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Effectiveness of watershed management on water balance components-a review 流域管理对水平衡成分的有效性研究综述
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-09 DOI: 10.1016/j.pce.2026.104277
Saeedreza Moazeni , Ali Salajegheh , Shahram Khalighi-Sigaroodi , Ali Golkarian , Artemi Cerda
Watersheds serve as fundamental units of hydrological systems, playing a crucial role in freshwater supply, biodiversity conservation, and ecosystem sustainability. This study conducts a bibliometric and qualitative analysis of global research (1979–2024) to evaluate the effectiveness of watershed management interventions on key water-balance components, including runoff, infiltration, evapotranspiration, and groundwater recharge. Findings indicate a significant increase in publications, particularly after 2011. We used VOSviewer and Bibliometrix to map publication trends, co-occurrence and co-citation networks, leading authors and journals, and thematic clusters. Prominent studies focus on Land-use impacts on water resources, the application of hydrological models, and the role of vegetation in water regulation. The United States, China, and Canada lead research efforts in this field. Our synthesis classifies interventions into biological, mechanical and managerial types and summarizes reported effects on runoff, infiltration, evapotranspiration (ET), soil moisture, surface storage and groundwater recharge. Results show a marked increase in publications after 2011 and concentration of research activity in the United States, China and Canada. Among water-balance components, runoff (n = 447) and ET (n = 308) dominate the literature, whereas soil moisture (n = 66), surface storage (n = 40) and baseflow (n = 38) are comparatively underrepresented. Hydrological process models were the most used estimation approach (n = 440), followed by remote sensing (n = 140), groundwater models (n = 82) and machine-learning methods (n = 38). From the reviewed studies we synthesise typical outcomes: mechanical structures (e.g., terraces, check-dams) are frequently associated with reductions in surface runoff (up to ∼25 % in reported cases) and context-dependent increases in recharge (reported ranges of ∼40–70 %), while biological measures (e.g., afforestation) often improve infiltration but can elevate ET in water-limited environments. We identify recurrent methodological shortcomings — inconsistent reporting of uncertainty, limited reproducibility of bibliometric settings, and scarce comparative field studies — and propose a focused research agenda: transparent bibliometric reporting, prioritized monitoring of underexplored components (soil moisture, baseflow), development of hybrid process–data modeling frameworks, and targeted, context-specific evaluations of interventions under climate variability. This synthesis provides a state-of-the-art overview and a structured set of priorities to guide future watershed management research and policy.
流域是水文系统的基本单元,在淡水供应、生物多样性保护和生态系统可持续性方面发挥着至关重要的作用。本研究对全球研究(1979-2024)进行了文献计量学和定性分析,以评估流域管理干预对关键水平衡成分(包括径流、入渗、蒸散发和地下水补给)的有效性。研究结果表明,特别是在2011年之后,出版物显著增加。我们使用VOSviewer和Bibliometrix来绘制出版趋势、共现共引网络、主要作者和期刊以及专题集群。突出的研究集中在土地利用对水资源的影响、水文模型的应用以及植被在水调节中的作用。美国、中国和加拿大在这一领域的研究工作处于领先地位。我们的综合研究将干预措施分为生物、机械和管理类型,并总结了对径流、入渗、蒸散发(ET)、土壤湿度、地表储存和地下水补给的影响。结果显示,2011年之后,论文发表量显著增加,研究活动集中在美国、中国和加拿大。在水分平衡组分中,径流(n = 447)和ET (n = 308)占主导地位,而土壤水分(n = 66)、地表储水量(n = 40)和基流(n = 38)相对较少。水文过程模型是最常用的估算方法(n = 440),其次是遥感(n = 140)、地下水模型(n = 82)和机器学习方法(n = 38)。从所回顾的研究中,我们综合了典型的结果:机械结构(如阶地、堤坝)通常与地表径流的减少(在报道的案例中高达25%)和依赖于环境的补给增加(报道的范围为40 - 70%)有关,而生物措施(如造林)通常改善入渗,但在水有限的环境中可以提高ET。我们发现了反复出现的方法学缺陷——不确定性报告不一致,文献计量设置的可重复性有限,以及缺乏比较实地研究——并提出了一个重点研究议程:透明的文献计量报告,优先监测未充分开发的成分(土壤湿度,基流),开发混合过程数据建模框架,以及针对气候变化的干预措施进行有针对性的具体环境评估。这一综合提供了最新的概况和一套结构化的优先事项,以指导未来的流域管理研究和政策。
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引用次数: 0
Emerging contaminants in soil: Source-oriented probabilistic health risks of potentially toxic elements and environmental impacts in Southern India 土壤中新出现的污染物:印度南部潜在有毒元素的面向来源的概率健康风险和环境影响
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-09 DOI: 10.1016/j.pce.2026.104291
Muthusamy Subramanian , Gopal Veeramalai , Mohana Perumal , Prasenjeet Chakraborty , Ribu Cherian , Ramamoorthy Ayyamperumal
Potentially toxic elements (PTEs) in roadside soils pose serious risks to human health and the environment, with anthropogenic activities being the primary source of contamination. In this study, we evaluated the contamination levels, ecological risks, and human health hazards of heavy metals (Fe, Mn, Cr, Cu, Pb, Ni, Co, Zn) in soil samples collected from Tuticorin, Southern India. Elemental concentrations were determined using Energy Dispersive X-ray Fluorescence (EDXRF) and validated with HISS-1 standard reference material, showing recoveries of 92.3–100 %. Geochemical indices (Igeo, EF, CF, CD, PLI, PERF, PERI, and GUFI) revealed that Cu (Igeo = 2.17; EF = 5.55; CF = 7.70), Zn (Igeo = 1.22; EF = 2.77; CF = 3.71), and Pb (Igeo = 0.60; EF = 1.95; CF = 2.48) were the most enriched metals, reflecting moderate to severe contamination, while Fe, Mn, Co, and Ni were largely of natural origin. Principal component and correlation analyses indicated two main sources of contamination: industrial emissions (thermal power plants, leather industry) and traffic/maritime activities. Ecological risk assessment identified hotspots at sampling points 14, 17, 27–29, and 31–33, primarily due to Cu, Zn, and Pb. Probabilistic human health risk assessment showed that children were exposed to elevated non-carcinogenic risks (THI = 1.90) and carcinogenic risks (TCRI = 4.51 × 10−4), mainly from Cr, Ni, Zn, and Mn, while adults experienced lower risks (THI = 0.26; TCRI = 5.02 × 10−5). These findings highlight the need for continuous monitoring, targeted mitigation, and regulatory measures to control heavy metal contamination in roadside soils and protect vulnerable populations, especially children.
路边土壤中的潜在有毒元素(pte)对人类健康和环境构成严重风险,人为活动是主要污染源。在这项研究中,我们评估了在印度南部Tuticorin收集的土壤样品中重金属(Fe, Mn, Cr, Cu, Pb, Ni, Co, Zn)的污染水平,生态风险和人类健康危害。采用能量色散x射线荧光(EDXRF)测定元素浓度,并用HISS-1标准对照品进行验证,回收率为92.3 - 100%。地球化学指标(Igeo、EF、CF、CD、PLI、PERF、PERI和GUFI)显示,Cu (Igeo = 2.17, EF = 5.55, CF = 7.70)、Zn (Igeo = 1.22, EF = 2.77, CF = 3.71)和Pb (Igeo = 0.60, EF = 1.95, CF = 2.48)是富集程度最高的金属,反映了中~重度污染,Fe、Mn、Co和Ni主要为天然来源。主成分分析和相关分析表明两个主要污染源:工业排放(火力发电厂、皮革工业)和交通/海事活动。生态风险评价在14、17、27-29和31-33采样点发现热点,主要是Cu、Zn和Pb。人类健康风险概率评估显示,儿童暴露于Cr、Ni、Zn和Mn的非致癌风险(THI = 1.90)和致癌风险(TCRI = 4.51 × 10−4)升高,而成人暴露于Cr、Ni、Zn和Mn的风险较低(THI = 0.26; TCRI = 5.02 × 10−5)。这些发现突出表明,需要持续监测、有针对性的缓解和管理措施,以控制路边土壤中的重金属污染,并保护弱势群体,特别是儿童。
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引用次数: 0
Synergistic stability appraisal of engineered slopes along NH-7 in the lesser Himalaya using multiparametric empirical indices 基于多参数经验指标的小喜马拉雅NH-7沿线工程边坡协同稳定性评价
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-09 DOI: 10.1016/j.pce.2026.104268
Tarique Zafeer, Tariq Siddique, Harsh Varshney, Atif Ahamad, Pirzada Mohammad Haris, Md Erfan Ali Mondal
Slope instability along engineered slopes in the Himalaya is one of the major concerns for stakeholders. The present research delves into slope stability appraisal along a strategic and critical segment of National Highway 7 (NH-7) in Uttarakhand. The evaluation employs a synergistic geotechnical appraisal using kinematic analysis, Hazard Index (HI) and Continuous Slope Mass Rating (CoSMR). Fifteen slopes prone to failure were examined by determining the pertinent input geotechnical parameters. Kinematic analysis was applied to define the failure, which indicated that six slopes are prone to planar sliding, four are vulnerable to wedge sliding and five may offer toppling failures. Stability assessments incorporated the Factor of Safety (FoS) from kinematic principles and triggering factors to calculate HI. According to the geotechnical assessment, the FoS values for investigated slopes range from 0.17 to 2.82, whereas the CoSMR values range between 25 and 77, which corresponds to unstable to stable and the HI score varies from 1 to 8.8 and which corresponds to good to very poor slope conditions. Comparative analysis of HI and CoSMR for structurally controlled slopes demonstrates a strong correlation (R2 = 0.9), highlighting the synergistic control of rock mass quality, structural orientation and external triggers on stability of cut slopes. These findings provide a rapid and cost-effective framework for slope stability assessment, enabling identification and prioritisation of critical road-cut slopes and guiding slope-specific mitigation measures. This multiple rock mass classification (RMC) approach lays a foundation for future advanced numerical simulation studies to quantify the failure mechanism.
喜马拉雅地区工程边坡的边坡失稳是利益相关者关注的主要问题之一。本文研究了北阿坎德邦7号国道(NH-7)战略关键路段的边坡稳定性评价。该评价采用了运动学分析、危险指数(HI)和连续边坡质量等级(CoSMR)的协同岩土工程评价方法。通过确定相关的输入岩土参数,对15个容易破坏的斜坡进行了检查。运动学分析表明,6个边坡易发生平面滑动,4个边坡易发生楔形滑动,5个边坡易发生倾倒破坏。稳定性评估结合了运动学原理和触发因素的安全系数(FoS)来计算HI。根据岩土工程评价,所调查边坡的FoS值在0.17 ~ 2.82之间,CoSMR值在25 ~ 77之间,对应于不稳定到稳定,HI值在1 ~ 8.8之间,对应于良好到极差的边坡状况。构造控制边坡的HI和CoSMR对比分析显示,两者具有较强的相关性(R2 = 0.9),突出了岩体质量、构造取向和外部触发因素对切堑边坡稳定性的协同控制。这些研究结果为边坡稳定性评估提供了一个快速和具有成本效益的框架,使其能够识别和确定关键路堑边坡的优先次序,并指导针对特定边坡的缓解措施。这种多重岩体分类(RMC)方法为未来进一步的数值模拟研究奠定了基础,从而量化破坏机制。
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引用次数: 0
Temporal evolution and dominant drivers of groundwater sulfate in China 中国地下水硫酸盐的时间演变及其主导因素
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-09 DOI: 10.1016/j.pce.2026.104297
Qing Zhou , Ke Xing , Jun Zhang , Yijun Yao
China's groundwater is facing a significant threat from sulfate pollution. Here we analyzed 2804 regional surveys of groundwater sulfate levels in China from 1990 to 2020, examining distribution, trends, and drivers. This study identifies a sustained rise in sulfate, with median concentrations increasing from 53.7 mg/L in 1990 to 137.3 mg/L in 2020. A stark contrast is observed between regions: levels are generally higher in northern and northwestern China than in the south and southeast; nationally, 24.2 % of counties exceed the Chinese standard of 250 mg/L and 12.0 % exceed the threshold of 500 mg/L, whereas about 64.4 % remain at or below 150 mg/L. From 1990 to 2020, non-ferrous metal mining emerged as the dominant driver of changes in groundwater sulfate concentrations, with additional contributions from coal consumption and industrial discharges; domestic sources show a gradual rise, while agriculture acts as a diffuse but smaller contributor. This analysis underscores the need for region-specific policies and interventions—particularly in northern and northwestern provinces—to curb sulfate inputs, strengthen wastewater management in urbanizing areas, and protect vulnerable shallow aquifers.
中国的地下水正面临硫酸盐污染的严重威胁。在这里,我们分析了1990年至2020年中国地下水硫酸盐水平的2804个区域调查,研究了分布、趋势和驱动因素。该研究确定了硫酸盐的持续上升,中位数浓度从1990年的53.7 mg/L增加到2020年的137.3 mg/L。不同地区之间存在明显的对比:中国北部和西北部的水平普遍高于南部和东南部;在全国范围内,24.2%的县超过了250 mg/L的国家标准,12.0%的县超过了500 mg/L的国家标准,64.4%的县在150 mg/L以下。从1990年到2020年,有色金属开采成为地下水硫酸盐浓度变化的主要驱动因素,煤炭消费和工业排放也有额外的贡献;国内来源显示逐渐上升,而农业是一个分散但较小的贡献。这一分析强调了有必要制定针对具体地区的政策和干预措施,特别是在北部和西北部省份,以遏制硫酸盐的投入,加强城市化地区的废水管理,并保护脆弱的浅层含水层。
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引用次数: 0
Integrated source apportionment, risk assessment, and probabilistic modeling of potentially toxic elements in soils from an undeveloped metallogenic region, northwest China 西北欠发达成矿区土壤中潜在有毒元素的综合来源分配、风险评估和概率模型
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-08 DOI: 10.1016/j.pce.2026.104288
Qiong Han , Wenfeng Wang , Tongyang Zhao , Liuyuan Jin , Yangshuang Wang , Shiming Yang , Yunhui Zhang
While risk zones of potentially toxic elements (PTEs) are generally associated with intensive anthropogenic disturbances, undeveloped metallogenic regions (UMRs) feature naturally high PTE concentrations that have received limited scientific attention. To fill this gap, this study investigated the sources and quantified the contributions of PTEs in the soils of a UMR in Northwest China, while assessing their associated ecological-health risks. A total of 480 soil samples were collected for analysis. A multi-method framework combining geochemical baseline values (GBVs), Positive Matrix Factorization (PMF), integrated pollution indices, and probabilistic health risk modeling was established. The results revealed that Mercury (Hg) exhibited the highest exceedance rate (13.33 %) compared with other PTEs. PTEs were predominantly derived from natural sources: soil parent material (61.91 %), Pb enrichment (22.98 %), Cu mineralization (10.50 %), and hydrothermal processes (4.61 %), suggesting a primarily geogenic origin. Ecological risk assessment identified Hg as the main contributor to ecological risk. Overall, soil quality in the study area ranged from unpolluted to slightly polluted, with localized high-risk zones mainly distributed in the eastern region. Health risk assessment showed that chromium (Cr) and cobalt (Co) were the major contributors to non-carcinogenic risk, while Cr dominated the carcinogenic risk. Notably, 49.32 % of the samples posed unacceptable non-carcinogenic risks to children, 10.01 % and 0.90 % posed unacceptable carcinogenic risks to children and adults, respectively. These results highlighted that natural metallogenic processes alone could generate unacceptable risks to ecological systems and vulnerable populations. Based on these findings, long-term monitoring of Cr, Co, and Hg in soils near PTE-enriched areas is recommended to mitigate potential ecological and health threats. The study results can provide a scientific basis for the management of soil PTEs in high-background metallogenic regions worldwide.
虽然潜在有毒元素(PTE)的危险区通常与强烈的人为干扰有关,但未开发的成矿区(UMRs)具有天然的高PTE浓度,但受到的科学关注有限。为了填补这一空白,本研究调查了中国西北一个UMR土壤中pte的来源并量化了其贡献,同时评估了其相关的生态健康风险。共收集了480份土壤样本进行分析。建立了地球化学基线值(GBVs)、正矩阵分解(PMF)、综合污染指数和概率健康风险建模相结合的多方法框架。结果表明,汞(Hg)的超标率最高,为13.33%。pte主要来源于土壤母质(61.91%)、Pb富集(22.98%)、Cu矿化(10.50%)和热液作用(4.61%),以地成因为主。生态风险评价认为汞是生态风险的主要因素。总体而言,研究区土壤质量从未污染到轻度污染,局部高危区主要分布在东部地区。健康风险评价结果显示,铬(Cr)和钴(Co)是造成非致癌性风险的主要因素,而铬(Cr)是致癌风险的主要因素。值得注意的是,49.32%的样品对儿童具有不可接受的非致癌风险,10.01%和0.90%的样品对儿童和成人具有不可接受的致癌风险。这些结果表明,自然成矿过程本身可能对生态系统和脆弱人群产生不可接受的风险。基于这些发现,建议对pte富集地区附近土壤中的Cr、Co和Hg进行长期监测,以减轻潜在的生态和健康威胁。研究结果可为全球高背景成矿地区土壤pte的管理提供科学依据。
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引用次数: 0
Estimating reference evapotranspiration in data-scarce regions: Comparative analysis and calibration of empirical models against the Penman-Monteith method in Malawi 估算数据稀缺地区的参考蒸散量:马拉维Penman-Monteith方法对经验模型的比较分析和校准
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-08 DOI: 10.1016/j.pce.2026.104269
Patsani Gregory Kumambala , Lenard Kumwenda , Deogratias M.M. Mulungu , Sheila Kavwenje
Accurate estimation of reference evapotranspiration (ET0) is vital for irrigation planning and hydrological modelling yet remains challenging in data-scarce regions such as Malawi. This study evaluated three empirical ET0 models—the Hargreaves–Samani (HS), Priestley–Taylor (PT), and Turc methods—against the FAO-56 Penman–Monteith (PM) standard across six meteorological stations representing Malawi's major agro-climatic zones. Daily temperature, humidity, wind speed, and sunshine data were obtained from the Department of Climate Change and Meteorological Services in Malawi and aggregated to monthly scales. Linear regression calibration aligned empirical estimates with FAO-56 p.m. values, while the F-test and Jarque–Bera test assessed statistical significance and residual normality. Results show that radiation-based models outperformed the temperature-based HS method. The calibrated Turc model achieved the highest accuracy (R2 = 0.79–0.94), followed by PT (R2 = 0.55–0.95), whereas HS showed lower accuracy (R2 = 0.40–0.74) and strong sensitivity to wind speed. Model performance declined from humid highlands to arid lakeshore regions, highlighting the influence of aerodynamic factors. Overall, the calibrated Turc and Priestley–Taylor models provide robust, low-data alternatives to FAO-56 p.m., particularly in humid and moderate-wind environments. These findings offer practical tools for irrigation management, drought monitoring, and water-resource assessment in Malawi and similar tropical data-limited settings.
准确估算参考蒸散量(ET0)对于灌溉规划和水文建模至关重要,但在马拉维等数据匮乏的地区仍然具有挑战性。本研究针对代表马拉维主要农业气候带的六个气象站的FAO-56 Penman-Monteith (PM)标准,评估了三种经验性ET0模型——Hargreaves-Samani (HS)、Priestley-Taylor (PT)和Turc方法。每天的温度、湿度、风速和日照数据是从马拉维气候变化和气象服务部获得的,并按月汇总。线性回归校准使经验估计值与FAO-56 pm值一致,而f检验和Jarque-Bera检验评估了统计显著性和剩余正态性。结果表明,基于辐射的模型优于基于温度的HS方法。校正后的Turc模型精度最高(R2 = 0.79 ~ 0.94), PT模型次之(R2 = 0.55 ~ 0.95), HS模型精度较低(R2 = 0.40 ~ 0.74),对风速的敏感性较强。从湿润高地到干旱湖滨地区,模型性能下降,突出了空气动力因素的影响。总体而言,经过校准的Turc和Priestley-Taylor模型为FAO-56 p.m.提供了可靠的低数据替代方案,特别是在潮湿和中风环境中。这些发现为马拉维和类似热带数据有限地区的灌溉管理、干旱监测和水资源评估提供了实用工具。
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引用次数: 0
Thermo-mechanical response of Sakesar limestone under cyclic steam injection: Insights from the Potwar Basin, Pakistan 循环注蒸汽作用下Sakesar石灰岩热力学响应:来自巴基斯坦Potwar盆地的启示
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-08 DOI: 10.1016/j.pce.2026.104285
Syed Bilawal Ali Shah
Thermal enhanced oil recovery (EOR) is an effective method for extending production from mature fractured carbonate reservoirs. This study examines the thermo-mechanical behavior of the Eocene Sakesar Formation in the Balkassar Oil Field, Potwar Basin, Pakistan, under cyclic steam stimulation (CSS) conditions representative of near-wellbore operations. An integrated experimental and numerical approach was employed, including uniaxial compressive and Brazilian tensile strength tests, joint shear tests, permeability measurements, micro-computed tomography (micro-CT), and coupled thermo-hydro-mechanical (THM) modeling. Limestone cores were subjected to ten heating–cooling cycles between 25 °C and 180 °C, with properties assessed after each cycle. Results show progressive, non-linear mechanical degradation, with uniaxial compressive strength decreasing from 47.5 MPa to 31.5 MPa and Young's modulus from 22.4 GPa to 16.7 GPa. In contrast, permeability increased irreversibly from 28 mD to 56 mD. Micro-CT analysis indicates that permeability enhancement is governed mainly by fracture network connectivity and coalescence rather than aperture enlargement alone, despite mean fracture aperture increasing from 0.15 mm to 0.39 mm. THM simulations reveal significant near-wellbore thermal stress redistribution and identify a high slip-tendency zone within ∼10 m of the wellbore during heating, suggesting potential shear reactivation of pre-existing fractures. These findings highlight the dual impact of cyclic thermal stimulation: improved injectivity through fracture connectivity evolution and increased geomechanical risk related to fracture reactivation and wellbore stability in compressional settings. This integrated framework supports safer and more efficient thermal EOR design for the Balkassar Oil Field and similar fractured carbonate reservoirs.
热采是成熟裂缝性碳酸盐岩油藏增产的有效手段。本研究考察了巴基斯坦Potwar盆地Balkassar油田始新世Sakesar组在循环蒸汽增产(CSS)条件下近井作业的热力学行为。采用了综合实验和数值方法,包括单轴压缩和巴西拉伸强度测试、节理剪切测试、渗透率测量、微计算机断层扫描(micro-CT)和热-水-力学耦合(THM)建模。石灰石岩心在25°C和180°C之间进行了10次加热-冷却循环,每次循环后评估其性能。结果表明:试件的单轴抗压强度从47.5 MPa降至31.5 MPa,杨氏模量从22.4 GPa降至16.7 GPa;相比之下,渗透率从28 mD不可逆地增加到56 mD。Micro-CT分析表明,尽管平均裂缝孔径从0.15 mm增加到0.39 mm,但渗透率的增加主要是由裂缝网络的连通性和聚结决定的,而不仅仅是裂缝孔径的扩大。THM模拟显示了显著的近井热应力重分布,并在加热过程中在距井筒约10米的范围内发现了一个高滑移倾向区,这表明存在裂缝的潜在剪切重新激活。这些发现强调了循环热增产的双重影响:通过裂缝连通性的演变提高了注入能力,同时增加了与裂缝再激活和井筒稳定性相关的地质力学风险。该集成框架为Balkassar油田和类似的裂缝性碳酸盐岩油藏提供了更安全、更高效的热驱设计。
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引用次数: 0
Hydrolytic pretreatment strategies of brewery mashing wastewater for improved succinic acid production 提高琥珀酸产量的啤酒醪废水水解预处理策略
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-08 DOI: 10.1016/j.pce.2026.104290
Haidong Zhu, Dafang Fu, Yixin Yan, Rajendra Prasad Singh
Brewery mashing wastewater (BMW), rich in oligosaccharides and organic matter, was evaluated as a low-cost substrate for succinic acid (SA) production by Actinobacillus succinogenes. To enhance fermentability, BMW pretreatment was conducted in acid, alkaline, and enzymatic conditions, and their effects on sugar release, inhibitor formation, and fermentation performance were systematically compared. Pectinase hydrolysis (PH) proved most effective, releasing 26.47 g/L glucose and simultaneously minimizing inhibitor accumulation. Fermentation with pectinase hydrolysates achieved an SA titer of 16.19 g/L and a yield of 0.61 g SA/g glucose, exceeding reported values for food-waste hydrolysates (0.43 g SA/g glucose) and approaching yields typically obtained with refined substrates. In contrast, acid and alkaline hydrolysis generated high levels of furanic inhibitors, impairing glucose utilization and limiting SA titers (<1.40 and < 1.61 g/L, respectively). α-Amylase hydrolysis exhibited moderate saccharification efficiency, and glucose supplementation was required to achieve yields comparable to PH. These results highlight that pretreatment choice is pivotal in shaping fermentation outcomes by balancing sugar accessibility against inhibitor toxicity. Enzymatic hydrolysis, particularly PH, offers a scalable and environmentally friendly path to convert BMW into platform chemicals. This study provides both mechanistic insights and practical evidence supporting the integration of BMW into circular bioeconomy strategies.
研究了啤酒醪液(BMW)作为琥珀酸放线菌(Actinobacillus succinogenes)生产琥珀酸(SA)的低成本底物。为了提高发酵性能,对BMW进行了酸、碱、酶三种条件下的预处理,系统比较了三种条件对糖释放、抑制剂形成和发酵性能的影响。果胶酶水解(PH)被证明是最有效的,释放26.47 g/L葡萄糖,同时最小化抑制剂的积累。果胶酶水解物发酵获得的SA滴度为16.19 g/L,产量为0.61 g SA/g葡萄糖,超过了报道的食物垃圾水解物的值(0.43 g SA/g葡萄糖),接近精制底物通常获得的产量。相比之下,酸和碱水解产生高水平的呋喃抑制剂,损害葡萄糖利用和限制SA滴度(分别为1.40和1.61 g/L)。α-淀粉酶水解表现出中等的糖化效率,需要添加葡萄糖才能达到与ph相当的产率。这些结果表明,通过平衡糖的可及性和抑制剂的毒性,预处理的选择是决定发酵结果的关键。酶水解,特别是PH,提供了一种可扩展和环保的途径,将宝马转化为平台化学品。本研究为宝马融入循环生物经济战略提供了机制见解和实践证据。
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引用次数: 0
Robust monthly precipitation forecasts using VMD-decomposed hybrid LSSVM–BiLSTM model optimized by Harris Hawks algorithm 基于Harris Hawks算法优化的vmd分解混合LSSVM-BiLSTM模型的稳健月降水预报
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-29 DOI: 10.1016/j.pce.2025.104257
Behnoush Farokhzadeh , Sepideh Choobeh , Rasool Imani
Accurate prediction of monthly precipitation is crucial for sustainable water resources management in climate-sensitive regions such as the Urmia Lake Basin, northwestern Iran. This study proposes an optimized hybrid forecasting framework integrating Variational Mode Decomposition (VMD), Least Squares Support Vector Machine (LSSVM), Bidirectional Long Short-Term Memory (BiLSTM) networks, and the Harris Hawks Optimization (HHO) algorithm. The normalized monthly precipitation series (1980–2024) was decomposed into five Intrinsic Mode Functions (IMFs) and a residual component using VMD. LSSVM was applied to model the high- and medium-frequency IMFs, while BiLSTM captured the long-term residual trend. The HHO algorithm was employed to optimize model hyperparameters, minimizing reconstruction and prediction errors. Model evaluation revealed outstanding predictive performance, with Nash–Sutcliffe Efficiency (NSE) exceeding 0.97 and Root Mean Square Error (RMSE) below 1.6 mm across both training and testing phases, and strong correlation between observed and simulated rainfall. Bootstrap-based uncertainty analysis confirmed the model's stability and reliability. The optimized hybrid model was further applied to project monthly precipitation for 2030–2050, indicating an approximate 7 % increase in mean annual rainfall relative to the historical average (1980–2024). These results demonstrate that the VMD–HHO–LSSVM–BiLSTM hybrid framework effectively captures nonlinear, nonstationary rainfall dynamics across multiple temporal scales and provides a robust tool for hydrological forecasting and adaptive water management in the Urmia Lake Basin.
月降水量的准确预测对于气候敏感地区(如伊朗西北部的乌尔米亚湖盆地)的可持续水资源管理至关重要。本文提出了一种结合变分模态分解(VMD)、最小二乘支持向量机(LSSVM)、双向长短期记忆(BiLSTM)网络和哈里斯鹰优化(HHO)算法的优化混合预测框架。将逐月降水序列(1980—2024)归一化,利用VMD分解为5个本征模态函数(IMFs)和1个残差分量。LSSVM用于高频和中频IMFs的建模,而BiLSTM捕获了长期残差趋势。采用HHO算法优化模型超参数,使重建和预测误差最小化。模型的预测效果非常好,在训练和测试阶段,Nash-Sutcliffe效率(NSE)均超过0.97,均方根误差(RMSE)均低于1.6 mm,且观测值与模拟值之间具有很强的相关性。基于bootstrap的不确定性分析验证了模型的稳定性和可靠性。将优化后的混合模型进一步应用于2030-2050年的月降水量预测,结果表明,相对于1980-2024年的历史平均值,年平均降雨量增加了约7%。这些结果表明,VMD-HHO-LSSVM-BiLSTM混合框架可以有效地捕获跨时间尺度的非线性、非平稳降雨动态,为乌尔米亚湖流域的水文预报和适应性水管理提供了强有力的工具。
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引用次数: 0
Designing landslide mitigation strategies through developing knowledge aware deep learning model integrated explainable artificial intelligence 通过开发集成可解释人工智能的知识感知深度学习模型设计滑坡缓解策略
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-27 DOI: 10.1016/j.pce.2025.104266
Inzamam Ul Haq , Habibullah , Shafiq Ahmed , Swapan Talukdar , Mansoor Ahmad , Md Sarfaraz Asgher , Imran Khan , G.V. Ramana
Landslides are a recurrent and damaging hazard in the Pir Panjal Range of Jammu and Kashmir, India, where steep slopes, fragile lithology and rapid human interventions coincide. This study develops an integrated landslide susceptibility mapping framework that combines machine learning (ML), deep learning (DL) and explainable artificial intelligence (XAI) to support risk-informed planning. An inventory of 1105 landslides and eighteen conditioning factors trains four ML models: Random Forest (RF), Support Vector Machine (SVM), Gradient Boosting Machine (GBM) and Categorical Boosting (CatBoost), evaluated with five-fold stratified cross-validation and a held-out test set. In parallel, a Bayesian-optimised DL model, in which a Variational Autoencoder (VAE) learns latent features that are classified by a Multilayer Perceptron (MLP), captures complex non-linear controls on slope failure. The best performing models achieve an area under the receiver operating characteristic curve (AUC-ROC) of about 0.96 and overall accuracy close to 0.90 on validation data, indicating high discriminatory skill. Spatially, High and Very High susceptibility zones together occupy roughly one quarter of the range and are concentrated in tehsils such as Gool Gulabgarh, Ramban, Thathri and Banihal, which emerge as hotspots for intervention. XAI diagnostics highlight vegetation condition, monsoon rainfall, lineament density and drainage density as dominant controls on susceptibility, while counterfactual experiments show that realistic improvements in vegetation cover, surface drainage and slope management can shift many locations from high to lower risk classes. The framework therefore provides accurate, interpretable and useful susceptibility maps for land-use regulation, infrastructure planning and landslide mitigation in data-constrained mountain environments.
在印度查谟和克什米尔的Pir Panjal山脉,陡峭的山坡、脆弱的岩性和快速的人为干预同时发生,山体滑坡是一个经常性的破坏性灾害。本研究开发了一个集成的滑坡易感性测绘框架,该框架结合了机器学习(ML)、深度学习(DL)和可解释的人工智能(XAI),以支持风险知情规划。1105个滑坡和18个调节因素的清单训练了四种ML模型:随机森林(RF)、支持向量机(SVM)、梯度增强机(GBM)和分类增强(CatBoost),并通过五倍分层交叉验证和持续测试集进行评估。与此同时,贝叶斯优化DL模型,其中变分自编码器(VAE)学习由多层感知器(MLP)分类的潜在特征,捕获斜坡破坏的复杂非线性控制。表现最好的模型在验证数据上的受试者工作特征曲线下面积(AUC-ROC)约为0.96,总体准确率接近0.90,表明具有较高的区分能力。在空间上,高易感区和极高易感区共同占据了大约四分之一的范围,集中在古尔古拉加尔、拉姆班、塔特里和巴尼哈尔等地区,这些地区成为干预的热点。XAI诊断强调植被条件、季风降雨、地形密度和排水密度是影响易感性的主要控制因素,而反事实实验表明,在植被覆盖、地表排水和斜坡管理方面的现实改进可以将许多地点从高风险等级转移到低风险等级。因此,该框架为数据有限的山地环境中的土地使用管制、基础设施规划和滑坡缓解提供了准确、可解释和有用的易感性地图。
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Physics and Chemistry of the Earth
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