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Fabrication of novel polyethersulfone (PES) photocatalytic membranes with excellent permeability and antifouling properties using TiO2–AgBr–Ag–SBA-15 nanofillers for cefixime removal 利用 TiO2-AgBr-Ag-SBA-15 纳米填料制备具有优异渗透性和防污性能的新型聚醚砜(PES)光催化膜,用于去除头孢克肟
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-24 DOI: 10.1007/s13738-024-03031-9
Shahnaz Nayeri, Jalal Basiri Parsa

This study aimed to enhance the permeability and antifouling properties of the polymer membrane of polyethersulfone (PES) through the modification with TiO2–AgBr–Ag–SBA-15. The hydrothermal process is used to create silica nanoparticles (SBA-15), which involved the use of tetraethylorthosilicate as a precursor and a copolymer Pluronic P123 (as a mold and the structure maintainer after solvent exiting). Then, SBA-15 nanoparticles are added to the preparation solution of TiO2–AgBr–Ag, resulting doping nanoparticles (TiO2–AgBr–Ag–SBA-15) were incorporated into the casting solution to achieve weight percentages of 0.4, 0.6, 0.8 and 1 in the final membranes. The nanoparticles were characterized using FESEM, FT-IR, XRD, XPS and EDX. Meanwhile, the membrane properties were studied using FESEM, FT-IR, CA, AFM and membrane performance tests. The hybrid membranes exhibited a less hydrophobic surface, which consequently resulted in water permeability. Moreover, the antifouling properties were notably improved, resulting in a considerable improvement in permeability without compromising the membrane's ability to remove unwanted substances. At 3.5 bar pressure, the pure water flux of the 0.8 wt% PES/TiO2–AgBr–Ag–SBA-15 membrane was two times higher than that of the pristine membrane. Flux recovery rate of 1 wt% PES/TiO2–AgBr–Ag–SBA-15 membrane can reach 90%, and the antifouling performance is excellent.

本研究旨在通过使用 TiO2-AgBr-Ag-SBA-15 改性聚醚砜(PES)聚合物膜,提高其渗透性和防污性能。采用水热法制造二氧化硅纳米颗粒(SBA-15),其中包括使用四乙基正硅酸盐作为前驱体和共聚物 Pluronic P123(作为模具和溶剂排出后的结构保持剂)。然后,在 TiO2-AgBr-Ag 的制备溶液中加入 SBA-15 纳米粒子,最后在浇铸溶液中加入掺杂纳米粒子(TiO2-AgBr-Ag-SBA-15),使最终膜的重量百分比分别达到 0.4、0.6、0.8 和 1。使用 FESEM、FT-IR、XRD、XPS 和 EDX 对纳米颗粒进行了表征。同时,利用 FESEM、FT-IR、CA、AFM 和膜性能测试研究了膜的特性。混合膜的表面疏水性较低,因此透水性较好。此外,膜的防污性能也得到了显著改善,从而在不影响膜去除有害物质能力的情况下大大提高了透水性。在 3.5 巴压力下,0.8 wt% PES/TiO2-AgBr-Ag-SBA-15 膜的纯水通量是原始膜的两倍。1 wt% PES/TiO2-AgBr-Ag-SBA-15 膜的通量回收率可达 90%,防污性能优异。
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引用次数: 0
Optical and electrochemical investigation on one-step three electron reduction of [AuIII(Salen)]Cl to Au(0): a comprehensive analysis 一步法三电子还原[AuIII(Salen)]Cl 至 Au(0)的光学和电化学研究:综合分析
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-22 DOI: 10.1007/s13738-024-03039-1
Sontara Konwar Boruah, Hirendra Das, Prabin Kumar Boruah

This work presents a comprehensive study of the UV–Visible and fluorescence properties, as well as the redox behavior of the [AuIII(Salen)]Cl complex in acetonitrile. The [AuIII(Salen)]+ complex exhibited intriguing fluorescence and phosphorescence characteristics on an indium tin oxide (ITO)-coated glass plate when excited at wavelength λexc ~ 260 nm, with fluorescence emission observed at λems ~ 437 nm and phosphorescence at λems ~ 520 nm. The origin of fluorescence emission was attributed to the intra-ligand charge transfer effect, commonly known as the "Push–Pull" effect. The electrochemical behavior of [AuIII(Salen)]+ on a glassy carbon electrode (GCE) revealed a remarkable one-step three-electron reduction process, leading to the reduction of [AuIII(Salen)]+ to Au(0). Furthermore, the reduction of [AuI(Salen)] to Au(0) resulted in the removal of gold metal from the SalenH2 ligand. The electrochemical results suggested a mixed diffusion-adsorption redox process occurring at the GCE surface, indicating the involvement of both diffusion and adsorption during redox reactions. The cyclic voltammogram demonstrated the non-reversibility of the electrochemical redox reactions. Overall, the redox behavior of the [AuIII(Salen)]Cl complex proved to be intriguing, opening up avenues for further exploration and potential applications of this complex in various fields.

Graphical abstract

这项工作全面研究了[AuIII(Salen)]Cl 复合物在乙腈中的紫外可见光和荧光特性以及氧化还原行为。当波长为 λexc ~ 260 nm 时,[AuIII(Salen)]+ 复合物在铟锡氧化物(ITO)镀膜玻璃板上显示出奇特的荧光和磷光特性,在 λems ~ 437 nm 处观察到荧光发射,在 λems ~ 520 nm 处观察到磷光。荧光发射的原因是配体内电荷转移效应,即通常所说的 "推拉 "效应。玻璃碳电极(GCE)上[AuIII(Salen)]+ 的电化学行为显示了一个显著的一步三电子还原过程,导致[AuIII(Salen)]+ 还原成 Au(0)。此外,[AuI(Salen)]- 还原成 Au(0)时,金金属从 SalenH2 配体中脱落。电化学结果表明,在 GCE 表面发生了扩散和吸附混合氧化还原过程,表明在氧化还原反应中扩散和吸附都参与其中。循环伏安图显示了电化学氧化还原反应的不可逆性。总之,[AuIII(Salen)]Cl 复合物的氧化还原行为证明是耐人寻味的,为该复合物在各个领域的进一步探索和潜在应用开辟了途径。
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引用次数: 0
Synthesis, characterization, and adsorption capacity of sodium alginate poly grafted (fumaric acid-co-polyacrylic acid)/graphene oxide hydrogel as adsorbent for Cr (VI) and Pb (II) removal 海藻酸钠聚接枝(富马酸-聚丙烯酸)/氧化石墨烯水凝胶作为吸附剂去除铬 (VI) 和铅 (II) 的合成、表征和吸附能力
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-18 DOI: 10.1007/s13738-024-03037-3
Hiba Alnasery, Abdolhossein Naseri, Layth Samir Jasim, Sanaz Sajedi-Amin

This study involves the preparation of sodium alginate poly grafted (fumaric acid-polyacrylic acid)/graphene oxide, SA-g-p(FA-AA)/GO hydrogel to explore its potential as a promising adsorbent for water treatment mainly chromium (VI) and lead (II) removal. Prepared adsorbent was characterized by FTIR, TGA, XRD, FESEM, and TEM techniques for exploring the chemical structure, thermal stability, crystallography, surface area and morphology, as well as pore size and distribution of SA-g-p(FA-AA)/GO, respectively. The average size of the prepared nanoparticles was observed to be 78.48 nm. The TEM images exhibit a predominantly spherical shape and heterogeneous. Effect of different physiochemical parameters such as pH, temperature, adsorbent dosage, and contact time was explored for maximum metal adsorption. The results of the study revealed that the maximum adsorption capacity of SA-g-p(FA-AA)/GO (0.045 mg g−1 for Cr (VI) and 22.371 mg g−1 for Pb (II)) was achieved under optimized conditions, i.e., adsorbent dose of 0.05 g at 25 °C for pH of 2, 4.5 when contact time of 5 and 100 min was used for Cr(VI) and Pb(II), respectively. Data fits best to the pseudo-second-order kinetic equation revealing the multilayer adsorption of Cr (VI) and Pb (II) ions on the heterogeneous adsorbent surface. Thermodynamically, the process of Cr (VI) and Pb (II) adsorption was non-spontaneous, exothermic and feasible revealing the potential of the prepared adsorbent to be used as an efficient adsorbent for metal removal.

本研究涉及海藻酸钠聚接枝(富马酸-聚丙烯酸)/氧化石墨烯(SA-g-p(FA-AA)/GO)水凝胶的制备,以探索其作为水处理吸附剂的潜力,主要是去除铬(VI)和铅(II)。利用傅立叶变换红外光谱(FTIR)、热重分析(TGA)、X射线衍射(XRD)、可见分光光电子能谱(FESEM)和可见分光光电子能谱(TEM)技术对制备的吸附剂进行了表征,分别探讨了SA-g-p(FA-AA)/GO的化学结构、热稳定性、结晶学、表面积和形貌以及孔径和分布。制备的纳米粒子的平均尺寸为 78.48 nm。TEM 图像显示,纳米颗粒主要呈球形,且具有异质性。研究人员探讨了 pH 值、温度、吸附剂用量和接触时间等不同理化参数对金属吸附量最大化的影响。研究结果表明,SA-g-p(FA-AA)/GO 的最大吸附容量(0.045 mg g-1(六价铬)和 22.371 mg g-1(二价铅))是在优化条件下实现的,即吸附剂剂量为 0.05 g,温度为 25 °C,pH 值为 2、4.5,六价铬和二价铅的接触时间分别为 5 分钟和 100 分钟。数据与伪二阶动力学方程的拟合度最高,表明铬(VI)和铅(II)离子在异质吸附剂表面的多层吸附。从热力学角度看,Cr (VI) 和 Pb (II) 的吸附过程是非自发的、放热的和可行的,这揭示了所制备的吸附剂作为一种高效吸附剂去除金属的潜力。
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引用次数: 0
Ruthenium-exchanged montmorillonite as an efficient and reusable catalyst for the synthesis of bis(indolyl)methanes 钌交换蒙脱石作为合成双(吲哚基)甲烷的高效且可重复使用的催化剂
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-18 DOI: 10.1007/s13738-024-03038-2
Sam Takbiri, Mahmood Tavakoli Hafshejani, Farhad Shirini, Zahra Vari

The catalytic efficacy of ruthenium (Ru)-exchanged montmorillonite, a well-established heterogeneous catalyst, was systematically explored to synthesize diverse bis(indolyl)methanes. The developed methodology consistently yielded the desired products with satisfactory to excellent yields, while notable advantages of the proposed approach encompassed minimal reaction times and solvent-free conditions. Furthermore, the method was characterized by its procedural simplicity, facile catalyst synthesis, ready accessibility of the starting materials from commercial sources, and the potential for catalyst recyclability.

本研究系统地探讨了钌 (Ru) 交换蒙脱石(一种成熟的异相催化剂)在合成各种双(吲哚基)甲烷方面的催化功效。所开发的方法始终能以令人满意到极佳的收率获得所需的产品,同时,所提议的方法还具有反应时间最短和无溶剂条件等显著优势。此外,该方法还具有程序简单、催化剂合成方便、可从商业来源获得起始材料以及催化剂可回收利用的潜力等特点。
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引用次数: 0
Fabrication of Fe3O4/Al2O3/CuO magnetic nanocomposite and effective in the photedegradation of methylene blue 制备 Fe3O4/Al2O3/CuO 磁性纳米复合材料并有效光降解亚甲基蓝
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-18 DOI: 10.1007/s13738-024-03027-5
Sheida Makaremi, Ali Hossein Kianfar, Mohammad Amin Arayesh

In this research, a Fe3O4/Al2O3/CuO magnetic nanocomposite (NC) was prepared by co-precipitation method for photocatalytic activity and identified using VSM, TEM, FE-SEM, EDX, XRD and DRS techniques. Based on the TEM analysis, the structure of NC was observed as nanorods. Also, the presence of CuO was confirmed by EDX and XRD analyses. Using the DRS spectrum results, the energy band gap of Fe3O4/Al2O3/CuO NC was determined as ~ 2 eV. The synthesized compound was used as a photocatalyst for the degradation of methylene blue under sunlight irradiation. The reaction process was investigated by ultraviolet–visible spectroscopy. According to the obtained results from MB degradation about 95 percent of MB (10 mg/L) was decomposed after 25 min under sunlight irradiation. Furthermore, even after five cycles, the rate of MB degradation could still exceed 90 percent. Also, based on the obtained results, the synthesized NC can be recovered and reused in the photochemistry process. Additionally, based on the results, the Fe3O4/Al2O3/CuO NCs show high performance photocatalytic activity toward the degradation of MB under solar radiation.

Graphical abstract

本研究采用共沉淀法制备了一种具有光催化活性的 Fe3O4/Al2O3/CuO 磁性纳米复合材料(NC),并使用 VSM、TEM、FE-SEM、EDX、XRD 和 DRS 技术对其进行了鉴定。根据 TEM 分析,NC 的结构为纳米棒。此外,EDX 和 XRD 分析也证实了氧化铜的存在。利用 DRS 光谱结果,确定了 Fe3O4/Al2O3/CuO NC 的能带隙为 ~ 2 eV。合成的化合物被用作光催化剂,在阳光照射下降解亚甲基蓝。反应过程通过紫外可见光谱进行了研究。根据所获得的甲基溴降解结果,在阳光照射下 25 分钟后,约 95% 的甲基溴(10 mg/L)被分解。此外,即使经过五个循环,甲基溴的降解率仍可超过 90%。同时,根据所获得的结果,合成的 NC 可以在光化学过程中回收和重复使用。此外,根据研究结果,Fe3O4/Al2O3/CuO NCs 对在太阳辐射下降解甲基溴显示出高性能的光催化活性。
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引用次数: 0
Magnetic dispersive micro-solid-phase extraction integrated with hollow fiber liquid-phase microextraction for preconcentration of trace amounts of chlorpyrifos pesticide in aqueous samples 磁分散微固相萃取与中空纤维液相微萃取相结合预富集水样中的痕量毒死蜱农药
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-14 DOI: 10.1007/s13738-024-03028-4
Reyhaneh Kouchakinejad, Shahab Shariati, Jafar Abolhasani, Ebrahim Ghorbani Kalhor, Mohammad Taghi Vardini, Ameneh Dorri

In the present study, the integration of magnetic dispersive micro-solid-phase extraction (MD-µSPE) with hollow fiber liquid-phase microextraction (HF-LPME) prior to gas chromatography–mass spectrometry (GC/MS) was developed to preconcentrate and determine trace amounts of chlorpyrifos pesticide. Azolla filiculoides fern biomass was loaded by magnetite nanoparticles to prepare magnetic adsorbent (azolla@Fe3O4). The structural characteristics of the produced magnetic nanocomposites (MNCs) were investigated by FESEM, TEM, VSM, FTIR, EDX, and XRD methods. In the proposed MD-µSPE/HF-LPME method, the adsorption/desorption variables in MD-µSPE step were optimized by Taguchi fractional factorial design. After chlorpyrifos adsorption in the optimized condition of MD-µSPE (Vsample = 50 mL, contact time = 15 min, solution pH = 3, adsorbent mass = 0.05 g, ionic strength = 0.01 mol L−1, and eluent type = ethanol), 2.0 mL of the desorbed ethanolic solution was added to 16 mL of 10% (w/v) NaCl aqueous solution for the next HF-LPME method and the final analysis was performed by GC/MS. The developed method showed a limit of detection of 0.05 μg L−1, a limit of quantification of 0.5 μg L−1, a dynamic linear range of 0.5–1000.0 μg L−1, preconcentration factors between 700 and 1050, and a repeatability (RSD%) of 6.9%. The suitability of the MD-µSPE/HF-LPME method was confirmed by measuring chlorpyrifos in real samples with relative recoveries in the range of 97.0–108.5%. The results showed good accuracy and precision of the developed MD-µSPE/HF-LPME method for the preconcentration and determination of trace amounts of chlorpyrifos in the aqueous samples.

Graphical abstract

本研究将磁性分散微固相萃取(MD-µSPE)与中空纤维液相微萃取(HF-LPME)相结合,在气相色谱-质谱联用(GC/MS)前对毒死蜱农药进行预浓缩和痕量测定。用磁铁矿纳米颗粒负载蕨类植物 Azolla filiculoides 生物质,制备磁性吸附剂(azolla@Fe3O4)。利用 FESEM、TEM、VSM、FTIR、EDX 和 XRD 方法研究了所制备的磁性纳米复合材料(MNCs)的结构特征。在拟议的 MD-µSPE/HF-LPME 方法中,MD-µSPE 步骤中的吸附/解吸变量通过田口分数因子设计进行了优化。毒死蜱在MD-µSPE的优化条件(样品体积=50 mL,接触时间=15 min,溶液pH=3,吸附剂质量=0.05 g,离子强度=0.01 mol L-1,洗脱剂类型=乙醇)下吸附后,将2.0 mL解吸后的乙醇溶液加入16 mL 10%(w/v)NaCl水溶液中进行下一步HF-LPME方法的测定,最后采用GC/MS进行分析。该方法的检出限为 0.05 μg L-1,定量限为 0.5 μg L-1,动态线性范围为 0.5-1000.0 μg L-1,预浓缩因子在 700-1050 之间,重复性(RSD%)为 6.9%。通过测定实际样品中的毒死蜱,证实了 MD-µSPE/HF-LPME 方法的适用性,相对回收率在 97.0-108.5% 之间。结果表明所开发的 MD-µSPE/HF-LPME 方法具有良好的准确度和精密度,可用于水样中痕量毒死蜱的预浓缩和测定。
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引用次数: 0
Adsorptive performance of graphene oxide-activated carbon composite for simultaneous removal of diclofenac sodium and ibuprofen from aqueous solutions in batch mode 批处理模式下氧化石墨烯活性炭复合材料同时去除水溶液中双氯芬酸钠和布洛芬的吸附性能
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-13 DOI: 10.1007/s13738-024-03029-3
Bentolhoda Chenarani, Mohammad Nader Lotfollahi

Graphene oxide-activated carbon (GO–AC) composite with different ratios of GO and AC (0.5/0.5, 0.3/0.7 and 0.1/0.9) were synthesized via direct chemical bonding of them using hydrogen peroxide as a chemical linker and used for selective removal of diclofenac sodium (DCF) and ibuprofen (IBP) from aqueous solutions. The adsorbents' surface morphology, composition, and physicochemical structure of the adsorbents were characterized by FE-SEM, FTIR, BET and XRD analysis. The synthesized composite with a ratio of GO and AC (0.1/0.9) was the most suitable among the synthesized adsorbents for both DCF and IBP adsorption. The optimal working conditions for DCF removal were at pH of 2, contact time of 40 min, initial concentration of 100 mg/L, and temperature of 293 K. For IBP removal, the optimal operating conditions were at pH of 2, contact time of 60 min, initial concentration of 20 mg/L, and temperature of 293 K. The highest adsorption capacities of 0.1/0.9 composite for DCF and IBP were 833.33 and 238.095 mg/g at 298 K, respectively. Isotherm, kinetic, and thermodynamic characteristics were assessed to analyze the adsorption process. The synthesized adsorbent displays high removal efficiency by simple recyclability with low-cost reagent and high selectivity for drug pollutants such as DCF and IBP in single and binary systems.

以过氧化氢为化学连接剂,通过直接化学键合的方法合成了不同比例的氧化石墨烯-活性炭(GO-AC)复合材料(GO 和 AC 的比例分别为 0.5/0.5、0.3/0.7 和 0.1/0.9),并将其用于选择性去除水溶液中的双氯芬酸钠(DCF)和布洛芬(IBP)。通过 FE-SEM、FTIR、BET 和 XRD 分析对吸附剂的表面形貌、组成和理化结构进行了表征。在已合成的吸附剂中,GO 和 AC 的比例(0.1/0.9)最适合吸附 DCF 和 IBP。去除 DCF 的最佳工作条件为:pH 值为 2,接触时间为 40 分钟,初始浓度为 100 mg/L,温度为 293 K;去除 IBP 的最佳工作条件为:pH 值为 2,接触时间为 60 分钟,初始浓度为 20 mg/L,温度为 293 K。对等温线、动力学和热力学特性进行了评估,以分析吸附过程。所合成的吸附剂具有简单的可回收性和低成本试剂的特点,在单一和二元体系中对 DCF 和 IBP 等药物污染物具有较高的选择性,因而具有较高的去除效率。
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引用次数: 0
Effect of terminal donors on the structures and photophysical properties of D–A-π-D small fluorophores 末端供体对 D-A-π-D 小荧光团结构和光物理特性的影响
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-11 DOI: 10.1007/s13738-024-03035-5
Xue-Lian Li, Qing-Hui Guo, Jia-Han Wu, Xin Chen, Dong-En Wu

In order to investigate the effect of terminal donors on the structures and photophysical properties, four donor (D1)-acceptor (A)-π bridge-donor (D2) prototype fluorophores were synthesized and characterized. Single crystal analysis indicated that changing the types of terminal donors (D2) would give rise to different frontier molecular orbitals and molecular packing modes, leading to their different emission behaviors in solid states. In dilute solution, the four D–A–π-D compounds displayed different absorption and emission behaviors in dilute solution with solvatochromism properties. Assisted by the quantum chemical calculations and wave function analysis, the essence of optical properties of four compounds were explored. The results indicated that changing the types of terminal donors (D2) can affect the structures and photophysical properties of such donor (D1)-acceptor (A)-π bridge-donor (D2) prototype fluorophores, which provided guidance to design new fluorophores.

为了研究末端供体对结构和光物理性质的影响,我们合成并表征了四种供体(D1)-受体(A)-π桥-供体(D2)原型荧光团。单晶分析表明,改变末端供体(D2)的类型会产生不同的前沿分子轨道和分子堆积模式,从而导致它们在固态下的不同发射行为。在稀溶液中,四种 D-A-π-D 化合物显示出不同的吸收和发射行为,并具有溶解变色特性。在量子化学计算和波函数分析的辅助下,探究了四种化合物光学性质的本质。结果表明,改变末端供体(D2)的类型会影响这种供体(D1)-受体(A)-π桥-供体(D2)原型荧光团的结构和光物理性质,为设计新型荧光团提供了指导。
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引用次数: 0
Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies 具有混合配体系统的镍(II)配位配合物的合成和结构表征:探索超分子组装中的π-π堆积和氢键作用
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-10 DOI: 10.1007/s13738-024-03034-6
Abdul Samad Hamid, Masoud Mirzaei, Maryam Bazargan, Joel T. Mague, Diego M. Gil, Antonio Frontera

Two coordination complexes [Ni(Hpydco)2(bpy)] (1) and [Ni(pydco)(phen)(H2O)2]·4.5H2O 0.5CH3OH (2) have been synthesized using a mixed-ligand system including pyridine-2,5-dicarboxylic acid N-oxide (H2pydco) as an O-donor ligand and 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen) as a chelating N-donor ligand and NiCl2.6H2O as a source for Ni ions. The crystal structures of 1 and 2 form discrete complexes in which extensive π−π stacking interactions between aromatic rings of the N-donor ligands resulted in the formation of one dimensional (1D) chain-like structures. The chains are connected by hydrogen bonds to expand the structures into 2D-supramolecular networks. Hirshfeld surface analysis and Density Functional Theory (DFT) calculations were included to rationalize the relative strength of the π-stacking assemblies observed in both complexes.

以吡啶-2,5-二羧酸 N-氧化物(H2pydco)作为 O-供体配体,合成了两个配位配合物 [Ni(Hpydco)2(bpy)] (1) 和 [Ni(pydco)(phen)(H2O)2]-4.5H2O 0.5CH3OH (2) 。5CH3OH (2)的合成采用了混合配体体系,包括作为 O-供体配体的吡啶-2,5-二甲酸 N-氧化物(H2pydco)和作为螯合 N-供体配体的 2,2'-联吡啶(bpy)或 1,10-菲罗啉(phen),以及作为镍离子源的 NiCl2.6H2O。1 和 2 的晶体结构形成了离散的配合物,其中 N-供体配体的芳香环之间广泛的 π-π 堆积相互作用导致形成了一维(1D)链状结构。这些链通过氢键连接,将结构扩展为二维超分子网络。Hirshfeld 表面分析和密度泛函理论(DFT)计算的目的是合理解释在这两种复合物中观察到的π堆叠组装的相对强度。
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引用次数: 0
Synthesis, crystal structure, quantum chemical computation and molecular docking analysis of 1-(4(tert-butyl)-4-methoxy-[1,1-biphenyl]-4-yl) ethenone 1-(4(叔丁基)-4-甲氧基-[1,1-联苯]-4-基)乙烯酮的合成、晶体结构、量子化学计算和分子对接分析
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-05-10 DOI: 10.1007/s13738-024-03032-8
Neha Kumari, Archana Akaram Yadav, Sandeep Ashok Sankpal, Saminathan Murugavel, Duraiswamy Lakshmanan, Rajni Kant

The synthesis of 1-(4(tert-butyl)-4-methoxy-[1,1-biphenyl]-4-yl) ethenone (4TBMBE) has been realized in excellent yield by using 4-tert-butyl phenylboronic acid and 1-bromonitrobenzene as the reactants. The single crystals were obtained by solvent-loss technique and its characterization was carried out using the spectral and X-ray diffraction methods. The molecule crystallizes in the monoclinic crystal system with space group (P21/c). There exists one C–H…O intramolecular and an intermolecular C–H···π interaction, besides one π···π (Cg···Cg) interaction responsible for stabilizing the unit cell molecular packing. The density functional theory has been employed to optimize the structure and to carry out the HOMO/LUMO analysis, computation of reactivity parameters, molecular electrostatic potential map and Mulliken population analysis. The Hirshfeld surface analysis probes the existence of various interactions in the crystal structure. Crystal voids analysis confirmed the absence of any significant cavity within the crystal packing. The relative contribution for each contact has been analyzed using the 2D fingerprint plots and their favourability has been validated by the enrichment ratio. The 3D topology of molecular packing has been visualized using energy framework analysis and the nature of molecular interactions existing within the structure has been ascertained using NCI-RDG analysis. The molecular docking investigations have been performed to study the anti-inflammatory action of 4TBMBE against the p38 MAP kinase inhibitor.

以 4-叔丁基苯硼酸和 1-溴硝基苯为反应物,合成了 1-(4(叔丁基)-4-甲氧基-[1,1-联苯]-4-基) 乙酮 (4TBMBE),收率极高。通过溶剂流失技术获得了单晶体,并使用光谱和 X 射线衍射方法对其进行了表征。该分子在单斜晶系中结晶,空间群为 (P21/c)。分子内存在一个 C-H...O,分子间存在一个 C-H---π 相互作用,此外还有一个 π---π (Cg---Cg) 相互作用,负责稳定单胞分子堆积。该化合物采用密度泛函理论优化结构,并进行了 HOMO/LUMO 分析、反应性参数计算、分子静电位图和 Mulliken 群体分析。Hirshfeld 表面分析探测了晶体结构中存在的各种相互作用。晶体空隙分析证实了晶体结构中不存在任何明显的空隙。利用二维指纹图谱分析了每种接触的相对贡献,并通过富集比验证了它们的有利性。利用能量框架分析对分子填料的三维拓扑结构进行了可视化,并利用 NCI-RDG 分析确定了结构中存在的分子相互作用的性质。为研究 4TBMBE 对 p38 MAP 激酶抑制剂的抗炎作用,进行了分子对接研究。
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Journal of the Iranian Chemical Society
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