首页 > 最新文献

Defence Technology(防务技术)最新文献

英文 中文
Crack propagation and damage evolution of metallic cylindrical shells under internal explosive loading 内部爆炸加载下金属圆柱壳的裂纹扩展和损伤演化
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.04.010

This paper investigates the three-dimensional crack propagation and damage evolution process of metallic column shells under internal explosive loading. The calibration of four typical failure parameters for 40CrMnSiB steel was conducted through experiments and subsequently applied to simulations. The numerical simulation results employing the four failure criteria were compared with the differences and similarities observed in freeze-recovery tests and ultra-high-speed tests. This analysis addressed the critical issue of determining failure criteria for the fracture of a metal shell under internal explosive loads. Building upon this foundation, the damage parameter Dc, linked to the cumulative crack density, was defined based on the evolution characteristics of a substantial number of cracks. The relationship between the damage parameter and crack velocity over time was established, and the influence of the internal central pressure on the damage parameter and crack velocity was investigated. Variations in the fracture modes were found under different failure criteria, with the principal strain failure criterion proving to be the most effective for simulating 3D crack propagation in a pure shear fracture mode. Through statistical analysis of the shell penetration fracture radius data, it was determined that the fracture radius remained essentially constant during the crack evolution process and could be considered a constant. The propagation velocity of axial cracks ranged between 5300 m/s and 12600 m/s, surpassing the Rayleigh wave velocity of the shell material and decreasing linearly with time. The increase in shell damage exhibited an initial rapid phase, followed by deceleration, demonstrating accelerated damage during the propagation stage of the blast wave and decelerated damage after the arrival of the rarefaction wave. This study provides an effective approach for investigating crack propagation and damage evolution. The derived crack propagation and damage evolution law serves as a valuable reference for the development of crack velocity theory and the construction of shell damage evolution modes.

本文研究了金属柱壳在内部爆炸荷载作用下的三维裂纹扩展和损伤演化过程。通过实验校准了 40CrMnSiB 钢的四个典型失效参数,并将其应用于模拟。采用四种失效标准的数值模拟结果与在冻结恢复试验和超高速试验中观察到的异同进行了比较。这项分析解决了确定金属壳体在内部爆炸载荷作用下断裂的失效标准这一关键问题。在此基础上,根据大量裂纹的演变特征,定义了与累积裂纹密度相关的损伤参数 Dc。建立了损伤参数与裂纹速度随时间变化的关系,并研究了内部中心压力对损伤参数和裂纹速度的影响。在不同的破坏准则下,发现了断裂模式的变化,其中主应变破坏准则被证明是模拟纯剪切断裂模式下三维裂纹扩展的最有效准则。通过对穿壳断裂半径数据进行统计分析,确定在裂纹演变过程中断裂半径基本保持不变,可视为一个常数。轴向裂纹的传播速度介于 5300 米/秒和 12600 米/秒之间,超过了壳体材料的瑞利波速度,并随时间呈线性下降。壳体损伤的增加表现为最初的快速阶段,随后是减速阶段,显示出在爆炸波传播阶段的加速损伤和稀释波到达后的减速损伤。这项研究为研究裂纹扩展和损伤演变提供了一种有效方法。推导出的裂纹扩展和损伤演化规律对裂纹速度理论的发展和壳体损伤演化模式的构建具有重要的参考价值。
{"title":"Crack propagation and damage evolution of metallic cylindrical shells under internal explosive loading","authors":"","doi":"10.1016/j.dt.2024.04.010","DOIUrl":"10.1016/j.dt.2024.04.010","url":null,"abstract":"<div><p>This paper investigates the three-dimensional crack propagation and damage evolution process of metallic column shells under internal explosive loading. The calibration of four typical failure parameters for 40CrMnSiB steel was conducted through experiments and subsequently applied to simulations. The numerical simulation results employing the four failure criteria were compared with the differences and similarities observed in freeze-recovery tests and ultra-high-speed tests. This analysis addressed the critical issue of determining failure criteria for the fracture of a metal shell under internal explosive loads. Building upon this foundation, the damage parameter <em>D</em><sub>c</sub>, linked to the cumulative crack density, was defined based on the evolution characteristics of a substantial number of cracks. The relationship between the damage parameter and crack velocity over time was established, and the influence of the internal central pressure on the damage parameter and crack velocity was investigated. Variations in the fracture modes were found under different failure criteria, with the principal strain failure criterion proving to be the most effective for simulating 3D crack propagation in a pure shear fracture mode. Through statistical analysis of the shell penetration fracture radius data, it was determined that the fracture radius remained essentially constant during the crack evolution process and could be considered a constant. The propagation velocity of axial cracks ranged between 5300 m/s and 12600 m/s, surpassing the Rayleigh wave velocity of the shell material and decreasing linearly with time. The increase in shell damage exhibited an initial rapid phase, followed by deceleration, demonstrating accelerated damage during the propagation stage of the blast wave and decelerated damage after the arrival of the rarefaction wave. This study provides an effective approach for investigating crack propagation and damage evolution. The derived crack propagation and damage evolution law serves as a valuable reference for the development of crack velocity theory and the construction of shell damage evolution modes.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 133-146"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000874/pdfft?md5=994444dc66899b46e232f65060c5f50d&pid=1-s2.0-S2214914724000874-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140790610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of radiation effects on solder alloys and solder joints 全面回顾辐射对焊料合金和焊点的影响
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.02.007

In the realm of military and defence applications, exposure to radiation significantly challenges the performance and reliability of solder alloys and joints in electronic systems. This comprehensive review examines radiation-induced effects on solder alloys and solder joints in terms of microstructure and mechanical properties. In this paper, we evaluate the existing literature, including experimental studies and fundamental theory, to provide a comprehensive overview of the behavior of solder materials under radiation. A review of the literature highlights key mechanisms that contribute to radiation-induced changes in the microstructure, such as the formation of intermetallic compounds, grain growth, micro-voids and micro-cracks. Radiation is explored as a factor influencing solder alloy hardness, strength, fatigue and ductility. Moreover, the review addresses the challenges and limitations inherent in studying the effects of radiation on solder materials and offers recommendations for future research. It is crucial to understand radiation-induced effects on solder performance to design robust and radiation-resistant electronic systems. A review of radiation effects on solder materials and their applications in electronics serves as a valuable resource for researchers, engineers, and practitioners in that field.

在军事和国防应用领域,辐照对电子系统中焊料合金和焊点的性能和可靠性提出了重大挑战。本综述从微观结构和机械性能的角度研究了辐射对焊料合金和焊点的影响。在本文中,我们对包括实验研究和基础理论在内的现有文献进行了评估,以全面概述焊接材料在辐射下的行为。文献综述强调了导致辐射引起的微观结构变化的关键机制,如金属间化合物的形成、晶粒生长、微空洞和微裂纹。研究还探讨了辐照对焊料合金硬度、强度、疲劳和延展性的影响。此外,该综述还探讨了研究辐射对焊料的影响所固有的挑战和局限性,并为今后的研究提出了建议。了解辐射对焊料性能的影响对于设计坚固耐用的抗辐射电子系统至关重要。关于辐射对焊接材料的影响及其在电子产品中的应用的综述是该领域研究人员、工程师和从业人员的宝贵资源。
{"title":"A comprehensive review of radiation effects on solder alloys and solder joints","authors":"","doi":"10.1016/j.dt.2024.02.007","DOIUrl":"10.1016/j.dt.2024.02.007","url":null,"abstract":"<div><p>In the realm of military and defence applications, exposure to radiation significantly challenges the performance and reliability of solder alloys and joints in electronic systems. This comprehensive review examines radiation-induced effects on solder alloys and solder joints in terms of microstructure and mechanical properties. In this paper, we evaluate the existing literature, including experimental studies and fundamental theory, to provide a comprehensive overview of the behavior of solder materials under radiation. A review of the literature highlights key mechanisms that contribute to radiation-induced changes in the microstructure, such as the formation of intermetallic compounds, grain growth, micro-voids and micro-cracks. Radiation is explored as a factor influencing solder alloy hardness, strength, fatigue and ductility. Moreover, the review addresses the challenges and limitations inherent in studying the effects of radiation on solder materials and offers recommendations for future research. It is crucial to understand radiation-induced effects on solder performance to design robust and radiation-resistant electronic systems. A review of radiation effects on solder materials and their applications in electronics serves as a valuable resource for researchers, engineers, and practitioners in that field.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 86-102"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000394/pdfft?md5=032bcb45039a7725fd8dead1fb1a9338&pid=1-s2.0-S2214914724000394-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140324526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical study of effecting core configurations on the static and dynamic behavior of honeycomb plate with aluminum material 芯型对铝蜂窝板静动力性能影响的实验与数值研究
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2023.11.016

The sandwich panel incorporated a honeycomb core, a widely utilized composite structure recognized as a fundamental classification of composite materials. Comprised a core resembling a honeycomb, possessing thickness and softness, and is flank by rigid face sheets that sandwich various shapes and materials. This paper presents an examination of the static and dynamic analysis of lightweight plates made of aluminum honeycomb sandwich composites. Honeycomb sandwich plate samples are 300 mm long, and 300 mm wide, the heights of the core have been varied at four values ranging from 10 to 25 mm. The honeycomb core is manufactured from Aluminum material by using a novel technique namely resistance spot welding (RSW) instead of using adhesive material, which is often used when an industrial flaw is detected. Numerical optimization based on response surface methodology (RSM) and design of experiment software (DOE) was used to verify the current work. A theoretical examination of the crashworthiness behavior (maximum bending load, maximum deflection) and vibration attributes (natural frequency, damping ratio, transient temporal response) of honeycomb sandwich panels with different design parameters was also carried out. In addition, the finite element method-based ANSYS software was used to confirm the theoretical conclusions. The findings of the present work showed that the relationship between the natural frequency, core height, and cell size is direct. In contrast, the relationship between the natural frequency and the thickness of the cell wall is inverse. Conversely, the damping ratio is inversely proportional to the core height and cell size but directly proportional to the thickness of the cell wall. The study indicates that altering the core height within 10–25 mm leads to a significant increase of 82 % in the natural frequency and a notable decrease of 49 % in the damping ratio. These findings are based on a specific cell size value of 0.01 m and a cell wall thickness of 0.001 m. Also, the results indicate that for a given set of cell wall thickness and size values, an increase in core height from (0.01–0.025) m, leads to a reduction of the percentage of maximum response approximately 76 %. Conversely, the increasing thickness of the wall of cell wall, ranging 0.3–0.7 mm with a constant core height equal to 0.015 m, resulted in a de crease of maximum transient response by 7.8 %.

夹芯板采用蜂窝芯,这是一种广泛使用的复合材料结构,被认为是复合材料的基本分类。由一个类似蜂窝的核心组成,具有厚度和柔软性,并且侧面由刚性面片夹夹各种形状和材料。本文对铝蜂窝夹层复合材料轻量化板进行了静动力分析研究。蜂窝夹芯板样品长300 mm,宽300 mm,高度(10、15、20、25)mm不等。铝蜂窝芯采用电阻点焊(RSW)技术制造,取代了工业缺陷检测中常用的粘结材料。基于响应面法(RSM)的数值优化和实验软件设计(DOE)对现有工作进行了验证。对不同设计参数下蜂窝夹芯板的耐撞性能(最大弯曲载荷、最大挠度)和振动属性(固有频率、阻尼比、瞬态时间响应)进行了理论研究。此外,利用基于有限元法的ANSYS软件对理论结论进行了验证。本工作的发现表明,固有频率,核心高度和细胞大小之间的关系是直接的。相反,固有频率与细胞壁厚度之间的关系是相反的。相反,阻尼比与核心高度和细胞大小成反比,而与细胞壁厚度成正比。研究表明,将岩心高度改变在10 ~ 25 mm范围内,固有频率显著提高82 %,阻尼比显著降低49 %。这些发现是基于特定的细胞尺寸值0.01 m和细胞壁厚度0.001 m。此外,结果表明,对于一组给定的细胞壁厚度和尺寸值,岩心高度从0.01 m增加到0.025 m,导致最大瞬态响应百分比降低约76 %。相反,当芯高为0.015 m时,细胞壁厚度从0.3到0.7 mm增加,最大瞬态响应降低了7.8 %。
{"title":"Experimental and numerical study of effecting core configurations on the static and dynamic behavior of honeycomb plate with aluminum material","authors":"","doi":"10.1016/j.dt.2023.11.016","DOIUrl":"10.1016/j.dt.2023.11.016","url":null,"abstract":"<div><p>The sandwich panel incorporated a honeycomb core, a widely utilized composite structure recognized as a fundamental classification of composite materials. Comprised a core resembling a honeycomb, possessing thickness and softness, and is flank by rigid face sheets that sandwich various shapes and materials. This paper presents an examination of the static and dynamic analysis of lightweight plates made of aluminum honeycomb sandwich composites. Honeycomb sandwich plate samples are 300 mm long, and 300 mm wide, the heights of the core have been varied at four values ranging from 10 to 25 mm. The honeycomb core is manufactured from Aluminum material by using a novel technique namely resistance spot welding (RSW) instead of using adhesive material, which is often used when an industrial flaw is detected. Numerical optimization based on response surface methodology (RSM) and design of experiment software (DOE) was used to verify the current work. A theoretical examination of the crashworthiness behavior (maximum bending load, maximum deflection) and vibration attributes (natural frequency, damping ratio, transient temporal response) of honeycomb sandwich panels with different design parameters was also carried out. In addition, the finite element method-based ANSYS software was used to confirm the theoretical conclusions. The findings of the present work showed that the relationship between the natural frequency, core height, and cell size is direct. In contrast, the relationship between the natural frequency and the thickness of the cell wall is inverse. Conversely, the damping ratio is inversely proportional to the core height and cell size but directly proportional to the thickness of the cell wall. The study indicates that altering the core height within 10–25 mm leads to a significant increase of 82 % in the natural frequency and a notable decrease of 49 % in the damping ratio. These findings are based on a specific cell size value of 0.01 m and a cell wall thickness of 0.001 m. Also, the results indicate that for a given set of cell wall thickness and size values, an increase in core height from (0.01–0.025) m, leads to a reduction of the percentage of maximum response appro<span>x</span>imately 76 %. Conversely, the increasing thickness of the wall of cell wall, ranging 0.3–0.7 mm with a constant core height equal to 0.015 m, resulted in a de crease of maximum transient response by 7.8 %.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 177-192"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914723003045/pdfft?md5=213b78981823726e349044dde7ef07cc&pid=1-s2.0-S2214914723003045-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138520188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Constitutive model of viscoelastic dynamic damage for the material of gas obturator in modular-charge howitzer 模块化装药榴弹炮气体钝器材料粘弹性动态损伤的构成模型
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.05.003

In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism, made of polychloroprene rubber (PCR), uniaxial compression experiments were carried out by using a universal testing machine and a split Hopkinson pressure bar (SHPB), obtaining stress-strain responses at different temperatures and strain rates. The results revealed that, in comparison to other polymers, the gas obturator material exhibited inconspicuous strain softening and hardening effects; meanwhile, the mechanical response was more affected by the strain rate than by temperature. Subsequently, a succinct viscoelastic damage constitutive model was developed based on the ZWT model, including ten undetermined parameters, formulated with incorporating three parallel components to capture the viscoelastic response at high strain rate and further enhanced by integrating a three-parameter Weibull function to describe the damage. Compared to the ZWT model, the modified model could effectively describe the mechanical response behavior of the gas obturator material at high strain rates. This research laid a theoretical foundation for further investigation into the influence of chamber sealing issues on artillery firing.

为了研究由聚氯丁二烯橡胶(PCR)制成的后膛机构气体闭塞器的机械响应行为,使用万能试验机和分体式霍普金森压力棒(SHPB)进行了单轴压缩实验,获得了不同温度和应变速率下的应力-应变响应。结果表明,与其他聚合物相比,气体钝化剂材料表现出不明显的应变软化和硬化效应;同时,机械响应受应变速率的影响比受温度的影响更大。随后,在 ZWT 模型的基础上建立了一个简洁的粘弹性损伤构成模型,该模型包括 10 个未确定的参数,通过加入三个平行分量来捕捉高应变速率下的粘弹性响应,并通过集成一个三参数 Weibull 函数来进一步增强对损伤的描述。与 ZWT 模型相比,改进后的模型能有效地描述气体封堵器材料在高应变速率下的机械响应行为。这项研究为进一步研究炮膛密封问题对火炮发射的影响奠定了理论基础。
{"title":"Constitutive model of viscoelastic dynamic damage for the material of gas obturator in modular-charge howitzer","authors":"","doi":"10.1016/j.dt.2024.05.003","DOIUrl":"10.1016/j.dt.2024.05.003","url":null,"abstract":"<div><p>In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism, made of polychloroprene rubber (PCR), uniaxial compression experiments were carried out by using a universal testing machine and a split Hopkinson pressure bar (SHPB), obtaining stress-strain responses at different temperatures and strain rates. The results revealed that, in comparison to other polymers, the gas obturator material exhibited inconspicuous strain softening and hardening effects; meanwhile, the mechanical response was more affected by the strain rate than by temperature. Subsequently, a succinct viscoelastic damage constitutive model was developed based on the ZWT model, including ten undetermined parameters, formulated with incorporating three parallel components to capture the viscoelastic response at high strain rate and further enhanced by integrating a three-parameter Weibull function to describe the damage. Compared to the ZWT model, the modified model could effectively describe the mechanical response behavior of the gas obturator material at high strain rates. This research laid a theoretical foundation for further investigation into the influence of chamber sealing issues on artillery firing.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 203-216"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724001107/pdfft?md5=2a3b07d1b160c8d9a09aac517a4d0839&pid=1-s2.0-S2214914724001107-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141041050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of system parameters towards safer impact based shock-to-detonation transition in a novel laser driven flyer plate prototype 在新型激光驱动飞碟板原型中研究系统参数,以实现更安全的基于冲击的震荡到爆炸的转变
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.04.003

Laser driven flyer plate technology offers improved safety and reliability for detonation of explosives in industrial applications ranging from mining and stone quarrying to the aerospace and defense industries. This study is based on developing a safer laser driven flyer plate prototype comprised of a laser initiator and a flyer plate subsystem that can be used with secondary explosives. System parameters were optimized to initiate the shock-to-detonation transition (SDT) of a secondary explosive based on the impact created by the flyer plate on the explosive surface. Rupture of the flyer was investigated at the mechanically weakened region located on the interface of these subsystems, where the product gases from the deflagration of the explosive provide the required energy. A bilayer energetic material was used, where the first layer consisted of a pyrotechnic component, zirconium potassium perchlorate (ZPP), for sustaining the ignition by the laser beam and the second layer consisted of an insensitive explosive, cyclotetramethylene-tetranitramine (HMX), for deflagration. A plexiglass interface was used to enfold the energetic material. The focal length of the laser beam from the diode was optimized to provide a homogeneous beam profile with maximum power at the surface of the ZPP. Closed bomb experiments were conducted in an internal volume of 10 cm3 for evaluation of performance. Dependency of the laser driven flyer plate system output on confinement, explosive density, and laser beam power were analyzed. Measurements using a high-speed camera resulted in a flyer velocity of 670 ± 20 m/s that renders the prototype suitable as a laser detonator in applications, where controlled employment of explosives is critical.

激光驱动飞板技术为从采矿、采石到航空航天和国防工业等各种工业应用中的炸药引爆提供了更高的安全性和可靠性。这项研究的基础是开发一种更安全的激光驱动飞板原型,由激光引发器和飞板子系统组成,可与二次炸药一起使用。对系统参数进行了优化,以根据飞板对爆炸物表面产生的冲击力启动二次爆炸的冲击-爆炸转换(SDT)。在位于这些子系统界面上的机械削弱区域研究了飞行器的破裂情况,炸药爆燃产生的产物气体在该区域提供了所需的能量。使用了一种双层高能材料,其中第一层由烟火成分高氯酸锆钾(ZPP)组成,用于维持激光束的点火,第二层由不敏感的炸药环四亚甲基四硝胺(HMX)组成,用于爆燃。有机玻璃界面用于包裹高能材料。对二极管激光束的焦距进行了优化,以便在 ZPP 表面提供具有最大功率的均匀光束轮廓。为评估性能,在 10 厘米的内部容积中进行了封闭式炸弹实验。分析了激光驱动飞板系统的输出对封闭性、爆炸密度和激光束功率的依赖性。使用高速照相机进行测量的结果显示,飞碟速度为 670 ± 20 m/s,这使得原型适合作为激光雷管应用于对炸药使用控制至关重要的场合。
{"title":"Investigation of system parameters towards safer impact based shock-to-detonation transition in a novel laser driven flyer plate prototype","authors":"","doi":"10.1016/j.dt.2024.04.003","DOIUrl":"10.1016/j.dt.2024.04.003","url":null,"abstract":"<div><p>Laser driven flyer plate technology offers improved safety and reliability for detonation of explosives in industrial applications ranging from mining and stone quarrying to the aerospace and defense industries. This study is based on developing a safer laser driven flyer plate prototype comprised of a laser initiator and a flyer plate subsystem that can be used with secondary explosives. System parameters were optimized to initiate the shock-to-detonation transition (SDT) of a secondary explosive based on the impact created by the flyer plate on the explosive surface. Rupture of the flyer was investigated at the mechanically weakened region located on the interface of these subsystems, where the product gases from the deflagration of the explosive provide the required energy. A bilayer energetic material was used, where the first layer consisted of a pyrotechnic component, zirconium potassium perchlorate (ZPP), for sustaining the ignition by the laser beam and the second layer consisted of an insensitive explosive, cyclotetramethylene-tetranitramine (HMX), for deflagration. A plexiglass interface was used to enfold the energetic material. The focal length of the laser beam from the diode was optimized to provide a homogeneous beam profile with maximum power at the surface of the ZPP. Closed bomb experiments were conducted in an internal volume of 10 cm<sup>3</sup> for evaluation of performance. Dependency of the laser driven flyer plate system output on confinement, explosive density, and laser beam power were analyzed. Measurements using a high-speed camera resulted in a flyer velocity of 670 ± 20 m/s that renders the prototype suitable as a laser detonator in applications, where controlled employment of explosives is critical.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 103-113"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000801/pdfft?md5=5287aad3cbe033a27aa057e2f34b7008&pid=1-s2.0-S2214914724000801-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141528358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust fixed-time flight controller for a dual-system convertible UAV in the cruise mode 巡航模式下双系统可转换无人机的稳健固定时间飞行控制器
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.04.009

This paper investigates the attitude tracking control problem for the cruise mode of a dual-system convertible unmanned aerial vehicle (UAV) in the presence of parameter uncertainties, unmodeled uncertainties and wind disturbances. First, a fixed-time disturbance observer (FXDO) based on the bi-limit homogeneity theory is designed to estimate the lumped disturbance of the convertible UAV model. Then, a fixed-time integral sliding mode control (FXISMC) is combined with the FXDO to achieve strong robustness and chattering reduction. Bi-limit homogeneity theory and Lyapunov theory are applied to provide detailed proof of the fixed-time stability. Finally, numerical simulation experimental results verify the robustness of the proposed algorithm to model parameter uncertainties and wind disturbances. In addition, the proposed algorithm is deployed in a open-source UAV autopilot and its effectiveness is further demonstrated by hardware-in-the-loop experimental results.

本文研究了存在参数不确定性、未建模不确定性和风扰动的双系统可转换无人飞行器(UAV)巡航模式的姿态跟踪控制问题。首先,设计了基于双极限同质性理论的定时扰动观测器(FXDO)来估计可转换无人飞行器模型的整块扰动。然后,将定时积分滑模控制(FXISMC)与 FXDO 相结合,以实现较强的鲁棒性和减少颤振。应用双极限同质性理论和 Lyapunov 理论详细证明了定时稳定性。最后,数值模拟实验结果验证了所提算法对模型参数不确定性和风扰动的鲁棒性。此外,还在开源无人机自动驾驶仪中部署了该算法,并通过硬件在环实验结果进一步证明了其有效性。
{"title":"Robust fixed-time flight controller for a dual-system convertible UAV in the cruise mode","authors":"","doi":"10.1016/j.dt.2024.04.009","DOIUrl":"10.1016/j.dt.2024.04.009","url":null,"abstract":"<div><p>This paper investigates the attitude tracking control problem for the cruise mode of a dual-system convertible unmanned aerial vehicle (UAV) in the presence of parameter uncertainties, unmodeled uncertainties and wind disturbances. First, a fixed-time disturbance observer (FXDO) based on the bi-limit homogeneity theory is designed to estimate the lumped disturbance of the convertible UAV model. Then, a fixed-time integral sliding mode control (FXISMC) is combined with the FXDO to achieve strong robustness and chattering reduction. Bi-limit homogeneity theory and Lyapunov theory are applied to provide detailed proof of the fixed-time stability. Finally, numerical simulation experimental results verify the robustness of the proposed algorithm to model parameter uncertainties and wind disturbances. In addition, the proposed algorithm is deployed in a open-source UAV autopilot and its effectiveness is further demonstrated by hardware-in-the-loop experimental results.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 53-66"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000862/pdfft?md5=ad8c503cbf1fc6b4c4c0e56a06273359&pid=1-s2.0-S2214914724000862-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation for temperature and emissivity by flame emission spectrum in a cavity of rocket based combined cycle combustor chamber 基于火焰发射光谱的火箭联合循环燃烧室空腔温度和发射率实验研究
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.04.019

Flame temperature and spectral emissivity were the important parameters characterizing the sufficient degree of fuel combustion and the particle radiative characteristics in the Rocket Based Combined Cycle (RBCC) combustor. To investigate the combustion characteristics of the complex supersonic flame in the RBCC combustor, a new radiation thermometry combined with Levenberg-Marquardt (LM) algorithm and the least squares method was proposed to measure the temperature, emissivity and spectral radiative properties based on the flame emission spectrum. In-situ measurements of the flame temperature, emissivity and spectral radiative properties were carried out in the RBCC direct-connected test bench with laser-induced plasma combustion enhancement (LIPCE) and without LIPCE. The flame average temperatures at fuel global equivalence ratio (α) of 1.0b and 0.6 with LIPCE were 4.51% and 2.08% higher than those without LIPCE. The flame combustion oscillation of kerosene tended to be stable in the recirculation zone of cavity with the thermal and chemical effects of laser induced plasma. The differences of flame temperature at α = 1.0b and 0.6 were 503 K and 523 K with LIPCE, which were 20.07% and 42.64% lower than those without LIPCE. The flame emissivity with methane assisted ignition was 80.46% lower than that without methane assisted ignition, due to the carbon-hydrogen ratio of kerosene was higher than that of methane. The spectral emissivities at 600 nm with LIPCE were 1.25%, 22.2%, and 4.22% lower than those without LIPCE at α = 1.0a (with methane assisted ignition), 1.0b (without methane assisted ignition) and 0.6. The effect of concentration in the emissivity was removed by normalization to analyze the flame radiative properties in the RBCC combustor chamber. The maximum differences of flame normalized emissivity were 50.91% without LIPCE and 27.53% with LIPCE. The flame radiative properties were stabilized under the thermal and chemical effects of laser induced plasma at α = 0.6.

火焰温度和光谱发射率是表征火箭联合循环(RBCC)燃烧器中燃料燃烧充分程度和颗粒辐射特性的重要参数。为研究 RBCC 燃烧器中复杂超音速火焰的燃烧特性,提出了一种结合 Levenberg-Marquardt (LM) 算法和最小二乘法的新型辐射测温方法,用于测量基于火焰发射光谱的温度、发射率和光谱辐射特性。在带激光诱导等离子体燃烧增强(LIPCE)和不带激光诱导等离子体燃烧增强的 RBCC 直接连接试验台上对火焰温度、发射率和光谱辐射特性进行了现场测量。在燃料总当量比(α)为 1.0b 和 0.6 时,有 LIPCE 的火焰平均温度比没有 LIPCE 的火焰平均温度分别高出 4.51% 和 2.08%。在激光诱导等离子体的热效应和化学效应作用下,煤油在空腔再循环区的火焰燃烧振荡趋于稳定。有 LIPCE 时,α = 1.0b 和 0.6 时的火焰温度分别为 503 K 和 523 K,比无 LIPCE 时分别低 20.07% 和 42.64%。采用甲烷辅助点火的火焰发射率比不采用甲烷辅助点火的火焰发射率低 80.46%,这是由于煤油的碳氢比高于甲烷。在 α = 1.0a(有甲烷辅助点火)、1.0b(无甲烷辅助点火)和 0.6 时,有 LIPCE 的 600 纳米处光谱发射率分别比无 LIPCE 的低 1.25%、22.2% 和 4.22%。通过归一化处理,消除了发射率中浓度的影响,从而分析了 RBCC 燃烧室中的火焰辐射特性。不使用 LIPCE 时,火焰归一化发射率的最大差异为 50.91%,使用 LIPCE 时为 27.53%。在 α = 0.6 时,火焰辐射特性在激光诱导等离子体的热效应和化学效应下趋于稳定。
{"title":"Experimental investigation for temperature and emissivity by flame emission spectrum in a cavity of rocket based combined cycle combustor chamber","authors":"","doi":"10.1016/j.dt.2024.04.019","DOIUrl":"10.1016/j.dt.2024.04.019","url":null,"abstract":"<div><p>Flame temperature and spectral emissivity were the important parameters characterizing the sufficient degree of fuel combustion and the particle radiative characteristics in the Rocket Based Combined Cycle (RBCC) combustor. To investigate the combustion characteristics of the complex supersonic flame in the RBCC combustor, a new radiation thermometry combined with Levenberg-Marquardt (LM) algorithm and the least squares method was proposed to measure the temperature, emissivity and spectral radiative properties based on the flame emission spectrum. In-situ measurements of the flame temperature, emissivity and spectral radiative properties were carried out in the RBCC direct-connected test bench with laser-induced plasma combustion enhancement (LIPCE) and without LIPCE. The flame average temperatures at fuel global equivalence ratio (<em>α</em>) of 1.0b and 0.6 with LIPCE were 4.51% and 2.08% higher than those without LIPCE. The flame combustion oscillation of kerosene tended to be stable in the recirculation zone of cavity with the thermal and chemical effects of laser induced plasma. The differences of flame temperature at <em>α</em> = 1.0b and 0.6 were 503 K and 523 K with LIPCE, which were 20.07% and 42.64% lower than those without LIPCE. The flame emissivity with methane assisted ignition was 80.46% lower than that without methane assisted ignition, due to the carbon-hydrogen ratio of kerosene was higher than that of methane. The spectral emissivities at 600 nm with LIPCE were 1.25%, 22.2%, and 4.22% lower than those without LIPCE at <em>α</em> = 1.0a (with methane assisted ignition), 1.0b (without methane assisted ignition) and 0.6. The effect of concentration in the emissivity was removed by normalization to analyze the flame radiative properties in the RBCC combustor chamber. The maximum differences of flame normalized emissivity were 50.91% without LIPCE and 27.53% with LIPCE. The flame radiative properties were stabilized under the thermal and chemical effects of laser induced plasma at <em>α</em> = 0.6.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 114-122"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724001053/pdfft?md5=d3a66145427bd70dfae2613378c03596&pid=1-s2.0-S2214914724001053-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141044432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Model-driven full system dynamics estimation of PMSM-driven chain shell magazine PMSM 驱动链式壳体料仓的模型驱动全系统动力学估算
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.04.008

Based on the system dynamic model, a full system dynamics estimation method is proposed for a chain shell magazine driven by a permanent magnet synchronous motor (PMSM). An adaptive extended state observer (AESO) is proposed to estimate the unmeasured states and disturbance, in which the model parameters are adjusted in real time. Theoretical analysis shows that the estimation errors of the disturbances and unmeasured states converge exponentially to zero, and the parameter estimation error can be obtained from the extended state. Then, based on the extended state of the AESO, a novel parameter estimation law is designed. Due to the convergence of AESO, the novel parameter estimation law is insensitive to controllers and excitation signal. Under persistent excitation (PE) condition, the estimated parameters will converge to a compact set around the actual parameter value. Without PE signal, the estimated parameters will converge to zero for the extended state. Simulation and experimental results show that the proposed method can accurately estimate the unmeasured states and disturbance of the chain shell magazine, and the estimated parameters will converge to the actual value without strictly continuous PE signals.

基于系统动态模型,针对永磁同步电机(PMSM)驱动的链壳料仓提出了一种全系统动态估算方法。提出了一种自适应扩展状态观测器(AESO)来估计未测量状态和干扰,其中模型参数是实时调整的。理论分析表明,扰动和未测量状态的估计误差以指数形式收敛为零,参数估计误差可从扩展状态中获得。然后,基于 AESO 的扩展状态,设计了一种新的参数估计法则。由于 AESO 的收敛性,新型参数估计法则对控制器和激励信号不敏感。在持续激励(PE)条件下,估计参数将收敛到实际参数值周围的一个紧凑集合。如果没有 PE 信号,对于扩展状态,估计参数将收敛为零。仿真和实验结果表明,所提出的方法能准确估计链壳杂志的未测量状态和干扰,并且在没有严格连续的 PE 信号的情况下,估计参数将收敛到实际值。
{"title":"Model-driven full system dynamics estimation of PMSM-driven chain shell magazine","authors":"","doi":"10.1016/j.dt.2024.04.008","DOIUrl":"10.1016/j.dt.2024.04.008","url":null,"abstract":"<div><p>Based on the system dynamic model, a full system dynamics estimation method is proposed for a chain shell magazine driven by a permanent magnet synchronous motor (PMSM). An adaptive extended state observer (AESO) is proposed to estimate the unmeasured states and disturbance, in which the model parameters are adjusted in real time. Theoretical analysis shows that the estimation errors of the disturbances and unmeasured states converge exponentially to zero, and the parameter estimation error can be obtained from the extended state. Then, based on the extended state of the AESO, a novel parameter estimation law is designed. Due to the convergence of AESO, the novel parameter estimation law is insensitive to controllers and excitation signal. Under persistent excitation (PE) condition, the estimated parameters will converge to a compact set around the actual parameter value. Without PE signal, the estimated parameters will converge to zero for the extended state. Simulation and experimental results show that the proposed method can accurately estimate the unmeasured states and disturbance of the chain shell magazine, and the estimated parameters will converge to the actual value without strictly continuous PE signals.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 147-156"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000850/pdfft?md5=120f1973d1a26950db4c28e2c27c5852&pid=1-s2.0-S2214914724000850-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140774256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of nano-metal oxide additives on ignition and combustion properties of MICs-boron rich fuels 纳米金属氧化物添加剂对富 MICs 硼燃料点火和燃烧特性的影响
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.03.005

Boron has been considered a promising powdered metal fuel for enhancing composite propellants' energy output due to its high energy density. However, the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer. Much research is ongoing to overcome these shortcomings, and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron. This study prepared boron-rich fuels with 10 wt% of eight nano-metal oxide additives by mechanical ball milling. The effect of metal oxides on the thermo-oxidation, ignition, and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis (TG), the electrically heated filament setup (T-jump), and the laser-induced combustion experiments. TG experiments at 5 K/min found that Bi2O3, MoO3, TiO2, Fe2O3, and CuO can promote thermo-oxidation of boron. Compared to pure boron, Tonset can be reduced from 569 °C to a minimum of 449 °C (B/Bi2O3). Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s, the ignition temperatures of B/Bi2O3 are the lowest, even lower than the melting point of boron oxide. Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state. Fuels (B/Bi2O3, B/MoO3, and B/CuO) were mixed with the oxidant AP and ignited by laser to study the combustion performance. The results showed that B/CuO/AP has the largest flame area, the highest BO2 characteristic spectral intensity, and the largest burn rate for powder lines. To combine the advantages of CuO and Bi2O3, binary metal oxide (CBO, mass ratio of 3:1) was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron. Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives. It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive. These findings contribute to the development of boron-rich fuels and their application in propellants.

硼因其能量密度高,一直被认为是一种很有前途的粉末状金属燃料,可用于提高复合推进剂的能量输出。然而,由于氧化硼层的沸点较高,点火温度高、燃烧效率低,限制了硼粉的应用。为克服这些缺点,目前正在进行大量研究,其中一种可能的方法是引入少量金属氧化物添加剂来促进硼的反应。本研究通过机械球磨法制备了富硼燃料,其中含有 10 wt% 的八种纳米金属氧化物添加剂。通过热重分析(TG)、电加热丝装置(T-jump)和激光诱导燃烧实验,全面研究了金属氧化物对硼粉热氧化、着火和燃烧性能的影响。在 5 K/min 下进行的 TG 实验发现,Bi2O3、MoO3、TiO2、Fe2O3 和 CuO 可促进硼的热氧化。与纯硼相比,Tonset 可从 569 ℃ 降至最低 449 ℃(B/Bi2O3)。T-jump 试验中的红外温度测量显示,当电热丝以 1000 K/s 至 25000 K/s 的速度加热时,B/Bi2O3 的点火温度最低,甚至低于氧化硼的熔点。产品的点火图像和扫描电镜进一步表明,高加热速率有利于硼粉在单颗粒燃烧状态下快速反应。将燃料(B/Bi2O3、B/MoO3 和 B/CuO)与氧化剂 AP 混合并用激光点燃,研究其燃烧性能。结果表明,B/CuO/AP 具有最大的火焰面积、最高的 BO2 特征光谱强度和最大的粉末线燃烧速率。为了结合 CuO 和 Bi2O3 的优点,制备了二元金属氧化物(CBO,质量比为 3:1),试验结果表明,CBO 可以很好地改善硼的点火和燃烧性能。试验结果表明,CBO 能很好地改善硼的点火和燃烧性能,尤其是 B/CBO/AP 与含有其他添加剂的所有燃料相比,燃烧率最高。研究发现,多组分金属氧化物添加剂比单组分添加剂更能协同改善硼粉的反应特性。这些发现有助于富硼燃料的开发及其在推进剂中的应用。
{"title":"Effects of nano-metal oxide additives on ignition and combustion properties of MICs-boron rich fuels","authors":"","doi":"10.1016/j.dt.2024.03.005","DOIUrl":"10.1016/j.dt.2024.03.005","url":null,"abstract":"<div><p>Boron has been considered a promising powdered metal fuel for enhancing composite propellants' energy output due to its high energy density. However, the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer. Much research is ongoing to overcome these shortcomings, and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron. This study prepared boron-rich fuels with 10 wt% of eight nano-metal oxide additives by mechanical ball milling. The effect of metal oxides on the thermo-oxidation, ignition, and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis (TG), the electrically heated filament setup (T-jump), and the laser-induced combustion experiments. TG experiments at 5 K/min found that Bi<sub>2</sub>O<sub>3</sub>, MoO<sub>3</sub>, TiO<sub>2</sub>, Fe<sub>2</sub>O<sub>3</sub>, and CuO can promote thermo-oxidation of boron. Compared to pure boron, <em>T</em><sub>onset</sub> can be reduced from 569 °C to a minimum of 449 °C (B/Bi<sub>2</sub>O<sub>3</sub>). Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s, the ignition temperatures of B/Bi<sub>2</sub>O<sub>3</sub> are the lowest, even lower than the melting point of boron oxide. Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state. Fuels (B/Bi<sub>2</sub>O<sub>3</sub>, B/MoO<sub>3</sub>, and B/CuO) were mixed with the oxidant AP and ignited by laser to study the combustion performance. The results showed that B/CuO/AP has the largest flame area, the highest BO<sub>2</sub> characteristic spectral intensity, and the largest burn rate for powder lines. To combine the advantages of CuO and Bi<sub>2</sub>O<sub>3</sub>, binary metal oxide (CBO, mass ratio of 3:1) was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron. Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives. It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive. These findings contribute to the development of boron-rich fuels and their application in propellants.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 157-167"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000709/pdfft?md5=ac7a8a195794169daae35608be2b6e83&pid=1-s2.0-S2214914724000709-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140402128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid HMX multi-level assembled under the constraint of 2D materials with efficiently reduced sensitivity and optimized thermal stability 二维材料约束下的混合 HMX 多层次组装,有效降低灵敏度并优化热稳定性
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-09-01 DOI: 10.1016/j.dt.2024.03.007

The interfacial interaction between HMX molecules and coating materials is the key to the safety performance of explosives and has received extensive attention. However, screening suitable coating agents to enhance the interfacial effect to obtain high-energy and low-sensitivity explosives has long been a major challenge. In this work, HMX-PEI/rGO/g-C3N4 (HPrGC) composites were innovatively prepared by a multi-level coating strategy of two-dimensional graphite rGO and g-C3N4. The g-C3N4 used for desensitization has a rich π-conjugated system and shows outstanding ability in reducing friction sensitivity. The hierarchical structure of HPrGC formed by electrostatic self-assembly and π-π stacking can effectively dissipate energy accumulation under heat and mechanical stimulation through structural evolution, thus exhibiting a prominent synergistic desensitization effect on HMX. The results show that rGO/g-C3N4 coating has no effect on the crystal structure and chemical structure of HMX. More importantly, the perfect combination of g-C3N4 and rGO endows HPrGC with enhanced thermal stability and ideal mechanical sensitivity (IS: 21 J, FS: 216 N). Obviously, the new fabrication of HPrGC enriches the variety of desensitizer materials and helps to deepen the understanding of the interaction between explosives and coatings.

HMX 分子与涂层材料之间的界面相互作用是炸药安全性能的关键,已受到广泛关注。然而,如何筛选合适的包覆剂来增强界面效应,从而获得高能低敏炸药一直是一大挑战。在这项工作中,通过二维石墨 rGO 和 g-C3N4 的多层次涂层策略,创新性地制备了 HMX-PEI/rGO/g-C3N4 (HPrGC)复合材料。用于脱敏的 g-C3N4 具有丰富的 π 共轭体系,在降低摩擦敏感性方面表现突出。静电自组装和π-π堆叠形成的 HPrGC 分层结构能通过结构演化有效消散热和机械刺激下的能量积累,从而对 HMX 表现出突出的协同脱敏效应。结果表明,rGO/g-C3N4 涂层对 HMX 的晶体结构和化学结构没有影响。更重要的是,g-CN4 和 rGO 的完美结合赋予了 HPrGC 更强的热稳定性和理想的机械灵敏度(IS:21 J,FS:216 N)。显然,HPrGC 的新制造方法丰富了脱敏材料的种类,有助于加深对炸药与涂层之间相互作用的理解。
{"title":"Hybrid HMX multi-level assembled under the constraint of 2D materials with efficiently reduced sensitivity and optimized thermal stability","authors":"","doi":"10.1016/j.dt.2024.03.007","DOIUrl":"10.1016/j.dt.2024.03.007","url":null,"abstract":"<div><p>The interfacial interaction between HMX molecules and coating materials is the key to the safety performance of explosives and has received extensive attention. However, screening suitable coating agents to enhance the interfacial effect to obtain high-energy and low-sensitivity explosives has long been a major challenge. In this work, HMX-PEI/rGO/g-C<sub>3</sub>N<sub>4</sub> (HPrGC) composites were innovatively prepared by a multi-level coating strategy of two-dimensional graphite rGO and g-C<sub>3</sub>N<sub>4</sub>. The g-C<sub>3</sub>N<sub>4</sub> used for desensitization has a rich π-conjugated system and shows outstanding ability in reducing friction sensitivity. The hierarchical structure of HPrGC formed by electrostatic self-assembly and π-π stacking can effectively dissipate energy accumulation under heat and mechanical stimulation through structural evolution, thus exhibiting a prominent synergistic desensitization effect on HMX. The results show that rGO/g-C<sub>3</sub>N<sub>4</sub> coating has no effect on the crystal structure and chemical structure of HMX. More importantly, the perfect combination of g-C<sub>3</sub>N<sub>4</sub> and rGO endows HPrGC with enhanced thermal stability and ideal mechanical sensitivity (IS: 21 J, FS: 216 N). Obviously, the new fabrication of HPrGC enriches the variety of desensitizer materials and helps to deepen the understanding of the interaction between explosives and coatings.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"39 ","pages":"Pages 123-132"},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000722/pdfft?md5=ed4ea41aba6ee689110b06ed1bd2dfe3&pid=1-s2.0-S2214914724000722-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140404014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Defence Technology(防务技术)
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1