Chemical-enhanced electrokinetic geosynthetics (EKG) electro-osmosis combined with vacuum preloading was employed to simultaneously consolidate and remediate copper-contaminated dredged sludge. Five chemical additives—citric acid, tartaric acid, hydrogen peroxide, rhamnolipids, and sodium chloride—were systematically evaluated via model tests. Results show that all additives improve both drainage and copper removal, with sodium chloride exhibited the enhancement in dewatering performance, while rhamnolipid achieved the highest copper removal efficiencies. Mechanistic analysis revealed that chemical additives improved sludge dewatering by enhancing pore water migration—through modifying soil structure, increasing ionic conductivity, or reducing surface tension. They also promoted copper removal by altering speciation: acidic chelating agents reduced pH and stabilized Cu2+ in soluble complexes, suppressing precipitation, while in near-neutral conditions, cathodic OH− dissolved Cu(OH)2 into mobile species, facilitating transport. Energy analysis confirmed that chemical-enhanced systems improved the energy efficiency of copper removal. These findings support the integrated use of EKG electro-osmosis combined with vacuum preloading, coupled with appropriate chemical agents, as a viable and energy-efficient strategy for the remediation of heavy metal-contaminated dredged sludge.
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