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Review on micro-gas chromatography system for analysis of multiple low-concentration volatile organic compounds: preconcentration, separation, detection, integration, and challenges 用于分析多种低浓度挥发性有机化合物的微型气相色谱系统综述:预浓缩、分离、检测、集成与挑战
IF 3.6 Q1 Engineering Pub Date : 2024-06-13 DOI: 10.1186/s40486-024-00203-3
Yeongseok Lee, Hyeonwoo Son, Junwoo Lee, Si-Hyung Lim

As the dangers of volatile organic compounds (VOCs) and their potential as non-invasive diagnosis biomarkers have been reported, there has been a need for instrument capable of real-time and in-situ monitoring of multiple low-concentration VOCs in indoor air or human metabolites. A promising technology that can qualitatively and quantitatively analyze numerous VOCs as an alternative to conventional bench-top instruments is a micro-gas chromatography (µ-GC) system, which integrates three main components: a micro-gas preconcentrator, a µ-GC column, and a mini- or micro-detector fabricated using microelectromechanical system (MEMS) processes. This review covers the integration methods, features, and analysis capabilities of recently developed µ-GC systems and examines the materials, designs, and principles of the three main components. In addition, the challenging issues that must be addressed for the commercialization of this technology are discussed.

随着挥发性有机化合物(VOCs)的危害及其作为非侵入性诊断生物标志物的潜力不断被报道,人们需要能够实时和原位监测室内空气中多种低浓度 VOCs 或人体代谢物的仪器。微气相色谱(µ-GC)系统是一项很有前途的技术,它可以定性和定量分析多种挥发性有机化合物,是传统台式仪器的替代品,该系统集成了三个主要组件:微气预浓缩器、µ-GC 柱和利用微机电系统(MEMS)工艺制造的微型或微型检测器。本综述涵盖了最近开发的 µ-GC 系统的集成方法、特点和分析能力,并研究了这三个主要组件的材料、设计和原理。此外,还讨论了该技术商业化必须解决的挑战性问题。
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引用次数: 0
Design of enlarged phononic bandgap 2.5D acoustic resonator via active learning and non-gradient optimization 通过主动学习和非梯度优化设计扩大声带隙的 2.5D 声共振器
IF 3.6 Q1 Engineering Pub Date : 2024-06-04 DOI: 10.1186/s40486-024-00202-4
Syed Muhammad Anas Ibrahim, Jungyul Park

Identifying the phononic crystal (PnC) with bandgap is a problematic process because all phononic crystals don’t have bandgap. Predicting the Phononic bandgaps (PnBGs) is a computationally expensive task. Here we explore the potential of machine learning (ML) tools to expedite the prediction and maximize the resonator based PnBG. The Gaussian process regression (GPR) model is trained to learn the relationship between complicated shape and band structure of cavity. Bayesian optimization (BO) derives a new shape by leveraging the fast inference of the trained model, which is updated with the augmentation of newly explored structures to escalate the prediction power over performance expansion through active learning. Artificial intelligence (AI) assisted optimization requires a small number of generations to achieve convergence. The obtained results are validated via experimental measurements.

识别具有带隙的声子晶体(PnC)是一个难题,因为所有的声子晶体都不具有带隙。预测声波带隙(PnBGs)是一项计算成本高昂的任务。在此,我们探索了机器学习(ML)工具的潜力,以加快预测并最大限度地提高基于谐振器的 PnBG。通过训练高斯过程回归(GPR)模型来学习复杂形状与腔体带状结构之间的关系。贝叶斯优化(BO)通过利用训练有素模型的快速推理得出新的形状,并随着新探索结构的增加而更新,从而通过主动学习在性能扩展的基础上提升预测能力。人工智能(AI)辅助优化只需少量代次即可实现收敛。实验测量验证了所获得的结果。
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引用次数: 0
Haptic interface with multimodal tactile sensing and feedback for human–robot interaction 用于人机交互的多模式触觉传感和反馈触觉界面
IF 3.6 Q1 Engineering Pub Date : 2024-03-14 DOI: 10.1186/s40486-024-00199-w
Mingyu Kang, Cheol-Gu Gang, Sang-Kyu Ryu, Hyeon-Ju Kim, Da-Yeon Jeon, Soonjae Pyo

Novel sensing and actuation technologies have notably advanced haptic interfaces, paving the way for more immersive user experiences. We introduce a haptic system that transcends traditional pressure-based interfaces by delivering more comprehensive tactile sensations. This system provides an interactive combination of a robotic hand and haptic glove to operate devices within the wireless communication range. Each component is equipped with independent sensors and actuators, enabling real-time mirroring of user’s hand movements and the effective transmission of tactile information. Remarkably, the proposed system has a multimodal feedback mechanism based on both vibration motors and Peltier elements. This mechanism ensures a varied tactile experience encompassing pressure and temperature sensations. The accuracy of tactile feedback is meticulously calibrated according to experimental data, thereby enhancing the reliability of the system and user experience. The Peltier element for temperature feedback allows users to safely experience temperatures similar to those detected by the robotic hand. Potential applications of this system are wide ranging and include operations in hazardous environments and medical interventions. By providing realistic tactile sensations, our haptic system aims to improve both the performance and safety of workers in such critical sectors, thereby highlighting the great potential of advanced haptic technologies.

新颖的传感和驱动技术显著推动了触觉界面的发展,为更身临其境的用户体验铺平了道路。我们介绍了一种触觉系统,它超越了传统的基于压力的界面,能提供更全面的触觉感受。该系统提供了机器人手和触觉手套的互动组合,可在无线通信范围内操作设备。每个组件都配备了独立的传感器和执行器,能够实时反映用户的手部动作,并有效传输触觉信息。值得注意的是,该系统具有基于振动电机和珀尔帖元件的多模式反馈机制。这种机制确保了包括压力和温度感觉在内的多种触觉体验。触觉反馈的精确度是根据实验数据精心校准的,从而提高了系统的可靠性和用户体验。用于温度反馈的珀尔帖(Peltier)元件可让用户安全地体验与机械手检测到的温度相似的温度。该系统的潜在应用范围很广,包括在危险环境中的操作和医疗干预。通过提供逼真的触觉,我们的触觉系统旨在提高此类关键领域工作人员的工作表现和安全性,从而凸显先进触觉技术的巨大潜力。
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引用次数: 0
Possibility of large-area carbon nanotube films formation through spray coating 通过喷涂形成大面积碳纳米管薄膜的可能性
IF 3.6 Q1 Engineering Pub Date : 2024-03-04 DOI: 10.1186/s40486-023-00193-8
Jinkyeong Kim, TaeGu Lee, Ji-Hoon Han, Joon Hyub Kim

This study deals with the process of developing and optimizing the spray coating method for large-area deposition of carbon nanotubes. Carbon nanotubes have excellent electrical and thermal properties and strength, so they are used in various fields of application. However, existing deposition methods have limitations. In this study, the possibility of the spray coating method for large-area deposition of carbon nanotubes is presented, and additional conditions for this are introduced. A spray coating solution was prepared using dichlorobenzene as a solvent for 3 mg carbon nanotubes. By controlling the spray coating speed, the spray coating conditions were optimized by analyzing the surface shape, structure, and resistance of the deposited carbon nanotubes. As a result, we confirmed the possibility of depositing carbon nanotubes on a large area through the spray coating method, and it is expected to contribute to increasing the application possibilities in industrial and scientific fields.

本研究涉及开发和优化大面积沉积碳纳米管的喷涂方法的过程。碳纳米管具有优异的电性能、热性能和强度,因此被广泛应用于各个领域。然而,现有的沉积方法存在局限性。本研究提出了喷涂法大面积沉积碳纳米管的可能性,并介绍了相关的附加条件。以二氯苯为溶剂制备了 3 毫克碳纳米管的喷涂溶液。通过控制喷涂速度,分析沉积碳纳米管的表面形状、结构和电阻,优化了喷涂条件。结果,我们证实了通过喷涂方法在大面积上沉积碳纳米管的可能性,有望为提高工业和科学领域的应用可能性做出贡献。
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引用次数: 0
Exploring graphene structure, material properties, and electrochemical characteristics through laser-induced temperature analysis 通过激光诱导温度分析探索石墨烯结构、材料特性和电化学特征
IF 3.6 Q1 Engineering Pub Date : 2024-02-27 DOI: 10.1186/s40486-024-00198-x
Na-Kyoung Yang, Yoo-Kyum Shin, Saeyoung Park, Sang-Min Kim, Bon-Jae Koo, Joonsoo Jeong, Min-Ho Seo

Laser-induced graphene (LIG) is a three-dimensional graphene structure fabricated through the irradiation of a polymer substrate with laser energy (or fluence, equivalently). This methodology offers a cost-effective and facile means of producing 3D nanostructures, yielding graphene materials characterized by extremely high surface area and superior electrical properties, rendering them advantageous for various electrochemical applications. Nonetheless, it is imperative to acknowledge that the structures and material properties of LIG are subject to substantial variations contingent upon processing parameters, thereby underscoring the necessity for systematic inquiry and systematic comprehension of processing conditions, such as fluence and multi-passing, and resultant outcomes. Herein, we explored the impact of different laser fluence levels on the structural and material properties of LIG. We, especially, focused on how laser fluence affected substrate temperature and found that it caused polyimide (PI) substrate pyrolysis, resulting in changes in 3D structures and material density to LIG properties. We also investigated the effects of a multi-passing process on 3D LIG structures and material qualities, varying fluences, and temperature fluctuations. Lastly, we assessed electrochemical properties using LIGs produced under different conditions as working electrodes, leading to distinct impedance profiles and cyclic voltammetry (CV) curves. These variations were linked to the unique structural and material characteristics of the LIG samples.

激光诱导石墨烯(LIG)是一种三维石墨烯结构,通过用激光能量(或等效通量)照射聚合物基底而制成。这种方法提供了一种生产三维纳米结构的成本效益高且简便的手段,生产出的石墨烯材料具有极高的比表面积和卓越的电学特性,使其在各种电化学应用中具有优势。然而,必须承认的是,LIG 的结构和材料特性会因加工参数的不同而发生很大变化,因此有必要对加工条件(如通量和多通道)及其结果进行系统的探究和系统的理解。在此,我们探讨了不同激光通量水平对 LIG 结构和材料特性的影响。我们特别关注了激光通量对基底温度的影响,发现激光通量会导致聚酰亚胺(PI)基底热解,从而改变三维结构和材料密度,影响 LIG 性能。我们还研究了多通道工艺对三维 LIG 结构和材料质量、不同流率和温度波动的影响。最后,我们使用在不同条件下生产的 LIG 作为工作电极,对其电化学特性进行了评估,从而得出了不同的阻抗曲线和循环伏安 (CV) 曲线。这些变化与 LIG 样品独特的结构和材料特性有关。
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引用次数: 0
Quasi-statically actuated MEMS scanner with concentric vertical comb electrodes 带同心垂直梳状电极的准静致动 MEMS 扫描仪
IF 3.6 Q1 Engineering Pub Date : 2024-01-31 DOI: 10.1186/s40486-023-00188-5
Daehwan Chae, Do-hyeon Jeong, Seong-jong Yun, Kyoung-woo Jo, Jong-Hyun Lee

A quasi-static (QS) MEMS mirror scanner with concentric vertical combs (CVC) is presented. The increase rate of overlapped area of the CVC, tends to show larger values and more uniform than that of conventional vertical combs, resulting in improved linearity and scanning angle, respectively. In this paper, the performance of the QS scanner with CVC, whose equivalent mirror diameter is 3.9 mm, was theoretically analyzed and compared with the fabricated one and also other types of vertical combs such as staggered vertical combs (SVC) and angular vertical combs (AVC). The linearity was less than 0.1%, and the average value of the experimental OSA (optical scanning angle) was up to 13.5 degrees, which is only 1/3 and 39% larger than other scanners, respectively, under the condition that the configuration and dimension of each MEMS scanner is similar each other.

本文介绍了一种带有同心垂直梳状器(CVC)的准静态(QS)MEMS 镜面扫描仪。与传统的垂直梳状扫描仪相比,同心垂直梳状扫描仪重叠面积的增加率趋向于更大值和更均匀,从而分别提高了线性度和扫描角度。本文从理论上分析了等效镜面直径为 3.9 毫米的 CVC QS 扫描仪的性能,并将其与制造的垂直梳状器以及交错垂直梳状器(SVC)和角度垂直梳状器(AVC)等其他类型的垂直梳状器进行了比较。在每个 MEMS 扫描器的配置和尺寸相似的条件下,线性度小于 0.1%,实验 OSA(光学扫描角度)的平均值高达 13.5 度,分别只比其他扫描器大 1/3 和 39%。
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引用次数: 0
Comprehensive study and scientific process to increase the accuracy in estimating the thermal conductivity of nanofluids containing SWCNTs and CuO nanoparticles using an artificial neural network 利用人工神经网络提高含 SWCNT 和 CuO 纳米颗粒的纳米流体导热系数估算精度的综合研究和科学过程
IF 3.6 Q1 Engineering Pub Date : 2024-01-10 DOI: 10.1186/s40486-023-00195-6
Mohammad Hemmat Esfe, Fatemeh Amoozad, Hossein Hatami, Davood Toghraie

This investigation aimed to evaluate the thermal conductivity ratio (TCR) of SWCNT-CuO/Water nanofluid (NF) using experimental data in the T range of 28–50 ℃ and solid volume fraction range of SVF = 0.03 to 1.15% by an artificial neural network (ANN). MLP network with Lundberg-Marquardt algorithm (LMA) was utilized to predict data (TCR) by ANN. In the best case, from the set of various structures of ANN for this nanofluid, the optimal structure was chosen, which consists of 2 hidden layers, the first layer with the optimal structure consisting of 5 neurons and the second layer containing 7 neurons. Eventually, for the optimal structure, the R2 coefficient and MSE are 0.9999029 and 6.33377E-06, respectively. Based on all ANN information, MOD is in a limited area of − 3% < MOD <  + 3%. Comparison of test, correlation yield, and ANN yield display that ANN evaluates laboratory information more exactly.

本研究旨在利用人工神经网络(ANN),在 28-50 ℃ 的温度范围和 SVF = 0.03 至 1.15% 的固体体积分数范围内,使用实验数据评估 SWCNT-CuO/Water 纳米流体(NF)的导热率(TCR)。采用 Lundberg-Marquardt 算法(LMA)的 MLP 网络通过人工神经网络预测数据(TCR)。在最佳情况下,从适用于该纳米流体的各种人工神经网络结构集合中,选择了最佳结构,它由 2 个隐藏层组成,第一层的最佳结构由 5 个神经元组成,第二层包含 7 个神经元。最终,最优结构的 R2 系数和 MSE 分别为 0.9999029 和 6.33377E-06。根据所有 ANN 信息,MOD 处于 - 3% < MOD < + 3% 的有限区域。测试、相关收益率和 ANN 收益率的比较表明,ANN 对实验室信息的评估更为精确。
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引用次数: 0
Study on repetitive damage-recovery cycle of hydrophobic coating for electrowetting-on-dielectric (EWOD) applications 电介质上电泳 (EWOD) 应用中疏水涂层的重复损伤恢复周期研究
IF 3.6 Q1 Engineering Pub Date : 2024-01-08 DOI: 10.1186/s40486-023-00197-4
Youngdoo Son, Woochan Kim, Daeyoung Lee, Sang Kug Chung

This study is focusing on the durability of fluoropolymer hydrophobic coatings against falling droplets. Devices such as smart self-cleaning lens or droplet-based energy generators are open-air electrowetting-on-dielectric (EWOD) devices, which are applications that utilize falling droplets. Therefore, the hydrophobic coatings of these devices are exposed to environment factors such as raindrop, and it is necessary to examine the durability of hydrophobic coatings in similar environments and the effectiveness of recovery. Thus, in this study, we simulate raindrops to damage samples with various thicknesses of Cytop (CTX-809SP2). Subsequently, damaged samples are heated to recover their hydrophobicity, and we repeat this damage-recovery cycle several times to evaluate the long-term durability of hydrophobic coating. The EWOD samples of three different hydrophobic coating thicknesses (0.1 μm, 0.5 μm, and 1.0 μm) are damaged by falling droplets from a certain height for 10 days. The damaged samples are then recovered by heating them on a hot plate at 200 ℃ for 24 h and evaluate their EWOD performance. In addition, the hydrophobic coatings are repeatedly damaged and recovered several times to examine the number of recovery limitations of the coatings. After the second damage-recovery cycle, the thickest hydrophobic coating sample shows 7 % better EWOD performance than others. Additionally, after the third damage-recovery cycle, the EWOD performance of all samples significantly degrade, experimentally verifying the number of recovery limitations of the hydrophobic coating. The results of this study are expected to provide useful information for open-air EWOD devices on the methods for evaluating their durability and the thickness selection of hydrophobic coating.

本研究的重点是含氟聚合物疏水涂层对液滴下落的耐久性。智能自清洁透镜或基于液滴的能量发生器等设备属于露天电润湿(EWOD)设备,是利用下落液滴的应用。因此,这些设备的疏水涂层会受到雨滴等环境因素的影响,有必要研究疏水涂层在类似环境中的耐用性和恢复效果。因此,在本研究中,我们模拟了雨滴对不同厚度的 Cytop(CTX-809SP2)样品造成的损坏。随后,加热受损样品以恢复其疏水性,我们多次重复这种受损-恢复循环,以评估疏水涂层的长期耐久性。三种不同疏水涂层厚度(0.1 μm、0.5 μm 和 1.0 μm)的 EWOD 样品被从一定高度落下的液滴损坏了 10 天。然后将受损样品放在 200 ℃ 的热板上加热 24 小时,使其复原,并评估其 EWOD 性能。此外,还对疏水涂层进行多次反复损坏和恢复,以考察涂层的恢复次数限制。在第二次损伤恢复循环后,最厚的疏水涂层样品的 EWOD 性能比其他样品高出 7%。此外,在第三个损坏恢复周期后,所有样品的 EWOD 性能都明显下降,这也从实验上验证了疏水涂层的恢复次数限制。这项研究的结果有望为露天 EWOD 设备的耐用性评估方法和疏水涂层的厚度选择提供有用信息。
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引用次数: 0
SnO2 nanostructure-based acetone sensors for breath analysis 基于二氧化锡纳米结构的丙酮呼吸分析传感器
IF 3.6 Q1 Engineering Pub Date : 2024-01-04 DOI: 10.1186/s40486-023-00196-5
Arunkumar Shanmugasundaram, Karthikeyan Munirathinam, Dong-Weon Lee

The World Health Organization reports that metabolic disorders are responsible for a significant proportion of global mortality. Considering this, breath sensors have gained prominence as effective tools for monitoring and diagnosing metabolic disorders, thanks to recent advancements in science and technology. In human exhaled breath, over 870 distinct volatile organic components (VOCs) have been identified. Among several VOCs, the detection of acetone in exhaled breath has received considerable attention in biomedical applications. Research indicates a strong correlation between high acetone levels in human breath and several diseases, such as asthma, halitosis, lung cancer, and diabetes mellitus. For instance, acetone is particularly noteworthy as a biomarker in diabetes, where its concentration in exhaled breath often surpasses 1.76 parts per million (ppm), compared to less than 0.8 ppm in healthy individuals. Early diagnosis and intervention in diseases associated with elevated acetone levels, aided by such non-invasive techniques, have the potential to markedly reduce both mortality and the financial burden of healthcare. Over time, various nanostructured gas sensing technologies have been developed for detecting acetone in both ambient air and exhaled breath. This article presents a mini review of cutting-edge research on acetone gas sensing, focusing specifically on nanostructured metal oxides. It discusses critical factors influencing the performance of acetone gas sensors, including acetone concentration levels and operational temperature, which affect their sensitivity, selectivity, and response times. The aim of this review is to encourage further advancements in the development of high-performance acetone gas sensors utilizing nanostructured materials, contributing to more effective management of metabolic disorders.

世界卫生组织报告称,代谢紊乱在全球死亡率中占很大比例。有鉴于此,呼吸传感器作为监测和诊断代谢紊乱的有效工具,在最近的科技进步中占据了重要地位。在人类呼出的气体中,已发现 870 多种不同的挥发性有机成分 (VOC)。在几种挥发性有机化合物中,呼出气体中丙酮的检测在生物医学应用中受到了广泛关注。研究表明,人体呼气中丙酮含量高与多种疾病(如哮喘、口臭、肺癌和糖尿病)密切相关。例如,丙酮作为糖尿病的生物标志物尤其值得注意,因为在糖尿病患者呼出的气体中,丙酮的浓度往往超过百万分之 1.76,而健康人的浓度则低于百万分之 0.8。在这种非侵入性技术的帮助下,对与丙酮水平升高有关的疾病进行早期诊断和干预,有可能显著降低死亡率和医疗保健的经济负担。随着时间的推移,人们开发出了各种纳米结构气体传感技术,用于检测环境空气和呼出气体中的丙酮。本文简要回顾了丙酮气体传感的前沿研究,特别关注纳米结构金属氧化物。文章讨论了影响丙酮气体传感器性能的关键因素,包括影响其灵敏度、选择性和响应时间的丙酮浓度水平和工作温度。本综述旨在鼓励利用纳米结构材料进一步推动高性能丙酮气体传感器的开发,为更有效地控制代谢紊乱做出贡献。
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引用次数: 0
Electrohydrodynamic (EHD) printing of nanomaterial composite inks and their applications 纳米材料复合油墨的电流体动力(EHD)印刷及其应用
IF 3.6 Q1 Engineering Pub Date : 2024-01-03 DOI: 10.1186/s40486-023-00194-7
Rizwan Ul Hassan, Mirkomil Sharipov, WonHyoung Ryu

The utilization of high-resolution printed flexible electronic devices is prevalent in various fields, including energy storage, intelligent healthcare monitoring, soft robotics, and intelligent human–machine interaction, owing to its compact nature and mechanical flexibility. The EHD jet printing technology has the potential to develop the field of printing industry through its ability to fabricate high-resolution, flexible, stretchable, and 3D structures for electronic applications such as displays, sensors, and transistors. The EHD jet printing technology involves the use of solution-based inks made of diverse functional materials to print a wide range of structures. Consequently, it is imperative to have a comprehensive understanding of nanomaterial composites that are printed using EHD jet printing technology. This review provides a thorough overview of nanomaterial composite inks printed for electronic devices using EHD jet printing technology. In particular, a comprehensive overview has been provided about the utilization of EHD jet printing for nanomaterial composites in several domains, including flexible electrodes, flexible displays, transistors, energy harvesting, sensors, and biomedical applications. Moreover, this analysis presents a concise overview of the limitations and prospective future directions for nanomaterial composites fabricated by EHD jet printing.

高分辨率印刷柔性电子设备因其结构紧凑和机械灵活性,在能源存储、智能医疗监控、软机器人和智能人机交互等多个领域得到广泛应用。EHD 喷射打印技术能够为显示器、传感器和晶体管等电子应用制造高分辨率、柔性、可拉伸的三维结构,因此具有发展打印行业的潜力。超高清喷射打印技术涉及使用由各种功能材料制成的溶液型油墨来打印各种结构。因此,必须全面了解使用 EHD 喷射打印技术打印的纳米材料复合材料。本综述全面概述了使用 EHD 喷射打印技术为电子设备打印的纳米材料复合油墨。特别是全面概述了在多个领域中利用超高清喷射打印技术打印纳米材料复合材料的情况,包括柔性电极、柔性显示器、晶体管、能量收集、传感器和生物医学应用。此外,该分析还简明扼要地概述了采用 EHD 喷射打印技术制造纳米材料复合材料的局限性和未来发展方向。
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引用次数: 0
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Micro and Nano Systems Letters
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