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2010 International Conference on Enabling Science and Nanotechnology (ESciNano)最新文献

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Nanocolours: Correlating structure with function 纳米颜色:结构与功能的关联
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5701080
I. Gebeshuber
Structural colours refer to colours generated by nanostructures, with the characteristic dimension of the structures on the wavelength of the visible light (i.e., some hundreds of nanometers). Structural colouration occurs e.g., in CDs and DVDs, in soap bubbles or oil films on water, in butterfly wings [1] and in the wings of the carpenter bee [2].
结构色是指纳米结构产生的颜色,其特征尺寸在可见光波长上(即几百纳米左右)。结构着色发生在cd和dvd、肥皂泡或水中的油膜、蝴蝶翅膀[1]和木蜂的翅膀[2]中。
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引用次数: 0
Nonlinear enhancement of the efficiency of the second harmonic generation 二次谐波产生效率的非线性增强
N. Bidin, N. E. Khamsan, Enass Mauludi, F. Noor
Birefringent ND:YVO4 pumped by diode laser with fundamental wavelength of 1064 nm was used to pump nonlinear KTP crystal. Quartz crystals having natural birefringent property namely quarter and half waveplates were conducted in conjunction with the bulk of KTP to enhance the nonlinear beam. The result showed that half waveplate have electrical to optical conversion efficiency of 15.6 mW/A as compared to quarter waveplate is only 8.74 mW/A. The threshold current for SHG is found 5.3 A with half waveplate and 5.9 A with quarter waveplate. The high performance shown by half waveplate is realized due to the good mode matching after converting the polarization state.
采用基波长为1064 nm的二极管激光器泵浦双折射ND:YVO4,泵浦非线性KTP晶体。具有天然双折射特性的石英晶体,即四分之一波片和半波片,与KTP体结合以增强非线性光束。结果表明,半波片的光电转换效率为15.6 mW/A,而四分之一波片的光电转换效率仅为8.74 mW/A。半波片和四分之一波片的阈值电流分别为5.3 A和5.9 A。由于偏振态转换后的模式匹配良好,实现了半波片的高性能。
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引用次数: 0
Effect of chirality on the silicon-carbon nanotube thermal interface resistance 手性对硅碳纳米管热界面电阻的影响
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5700955
M. Osman, Taejin Kim
Thermal flow across the interface between two different materials is strongly affected by the differences in the electronic properties and vibrational modes of the two materials which give rise to the thermal interface resistance[1]. The thermal interface resistance results in a finite temperature discontinuity at the interface between the two materials. Reducing the thermal interface resistance between silicon chips and the packaging material is very critical for efficiently extracting heat and ensuring reliable operation of ICs. The large thermal conductivity of carbon nanotubes makes them very ideal for developing thermal switches and thermal interface materials [2]. We have investigated the thermal interface resistance between carbon nanotubes and silicon using molecular dynamic (MD) simulations.
通过两种不同材料界面的热流受到两种材料的电子特性和振动模式差异的强烈影响,从而产生热界面阻力[1]。热界面电阻导致两种材料界面处的有限温度不连续。降低硅芯片与封装材料之间的热界面电阻对于有效地提取热量和确保集成电路的可靠运行至关重要。碳纳米管的高导热性使其成为开发热开关和热界面材料的理想材料[2]。本文采用分子动力学方法研究了碳纳米管与硅之间的热界面电阻。
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引用次数: 0
Nanostructures and devices 纳米结构和器件
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5701081
Zhang Hua
Nanostructures have been attracted great attentation for many years due to their novel properties and advantages associated with the scale. In this plenary talk, I will present the artificial nanostructures and devices developed in our group. I will also discuss their applications in light source, light manipulation and high resolution imaging for next generation photonic technology.
近年来,纳米结构以其新颖的性质和规模优势受到人们的广泛关注。在这次全体会议上,我将介绍我们小组开发的人造纳米结构和器件。本文还将讨论它们在下一代光子技术的光源、光处理和高分辨率成像方面的应用。
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引用次数: 0
Nanotechnology for solid-state lighting 用于固态照明的纳米技术
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5701097
Chua Soo Jin
Lighting has evolved over the last 150 years from the primordial use of fire, incandescence from filaments, to fluorescence and electrical discharge in gases. The use of each new material has led to the improvement in luminous efficacy by an order of magnitude. The incandescent light bulb, invented by Edison in 1879, will be phased out over the next few years as governments sought to ban its manufacture and use because of its low efficiency (< 5%) and to introduce green technology. The fluorescent lamp, which is widely used to replace the incandescent bulb with its use of mercury and presence of lead in some phosphors, is seen as an interim measure.
在过去的150年里,照明已经从最初的火、灯丝的白炽灯发展到荧光和气体放电。每一种新材料的使用都使发光效率提高了一个数量级。1879年爱迪生发明的白炽灯泡将在未来几年内逐步淘汰,因为各国政府试图禁止白炽灯泡的生产和使用,因为它的效率很低。(5%)及引进绿色科技。荧光灯被广泛用于取代白炽灯,因为它使用汞,一些荧光粉中含有铅,被视为一种临时措施。
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引用次数: 0
Changes in physical properties and molecular structure of polystyrene nanospheres exposed with daily solar flux 日晒下聚苯乙烯纳米球物理性质和分子结构的变化
P. J. Wibawa, M. Agam, Hadi Nur, H. Saim
The effects of physical properties and molecular structure of 200 nm polystyrene nanospheres (PSN) coated on silicon wafer exposed with daily solar flux were explored by field emission scanning electron microscope (FE-SEM) and attenuated total reflectance-Fourier transform infrared (ATR-FT-IR) spectrometer. It is revealed that the particles shape of PSN changed from spheric to eight-shaped after solar radiation. Reduction of the size as much as 29.5% after 5 minutes exposure was also observed in PSN particles. Changes in the molecular structure of the PSN particles after solar radiation were observed where some of the phenyl moieties of polystyrene broke down to facilitate carbon-carbon cross linkage bonds. These results demonstrated that the shrinkage of PSN particles is caused by the change of the molecular structure of polystyrene.
利用场发射扫描电镜(FE-SEM)和衰减全反射-傅里叶变换红外光谱仪(ATR-FT-IR)研究了日晒下硅片表面涂覆200 nm聚苯乙烯纳米微球(PSN)的物理性质和分子结构的影响。结果表明,在太阳辐射作用下,PSN的粒子形状由球状变为八字形。PSN颗粒在暴露5分钟后也缩小了29.5%。在太阳辐射后,PSN粒子的分子结构发生了变化,聚苯乙烯的一些苯基部分被分解以促进碳-碳交叉键的形成。这些结果表明PSN颗粒的收缩是由聚苯乙烯分子结构的变化引起的。
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引用次数: 7
Heating effect of a one-dimensional molecular assembly on self-repairing capability in the nanoscopic channels of mesoporous silica 一维分子组装对介孔二氧化硅纳米通道中自修复能力的加热效应
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5700970
Hendrik Oktendy Lintang, K. Kinbara, T. Yamashita, T. Aida
Self-repairable optoelectronic devices from a heat-induced structural damaged are potentially important for sensor [1] and display [2] applications. Recently, self-healing phenomena have attracted particular attention for developing sustainable structural materials [3], where extensive studies have been reported on polymeric materials capable of autonomous repairing macroscopic fractures or restoration lost mechanical strengths [4, 5]. On the other hand, for exploiting molecular devices that can self-repair elaborate functions, one may encounter different problems originating from much smaller size regimes. However, no rational strategies have yet been proposed for addressing this challenging issue. In our previous paper, when a phosphorescent columnar assembly of trinuclear gold(I) pyrazolate complex [Au3Pz3] is confined in the nanoscopic channel of hexagonal mesoporous silica [Au3Pz3]/silicahex (Fig. 1), upon stepwise heating from 20 °C to 140 °C in 45 min, the one-dimensional molecular assemblies are not only protected from thermal disruption but also strongly encouraged to self-recover to 100% in 5 h from a heat-induced structural damaged [6].
热致结构损伤的自修复光电器件对于传感器[1]和显示器[2]的应用具有潜在的重要意义。最近,自修复现象在可持续结构材料的开发中引起了特别的关注[3],其中大量研究报道了能够自主修复宏观骨折或恢复失去的机械强度的聚合物材料[4,5]。另一方面,为了开发能够自我修复复杂功能的分子装置,人们可能会遇到来自更小尺寸体系的不同问题。然而,目前还没有提出合理的策略来解决这一具有挑战性的问题。在我们之前的论文中,当三核金(I)吡唑酸配合物[Au3Pz3]的磷光柱状组装体被限制在六方中孔二氧化硅[Au3Pz3]/硅己烯的纳米通道中(图1),在45分钟内从20°C逐步加热到140°C时,一维分子组装体不仅不受热破坏,而且强烈鼓励在5小时内从热引起的结构损伤中自我恢复到100%[6]。
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引用次数: 6
Effect of annealing atmosphere towards TiO2 nanoparticles on their photocatalytic performance in aquoues phase 退火气氛对TiO2纳米颗粒水相光催化性能的影响
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5701011
S. A. Ibrahim, S. Sreekantan
TiO2 is one of the most semiconductors metal oxides used in many applications covering various field such as optoelectronics, medicine, sensor devices and catalyst [1]. Such applications are depended strongly on the crystalline structure, morphology and particle size [2]. Among the common crystalline form of titania, anatase is proven to be excellent photocatalyst compared to rutile and brookite.
TiO2是应用最广泛的半导体金属氧化物之一,广泛应用于光电子、医药、传感器器件、催化剂等领域[1]。这些应用在很大程度上取决于晶体结构、形态和粒度[2]。在常见的二氧化钛晶型中,锐钛矿被证明是一种比金红石和布鲁克石更好的光催化剂。
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引用次数: 4
Growth of Au-catalyzed and self-catalyzed ZnO nanowires using chemical vapor deposition technique 化学气相沉积法生长au催化和自催化氧化锌纳米线
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5700937
Pu Yong, Choy Kwang Leong, Hou Xianghui
With the ongoing miniaturization of devices such as FETs [1], the synthesis of ZnO NWs (building blocks) has attracted extensive research interest. ZnO NWs have been synthesized via different routes by many research groups [2–4]. In order for these building blocks to be incorporated into functional nano-devices, controlled synthesis of the ZnO NWs to obtain features such as the desired size, shape and alignment should be fulfilled. This is a rather challenging task. A better understanding of the growth mechanism of ZnO NWs may be helpful to resolve these uncertainties. However, the underlying mechanism for the growth of the ZnO NWs for both self-catalyzed and Au-catalyzed ZnO NWs, have not been well elucidated. In addition, there is no fully developed cohesive model that explains the growth mechanism of both self-catalyzed and Au-catalyzed ZnO NWs.
随着fet[1]等器件的不断小型化,ZnO NWs(构建块)的合成引起了广泛的研究兴趣。许多研究小组已经通过不同的途径合成了ZnO纳米波[2-4]。为了将这些构建块整合到功能纳米器件中,必须控制ZnO NWs的合成以获得所需的尺寸,形状和排列等特征。这是一项颇具挑战性的任务。更好地了解ZnO NWs的生长机制可能有助于解决这些不确定性。然而,自催化和au催化ZnO NWs生长的潜在机制尚未得到很好的阐明。此外,目前还没有完整的内聚模型来解释自催化和au催化的ZnO NWs的生长机制。
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引用次数: 1
Syntheses and characterization of a new nano-structure lead (II) coordination polymer by sonochemical method 一种新型纳米结构铅(II)配位聚合物的合成与表征
Pub Date : 2010-12-01 DOI: 10.1109/ESCINANO.2010.5701073
H. Sadeghzadeh, A. Morsali
Nano-structure of a new Pb(II) two-dimensional coordination polymer, [Pb(2-pyc) (N3)(H2O)]n (1), 2-Hpyc =2-pyridinecarboxylic acid} were synthesized by a sonochemical method. The new nano-structures were characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterized by single-crystal X-ray diffraction and consists of two-dimensional polymeric units. The thermal stability of compounds 1 was studied by thermal gravimetric and differential thermal analyses and compared. PbO nanopowders were obtained by calcinations of the nano-structure of compound 1 at 400°C. This study demonstrates the coordination polymers may be suitable precursors for the preparation of nanoscale materials and dependent on their packing they may produce different and interesting morphologies.
用声化学方法合成了一种新型Pb(II)二维配位聚合物[Pb(2-pyc) (N3)(H2O)]n (1), 2-Hpyc =2-吡啶羧酸}的纳米结构。采用扫描电镜、x射线粉末衍射、红外光谱和元素分析对纳米结构进行了表征。化合物1由二维聚合物单元组成,通过单晶x射线衍射进行了结构表征。采用热重法和差热分析法对化合物1的热稳定性进行了研究和比较。将化合物1的纳米结构在400℃下煅烧得到PbO纳米粉体。该研究表明配位聚合物可能是制备纳米级材料的合适前驱体,并且根据它们的包装可以产生不同的和有趣的形态。
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2010 International Conference on Enabling Science and Nanotechnology (ESciNano)
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