nature of molecular alignment including a slow decline to average coinciding values depending on the molecular bonding pattern of vegetable oil samples. The activation energy (ΔH) in (kJ/mol) is calculated for all the samples which are indicative of endothermic nature which experimentally proves that high energy is required for rotation of unsaturated oil sample molecules with low relaxation times.</p><p>The highlight of the current dielectric spectroscopic study is that it conclusively divides the nine vegetable oil samples into","PeriodicalId":53443,"journal":{"name":"Information Processing in Agriculture","volume":"11 3","pages":"Pages 397-408"},"PeriodicalIF":7.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214317323000513/pdfft?md5=dd5c937752933ef085859c3a768dbf14&pid=1-s2.0-S2214317323000513-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46607529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Information Processing in Agriculture
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