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2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)最新文献

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Investigation of Radiative Coupling from InGaAsP Quantum Wells for Improving End-of-Life (EOL) Efficiency in Multijunction Solar Cells InGaAsP量子阱辐射耦合提高多结太阳能电池寿命终止效率的研究
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8981220
G. Bradshaw, M. Kacharia, E. Kessler-Lewis, D. Wilt, S. Polly, C. Mann, H. Kum, S. Hubbard
GaInP/(In)GaAs/Ge multijunction solar cells have been state-of-practice for power generation on spacecraft for over a decade but there are still potential improvements for endof-life (EOL) efficiency. Radiative coupling between GaInP and (In)GaAs subcells is not typically considered in the EOL design of space solar cells because radiative recombination in the GaInP is effectively quenched by radiation-induced damage. This paper shows that quantum well structures incorporated into a GaInP subcell may be less sensitive to radiation damage, thereby enabling radiative coupling between subcells at EOL and providing a current boost in the (In)GaAs subcell to improve EOL efficiency.
GaInP/(In)GaAs/Ge多结太阳能电池已经在航天器上进行了十多年的发电实践,但在寿命结束(EOL)效率方面仍有改进的潜力。在空间太阳能电池的EOL设计中,通常不考虑GaInP和(In)GaAs亚电池之间的辐射耦合,因为GaInP中的辐射复合被辐射引起的损伤有效地抑制了。本文表明,加入到GaInP亚电池中的量子阱结构可能对辐射损伤不太敏感,从而实现了EOL亚电池之间的辐射耦合,并在(in)GaAs亚电池中提供电流增强以提高EOL效率。
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引用次数: 0
Nanometer-Scale Imaging of Inhomogeneous Active Charge Carriers in Arsenic-Doped CdTe Thin Films 砷掺杂CdTe薄膜中非均匀活性电荷载流子的纳米成像
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980573
C. Jiang, J. Moseley, C. Xiao, S. Harvey, E. Colegrove, W. Metzger, M. Al‐Jassim
We report nanometer-scale imaging of active carrier distribution of As-doped CdTe films by scanning capacitance microscopy (SCM). We developed SCM sample preparation for CdTe by ion-milling followed by thermal processing. The nanometer-resolution carrier delineation for CdTe was validated by imaging on a CdTe cross-section sample made by a molecular beam epitaxy layer stack with As-doping concentrations of 1015~1018/cm3. We found that the carrier distribution in As-doped films was significantly nonuniform, with inhomogeneity ranging from sub-μm to a few μm and concentration variation of one order of magnitude (low 1016 to low 1017/cm3). This nonuniformity is distributed randomly, independent of grain structure and grain boundary (GB). We used Kelvin probe force microscopy (KPFM) and cathodoluminescence (CL) to further map the surface potential and radiative illumination on the same area as the SCM image. Higher potential and lower CL intensity were found on GBs but not on SCM contrast, illustrating positive GB charging and GB recombination but not GB-distinguished doping. The overall KPFM potential image is in rough agreement with the SCM carrier distribution, in terms of Fermi-level position relative to the bandgap edge—thus resulting in the band-edge potential fluctuation. Nonuniform carrier concentration, potential fluctuation, and defect recombination can all together cause the Voc deficit of the As-doped CdTe device.
我们报道了用扫描电容显微镜(SCM)对砷掺杂CdTe薄膜的有源载流子分布的纳米级成像。采用离子铣削和热加工的方法制备了碲化镉的单片机样品。通过对掺杂浓度为1015~1018/cm3的分子束外延层堆叠的CdTe横截面样品进行成像,验证了CdTe的纳米分辨率载流子描述。我们发现as掺杂薄膜中的载流子分布明显不均匀,不均匀性从亚μm到几μm不等,浓度变化为一个数量级(低1016到低1017/cm3)。这种非均匀性是随机分布的,与晶粒结构和晶界(GB)无关。我们使用开尔文探针力显微镜(KPFM)和阴极发光(CL)进一步绘制了与SCM图像相同区域的表面电位和辐射照明。在GB对比上发现了更高的电位和更低的CL强度,而在SCM对比上没有发现,说明了GB正充电和GB重组,而不是GB区分掺杂。总的KPFM电位图像在相对于带隙边缘的费米能级位置上与SCM载流子分布大致一致,从而导致带隙边缘电位波动。载流子浓度不均匀、电势波动和缺陷复合都会导致掺as CdTe器件的Voc亏缺。
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引用次数: 0
GaAs/Si Double-Junction Cells Fabricated by Sacrificial Layer Etching of Directly-Bonded III-V/Si Junctions 牺牲层蚀刻直接键合III-V/Si结制备GaAs/Si双结电池
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980757
Ryo Kozono, Sanji Yoon, Jianbo Liang, N. Shigekawa
A GaAs/Si double-junction cell is fabricated by directly bonding a GaAs single-junction cell structure grown on a GaAs (001) substrate to a n-on-p Si sub-cell and separating the GaAs substrate using a sacrificial layer etching. Before the sacrificial layer etching, the III-V/Si junction is annealed at 300 ℃ for 1 hour so as to recrystallize the interface and achieve an enough bonding strength based on the results of hard X-ray photoemission spectroscopy. We obtain a bonding yield of ~80% after the sacrificial layer etching. We confirm that the fabricated double-junction cell normally operates by measuring its current-voltage and spectral-response characteristics.
通过将生长在GaAs(001)衬底上的GaAs单结电池结构与n-on-p - Si亚电池直接键合,并使用牺牲层蚀刻分离GaAs衬底,制备了GaAs/Si双结电池。在牺牲层蚀刻之前,根据硬x射线光发射光谱结果,将III-V/Si结在300℃下退火1小时,使界面再结晶,达到足够的键合强度。在牺牲层蚀刻后,得到了约80%的成键率。通过测量双结电池的电流-电压和光谱响应特性,证实了双结电池正常工作。
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引用次数: 1
Post-Deposition Recrystallization of Co-Evaporated CuInxGa(1-x)Se2 Films by Bromide Vapor Treatments 溴化物蒸汽处理共蒸发CuInxGa(1-x)Se2薄膜沉积后的再结晶
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980803
Elizabeth Palmiotti, S. Karki, Benjamin Belfore, Sina Soltanmohammad, G. Rajan, S. Marsillac, A. Rockett
CIGS films deposited at 400°C onto molybdenum-coated soda-lime glass substrates by co-evaporation were annealed in InBr3 vapors or CuBr with Se vapors. The treatments were conducted at 400°C, 450°C, or 500°C for one hour. The InBr3 treatments above 400°C and CuBr with Se treatments at 500°C resulted in increased grain size, improved crystallinity, and a decrease in Cu2Se phase. Annealed samples also exhibited large surface facets. CIGS films deposited at 350°C were also investigated in InBr3 and CuBr with Se vapors at 450°C for one hour. These treatments resulted in increased grain size and less deviations from the as-deposited composition.
在400°C下通过共蒸发将CIGS薄膜沉积在钼包覆的钠石灰玻璃衬底上,并在InBr3蒸气或CuBr蒸气中与Se蒸气进行退火。分别在400°C、450°C或500°C下处理1小时。400°C以上的InBr3处理和500°C的cur + Se处理导致晶粒尺寸增大,结晶度提高,Cu2Se相减少。退火后的样品也表现出较大的表面切面。在350°C下沉积的CIGS薄膜也在450°C下用Se气相在InBr3和CuBr中沉积1小时进行了研究。这些处理增加了晶粒尺寸,减少了与沉积时成分的偏差。
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引用次数: 4
Real-world PV Module Degradation across Climate Zones Determined from Suns-Voc, Loss Factors and I-V Steps Analysis of Eight Years of I-V, Pmp Time-series Datastreams 从太阳- voc,损失因子和I-V步骤确定的真实世界PV组件跨气候区的退化,8年I-V的分析,Pmp时间序列数据流
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980541
Jiqi Liu, Menghong Wang, A. Curran, Ahmad Maroof Karimi, Wei-Heng Huang, Erdmut Schnabel, M. Köhl, J. Braid, R. French
We report here on performance and mechanistic degradation analysis of 8 years of I-V, Pmp time-series for eight commercial crystalline silicon photovoltaic (PV) modules, located in three distinct climate zones. A data-driven algorithm has been applied to extract I-V features and detect steps in 3.2 million I-V curves. Using the Y ear-on-Y ear determined linear PLR, we found that one brand F (glass-backsheet) module has a much greater (more negative) PLR than another brand G (double glass) in BWh hot desert climate zone. BSh hot semi-arid is shown to be the most aggressive climate zone of the three in which modules were fielded, the third being ET tundra climate. The mechanisms causing most significant power loss for modules in BWh, BSh and ET climate zones are current mismatch (shading), cell shunting, and series resistance, respectively based on Analytic Suns-Voc analysis derived from outdoor I-V curves. Using steps observed in the I-V curves of the systems we are also able to identify and characterize the shading of specific modules.
我们在此报告了8年I-V, Pmp时间序列的八个商用晶体硅光伏(PV)组件的性能和机理退化分析,位于三个不同的气候区。采用数据驱动算法对320万条I-V曲线进行I-V特征提取和步长检测。使用Y耳对Y耳确定的线性PLR,我们发现在BWh炎热的沙漠气候区,一个品牌F(玻璃背板)模块比另一个品牌G(双层玻璃)具有更大(更负)的PLR。BSh热半干旱被证明是三个模块中最具侵略性的气候区,第三个是ET苔原气候。根据室外I-V曲线的解析太阳- voc分析,在BWh、BSh和ET气候区,造成模块最显著功率损失的机制分别是电流不匹配(遮阳)、电池分流和串联电阻。使用在系统的I-V曲线中观察到的步骤,我们还能够识别和表征特定模块的阴影。
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引用次数: 9
Annual energy yield analysis of solar cell technology 太阳能电池技术年发电量分析
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980523
M. Abbott, G. Xing, G. Scardera, D. Payne, K. McIntosh, Ben A. Sudbury, J. Meydbray, T. Fung, Muhammad Umair Khan, Yu Zhang, S. Zou, Xusheng Wang
The ultimate value of any photovoltaic technology is the amount of energy it delivers once installed in the field. Gathering this data experimentally can take many years and requires great cost with limited scope to vary the input parameters. Simulations based on detailed lab measurements provide a more cost-effective option to predict the energy yield of a PV technology rapidly. This paper demonstrates the application of highly detailed ray tracing and SPICE modelling to determine the annual energy yield. It compares the simulated performance of different texturing technologies and predicts the losses at a cell, module and system level. Specifically, it studies upright random pyramids, isotexture and two types of MCCE black silicon applied to a Cz bifacial PERC cell. The difference between isotexture and random pyramids was close to 5% at the cell level, however this significantly reduced to less than 2% at a system level indicating that this analysis is critical to properly assess the ultimate value of a technology.
任何光伏技术的最终价值在于它在现场安装后提供的能量。通过实验收集这些数据可能需要多年的时间,并且需要很大的成本,而且改变输入参数的范围有限。基于详细实验室测量的模拟为快速预测光伏技术的能量产量提供了一种更具成本效益的选择。本文演示了高度详细的光线追踪和SPICE建模在确定年发电量方面的应用。比较了不同纹理技术的模拟性能,并预测了单元级、模块级和系统级的损耗。具体来说,它研究了直立随机金字塔,等织构和两种类型的MCCE黑硅应用于Cz双面PERC电池。在细胞水平上,等纹理和随机金字塔之间的差异接近5%,但在系统水平上,这一差异显著降低到不到2%,这表明这种分析对于正确评估一项技术的最终价值至关重要。
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引用次数: 4
The Case for Custom TMY’s: Examples Using the NSRDB 定制TMY的案例:使用NSRDB的例子
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980811
M. Sengupta, A. Habte, J. Freeman
A typical meteorological year (TMY) data set essentially represents an hourly compilation of median months constructed using multi-year datasets. Although TMY data sets are generated from irradiance data in the horizontal plane, they are used in photovoltaic (PV) modeling for systems inclined to various angles. This paper demonstrates that a POA TMY (plane of array TMY) generated by selecting median months from a multi-year POA irradiance timeseries dataset produces significantly different results than a POA TMY generated by transposing a TMY dataset constructed from horizontal data. In some months the differences can be more than 3%. These results point to the need for generating TMY’s using POA irradiance timeseries representing the orientation at which PV panels will be deployed.
一个典型的气象年(TMY)数据集本质上代表了使用多年数据集构建的中位数月份的每小时汇编。虽然TMY数据集是由水平面上的辐照度数据生成的,但它们用于光伏(PV)建模,用于倾斜不同角度的系统。本文证明,从多年POA辐照度时间序列数据集中选择中位数月份生成的POA TMY(阵列平面TMY)与从水平数据构建的TMY数据集转置生成的POA TMY结果显著不同。在某些月份,差异可能超过3%。这些结果表明,需要使用POA辐照度时间序列来生成TMY,该时间序列代表PV板将部署的方向。
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引用次数: 1
Effects of CsF Post-deposition Treatment on Cu(In, Ga)Se2 Thin Films and Solar Cells CsF沉积后处理对Cu(In, Ga)Se2薄膜和太阳能电池的影响
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980502
Hojin Lee, Kihwan Kim, Yuseong Jang, Seong-wook Nam, B. Shin
Heavy alkali (such as Cs, Rb) post-deposition treatment is an indispensable process step to achieve high performing CIGS solar cells. However, there is not enough understanding of the mechanisms leading to the performance improvement by heavy alkali. Here, we report a systematic study on the effects of elemental Cs on chemical and optoelectronic properties CIGS thin films and the final solar cells. We found that main beneficial role of Cs is passivation of deep-level defects and thereby enhancing p-type conduction of the CIGS.
重碱(如Cs、Rb)沉积后处理是实现高性能CIGS太阳能电池不可缺少的工艺步骤。然而,人们对重碱提高性能的机理还不够了解。本文系统地研究了元素Cs对CIGS薄膜和最终太阳能电池的化学和光电性能的影响。我们发现Cs的主要有益作用是钝化深能级缺陷,从而增强CIGS的p型导通。
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引用次数: 1
Electronic Properties and Molar Excitation Coefficient for Organic Solar Cells Materials by using TD-DFT Method 利用TD-DFT方法研究有机太阳能电池材料的电子特性和摩尔激发系数
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980795
M. Salim, R. Nekovei
This paper evaluated the oscillator strength and the band gap for specific organic photovoltaic cells (OPV) materials by using Time-Dependent Density Functional Theory (TD-DFT). The oscillator strength values are used to find absorption spectrum of those materials in term of the molar excitation coefficient, dielectric constant and the refractive indices for those materials. The band gap value is used to find the donor-acceptor materials combination that can give the highest open circuit voltage. The donor materials covered in this paper are P3HT, Octithiophene, Sexithiophene, Quaterthiophene, and Pentacene. Also, the study covers the following acceptor materials: C60, C70, PCBM, and Bis- PCBM
本文利用时变密度泛函理论(TD-DFT)对特定有机光伏电池(OPV)材料的振子强度和带隙进行了评价。利用振子强度值来计算这些材料的摩尔激发系数、介电常数和折射率的吸收光谱。带隙值用于寻找能提供最高开路电压的施主-受主材料组合。本文涉及的给体材料有P3HT、八硫噻吩、六硫噻吩、季硫噻吩和并戊烯。此外,本研究还涵盖了以下受体材料:C60、C70、PCBM和Bis- PCBM
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引用次数: 4
Rough and Straightforward Estimation of the Mismatching Loss by Partial Shading of the PV Modules Installed on an Urban Area or Car-Roof 通过部分遮阳对安装在城市地区或车顶的光伏组件进行不匹配损失的粗略和直接估计
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8981199
K. Araki, Kan‐Hua Lee, T. Masuda, Yoshitaka Hayakawa, N. Yamada, Y. Ota, M. Yamaguchi
Solar panels used for EV charging stations and car-roof PV are often partially shaded and lead to substantial energy loss. It is known that this mismatching loss can be reduced by increasing the number of parallel strings. First, a probability model was developed using a one-year solar irradiance monitoring around the car body in 5 directions. The developed model successfully matched to the measured solar resource in each direction and succeeded to quantify the probability of the partial shading on the car. Another related issue of the inherent mismatching loss of the car-roof PV is non-uniform illumination caused by the curved shape of the panel. This can also be modeled by ray-tracing simulation. Then, we calculated the PV output affected by mismatching due to various sunlight patterns and partial shade patterns by Monte Carlo method. It was found that the average efficiency asymptotically approached 1 - 1 / N (N is the number of strings). We also examined the relationship between partial shade quantity and power generation loss in a 30 kW solar system array and verified the above model.
用于电动汽车充电站和车顶光伏的太阳能电池板往往部分遮阳,导致大量的能量损失。众所周知,这种不匹配损失可以通过增加并行字符串的数量来减少。首先,利用为期一年的车身周围5个方向的太阳辐照度监测,建立了概率模型。所建立的模型成功地匹配了每个方向上实测的太阳能资源,并成功地量化了汽车部分遮阳的概率。车顶光伏固有的不匹配损失的另一个相关问题是由于面板的弯曲形状引起的不均匀照明。这也可以通过光线追踪模拟来建模。在此基础上,利用蒙特卡罗方法计算了不同光照模式和部分遮荫模式对光伏输出的影响。发现平均效率渐近于1 - 1 / N (N为串数)。我们还研究了30 kW太阳能系统阵列的部分遮荫量与发电损失之间的关系,并验证了上述模型。
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引用次数: 12
期刊
2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)
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