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2014 IEEE 40th Photovoltaic Specialist Conference (PVSC)最新文献

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Afterpulse background suppression in time-correlated single photon counting lifetime experiments using optimized gate filter 优化门滤波器在时间相关单光子计数寿命实验中的后脉冲背景抑制
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925296
M. Gerber, R. Kleiman
Using a monostable multivibrator, the signal-dependent afterpulsing background from a single photon avalanche diode was suppressed. This digital filter gate was characterized and optimized using photoluminescence decay lifetime measurements to show a reduction in systematic error that is 25% of the measured lifetime and ~500X improvement in acquisition time when compared with the time taken to obtain a comparably reliable result by reduction of the repetition rate to suppress afterpulsing. At 10 MHz, there is an increase in the linear dynamic range from ~2τ to ~6τ, where the lifetime, t, was measured to be (5.0±0.1)ns. Lifetime measurements were performed with a pulsed 510 nm diode laser, a 500 nm GaAs layer (sandwiched between InGaP capping layers), a silicon single-photon avalanche photodiode and time-correlated single photon counting electronics.
利用单稳态多谐振荡器,抑制了单光子雪崩二极管信号相关的后脉冲背景。使用光致发光衰减寿命测量对该数字滤波门进行了表征和优化,显示系统误差减少了测量寿命的25%,与通过降低重复率来抑制后脉冲获得相对可靠的结果所需的时间相比,采集时间提高了约500倍。在10 MHz时,线性动态范围从~2τ增加到~6τ,其中寿命t测量为(5.0±0.1)ns。使用510 nm脉冲二极管激光器、500 nm GaAs层(夹在InGaP封盖层之间)、硅单光子雪崩光电二极管和时间相关单光子计数电子器件进行寿命测量。
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引用次数: 2
Image aided dynamic reconfiguration of SPV array under non uniform illumination 非均匀光照下SPV阵列的图像辅助动态重构
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925037
B. Patnaik, U. Aswani, G. Sarkar, S. Duttagupta
In this paper, we studied Solar Photovoltaic (SPV) array output power as a function of dynamic illumination intensity pattern. A fine resolution pixel level analysis of 2D dynamic illumination intensity pattern is mapped to the module architecture. Images taken by high resolution cameras at regular intervals will help track the iso-insolation contours by mapping pixel pattern and estimate the illumination intensity state of the module. The aggregate intensity pattern on such an SPV module will be a mixed pattern classified as non-uniform illumination (NUI) states (BRIGHT, GREY, DARK). Optimization of a SPV array under such NUI conditions is a considerable challenge. We propose an image aided dynamic reconfiguration technique based on the classification of modules after pixelating the image of the array. The nature of the BRIGHT state and DARK state coverage on the SPV module has a significant implication on output power depending on the inter-connectivity of the PV cells (module architecture) and if bypass diodes are attached to individual cells or a packet of cells. The promise of this approach is to reduce disruption of the SPV array operation. Another significant point is the ability to predict the power. It has been demonstrated that a small change in the NUI pattern can cause a significant change in the power output. While certain individual hardware blocks have been developed, ongoing activity is focused on realization of a fully online implementation.
本文研究了太阳能光伏(SPV)阵列输出功率随光照强度的变化规律。将二维动态光照强度模式的高分辨率像素级分析映射到模块结构中。高分辨率相机定期拍摄的图像将通过映射像素模式帮助跟踪等日照等高线,并估计模块的照明强度状态。这种SPV模块上的总强度模式将是分类为非均匀照明(NUI)状态(BRIGHT, GREY, DARK)的混合模式。在这种NUI条件下,SPV阵列的优化是一个相当大的挑战。我们提出了一种基于模块分类的图像辅助动态重构技术。SPV模块上的BRIGHT状态和DARK状态覆盖的性质对输出功率有重要的影响,这取决于PV电池的互连性(模块结构),以及旁路二极管是连接到单个电池还是一组电池。这种方法有望减少SPV阵列操作的中断。另一个重要的点是预测能力。已经证明,NUI模式的微小变化会导致功率输出的显著变化。虽然已经开发了某些单独的硬件块,但正在进行的活动侧重于实现完全在线的实现。
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引用次数: 2
Microstructured ZnO coatings for improved performance in Cu(In,Ga)Se2 photovoltaic devices 改善Cu(in,Ga)Se2光电器件性能的微结构ZnO涂层
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6924929
J. Frantz, J. Myers, R. Bekele, J. Sanghera
The performance of thin film Cu(In,Ga)Se2 (CIGS) photovoltaics is typically degraded by light lost due to the high reflectivity of the transparent top contact and by recombination resulting from carrier generation far from the junction. Traditional antireflective (AR) coatings are insufficient to address the former issue, particularly at non-normal incidence. We present a novel microstructured ZnO coating that serves two functions; it acts an AR layer with superior non-normal performance in comparison to thin film AR coatings, and it scatters a significant fraction of the incoming radiation at a large angle, resulting in absorption that is on average closer to the junction. This coating, formed via a wet etch process, results in performance comparable to that of uncoated films at normal incidence and an increase of up to 25% in the short circuit current and 18% in device efficiency at non-normal incidence.
薄膜Cu(In,Ga)Se2 (CIGS)光伏电池的性能通常会因透明顶部接触的高反射率造成的光损失和远离结的载流子产生导致的复合而下降。传统的抗反射(AR)涂层不足以解决前一个问题,特别是在非正常入射下。我们提出了一种具有两种功能的新型微结构ZnO涂层;与薄膜AR涂层相比,它作为一种具有优越非正常性能的AR层,并且它以大角度散射入射辐射的很大一部分,从而导致平均更接近结的吸收。这种涂层是通过湿式蚀刻工艺形成的,在正常入射下,其性能与未涂层薄膜相当,在非正常入射下,短路电流可提高25%,器件效率可提高18%。
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引用次数: 2
Determining the maximum open circuit voltage from absorber photoluminescence in the presence of tail states 确定在尾态存在时吸收体光致发光的最大开路电压
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925052
John K. Katahara, H. Hillhouse
We develop a general model for sub-bandgap absorption that includes the Urbach, Franz-Keldysh, and Thomas-Fermi models as limiting forms. Combination of this absorption scheme with a generalized Kirchhoff law for spontaneous emission of photons yields a model of photoluminescence (PL) with broad applicability to many semiconductors. This model allows for full-spectrum fitting of absolute intensity PL data and outputs: (1) the functional form of sub-bandgap absorption, (2) the energy broadening term (3) the direct bandgap, (4) the local temperature, and (5) the quasi-Fermi Level Splitting (QFLS). The accuracy of the model is demonstrated by fitting the room temperature PL spectrum of GaAs. It is then applied to Cu(In,Ga)(S,Se)2 and Cu2ZnSn(S,Se)4 to reveal the nature of their tail states. The extracted QFLS is shown to accurately predict the open-circuit voltage of devices fabricated from the materials.
我们开发了一个通用的亚带隙吸收模型,其中包括厄巴赫,弗兰兹-凯尔迪什和托马斯-费米模型作为限制形式。这种吸收方案与光子自发发射的广义基尔霍夫定律相结合,产生了一种广泛适用于许多半导体的光致发光模型。该模型允许对绝对强度PL数据进行全光谱拟合,并输出:(1)子带隙吸收的函数形式,(2)能量展宽项,(3)直接带隙,(4)局部温度,以及(5)准费米能级分裂(QFLS)。通过对砷化镓室温PL谱的拟合,验证了该模型的准确性。然后将其应用于Cu(In,Ga)(S,Se)2和Cu2ZnSn(S,Se)4,以揭示其尾态的性质。结果表明,所提取的QFLS可以准确地预测由该材料制成的器件的开路电压。
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引用次数: 0
High-resolution residential feeder load characterization and variability modelling 高分辨率住宅馈线负荷表征和变异性建模
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925193
Andrew Pohl, Jay Johnson, S. Sena, R. Broderick, J. Quiroz
Data from of a highly instrumented residential feeder in Ota City, Japan was used to determine 1 second load variability for the aggregation of 50, 100, 250, and 500 homes. The load variability is categorized by binning the data into seasons, weekdays vs. weekends, and time of day to create artificial sub-15-minute variability estimates for modeling dynamic load profiles. An autoregressive, AR(1) function along with a high pass filter was used to simulate the high resolution variability. The simulated data were validated against the original 1-second measured data.
来自日本太田市一个高度仪表化的住宅馈电系统的数据被用来确定50、100、250和500个家庭的1秒负荷变异性。负载可变性通过将数据分成季节、工作日、周末和一天中的时间来分类,从而为建模动态负载概要创建人工的低于15分钟的可变性估计。使用自回归的AR(1)函数和高通滤波器来模拟高分辨率变异性。模拟数据与原始的1秒测量数据进行了验证。
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引用次数: 3
Relating indoor and outdoor performance of bifacial modules 有关双面模块的室内外性能
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925175
B. V. Van Aken, A. Carr
Although flash tests under standard test conditions yields lower power due to transmittance of the back sheet, bifacial modules are expected to outperform their monofacial equivalents in terms of yearly energy output in the field. Different transparent rear side materials have been compared. We compare flash tests for these bifacial modules at various incidence angles with and without a light scattering panel behind the modules. The results of an outdoor study comparing modules with transparent back sheet and modules with state-of-the-art AR coating on the front glass will be presented.
虽然在标准测试条件下,由于背板的透光性,闪蒸测试产生的功率较低,但双面模块预计在现场的年能量输出方面优于其单面等效组件。对不同的透明背面材料进行了比较。我们比较了这些双面模块在不同入射角下的闪光测试,在模块后面有和没有光散射面板。将展示一项户外研究的结果,该研究比较了带有透明背板的模块和在前玻璃上涂有最先进的AR涂层的模块。
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引用次数: 5
Non-toxic, colloidal ZnS-AgInS2 nanoparticles for organic-inorganic hybrid photovoltaics 用于有机-无机杂化光伏的无毒胶体ZnS-AgInS2纳米颗粒
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925211
E. Sanehira, C. Luscombe, Lih Y. Lin
Non-toxic, colloidal ZnS-AgInS2 nanoparticles are synthesized and characterized for organic-inorganic hybrid photovoltaic applications. The optical properties of these particles are easily tuned by changing the chemical composition of the nanoparticle. Additionally, the photoluminescence quantum yield of 37.5% suggests this material is a promising candidate for optoelectronic devices. A comparison of the photoluminescence spectra of ZnS-AgInS2 nanoparticle and poly-3(hexylthiophene) blends to poly-3(hexylthiophene) neat indicates charge transfer between the nanoparticle and the polymer occurs in solution. Photovoltaic devices were fabricated using blends of ZnS-AgInS2 nanoparticles, poly-3(hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester, yielding an average power conversion efficiency of 2.3%.
合成了无毒的胶体ZnS-AgInS2纳米粒子,并对其进行了表征,用于有机-无机杂化光伏应用。这些粒子的光学特性很容易通过改变纳米粒子的化学成分来调整。此外,37.5%的光致发光量子产率表明该材料是光电子器件的有前途的候选者。纳米ZnS-AgInS2和聚-3(己基噻吩)共混物与聚-3(己基噻吩)纯共混物的光致发光光谱比较表明,纳米ZnS-AgInS2与聚合物在溶液中发生电荷转移。采用ZnS-AgInS2纳米颗粒、聚-3(己基噻吩)和[6,6]-苯基- c61 -丁酸甲酯共混物制备光伏器件,平均功率转换效率为2.3%。
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引用次数: 0
The BOSCO cell concept: Bifacial operation with double-sided collection BOSCO细胞概念:双面操作,双面收集
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925348
F. Fertig, K. Krauss, J. Greulich, F. Clement, D. Biro, R. Preu, S. Rein
The recently introduced BOSCO (“Both Sides Collecting and Contacted”) solar cell exhibits emitter regions on front and rear side, which are interconnected by diffused vias. This allows double-sided collection of carriers in the base and bifacial operation while supporting standard module interconnection technology. This work gives a simplified loss analysis of the first batch of large-area multi-crystalline silicon cells. A potential efficiency improvement of 0.9 %abs in front-side efficiency and 25 %rel in rear-side efficiency is expected when implementing imminent technological measures.
最近推出的BOSCO(“两侧收集和接触”)太阳能电池在前后两侧展示发射极区域,它们通过扩散过孔相互连接。这样可以在支持标准模块互连技术的同时,在基地中双面采集载波和双面操作。本文对第一批大面积多晶硅电池的损耗进行了简化分析。在实施即将实施的技术措施时,预期在前侧面效率和后侧面效率方面的潜在效率提高0.9%和25%。
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引用次数: 1
III–V-N compounds for multi-junction solar cells on Si 硅基多结太阳能电池用III-V-N化合物
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925509
K. Yamane, N. Urakami, H. Sekiguchi, A. Wakahara
We proposed a GaPN/GaAsPN/Si multi-junction solar cell in which lattice constants for all layers matched to Si bottom cell. Initial growth of GaP layer on Si is an important role to suppress the anti-phase domain, stacking faults, threading dislocations and melt-back etching. According to theoretical estimation considering the strain effect, band-gap energy about 1.65 eV can be obtained by GaAs0.2P0.74N0.06 which satisfies the lattice-matching condition to Si. In order to clarify the possibility of this material system, we grew GaPN and GaAsPN on the structural defect-free GaP/Si template by using rf-MBE. We also investigated the pinning state at the GaP(N)/Si heterointerface to design a low-loss tunneling junction.
我们提出了一种GaPN/GaAsPN/Si多结太阳能电池,其所有层的晶格常数与Si底电池相匹配。硅表面GaP层的初始生长是抑制反相畴、层错、螺纹位错和熔回腐蚀的重要因素。根据考虑应变效应的理论估计,满足Si晶格匹配条件的GaAs0.2P0.74N0.06可获得约1.65 eV的带隙能量。为了明确这种材料体系的可能性,我们利用rf-MBE在无结构缺陷的GaP/Si模板上生长了GaPN和GaAsPN。我们还研究了GaP(N)/Si异质界面上的钉住状态,以设计低损耗的隧道结。
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引用次数: 3
Progress toward developing a novel module architecture for increased reliability and reduced costs 为提高可靠性和降低成本而开发新型模块体系结构的进展
Pub Date : 2014-06-08 DOI: 10.1109/PVSC.2014.6925483
K. Barth, Davis Hemenway
Module reliability has a direct impact on the levalized cost of energy, and reliability issues for thin film PV have been consistently reported. Direct Solar LLC is developing a new module architecture for thin film PV that has robustness to moisture and excellent adhesion under UV light exposure. Process cycle times for each manufacturing step is under 1 minute using low capital cost, small footprint tooling. The patent pending architecture utilizes a specialized two part edge seal. The modules are fabricated without lamination, vacuum pressing or module heating. An initial version of this design has passed IEC 61646 and UL 1703 certification tests and 4500+hrs. of the rigorous 85 C/85% relative humidity “damp heat test”.
组件的可靠性直接影响能源的平化成本,而薄膜光伏的可靠性问题一直被报道。Direct Solar LLC正在开发一种新的薄膜光伏组件架构,该组件具有抗湿性和紫外线照射下的优异附着力。每个制造步骤的工艺周期时间在1分钟以下,使用低资本成本,小足迹的工具。正在申请专利的架构采用专门的两部分边缘密封。该模块的制造无需层压,真空压制或模块加热。该设计的初始版本已通过IEC 61646和UL 1703认证测试和4500+小时。严格的85℃/85%相对湿度“湿热试验”。
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引用次数: 7
期刊
2014 IEEE 40th Photovoltaic Specialist Conference (PVSC)
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