Pub Date : 2024-06-18DOI: 10.1007/s10971-024-06442-5
Davit Hambardzumyan, Harutyun Gyulasaryan, Astghik Kuzanyan, Armenuhi Sargsyan, Vardges Avagyan, Stanislav Kubrin, Aram Manukyan, Alexander S. Mukasyan
We report the synthesis of iron oxide nanoparticles using solution combustion synthesis, focusing on the controlled manipulation of material characteristics, such as particle size, phase composition, and magnetic properties, by applying external inert gas pressure. It was shown that variation of nitrogen gas pressure in the reactor in the range 0.1 to 1.1 MPa changed the time-temperature history of the process and resulted in the gradual change of phase composition of the fabricated materials along the FeO → FeO∙Fe2O3 → Fe2O3 route. The particle size varied in the 50–400 nm range, with a maximum for powder synthesized at a pressure of 0.25 MPa. For magnetic fluid hyperthermia, the critical parameter is specific loss power. It was demonstrated that this parameter can be optimized by gas pressure variation. The maximum specific loss power measured under conditions suitable for magnetic hyperthermia (magnetic field 33.5 mT and frequency 259.6 kHz) appears to be 174 W/g. The proposed innovative approach is an effective tool for controlling the synthesis of various nanoparticles with desired properties.
{"title":"Solution combustion synthesis of iron-based magnetic nanoparticles: influence of inert gas pressure","authors":"Davit Hambardzumyan, Harutyun Gyulasaryan, Astghik Kuzanyan, Armenuhi Sargsyan, Vardges Avagyan, Stanislav Kubrin, Aram Manukyan, Alexander S. Mukasyan","doi":"10.1007/s10971-024-06442-5","DOIUrl":"https://doi.org/10.1007/s10971-024-06442-5","url":null,"abstract":"<p>We report the synthesis of iron oxide nanoparticles using solution combustion synthesis, focusing on the controlled manipulation of material characteristics, such as particle size, phase composition, and magnetic properties, by applying external inert gas pressure. It was shown that variation of nitrogen gas pressure in the reactor in the range 0.1 to 1.1 MPa changed the time-temperature history of the process and resulted in the gradual change of phase composition of the fabricated materials along the FeO → FeO∙Fe<sub>2</sub>O<sub>3</sub> → Fe<sub>2</sub>O<sub>3</sub> route. The particle size varied in the 50–400 nm range, with a maximum for powder synthesized at a pressure of 0.25 MPa. For magnetic fluid hyperthermia, the critical parameter is specific loss power. It was demonstrated that this parameter can be optimized by gas pressure variation. The maximum specific loss power measured under conditions suitable for magnetic hyperthermia (magnetic field 33.5 mT and frequency 259.6 kHz) appears to be 174 W/g. The proposed innovative approach is an effective tool for controlling the synthesis of various nanoparticles with desired properties.</p>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141520677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-18DOI: 10.1007/s10971-024-06432-7
Xiu Liu, Jing-Chao Xie, Qun-Yan Li, Li Liu, Qi Wei, Su-Ping Cui, Zuo-Ren Nie
The design and synthesis of porous carbons with unique structures and diverse functionalities as CO2 adsorbents constitute a challenging and intriguing research topic. In this study, the synthesis of hollow micro-mesoporous nitrogen-doped carbon nanoparticles (NPCS) and its adsorption of CO2 were investigated. Highly porous nitrogen-doped carbon nanoparticles were successfully synthesized by using economically available resorcinol and formaldehyde as carbon precursors, with N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (KH-792) as a soft template and silica sol as a hard template. The hollow nitrogen-doped carbon nanoparticles exhibit an evident microporous-mesoporous structure and have two different scales of mesopores with 9 nm and 12 nm, respectively. The effects of various synthetic parameters on the formation of hollow nitrogen-doped carbon nanoparticles were analyzed. The hollow nitrogen-doped carbon nanoparticles exhibited specific surface area of 1090 to 1716 m2/g and nitrogen content of 2.83 to 5.28%. At 273 K and 1 bar, the experimental results demonstrated the positive effects of the enriched pore structure and nitrogen doping on CO2 adsorption. The optimum adsorption capacity of activated NPCS (ANPCS) was 5.11 mmol/g with excellent CO2/N2 selectivity value of 20.44 at 273 K and 1 bar. The initial heat of adsorption value for ANPCS was 30.90 KJ/mol. Additionally, the hollow nitrogen-doped carbon nanoparticles retained 99.2% of the initial adsorbed amount after 5 cycles of adsorption. The excellent adsorption performance of the material can be ascribed not only to its extensive specific surface area and enriched nitrogen but also to its mesoporous and hollow structure, which facilitates rapid CO2 transport.
Graphical Abstract
设计和合成具有独特结构和多种功能的多孔碳作为二氧化碳吸附剂是一个极具挑战性和引人入胜的研究课题。本研究考察了中空微多孔掺氮纳米碳颗粒(NPCS)的合成及其对二氧化碳的吸附。该研究以N-(2-氨基乙基)-3-氨基丙基三甲氧基硅烷(KH-792)为软模板,以二氧化硅溶胶为硬模板,采用经济实惠的间苯二酚和甲醛为碳前驱体,成功合成了高孔隙氮掺杂碳纳米颗粒。掺氮空心碳纳米颗粒呈现出明显的微孔-介孔结构,并具有两种不同尺度的介孔,分别为 9 nm 和 12 nm。分析了各种合成参数对掺氮空心碳纳米颗粒形成的影响。空心掺氮碳纳米粒子的比表面积为 1090 至 1716 m2/g,氮含量为 2.83 至 5.28%。在 273 K 和 1 bar 条件下,实验结果表明丰富的孔隙结构和氮掺杂对二氧化碳的吸附具有积极作用。在 273 K 和 1 bar 条件下,活化 NPCS(ANPCS)的最佳吸附容量为 5.11 mmol/g,CO2/N2 选择性为 20.44。ANPCS 的初始吸附热值为 30.90 KJ/mol。此外,中空掺氮纳米碳颗粒在 5 个吸附周期后保留了 99.2% 的初始吸附量。该材料优异的吸附性能不仅归功于其广泛的比表面积和富集的氮,还归功于其介孔和中空结构,这有利于二氧化碳的快速传输。
{"title":"Synthesis of hollow micro-mesoporous nitrogen-doped carbon nanoparticles for enhanced CO2 capture","authors":"Xiu Liu, Jing-Chao Xie, Qun-Yan Li, Li Liu, Qi Wei, Su-Ping Cui, Zuo-Ren Nie","doi":"10.1007/s10971-024-06432-7","DOIUrl":"https://doi.org/10.1007/s10971-024-06432-7","url":null,"abstract":"<p>The design and synthesis of porous carbons with unique structures and diverse functionalities as CO<sub>2</sub> adsorbents constitute a challenging and intriguing research topic. In this study, the synthesis of hollow micro-mesoporous nitrogen-doped carbon nanoparticles (NPCS) and its adsorption of CO<sub>2</sub> were investigated. Highly porous nitrogen-doped carbon nanoparticles were successfully synthesized by using economically available resorcinol and formaldehyde as carbon precursors, with N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (KH-792) as a soft template and silica sol as a hard template. The hollow nitrogen-doped carbon nanoparticles exhibit an evident microporous-mesoporous structure and have two different scales of mesopores with 9 nm and 12 nm, respectively. The effects of various synthetic parameters on the formation of hollow nitrogen-doped carbon nanoparticles were analyzed. The hollow nitrogen-doped carbon nanoparticles exhibited specific surface area of 1090 to 1716 m<sup>2</sup>/g and nitrogen content of 2.83 to 5.28%. At 273 K and 1 bar, the experimental results demonstrated the positive effects of the enriched pore structure and nitrogen doping on CO<sub>2</sub> adsorption. The optimum adsorption capacity of activated NPCS (ANPCS) was 5.11 mmol/g with excellent CO<sub>2</sub>/N<sub>2</sub> selectivity value of 20.44 at 273 K and 1 bar. The initial heat of adsorption value for ANPCS was 30.90 KJ/mol. Additionally, the hollow nitrogen-doped carbon nanoparticles retained 99.2% of the initial adsorbed amount after 5 cycles of adsorption. The excellent adsorption performance of the material can be ascribed not only to its extensive specific surface area and enriched nitrogen but also to its mesoporous and hollow structure, which facilitates rapid CO<sub>2</sub> transport.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141510409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SrTiO3 based lead-free ceramics has enormous potential for dielectric capacitors. This work focuses on the fabrication of small size Sr1-xCaxTiO3 (SCT) ceramic capacitors. Initially, the ceramics with a high doping concentration of 0.36 ≤ x ≤ 0.40 were prepared using the sol-gel method and characterized for their structural, morphological (grain), and dielectric properties. An increase in calcium doping concentration revealed a notable decline in the dielectric dissipation factor. Further, small size ceramic capacitors with ≈ 1mm2 dimensions were micro-machined in order to replicate the size of high-frequency commercial capacitors and to emphasize the real potential of this class of ceramics for dielectric capacitors. The dielectric properties, measured from 100 Hz to 1 GHz, such as permittivity (ε′), loss tangent (tgδ), and quality coefficient (Q) revealed that these materials could have a great interest in the development of monolithic ceramic capacitors dedicated to a very large frequency range from 100 Hz to 1 GHz applications.
{"title":"Study and manufacturing of strontium calcium titanate lead-free ceramic capacitors for high-frequency applications","authors":"Parthiban Palani, Amina Tachafine, Christophe Poupin, Didier Fasquelle","doi":"10.1007/s10971-024-06433-6","DOIUrl":"https://doi.org/10.1007/s10971-024-06433-6","url":null,"abstract":"<p>SrTiO<sub>3</sub> based lead-free ceramics has enormous potential for dielectric capacitors. This work focuses on the fabrication of small size Sr<sub>1-<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> (SCT) ceramic capacitors. Initially, the ceramics with a high doping concentration of 0.36 ≤ <i>x</i> ≤ 0.40 were prepared using the sol-gel method and characterized for their structural, morphological (grain), and dielectric properties. An increase in calcium doping concentration revealed a notable decline in the dielectric dissipation factor. Further, small size ceramic capacitors with <b>≈</b> 1mm<sup>2</sup> dimensions were micro-machined in order to replicate the size of high-frequency commercial capacitors and to emphasize the real potential of this class of ceramics for dielectric capacitors. The dielectric properties, measured from 100 Hz to 1 GHz, such as permittivity (ε′), loss tangent (tgδ), and quality coefficient (Q) revealed that these materials could have a great interest in the development of monolithic ceramic capacitors dedicated to a very large frequency range from 100 Hz to 1 GHz applications.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141520679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-13DOI: 10.1007/s10971-024-06447-0
Ali Moulahi
{"title":"Nanosized Al/Cu-NiO catalyst: integrated adsorption-photocatalysis for fast removal of rhodamine B, reactive black 5 and chlorpyrifos waste","authors":"Ali Moulahi","doi":"10.1007/s10971-024-06447-0","DOIUrl":"https://doi.org/10.1007/s10971-024-06447-0","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141349547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-12DOI: 10.1007/s10971-024-06453-2
K. Serivalsatit, Adison Saelee, S. Jiemsirilers, S. Jinawath
{"title":"Effect of pH on the chemical composition, morphology, and densification of magnesium aluminate spinel nanopowder synthesized by the coprecipitation method","authors":"K. Serivalsatit, Adison Saelee, S. Jiemsirilers, S. Jinawath","doi":"10.1007/s10971-024-06453-2","DOIUrl":"https://doi.org/10.1007/s10971-024-06453-2","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141350260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-11DOI: 10.1007/s10971-024-06450-5
Edgar F. Armendáriz-Alonso, O. Meza, E. G. Villabona-Leal, Elías Pérez
{"title":"Study of the luminescence mechanism of gadolinium and yttrium oxide hosts for Eu3+ rare earth ion synthesized by sol-gel method assisted with oleic acid","authors":"Edgar F. Armendáriz-Alonso, O. Meza, E. G. Villabona-Leal, Elías Pérez","doi":"10.1007/s10971-024-06450-5","DOIUrl":"https://doi.org/10.1007/s10971-024-06450-5","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141355927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-11DOI: 10.1007/s10971-024-06434-5
Sheraz Yousaf, Mohammad Altaf, Mohd Zahid Ansari
{"title":"Boosting the electrochemical water splitting efficiency of Copper Vanadium Oxide by Annealing method","authors":"Sheraz Yousaf, Mohammad Altaf, Mohd Zahid Ansari","doi":"10.1007/s10971-024-06434-5","DOIUrl":"https://doi.org/10.1007/s10971-024-06434-5","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141356643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-11DOI: 10.1007/s10971-024-06454-1
Shiwei Shi, Z. Abbas, Xiaohu Zheng, Xiangyu Zhao, Dazhi Wang
{"title":"Direct writing of suspended nanowires using coaxial electrohydrodynamic jet with double tip assistance","authors":"Shiwei Shi, Z. Abbas, Xiaohu Zheng, Xiangyu Zhao, Dazhi Wang","doi":"10.1007/s10971-024-06454-1","DOIUrl":"https://doi.org/10.1007/s10971-024-06454-1","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141359138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-11DOI: 10.1007/s10971-024-06440-7
Danielle.L. Perry, Anthony. W. Wren
{"title":"Optimization of the sol–gel synthesis parameters on Zn–Cu–Co-doped silicate-based bioactive glass for tissue repair","authors":"Danielle.L. Perry, Anthony. W. Wren","doi":"10.1007/s10971-024-06440-7","DOIUrl":"https://doi.org/10.1007/s10971-024-06440-7","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141359888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-10DOI: 10.1007/s10971-024-06439-0
Rida Fatima, Nadim Ullah, Uzma Bilal, Hasnain Asghar Khan, T. M. Almutairi, Shahroz Saleem
{"title":"Facile and sustainable synthesis of metal nanoparticles (Ag, Fe, Cu, and Zn) using polyamide and polyhydrazide","authors":"Rida Fatima, Nadim Ullah, Uzma Bilal, Hasnain Asghar Khan, T. M. Almutairi, Shahroz Saleem","doi":"10.1007/s10971-024-06439-0","DOIUrl":"https://doi.org/10.1007/s10971-024-06439-0","url":null,"abstract":"","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141366542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}