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Investigation of the Destruction of Lubricating Layers of Sulfonate Greases under Friction and Corrosion 磺酸盐润滑脂润滑层在摩擦和腐蚀作用下的破坏情况调查
IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-12-07 DOI: 10.3103/S1068366623040049
I. A. Buyanovskii, I. R. Tatur, S. S. Strelnikova, V. D. Samusenko, O. A. Kal’yanova

To study such characteristics of sulfonate greases as the lubricity during friction of solids in the mode of boundary lubrication and the protective properties of these lubricants in corrosive environments. A common requirement for the implementation of these indicators is the formation of strong lubricating layers that protect the surfaces of parts from destruction. For each of the studied sulfonate greases with various thickeners and dispersion media, based on the analysis of experimental temperature dependences of the friction coefficients in the temperature range of 30–300°C, the values of the activation energies of the boundary layers destruction were calculated, and the values of Тcm were estimated. The conducted research has shown that for the examined sulfonate greases, there is a qualitative correlation between the values of temperature-energy criterion πD with the experimentally obtained values of the corrosion rates of the steel surface in a corrosive environment under the films of sulfonate greases.

摘要--研究磺酸盐润滑脂的特性,如在边界润滑模式下固体摩擦时的润滑性以及这些润滑剂在腐蚀环境中的保护特性。执行这些指标的一个共同要求是形成强大的润滑层,保护零件表面免受破坏。根据对 30-300°C 温度范围内摩擦系数的实验温度相关性分析,计算出了边界层破坏的活化能值,并估算出了Тcm 值。研究结果表明,对于所研究的磺酸盐润滑脂,温度-能量标准 πD 值与在磺酸盐润滑脂薄膜下腐蚀环境中钢表面腐蚀速率的实验值之间存在定性相关性。
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引用次数: 0
Effect of Basic Processing Factors for Obtaining TiN Vacuum Ion-Plasma Coatings on Their Mechanical and Tribological Characteristics 获得 TiN 真空离子等离子涂层的基本加工因素对其机械和摩擦学特性的影响
IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-12-07 DOI: 10.3103/S1068366623040062
D. S. Manturov, I. V. Kolesnikov, O. V. Kudryakov, V. I. Kolesnikov, P. G. Ivanochkin, S. A. Danilchenko

TiN coatings have been deposited using cathodic arc deposition at various nitrogen pressures and deposition temperatures. The structure and elemental coating composition are analyzed using a scanning electron microscope and an energy dispersive spectrometer. The mechanical properties and adhesion strength of the coating are measured using nanoindentation and scratch testing. The degree of wear is investigated with a tribometer using the ball-on-disk test method. The analysis of the results is carried out by the methods of two-factor orthogonal experiment planning with optimization elements. The results show that the coating structure has a columnar (fibrous) morphology, the composition is close to stoichiometric. The moment of coating destruction, when determining the adhesive strength, occurs at a load of about 600 mN. On the basis of the obtained regression equations for the optimized values of hardness, plasticity index and wear degree, the values of the process parameters of deposition should be in intervals T = 350–430°С and P = 0.065–0.075 Pa.

摘要 在不同的氮气压力和沉积温度下,采用阴极电弧沉积法沉积了氮化钛涂层。使用扫描电子显微镜和能量色散光谱仪分析了涂层的结构和元素组成。利用纳米压痕和划痕测试测量了涂层的机械性能和附着强度。使用摩擦磨损测试仪,采用球盘测试法对磨损程度进行了研究。结果分析采用了带有优化元素的双因素正交实验规划方法。结果表明,涂层结构具有柱状(纤维状)形态,成分接近于化学计量。在确定粘合强度时,涂层破坏的时刻发生在大约 600 mN 的载荷下。根据所得到的硬度、塑性指数和磨损程度优化值的回归方程,沉积工艺参数值的区间应为 T = 350-430°С 和 P = 0.065-0.075 Pa。
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引用次数: 0
Tribotechnical Characteristics of Solid Lubricating Coatings 固体润滑涂层的摩擦技术特性
IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-12-07 DOI: 10.3103/S1068366623040037
M. A. Bronovets

The results of experimental studies of solid lubricating coatings for space applications, in particular, one of the most effective coatings EONIT-3, are presented. The coefficients of friction of coatings and wear resistance at temperatures from minus 150 to plus 400°C in air and in vacuum 10–6 mm Hg were studied for various combinations of antifriction materials depending on the contact pressure, sliding speed, indenter—disk and shaft—sleeve test patterns. It is shown that in tribochemical process molybdenum disulfide, the main industrial solid lubricant, plays the role of an active catalyst. Optimal and stable antifriction and physico-mechanical properties of the EONIT-3 coatings are observed after two hours of heat treatment at 200°C.

本文介绍了太空应用固体润滑涂层的实验研究结果,特别是最有效的涂层之一 EONIT-3。根据接触压力、滑动速度、压头-圆盘和轴-套筒测试模式,研究了涂层在零下 150 到正 400 摄氏度的空气和 10-6 毫米汞柱真空条件下的摩擦系数和耐磨性。结果表明,在摩擦化学过程中,二硫化钼这种主要的工业固体润滑剂起到了活性催化剂的作用。在 200°C 下经过两小时热处理后,EONIT-3 涂层的抗摩擦性和物理机械性能达到最佳且稳定。
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引用次数: 0
Paired Modeling of the Tribological Process of the Abrasive Wear of Soil-Cutting Parts 土壤切割部件磨料磨损摩擦过程的配对建模
IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-12-07 DOI: 10.3103/S1068366623040086
V. I. Myalenko

The work of tillage machinery is accompanied by a natural process of abrasive wear of soil-cutting parts, which leads to a decrease in the quality of technological operations and requires consideration in the development of new designs of such parts. The application of the method of paired modeling of the tribological process of abrasive wear makes it possible to obtain the necessary data for choosing the forms of hardening of the friction surfaces of soil-cutting parts, providing them with the required working life. The pair model proposed here is based on a combination of the results of simulation modeling on bench equipment and the values of the measured pressures in real soils in the zones of subsequent operation. Simulation modeling was carried out on a soil background corresponding to medium loamy soils, and during loading, the values of normal pressures were measured at different points of the friction surfaces and geometric shapes of normal pressure plots were built on the entire friction surface of the part. The measurement of the pressures of real soils was carried out by dynamometry of soil-cutting parts on soils intended for operation with the determination of power equivalents of total loading cutting parts on soils intended for operation with determination of power equivalents of total loading. In the paired model, a combination of simulation data and force equivalents of loading obtained under dynamometry conditions is performed, which allows us to have reliable values for the exact selection of materials and geometric shapes of soil-cutting parts focused on the guaranteed service life.

在耕作机械工作的过程中,土壤切割部件会发生自然磨损,从而导致技术操作质量下降,因此在开发此类部件的新设计时需要加以考虑。应用磨料磨损摩擦学过程的配对建模方法,可以获得必要的数据,用于选择土壤切割部件摩擦表面的硬化形式,使其达到所需的工作寿命。这里提出的对偶模型是基于台式设备上的模拟建模结果与后续操作区域内实际土壤中的测量压力值的结合。仿真建模是在相当于中壤土的土壤背景上进行的,在加载过程中,在摩擦面的不同点测量了法向压力值,并在部件的整个摩擦面上建立了几何形状的法向压力图。实际土壤压力的测量是通过对用于作业的土壤上的土壤切割部件进行测功进行的,并测定了用于作业的土壤切割部件的总负载功率当量,测定了总负载功率当量。在配对模型中,将模拟数据与在测力条件下获得的加载力当量相结合,使我们能够获得可靠的数值,以准确选择材料和切土部件的几何形状,重点保证使用寿命。
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引用次数: 0
Structure and Properties of Antifriction Pseudo-Alloys of the Powder Steel–Copper Alloy, Infiltrated with Materials of Various Compositions 渗入不同成分材料的粉末钢铜合金抗摩擦伪合金的结构和性能
IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-12-07 DOI: 10.3103/S1068366623040050
L. N. Dyachkova

The structure and properties of powder steel–copper alloy antifriction pseudo-alloys infiltrated with materials of various compositions are studied, it is shown that mechanical and tribological properties are determined both by the composition and structure of the steel skeleton and, to a large extent, by the composition and structure of the infiltrate. It has been established that the limiting content of lead in the infiltrate, which ensures the absence of lead deposits on the sample surface and a large (10–15%) residual porosity, should not exceed 3%. The use of a mixture of copper powders and alloying additives for infiltration is more technologically advanced than atomized bronze powders. It is shown that the wear resistance of pseudo-alloys with a chromium steel skeleton depends to a lesser extent on the composition of the infiltrate, since the main contribution to wear resistance is made by a hard steel skeleton. The introduction of 3–5% ultrafine aluminum oxide powders into the infiltrate leads to an increase in the seizure pressure by 1.2 MPa and wear resistance by 20–30% due to the refinement of the copper alloy structure and the deceleration of dislocations that arise during deformation due to friction. It is shown that during the wear of pseudo-alloys in the surface layer the structure is refined, martensite is formed in the skeleton, and, accordingly, the microhardness increases by 720–760 MPa.

摘要 研究了渗入不同成分材料的粉末钢铜合金减摩伪合金的结构和性能,结果表明,机械性能和摩擦学性能既取决于钢骨架的成分和结构,也在很大程度上取决于渗入材料的成分和结构。为了确保试样表面没有铅沉积物和较大的残留孔隙率(10-15%),浸润液中铅的极限含量不应超过 3%。与雾化青铜粉相比,使用铜粉和合金添加剂的混合物进行浸渗的技术更为先进。研究表明,以铬钢为骨架的假合金的耐磨性在较小程度上取决于浸润料的成分,因为耐磨性的主要贡献来自于坚硬的钢骨架。在渗入液中加入 3-5% 的超细氧化铝粉末后,由于铜合金结构的细化和摩擦变形过程中产生的位错的减速,扣压压力提高了 1.2 兆帕,耐磨性提高了 20-30%。研究表明,在表层伪合金的磨损过程中,结构得到细化,骨架中形成了马氏体,因此显微硬度增加了 720-760 兆帕。
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引用次数: 0
Evaluation of the Performance of PTFE-Composites as Antifriction Layers in Supporting Parts with a Spherical Segment PTFE复合材料作为球形节段支撑件减摩层的性能评价
IF 0.7 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-09-25 DOI: 10.3103/S1068366623030029
A. A. Adamov, I. E. Keller, D. S. Petukhov, V. S. Kuzminykh, I. M. Patrakov, P. N. Grakovich, I. S. Shilko

Abstract

For the primary assessment of the operability of a number of filled polymer composites based on polytetrafluoroethylene (PTFE) as a material of antifriction layers, Brinell hardness, stiffness under free compression up to 10% deformation, stiffness under tight compression up to 160 MPa, friction coefficients and resistance to reverse sliding according to the plane-by-plane scheme of polished austenitic stainless steel were studied at room temperature as a counterbody. Seven types of PTFE-based composites filled with coke, bronze, colloidal graphite, as well as modified carbon fiber with a fluoropolymer coating and various additives (composites of the Superfluvis family) were studied. According to the totality of indicators, the composites of the Superfluvis family are superior to materials filled with coke or bronze, and the material filled with colloidal graphite as the main filler did not pass the tests for resistance to reverse sliding. The performance of the Superfluvis composite based on PTFE PN90 in reverse sliding tests under the pressure of 65 MPa at a distance of 10 000 m has been confirmed.

摘要——为了初步评估一些基于聚四氟乙烯(PTFE)作为减摩层材料的填充聚合物复合材料的可操作性,布氏硬度、自由压缩下的刚度高达10%变形、紧密压缩下的硬度高达160MPa,在室温条件下,以抛光奥氏体不锈钢为沉头,按照逐平面方案研究了其摩擦系数和反向滑动阻力。研究了七种填充焦炭、青铜、胶体石墨的PTFE基复合材料,以及带有含氟聚合物涂层和各种添加剂的改性碳纤维(Superfluvis家族的复合材料)。从总体指标来看,Superfluvis家族的复合材料优于填充有焦炭或青铜的材料,并且填充有胶体石墨作为主要填料的材料没有通过抗反向滑动测试。基于PTFE PN90的Superfluvis复合材料在65MPa压力下10 000米已被确认。
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引用次数: 0
Evolution of the Structure of a Near-Surface Layer of an Aluminum Matrix Composite of the Al–Sn–Fe System under Dry Friction Against a Steel Counterbody Al–Sn–Fe系铝基复合材料在与钢制配重干摩擦下近表面层结构的演变
IF 0.7 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-09-25 DOI: 10.3103/S106836662303008X
N. M. Rusin, A. L. Skorentsev, A. V. Chumaevskii

Abstract

An effect of friction forces on the structure and composition of the near-surface layer of an Al–13Sn–5Fe (at %) composite containing a large amount of agglomerates of FeAl3 particles cemented with tin was studied. The investigated composite was prepared by sintering a mixture of Al, Sn, and Fe elemental powders in vacuum for 1 h at a temperature of 620°C and subsequent compaction in a closed die at a pressure of about 300 MPa and a temperature of 250°C. The counterbody was made of heat-resistant X40CrMoV5-1 steel and was a truncated steel cone with a helical surface. The speed of material points lying on the outer perimeter of the section of the rotating cone pressed against the composite was 0.36 and 0.54 m/s. The normal pressure on the end surface of the composite specimen was 16 and 32 MPa with a load on the cone of 150 and 300 kg, respectively. It was found that three layers are formed under the friction surface, which differ in the value of the accumulated deformation. The closer to the friction surface the layer is located, the narrower it is. The uppermost layer consists of highly crushed iron aluminide particles mixed with ultrafine tin and aluminum particles. It also contains a lot of oxygen in the form of fragments of oxide films, which is why it has a high microhardness, reaching 2000 MPa or more. The thickness of this layer increases with increasing processing pressure and reaches several hundred micrometers. Based on the results of the study, it is concluded that pretreatment of the surface of aluminum matrix composites by smoothing with a flat steel counterbody leads to its charging. This fact will increase its wear resistance, however, the optimal mode of such processing and the shape of the processing tool require additional research.

摘要——研究了摩擦力对Al–13Sn–5Fe(at%)复合材料近表面层结构和成分的影响,该复合材料含有大量与锡胶结的FeAl3颗粒团聚体。所研究的复合材料是通过在620°C的温度下将Al、Sn和Fe元素粉末的混合物在真空中烧结1小时,然后在约300 MPa的压力和250°C的压力下在闭合模具中压实而制备的。沉头体由耐热X40CrMoV5-1钢制成,是具有螺旋表面的截头钢锥。位于压在复合材料上的旋转锥体截面的外周上的材料点的速度分别为0.36和0.54m/s。复合材料试样端面上的法向压力分别为16和32MPa,锥体上的载荷分别为150和300kg。研究发现,摩擦表面下形成了三层,累积变形值不同。该层越靠近摩擦表面,就越窄。最上层由高度破碎的铁铝化物颗粒与超细锡和铝颗粒混合而成。它还以氧化膜碎片的形式含有大量氧气,这就是为什么它具有高显微硬度,达到2000兆帕或更高。该层的厚度随着处理压力的增加而增加,并且达到几百微米。根据研究结果,得出结论:用扁钢沉头对铝基复合材料表面进行光滑预处理,可使其带电。这一事实将增加其耐磨性,然而,这种加工的最佳模式和加工工具的形状需要额外的研究。
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引用次数: 0
Influence of Protective Coatings of Inserts on Cutting Forces during Milling of Hadfield Steel Hadfield钢铣削过程中刀片保护层对切削力的影响
IF 0.7 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-09-25 DOI: 10.3103/S1068366623030078
A. S. Pyatykh, A. V. Savilov, S. A. Timofeev, V. M. Svinin, I. G. Maizel

Abstract

The present study analyzed the effect of protective coatings of replaceable hard-alloy plates on cutting forces when milling austenitic high-manganese Hadfield (110G13L) steel. S30T, 1130, S40T, and 4240 hard alloys with PVD and CVD coatings were explored. The analysis was conducted on a milling machining center with a dynamometer plate installed on the table. The experiment was based on the orthogonal planning matrix. The Taguchi method was employed to identify a coating with the best properties. The analysis of variance showed that the tool feed has the greatest effect on active cutting forces. The specific feed gravity was 65.22%. The regression analysis revealed that to minimize and predict cutting forces for the entire range of cutting conditions, S30T alloy with a protective TiAlN PVD coating is preferable in machining austenitic 110G13L stainless steel. The results can improve the machining efficiency for Hadfield steel products produced by machine-building enterprises.

摘要——分析了可更换硬质合金板保护层对奥氏体高锰哈德菲尔德(110G13L)钢铣削时切削力的影响。研究了具有PVD和CVD涂层的S30T、1130、S40T和4240硬质合金。分析是在一个铣削加工中心上进行的,测功机板安装在工作台上。实验基于正交规划矩阵。采用田口方法来鉴定具有最佳性能的涂层。方差分析表明,刀具进给对主动切削力的影响最大。进料比重为65.22%。回归分析表明,为了最大限度地减少和预测整个切削条件下的切削力,在加工奥氏体110G13L不锈钢时,具有保护性TiAlN PVD涂层的S30T合金是优选的。研究结果可以提高机械制造企业生产的哈德菲尔德钢产品的加工效率。
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引用次数: 0
The Influence of the Spatial Organization of Carbon Nanostructures on Antiwear Characteristics of Model Lubricating Systems under a Hard Friction Mode 纳米碳结构的空间组织对硬摩擦模式下模型润滑系统抗磨特性的影响
IF 0.7 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-09-25 DOI: 10.3103/S1068366623030091
M. A. Shilov, A. I. Smirnova, L. N. Zhukova, A. A. Gvozdev, N. N. Rozhkova, T. P. Dyachkova, N. V. Usol’tseva

The following carbon nanostructures (CNSs) are used: shungite nanocarbon (Sh), multilayered graphene oxide (GO), multiwalled carbon nanotubes (Taunit-M), and fullerene C60. Medical Vaseline (MV) free from any additives or thickeners is used as a lubricant base. Tribological tests are carried out using a 2070 SMT-1 friction machine at a load of 2000 N. The roughness parameters of steel rollers before and after the tests are studied by profilometry. Detailed characteristics of contacting surfaces before and after friction are obtained by scanning and transmission electron microscopy. The experimental data are analyzed using the Hertz and Johnson–Kendall–Roberts models. According to the data on efficiency coefficients kef, the studied dispersions are ranked as follows in the order of deterioration of antiwear properties: MV/GO (0.5 wt %), kef of 50% > MV/Taunit-M (1.5 wt %), kef of 40% > MV/C60 (0.5 wt %), kef of 15% > MV/Sh (0.5 wt %), kef of 5%, which is in agreement with the above-mentioned sequence of CNSs at low loads. The reason for the best and worst wear factors upon using CNSs in the dispersions under study and factors affecting the values of wear in the hard friction mode are considered. The results of the study can be a basis for the development of new plastic lubricating compositions with carbon nanostructure additives for use in heavily loaded friction units.

使用以下碳纳米结构(CNSs):顺土纳米碳(Sh)、多层氧化石墨烯(GO)、多壁碳纳米管(Tauni-M)和富勒烯C60。不含任何添加剂或增稠剂的医用凡士林(MV)用作润滑剂基础。使用2070 SMT-1摩擦机在2000N的载荷下进行了摩擦学试验。通过轮廓术研究了试验前后钢辊的粗糙度参数。通过扫描和透射电子显微镜获得了摩擦前后接触表面的详细特征。实验数据使用赫兹和约翰逊-肯德尔-罗伯茨模型进行分析。根据效率系数kef的数据,所研究的分散体按抗磨性能劣化的顺序排列如下:MV/GO(0.5wt%),kef为50%>;MV/Taunit-M(1.5wt%)、kef为40%>;MV/C60(0.5wt%)、kef为15%>;MV/Sh(0.5wt%),kef为5%,这与上述低负载下的CNSs序列一致。考虑了在所研究的分散体中使用CNSs时最佳和最差磨损因子的原因,以及影响硬摩擦模式下磨损值的因素。该研究结果可为开发用于重载摩擦装置的具有碳纳米结构添加剂的新型塑料润滑组合物奠定基础。
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引用次数: 0
Improvement of Tribotechnical Parameters of Bronze Parts by Applying a Molybdenum Coating 应用钼涂层改善青铜零件的摩擦学参数
IF 0.7 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2023-09-25 DOI: 10.3103/S1068366623030030
V. B. Balyakin, S. V. Falaleev, D. E. Dolgih, A. A. Yurtaev

Abstract

The results of experimental determination of the wear intensity coefficient and the friction coefficient in the steel-bronze BrNBT and steel–molybdenum coating contact are shown. To determine the tribotechnical parameters of the coating, experiments were carried out on a Tribometer TRB automated friction machine of the Swiss company ANTON PAAR according to the ball–disk scheme. It is shown that the average coefficient of friction for a sample with a molybdenum coating is almost two times lower than for a sample without a coating. With the help of the SURTRONIC 25 profile meter, a profilogram was obtained to determine the coefficient of wear intensity. At a run of 50,000 m, the coefficient of wear intensity for a sample made of BrNBT material without coating at a maximum contact voltage of 507 MPa is 2.48 × 10–4 mm3/m, and for a sample with a molybdenum coating was 1.98 × 10–5 mm3/m, which is 12.5 times less. Recommendations for the use of a molybdenum antifriction coating are given.

文摘——给出了钢-青铜-BrNBT与钢-钼涂层接触磨损强度系数和摩擦系数的实验测定结果。为了确定涂层的摩擦技术参数,根据球-盘方案,在瑞士ANTON PAAR公司的Tribometer TRB自动摩擦机上进行了实验。结果表明,具有钼涂层的样品的平均摩擦系数几乎是没有涂层的样品低两倍。在SURTRONIC25型面仪的帮助下,获得了用于确定磨损强度系数的轮廓图。在50000 m的行程中,由无涂层的BrNBT材料制成的样品在507 MPa的最大接触电压下的磨损强度系数为2.48×10–4 mm3/m,而具有钼涂层的样品的磨损强度为1.98×10-5 mm3/m。给出了使用钼减摩涂层的建议。
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引用次数: 0
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Journal of Friction and Wear
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