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UREASE ACTIVITY AND NITROGEN MINERALIZATION KINETICS AS AFFECTED BY TEMPERATURE AND UREA INPUT RATE IN SOUTHERN CHILEAN ANDISOLS 温度和尿素输入速率对智利南部地区脲酶活性和氮矿化动力学的影响
Pub Date : 2009-01-01 DOI: 10.4067/S0718-27912009000100006
P. Cartes, Alejandra A. Jara, R. Demanet, M. Mora
Se realizaron estudios de incubacion para evaluar el efecto de la temperatura y niveles de suministro de urea sobre la actividad ureasa y la cinetica de mineralizacion de N en dos Andisoles del Sur de Chile. Nuestros resultados mostraron que la actividad ureasa fue mas alta en el suelo Piedras Negras (PNS) que en el suelo Freire (FS) a 24 y 48 h, y la enzima fue activada cuando la temperatura incremento desde 5 a 21 °C. La actividad ureasa siguio una cinetica simple de Michaelis-Menten. En PNS, la constante de Michaelis-Menten (Km) disminuyo, mientras que la velocidad maxima de reaccion de la enzima (Vmax) y la eficiencia catalitica aumentaron cuando la temperatura fue elevada hasta 21 °C a 24 y 48 h de incubacion del suelo. En FS, la actividad ureasa fue la mas alta a las 24 h, y esta disminuyo a las 48 h como consecuencia del agotamiento del sustrato. Por otra parte, los datos de cinetica de mineralizacion de N estrechamente se ajustaron a un modelo exponencial simple. A etapas tempranas de la incubacion, cantidades similares de N mineralizado (Nmin) fueron encontradas en ambos suelos. Sin embargo, Nmin fue 27 a 64 % mas alto en PNS que FS al final del experimento. Estos resultados tuvieron directa relacion con el contenido de materia organica del suelo, la temperatura y el nivel suministro de urea. En PNS, nosotros observamos que 47 a 80 % de Nmin permanecio como NH4+-N, mientras que en FS N03--N represento entre 80 y 96 %. Tales diferencias en la dinamica de transformacion de N estuvieron de acuerdo con la variacion del pH registrada durante el periodo experimental. Estos hechos tienen implicancias practicas para el manejo de los sistemas agricolas en una localidad en particular, debido a que la dinamica de la mineralizacion de N en Andisoles es principalmente controlada por el contenido de materia organica y las propiedades biologicas de suelos, asi como por la temperatura y el nivel de suministro de urea al sistema suelo-planta.
本研究的目的是评估在智利南部的两个Andisoles中,温度和尿素供应水平对尿素酶活性和氮矿化动力学的影响。结果表明,在24和48 h时,Piedras Negras土壤(PNS)的脲酶活性高于Freire土壤(FS),当温度从5℃升高到21℃时,脲酶活性被激活。脲酶活性遵循简单的Michaelis-Menten动力学。在PNS中,当温度提高到21℃时,土壤培养24和48 h时,michaels - menten常数(Km)降低,酶的最大反应速率(Vmax)和催化效率提高。在FS中,脲酶活性在24 h时最高,在48 h时由于底物的消耗而降低。此外,N矿化动力学数据与简单指数模型密切相关。在孵化的早期阶段,两种土壤中都发现了相似数量的矿化N (Nmin)。然而,在实验结束时,PNS的Nmin比FS高27 - 64%。在本研究中,我们分析了不同施肥条件下土壤有机质含量、温度和尿素供应水平的差异。在PNS中,我们观察到47 ~ 80%的Nmin以NH4+-N的形式存在,而在FS N03 -N中,Nmin以80 ~ 96%的形式存在。在试验期间,pH值的变化与氮转化动力学的差异一致。这些事实影响agricolas系统管理实践在特定地域,由于动态mineralizacion Andisoles N是控制的主要内容方面organica以及土壤的生物特性,就是由温度和尿素供应水平suelo-planta系统。
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引用次数: 55
EFECTO DEL CAMBIO DE USO EN LA ESTABILIDAD DE LA ESTRUCTURA Y LA FUNCIÓN DE LOS POROS DE UN ANDISOL (TYPIC HAPLUDAND) DEL SUR DE CHILE 利用变化对智利南部ANDISOL(典型HAPLUDAND)孔隙结构和功能稳定性的影响
Pub Date : 2009-01-01 DOI: 10.4067/S0718-27912009000300003
J. Dörner, D. Dec, Xinhua Peng, R. Horn
Los suelos volcanicos del sur de Chile constituyen cerca del 60% del suelo arable del pais. Estos suelos se encuentran bajo un amplio rango de usos desde sistemas pristinos hasta otros con un uso intensivo. El objetivo de este trabajo fue determinar el efecto del cambio de uso de suelo sobre: i) la estabilidad del suelo frente a presiones externas e internas; ii) la conductividad hidraulica y iii) su resiliencia funcional. Muestras disturbadas y no disturbadas de suelo fueron recolectadas a 5, 20, 40 cm de profundidad en un suelo Andisol (Typic Hapludand) bajo un renoval de bosque nativo (NF), una pradera de 50 anos (P50) y otra de 1 ano de uso (Pl). Se determino la curva de retencion de agua, contraccion y consolidacion, la conductividad hidraulica saturada (Ks), permeabilidad de aire (Ka), contenidos de carbono organico (CO), textura y alofan. Se estimo la conductividad hidraulica no saturada (Ku) de acuerdo al modelo propuesto por van Genuchten (1980). Se definieron indices de deformacion de suelo como consecuencia de estreses mecanicos (COELm) e hidraulicos (COELh). El suelo estudiado esta sujeto a constantes cambios en su estructura como consecuencia de estreses mecanicos e hidraulicos afectando la distribucion de los poros y su funcionalidad. La magnitud de estos cambios disminuye con el incremento de la intensidad de uso del suelo. La gran capacidad de contraccion del suelo puede traer consecuencias en su comportamiento hidraulico dependiendo de la intensidad del secado a traves de la formacion de grietas y vias de flujo de preferencial. Finalmente, los poros del suelo son capaces de recuperar su integridad funcional despues de una compactacion, lo que esta estrechamente relacionado con los contenidos de materia organica.
智利南部的火山土壤约占该国可耕地的60%。这些土壤的用途范围很广,从原始系统到集约化系统。本研究的目的是确定土地利用变化对以下方面的影响:i)土壤在外部和内部压力下的稳定性;ii)水力导电性和iii)功能弹性。在5、20、40 cm深度的原生森林更新(NF)、50年草地(P50)和1年草地(Pl)下的Andisol土壤(典型的Hapludand)中采集扰动和未扰动土壤样品。测定了保水性、收缩固结曲线、饱和水力导电性(Ks)、透气性(Ka)、有机碳含量(CO)、质地和alofan。利用van Genuchten(1980)提出的模型估计了非饱和水力电导率(Ku)。定义了机械应力(COELm)和液压应力(COELh)引起的土壤变形指数。由于机械和液压应力影响孔隙分布和功能,所研究的土壤结构不断发生变化。这些变化的幅度随着土地利用强度的增加而减小。土壤的高收缩能力会对其水力性能产生影响,这取决于干燥的强度,通过形成裂缝和优先流动路径。最后,土壤孔隙在压实后能够恢复其功能完整性,这与有机质含量密切相关。
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引用次数: 26
KINETICS OF SOIL UREASE AFFECTED BY UREASE INHIBITORS AT CONTRASTING MOISTURE REGIMES 不同湿度条件下脲酶抑制剂对土壤脲酶动力学的影响
Pub Date : 2009-01-01 DOI: 10.4067/S0718-27912009000200004
Y. Juan, Lijun Chen, Z. Wu, R. Wang
With black soil (Pachic Udic Argiboroll) of Northeastern China as the test object, an incubation test was conducted to investigate the effects of urease inhibitors, hydroquinone (HQ), phenyl phosphorodiamidate (PPD) and N-(n-Butyl) thiophosphoric triamide (NBPT), on the kinetic characteristics of soil urease under normal moisture and waterlogged conditions, aimed to study the changes of catalytic potential of soil urease and the inhibition mechanisms. The results showed that test urease exhibited typical Michaelis-Menten kinetic behaviors, and all test inhibitors increased the Km and decreased the Vmax of soil urease, behaving as mixed inhibitors to soil urease. Under both normal and waterlogged conditions, compared with HQ, PPD and NBPT made Km increase and Vmax and Vmax/Km decrease more greatly, and the duration of these effects was longer (ca. 30 days vs. 10 days). Under water-logging, PPD made more increment of Km and more decrement of Vmax and Vmax/Km than NBPT, compared with that under normal soil moisture condition, suggesting that NBPT was more available under normal soil moisture condition, while PPD was promising under water-logging condition. To apply urease inhibitors and to control soil moisture condition could be a feasible way in increasing fertilizer N use efficiency affected by soil urease.
以东北黑土(Pachic Udic Argiboroll)为试验对象,通过培养试验研究了脲酶抑制剂对苯二酚(HQ)、苯基磷酸二酯(PPD)和N-(正丁基)硫磷三酰胺(NBPT)在正常水分和涝渍条件下对土壤脲酶动力学特性的影响,旨在研究土壤脲酶催化电位的变化及其抑制机制。结果表明,试验脲酶表现出典型的Michaelis-Menten动力学行为,各试验抑制剂均能提高土壤脲酶的Km,降低土壤脲酶的Vmax,表现为混合抑制剂。在正常和涝渍条件下,与HQ相比,PPD和NBPT的Km增加幅度更大,Vmax和Vmax/Km降低幅度更大,且持续时间更长(约30 d vs. 10 d)。在涝渍条件下,PPD比NBPT增加Km、减少Vmax和Vmax/Km,表明NBPT在涝渍条件下更有效,而PPD在涝渍条件下更有发展前景。施用脲酶抑制剂和控制土壤水分条件是提高脲酶对氮肥利用效率的可行途径。
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引用次数: 23
VARIABILIDAD ASOCIADA A LA DETERMINACIÓN DE RESIDUOS DE CLORPIRIFOS AL SER APLICADO EN UN HUERTO DE MANZANOS 在苹果园中应用毒死蜱残留量测定的变异性
Pub Date : 2009-01-01 DOI: 10.4067/S0718-27912009000300002
J. Junod, Erick Zagal, M. Sandoval, A. Venegas, J. Campos, R. Radrigan, Ricardo Barra, G. Vidal
El presente estudio tiene por objetivo probar mediante ensayos supervisados la variabilidad de los residuos de clorpirifos (CHP) asociados a una metodologia de muestreo validada en terreno, al aplicar el ingrediente activo (IA) en huerto de manzanos, con dos diferentes metodologias de aspersion y en epocas diferentes de desarrollo vegetativo. Se estudio la persistencia al aplicar 1,8 kg ha -1(Lorsban 50%WP®, Dow AgroScience, USA), mediante nebulizadora con bomba de espalda con motor (NBEM) y con nebulizadora de alto volumen (NAV). Se evaluo el modelo que representa el mejor ajuste de la declinacion de los residuos a traves de regresion no lineal. Los resultados muestran altos coeficientes de variacion (CV) en ambos metodos de aplicacion, NBEM (69%) y NAV (43%). La variabilidad del muestreo de manzanas contribuye con un 99.3% con NBEM y 97.7% con NAV. Los resultados muestran una disminucion inicial rapida del CHP, con una vida media para manzanas, hojas y suelo de 5,0; 2,3 y 4,5 dias para NBEM y de 8,3; 2,7 y 11,2 dias para NAV, respectivamente. El modelo de declinacion ajustado para cada sustrato no permite modelar la degradacion de los residuos de CHP a traves de un modelo simple.
本研究旨在通过监测试验测试毒死蜱(CHP)残留的变异性,并在田间验证了有效成分(ai)在苹果园的应用,采用两种不同的喷洒方法和营养发育的不同时期。采用电动背泵喷雾器(NBEM)和高容量喷雾器(NAV),对1.8 kg ha -1(Lorsban 50%WP®,Dow AgroScience, USA)的持久性进行了研究。本文提出了一种非线性回归模型,该模型代表了残差下降的最佳拟合。结果表明,NBEM(69%)和NAV(43%)两种方法的变异系数(CV)都很高。苹果取样变异性对NBEM的贡献为99.3%,对NAV的贡献为97.7%。结果表明,苹果、叶片和土壤的CHP初始降低迅速,半衰期为5.0;NBEM为2.3天和4.5天,8.3天;NAV分别为2.7天和11.2天。每个基质的赤纬调整模型不允许用一个简单的模型来模拟CHP残基的降解。
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引用次数: 4
SEWAGE SLUDGE LEVELS ON THE DEVELOPMENT AND NUTRITION OF SUNFLOWER PLANTS 污水污泥水平对向日葵植株发育和营养的影响
Pub Date : 2009-01-01 DOI: 10.4067/S0718-27912009000300007
Thomaz Figueiredo Lobo, H. G. Filho
This study aimed to evaluate the effect of substituting chemical nitrogen (N) fertilization for equivalent N levels from sewage sludge of Wastewater Treatment Plant (WTP) on sunflower plant development. Nutrient levels in physiologically mature leaves and seeds, besides nutrient exportation during a 130-day assay, were also assessed. The experiment was carried out in 100 m 2 permanent plots at Sao Manuel Farm, which belongs to School of Agronomical Sciences, Sao Paulo State University- UNESP, Botucatu, Sao Paulo State, Brazil. The farm is located in the municipality of Sao Manuel, Sao Paulo State. Experimental design was in randomized blocks including 5 treatments and 5 replicates. Treatments were: T1 - chemical N fertilization according to the recommendation for the culture; T2 - 50% N from sewage sludge and 50% N from chemical fertilization; T3 - 100% N from sewage sludge; T4 - 150% N from sewage sludge; T5 - 200% N from sewage sludge. For all treatments, equal amounts of P and K fertilization were applied. Treatments differed for plant height from 21 to 64 days, stem diameter from 28 to 57 days, and leaf number from 21 to 38 days. Seed nutrient levels slightly varied; however, the quantities of exported N, P, Mg, Fe and Zn varied as sewage sludge levels increased.
本研究旨在评价化学氮肥替代污水处理厂污泥等量氮肥对向日葵植株发育的影响。在130天的试验中,除了营养输出外,还评估了生理成熟叶片和种子的营养水平。实验在100 2进行永久性的情节在圣•曼努埃尔•农场,这属于农艺科学学院,圣保罗州立大学——UNESP Botucatu,圣保罗,巴西。该农场位于圣保罗州圣曼努埃尔市。试验设计为随机分组,包括5个处理和5个重复。处理方法为:按栽培推荐施肥T1 -化学施氮;T2 - 50%氮来自污水污泥,50%氮来自化学肥料;T3 - 100%氮来自污水污泥;T4 - 150%污水污泥氮;T5 - 200% N从污水污泥。所有处理均施等量磷钾肥。株高21 ~ 64 d,茎粗28 ~ 57 d,叶数21 ~ 38 d。种子养分水平略有变化;然而,随着污水污泥水平的增加,输出的N、P、Mg、Fe和Zn的数量有所变化。
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引用次数: 10
RESISTANCE MECHANISMS OF ALUMINUM (Al3+) PHYTOTOXICITY IN CEREALS: PHYSIOLOGICAL, GENETIC AND MOLECULAR BASES 谷物抗铝(Al3+)植物毒性机制:生理、遗传和分子基础
Pub Date : 2008-01-01 DOI: 10.4067/S0718-27912008000300006
C. Inostroza-Blancheteau, B. Soto, P. Ulloa, Felipe Aquea, M. Reyes-Díaz
Aluminum (Al) toxicity is one of the main factors limiting crop productivity in acid soils around the world. In cereals, this problem can affect between 30 and 40% of crop yields. One way to reduce the toxic effect of Al is to neutralize the acidity with calcareous amendments. However, this practice is demanding and not very effective. An alternative is the search for genetic variability in the genome of cropping grasses and/or their wild relatives to resist Al. The development of biotechnology and molecular genetics approach has facilitated the understanding of the physiological, genetic and molecular bases in the process of ameliorating these species. This review presents the main physiological mechanisms of Al resistance and the genetic and molecular bases that explain the degree of resistance between different cereals species.
铝毒性是限制酸性土壤作物产量的主要因素之一。在谷物中,这个问题会影响30%到40%的作物产量。减少铝的毒性作用的一种方法是用钙质改进剂中和铝的酸性。然而,这种做法要求很高,而且不是很有效。另一种方法是在作物和/或其野生近缘种的基因组中寻找遗传变异来抵抗Al。生物技术和分子遗传学方法的发展促进了对这些物种改良过程中生理、遗传和分子基础的理解。本文综述了铝抗性的主要生理机制以及不同谷物品种间铝抗性程度的遗传和分子基础。
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引用次数: 18
Soil Physicochemical and Biological Interfacial Interactions in the Rhizosphere: Impacts on Food Security and Ecosystem Integrity 根际土壤物理化学和生物界面相互作用:对粮食安全和生态系统完整性的影响
Pub Date : 2008-01-01 DOI: 10.4067/S0718-27912008000400005
P. Huang
The soil root interface (the rhizosphere) plays a vital role in sustaining life in the terrestrial ecosystem in the Earth’s Critical Zone (CZ). The CZ is defined as the volume extending from the upper limit of vegetation down to the lower limit of groundwater (Anderson et al., 2004). The CZ is the system of coupled chemical, biological, physical, and geological processes operating together to support life at the Earth’s surface (Brantley et al., 2007). While our understanding of this zone has increased over the last hundred years, further advance requires scientists to cross disciplines and scales to integrate understanding of processes in the CZ, ranging in scale from the mineral-organic matter-organism-water-air interfaces at a molecular level to the globe. Soil is the central organizer in the CZ. The rhizosphere is a hot spot of activity within soils. The rhizosphere is the ‘bottle neck” of the supply of vital elements to sustain ecosystem productivity and integrity and food security. The rhizosphere is also the “bottle neck’ of the contamination of the terrestrial food chain by inorganic and organic pollutants to endanger human and animal health.
土壤根界面(根际)在地球临界带陆地生态系统的生命维持中起着至关重要的作用。CZ被定义为从植被上限向下延伸到地下水下限的体积(Anderson et al., 2004)。CZ是一个耦合的化学、生物、物理和地质过程共同作用的系统,以支持地球表面的生命(Brantley et al., 2007)。虽然我们对这一区域的了解在过去的一百年中有所增加,但进一步的进展需要科学家跨学科和尺度来整合对CZ过程的理解,范围从分子水平的矿物-有机物-生物-水-空气界面到全球。土壤是CZ的中心组织者。根际是土壤中活动的热点。根际是维持生态系统生产力和完整性以及粮食安全的关键要素供应的“瓶颈”。根际也是陆地食物链受到无机和有机污染物污染、危害人类和动物健康的“瓶颈”。
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引用次数: 3
RESPOSTA NUTRICIONAL DO PORTA-ENXERTO DELIMOEIRO 'CITRUMELO' Á APLICACÃO DE NITROGÊNIO, FÓSFORO E POTÁSSIO 柑橘砧木对施氮、磷、钾的营养反应
Pub Date : 2008-01-01 DOI: 10.4067/S0718-27912008000300004
Diego Wyllyam do Vale, Renato de Mello Prado, W. Natale, Adriana Ursulino Alves
The effect of the application of three doses N, P and K on substrates on the nutritional status of root stock of 'Citrumelo' lemon (Citrus paradisi x Poncirus trifoliata) was evaluated. The experiment followed a fully randomized factorial design (3x3) (three nutrients x three doses plus a control) with three replicates. The treatments consisted of Dl = half standard dose, D2 = one standard dose and D3 = twice standard dose, in addition to the control that did not received fertilization at all. At four months after the emergence of the root stock of lemon 'Citrumelo' the plants tissue (leaves) were determined for nutrients analysis to obtain its accumulation. The results showed that plants of lemon 'Citrumelo' 'Swingle' are responsive to the application of N, P and K. The application of nitrogen showed a linear accumulation pattern of N and K, while the applications of phosphorus and potassium provided a quadratic response.
研究了在基质上施氮、磷、钾3个剂量对柑桔砧木营养状况的影响。试验采用完全随机因子设计(3x3)(三种营养素x三剂加对照),有三个重复。除完全不施肥的对照组外,Dl =一半标准剂量,D2 =一个标准剂量,D3 =两倍标准剂量。在柠檬'Citrumelo'砧木出苗4个月后,测定植株组织(叶片)进行养分分析,以获得其积累量。结果表明,柠檬‘Citrumelo’‘Swingle’植株对N、P、K的施用有响应,氮素的施用表现为N、K的线性累积模式,而磷、钾的施用则表现为二次响应模式。
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引用次数: 1
CARACTERIZAÇÃO DA FERTILIDADE DOS SOLOS DE QUATRO LEGUMINOSAS DE CAMPOS RUPESTRES, SERRA DO CIPÓ, MG, BRASIL 四种豆科植物的土壤肥力特征,CAMPOS RUPESTRES, SERRA DO cipo, MG,巴西
Pub Date : 2008-01-01 DOI: 10.4067/S0718-27912008000300003
Daniel Negreiros, Mateus Lanna Borges de Moraes, G. W. Fernandes
The goal of the present study was to characterize the nutritional quality of the soils colonized by four endemic leguminous shrubs of Serra do Cipo, southeastern Brazil: Calliandra fasciculata Benth., Chamaecrista ramosa (Vog.), Collaea cipoensis Fortunato and Mimosa foliolosa Benth. A mixed soil sample collected between 0 and 15cm depth was obtained in four subpopulations of each species. Each mixed sample resulted from the combination of 20 simple samples (four samples of five adult individuals) in each subpopulation. Routine, organic matter, micronutrients, and granulometric analysis were performed for each sample. The soils colonized by the four species were sandy, acidic, deficient in all macronutrients, and with high aluminum saturation. However, the levels of organic matter, zinc, iron, and bore ranged from medium to high. There was no significant difference in organic matter, phosphorus, iron, bore, sulphur, potential acidity, and granulometric parameters among the soils of the four species. The results of the present study corroborate previous studies in rupestrian field soils of Serra do Cipo. Management plans and land rehabilitation programs should keep the conditions of low soil fertility because the endemic flora adapt well on these soils and may have increased competitive ability under these nutritional ranges.
本研究的目的是表征巴西东南部Serra do Cipo四种特有豆科灌木:Calliandra fasciculata Benth的土壤营养质量。(1)、红叶含羞草(Mimosa fololosa);在每个物种的4个亚种群中采集0 ~ 15cm深度的混合土壤样品。每个混合样本由每个亚群中20个简单样本(4个样本,5个成年个体)的组合而成。对每个样品进行常规、有机物、微量元素和颗粒分析。4种植物所定殖的土壤均为砂质、酸性、所有常量养分缺乏、铝饱和度高的土壤。然而,有机质、锌、铁和钻孔的含量从中等到高不等。四种土壤的有机质、磷、铁、孔、硫、潜在酸度和粒度参数均无显著差异。本研究的结果证实了以前在西波山脉的古农田土壤中的研究。管理计划和土地恢复计划应该保持低土壤肥力的条件,因为特有植物群在这些土壤上适应得很好,并且在这些营养范围下可能具有更高的竞争能力。
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引用次数: 32
Sorption-Desorption Processes of Metals and Metalloids in Soil Environments 金属及类金属在土壤环境中的吸附-解吸过程
Pub Date : 2008-01-01 DOI: 10.4067/S0718-27912008000400015
A. Violante, M. Pigna
Trace elements may be present in solution with positive or negative charges and in different redox state. They occur predominantly in cationic form (Pb, Cu, Zn, Ni, Cd, Hg, Cr(III), Co) but some trace elements are present in anionic form (As, Se, Cr(VI), Mo and B). In soil environments, sorption/desorption reactions on/from inorganic and organic sorbents control the concentration of metals and metalloids in solution and affect their bioavailability, leaching and toxicity. Sorption-desorption processes of elements in cationic form differ greatly from those in anionic form. These reactions are affected by many factors, such as pH, nature of the sorbents, presence and concentration of organic and inorganic ligands, including humic and fulvic acids, root exudates and nutrients. Furthermore, redox reactions, both biotic and abiotic, are of great importance in controlling the oxidation state and thus, the mobility, the phytoavailability and the toxicity of many elements, such as Cr, Se, Co, Pb, As, Ni and Cu (Kabata-Pendias, 2001; Huang and Germida, 2002; Violante et al., 2002; Sparks, 2003; Huang and Gobran, 2005; Violante et al., 2007). The aim of this presentation is to provide information on the factors which affect the mobility of trace elements. Special attention is devoted to the influence of inorganic and organic ligands, including nutrients and root exudates, on the sorption/desorption processes of trace elements in cationic and anionic forms on/from soil components, soils and selected synthetic minerals (double layered hydroxides, the so called “anionic clays”). The soil components responsible for trace element sorption include, soil humic substances, phyllosilicates, carbonates and variable charge minerals (constituents such as Fe, Al, Mn and Ti oxides, short-range ordered aluminosilicates as well as phyllosilicates coated by OH-Al or OH-Fe species whose charge varies with the pH of the soil solution). Recently, evidence on the sorption of heavy metals on microorganisms have been reported (Jackson, 1998). Soil components differ greatly in their sorption capacities, their cation and anion exchange capacities, and the binding energies of their sorption sites. Trace element sorption kinetics depend on the type of surface and trace element, but generally are rapid. Half times for bivalent cations, such as Pb, Zn, Cu and Cd, sorption on peat range from 5 to 15 seconds. Except for some noncrystalline minerals that have very high specific surface charge density with highly reactive sites, humic substances appear to have the greatest capacity for sorption of trace elements in cationic form. A body of evidence has demonstrated that humic matter and metal oxides are much more effective scavengers of trace elements in cationic form, than even the most efficient sorbent among phyllosilicates, indicating that specific sorption and other complexation processes are the dominant binding mechanisms (Jackson, 1998; Huang and Germida, 2002; Spark, 2003). Compl
微量元素可以带正电荷或负电荷,以不同的氧化还原状态存在于溶液中。它们主要以阳离子形式存在(Pb, Cu, Zn, Ni, Cd, Hg, Cr(III), Co),但也有一些微量元素以阴离子形式存在(As, Se, Cr(VI), Mo和B)。在土壤环境中,无机和有机吸附剂的吸附/解吸反应控制了溶液中金属和类金属的浓度,并影响其生物有效性,淋溶性和毒性。阳离子形式元素的吸附-解吸过程与阴离子形式元素的吸附-解吸过程有很大不同。这些反应受到许多因素的影响,如pH值、吸附剂的性质、有机和无机配体(包括腐植酸和黄腐酸)的存在和浓度、根渗出物和营养物质。此外,生物和非生物氧化还原反应在控制氧化状态以及许多元素(如Cr、Se、Co、Pb、as、Ni和Cu)的迁移性、植物可利用性和毒性方面具有重要意义(Kabata-Pendias, 2001;Huang and Germida, 2002;Violante et al., 2002;火花,2003;Huang and Gobran, 2005;Violante et al., 2007)。本报告的目的是提供有关影响微量元素迁移的因素的信息。特别注意无机和有机配体,包括营养物和根渗出物,对阳离子和阴离子形式的微量元素在土壤成分、土壤和选定的合成矿物(双层氢氧化物,即所谓的"阴离子粘土")上/从土壤中吸附/解吸过程的影响。负责微量元素吸附的土壤成分包括土壤腐殖质、层状硅酸盐、碳酸盐和可变电荷矿物(如Fe、Al、Mn和Ti氧化物、短程有序铝硅酸盐以及被OH-Al或OH-Fe包覆的层状硅酸盐,其电荷随土壤溶液的pH值而变化)。最近,有证据表明微生物对重金属的吸附作用(Jackson, 1998)。土壤组分的吸附能力、阳离子和阴离子交换能力以及吸附位点的结合能差异很大。微量元素的吸附动力学取决于表面和微量元素的类型,但通常是快速的。对于二价阳离子,如Pb、Zn、Cu和Cd,在泥炭上的吸附时间为5至15秒。除了一些非晶矿物具有非常高的比表面电荷密度和高活性位点外,腐殖质物质对阳离子形式的微量元素的吸附能力最大。大量证据表明,腐殖质和金属氧化物是阳离子形式微量元素的更有效清除剂,甚至比层状硅酸盐中最有效的吸附剂还要有效,这表明特定的吸附和其他络合过程是主要的结合机制(Jackson, 1998;Huang and Germida, 2002;火花,2003)。络合反应有以下作用:1)防止金属离子析出;Ii)络合剂可作为土壤溶液中微量元素的载体;Iii)它们的毒性常因络合作用而降低。
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引用次数: 9
期刊
Revista De La Ciencia Del Suelo Y Nutricion Vegetal
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