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Silicon nanoparticles: fabrication, characterization, application and perspectives 硅纳米颗粒:制备、表征、应用与展望
IF 3.6 Q1 Engineering Pub Date : 2023-11-23 DOI: 10.1186/s40486-023-00184-9
Taeyeong Kim, Jungchul Lee

Silicon nanoparticles have emerged as pivotal components in nanoscience and nanoengineering due to their inherent characteristics such as high energy capacity and outstanding optical properties. Numerous fabrication and characterization techniques have been researched so far, while a range of applications utilizing them have been developed. In this review, we aim to provide a brief overview of the distinct and representative fabrication methods of silicon nanoparticles, including top-down, bottom-up, and reduction approaches. Then, we look into various characterization techniques essential for assessing and ensuring quality and performance of fabricated silicon nanoparticles. In addition, we provide insights for silicon nanoparticle technology towards further advancements.

硅纳米粒子由于其高能量容量和优异的光学性能等固有特性,已成为纳米科学和纳米工程领域的重要组成部分。到目前为止,已经研究了许多制造和表征技术,同时开发了一系列利用它们的应用。在这篇综述中,我们的目的是简要概述不同的和有代表性的硅纳米颗粒的制造方法,包括自顶向下,自底向上和还原方法。然后,我们研究了评估和确保制备的硅纳米颗粒的质量和性能所必需的各种表征技术。此外,我们还为硅纳米颗粒技术的进一步发展提供了见解。
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引用次数: 0
Plasma dicing before grinding process for highly reliable singulation of low-profile and large die sizes in advanced packages 在研磨前进行等离子切割,可在先进封装中实现低轮廓和大尺寸模具的高可靠性模拟
IF 3.6 Q1 Engineering Pub Date : 2023-11-18 DOI: 10.1186/s40486-023-00183-w
Keunhoi Kim, Jongcheol Park, Kyoungmin Kim, TaeHyun Kim, SooHyun Kwon, Yeeun Na

The demand for advanced packaging is driven by the need for low-profile, densely-integrated, large-die Si devices in substrate-based or wafer-level packaging. Die strength is a critical parameter for ultrathin dies, making die singulation a vital aspect of advanced packaging technology. In this work, we present a dicing before grinding (DBG) process to compare and analyze die strengths using a mechanical blade, stealth laser, and plasma dicing. The three DBG processes were applied to a 200 mm silicon (Si) wafer process with a die size of 10 × 10 mm2 and thicknesses of 100, 200, and 300 μm, respectively. Optical and electron microscopes were employed to investigate chipping quality, sidewall damage, and surface contamination. The bare Si die’s strength was assessed using a three-point bending test. Plasma dicing before grinding (PDBG) resulted in less contamination, chipping, and cracking compared to other DBG processes. Furthermore, PDBG exhibited the highest die strength of 1052 Pa.

对先进封装的需求是由对基于基板或晶圆级封装的低轮廓、密集集成、大芯片Si器件的需求驱动的。模具强度是超薄模具的关键参数,使模具仿真成为先进封装技术的一个重要方面。在这项工作中,我们提出了一种研磨前切割(DBG)工艺,以比较和分析机械刀片、隐形激光和等离子切割的模具强度。这三种DBG工艺分别应用于200 mm硅(Si)晶圆工艺,其芯片尺寸为10 × 10 mm2,厚度分别为100、200和300 μm。采用光学显微镜和电子显微镜观察切屑质量、侧壁损伤和表面污染。采用三点弯曲试验评估裸硅模的强度。与其他的等离子切割工艺相比,在研磨前等离子切割(PDBG)可以减少污染、碎裂和开裂。PDBG的模具强度最高,为1052 Pa。
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引用次数: 0
Fabrication and characterization of silicon-on-insulator wafers 绝缘体上硅晶圆的制备与表征
IF 3.6 Q1 Engineering Pub Date : 2023-11-13 DOI: 10.1186/s40486-023-00181-y
Taeyeong Kim, Jungchul Lee

Silicon-on-insulator (SOI) wafers offer significant advantages for both Integrated circuits (ICs) and microelectromechanical systems (MEMS) devices with their buried oxide layer improving electrical isolation and etch stop function. For past a few decades, various approaches have been investigated to make SOI wafers and they tend to exhibit strength and weakness. In this review, we aim to overview different manufacturing routes for SOI wafers with specific focus on advantages and inherent challenges. Then, we look into how SOI wafers are characterized for quality assessment and control. We also provide insights towards potential future directions of SOI technology to further accelerate ever-growing IC and MEMS industries.

绝缘体上硅(SOI)晶圆为集成电路(ic)和微机电系统(MEMS)器件提供了显著的优势,其埋藏的氧化层改善了电气隔离和蚀刻停止功能。在过去的几十年里,人们研究了各种方法来制造SOI晶圆,它们往往表现出强度和弱点。在这篇综述中,我们旨在概述不同的SOI晶圆制造路线,并特别关注其优势和固有的挑战。然后,我们研究了如何表征SOI晶圆的质量评估和控制。我们还提供了对SOI技术潜在未来方向的见解,以进一步加速不断增长的IC和MEMS行业。
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引用次数: 0
Rheological behavior of 10W40 base oil containing different combinations of MWCNT-Al2O3 nanoparticles and determination of the target nano-lubricant for industrial applications 含不同MWCNT-Al2O3纳米颗粒组合的10W40基础油流变行为及工业应用目标纳米润滑剂的测定
IF 3.6 Q1 Engineering Pub Date : 2023-10-31 DOI: 10.1186/s40486-023-00179-6
Mohammad Hemmat Esfe, Soheyl Alidoust, Hossein Hatami, Davood Toghraie

The main goal of this research is to compare the rheological behavior of hybrid nano lubricants (HNLs) with different composition ratios in a base oil. The purpose of the comparison is to determine the HNL with the best lubrication performance at the start of the vehicle. Theoretical methods have confirmed the non-Newtonian behavior in different laboratory conditions. HNLs with the composition ratio of 30:70 and 25:75 had the highest percentage of increase and decrease in viscosity, respectively 34.97% and − 1.85% at T = 55 °C, shear rate SR = 6665 s−1 and solid volume fraction SVF = 1% and T = 5 °C, SR = 3999 s−1 and SVF = 0.05%. To predict the viscosity of the desired HNL, in the RSM, a special model with an accuracy of R2 = 0.9997 has been used. The margin of deviation (MOD) is determined in the range of − 3.43% < MOD < 4.75%. Viscosity sensitivity analysis shows that the greatest sensitivity will result from SVF changes at high SVFs. The experimental results of this study will introduce the optimal nano polishing to the craftsmen, and the theoretical part of this study will save the researchers from spending time and excessive economic costs.

本研究的主要目的是比较不同成分比的混合纳米润滑油(HNLs)在基础油中的流变行为。比较的目的是确定车辆启动时润滑性能最佳的HNL。理论方法证实了在不同实验室条件下的非牛顿行为。在T = 55℃,剪切速率SR = 6665 s−1,固相体积分数SVF = 1%, T = 5℃,SR = 3999 s−1,SVF = 0.05%时,组成比为30:70和25:75的HNLs的粘度增减百分比最高,分别为34.97%和- 1.85%。为了预测期望HNL的粘度,在RSM中,使用了一个特殊的模型,其精度为R2 = 0.9997。偏差余量(margin of deviation, MOD)确定在−3.43% < MOD < 4.75%范围内。粘度敏感性分析表明,在高SVF时,SVF的变化将产生最大的敏感性。本研究的实验结果将为工匠们介绍最优的纳米抛光,本研究的理论部分将节省研究人员花费的时间和过高的经济成本。
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引用次数: 0
Designing wearable capacitive pressure sensors with arrangement of porous pyramidal microstructures 多孔锥体结构可穿戴电容式压力传感器的设计
IF 3.6 Q1 Engineering Pub Date : 2023-10-24 DOI: 10.1186/s40486-023-00178-7
Reza Javidi, Mahdi Moghimi Zand, Sara Alizadeh Majd

Capacitive pressure sensors are essential for advanced applications like wearable medical devices, electronic skins, and biological signal detection systems. Enhancing sensitivity in these sensors is achieved by incorporating porous microstructures into the dielectric layer. The present research focuses on designing a capacitive pressure sensor comprising a porous micro-pyramidal dielectric layer featuring diagonally arranged pyramids. The effects of geometric parameters and material properties such as dielectric constant, porosity, base length, tip width, height, and the distance between the pyramidal microstructures were examined using the three-dimensional finite element simulations. A comparative analysis was conducted to evaluate the accuracy of the numerical solution. The simulation results were compared to experimental measurements, and the findings revealed a high level of agreement. The optimal quantity of data for this analysis was determined using the design of the experiment method, specifically the response surface model. The results show that arranging microstructures diagonally or laterally can impact sensitivity and initial capacitance. Specifically, employing a diagonal arrangement enhanced sensor sensitivity by up to 1.65 times while maintaining the initial capacitance relatively unaffected. Ultimately, this study derived mathematical equations from the collected data to estimate the initial capacitance and sensitivity of the sensor. The model predictions were compared to simulation results, and it was found that the models performed effectively.

电容式压力传感器对于可穿戴医疗设备、电子皮肤和生物信号检测系统等先进应用至关重要。通过在介电层中加入多孔微结构来提高这些传感器的灵敏度。本研究的重点是设计一种电容式压力传感器,该传感器由具有对角线排列金字塔的多孔微金字塔介质层组成。采用三维有限元模拟方法研究了介电常数、孔隙率、基底长度、尖端宽度、高度以及锥体微结构之间的距离等几何参数和材料性能的影响。通过对比分析,评价了数值解的准确性。将模拟结果与实验测量结果进行了比较,结果显示出高度的一致性。通过实验方法的设计,特别是响应面模型,确定了本分析的最佳数据量。结果表明,沿对角线或横向排列微结构会影响灵敏度和初始电容。具体来说,采用对角线排列可将传感器灵敏度提高1.65倍,同时保持初始电容相对不受影响。最后,本研究从收集的数据推导出数学方程来估计传感器的初始电容和灵敏度。将模型预测结果与仿真结果进行了比较,结果表明模型是有效的。
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引用次数: 0
Evaluation of stability and functionality of zinc oxide nanofluids for enhanced oil recovery 氧化锌纳米流体提高采收率的稳定性和功能评价
IF 3.6 Q1 Engineering Pub Date : 2023-10-19 DOI: 10.1186/s40486-023-00180-z
Lengu Peter Tuok, Marwa Elkady, Abdelrahman Zkria, Tsuyoshi Yoshitake, Usama Nour Eldemerdash

Nanofluids for enhanced oil recovery offer a breakthrough solution towards tertiary recovery and consequently higher oil production. Their ability to reduce interfacial tension, alteration of formation’s wettability, higher adsorption capacity, and acceleration of disjoining pressure makes them excellent candidates for enhanced oil recovery. The main objective of this paper is to investigate the effect of polymers on zinc oxide (ZnO) nanofluids for enhanced oil recovery (EOR) and the role played by chemical modification using polymer stabilizers on nanoparticle stability in nanofluids. Nanoparticles with an average particle size of 34 nm were synthesized and used to prepare nanofluids of different concentrations and their stability was evaluated using sedimentation and UV–vis spectrophotometry tests. ZnO-synthesized nanofluids were used solely and in addition to Polyvinylpyrrolidone (PVP) and Polyvinyl alcohol (PVA) as stabilizing agents. It was noted that ZnO nanofluids with PVA stabilizer recorded the highest oil recovery of 82%. In contrast, the ZnO nanofluids without stabilizing agents registered the lowest recovery rate during the flooding experiment. The results revealed that a higher injection rate increases the oil recovery and reduces the viscous fingering effect with a better displacement front. Furthermore, nanofluids containing polymeric stabilizing agents achieved better recovery factors compared to ZnO nanofluids without stabilizing agents. This phenomenon was also observed in the interfacial tension test where nanofluids with PVA and PVP stabilizers reduced the IFT by 59% and 61% respectively.

用于提高采收率的纳米流体为三次采收率提供了突破性的解决方案,从而提高了石油产量。它们具有降低界面张力、改变地层润湿性、提高吸附能力和加速分离压力的能力,这使它们成为提高采收率的绝佳选择。本文的主要目的是研究聚合物对氧化锌(ZnO)纳米流体提高采收率(EOR)的影响,以及聚合物稳定剂对纳米流体中纳米颗粒稳定性的化学改性作用。合成了平均粒径为34 nm的纳米颗粒,并用其制备了不同浓度的纳米流体,并通过沉降和紫外-可见分光光度法对其稳定性进行了评价。采用zno合成的纳米流体,外加聚乙烯吡咯烷酮(PVP)和聚乙烯醇(PVA)作为稳定剂。结果表明,添加PVA稳定剂的ZnO纳米流体的采收率最高,达到82%。相比之下,不添加稳定剂的ZnO纳米流体在驱油实验中采收率最低。结果表明:注油速度越高,采收率越高,粘指效应越小,驱替效果越好;此外,与不含稳定剂的ZnO纳米流体相比,含聚合物稳定剂的纳米流体获得了更好的回收率。在界面张力测试中也观察到了这一现象,含有PVA和PVP稳定剂的纳米流体分别使IFT降低了59%和61%。
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引用次数: 0
Current status and further development of deterministic lateral displacement for micro-particle separation 微颗粒分离的确定性侧向位移研究现状及进一步发展
IF 3.6 Q1 Engineering Pub Date : 2023-10-04 DOI: 10.1186/s40486-023-00175-w
Alexander Zhbanov, Ye Sung Lee, Sung Yang

Deterministic lateral displacement (DLD) is a passive, label-free, continuous-flow method for particle separation. Since its discovery in 2004, it has been widely used in medical tests to separate blood cells, bacteria, extracellular vesicles, DNA, and more. Despite the very simple idea of the DLD method, many details of its mechanism are not yet fully understood and studied. Known analytical equations for the critical diameter of separated particles include only the gap between the columns in the DLD array and the fraction of the column shift. The dependence of the critical diameter on the post diameter, channel height, and a number of other geometric parameters remains unexplored. The problems also include the effect of flow rate and particle concentration on the critical diameter and separation efficiency. At present, DLD devices are mainly developed through numerical simulation and experimental validation. However, it is necessary to find fundamental regularities that would help to improve the separation quantitatively and qualitatively. This review discusses the principle of particle separation, the physical aspects of flow formation, and hydrodynamic forces acting on particles in DLD microchannels. Various analytical models of a viscous flow in an array of cylindrical posts are described. Prospects for further research are outlined.

确定性横向位移(DLD)是一种被动、无标记、连续流动的颗粒分离方法。自2004年发现以来,它已广泛用于医学测试,以分离血细胞、细菌、细胞外囊泡、DNA等。尽管DLD方法的思想非常简单,但其机制的许多细节尚未完全理解和研究。已知的分离颗粒临界直径的解析方程只包括DLD阵列中柱间的间隙和柱位移的分数。临界直径对柱直径、通道高度和其他一些几何参数的依赖性仍未得到探索。这些问题还包括流速和颗粒浓度对临界直径和分离效率的影响。目前,DLD器件主要是通过数值模拟和实验验证来开发的。然而,有必要找到基本的规律,这将有助于提高分离的定量和定性。本文讨论了颗粒分离的原理,流动形成的物理方面,以及作用于DLD微通道中颗粒的水动力。描述了圆柱柱阵列中粘性流动的各种解析模型。展望了今后的研究方向。
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引用次数: 0
Non-fullerene acceptor based photoelectric material for retinal prosthesis 基于非富勒烯受体的视网膜假体光电材料
IF 3.6 Q1 Engineering Pub Date : 2023-09-28 DOI: 10.1186/s40486-023-00177-8
Hyunsun Song, Hyeonhee Roh, Jae Young Kim, Byung Chul Lee, Bright Walker, Maesoon Im

Microelectronic retinal implants can restore a useful level of artificial vision in photoreceptor-damaged retina. Previously commercialized retinal prostheses require transocular connection lines to an external power supply and/or for data transmission, which are unwieldy and may cause unwanted side effects, such as infections. A recently reported wireless device used a rigid silicon substrate. However, it had the potential for a long-term mechanical mismatch with soft retinal tissue. In this work, we used organic photovoltaic materials which can be fabricated on flexible substrates as well as be operated without any physical connection to the external world. The present study employed PCE10 as an active layer for retinal prosthetic application for the first time. Compared to previously studied organic photovoltaic materials used in retinal prosthesis research (such as P3HT), our PCE10 devices showed higher efficiency, providing a huge advantage in this field. When the PCE10 was blended with other non-fullerene acceptors achieving a ternary organic photovoltaic layer (PCE10:ITIC:Y6 blend), it showed lower reduction of photocurrent under same irradiation frequency condition. The fabrication method for our organic photovoltaic device was simple and easy to control its thickness. The fabricated devices showed adequate photocurrent to stimulate the retinal neurons with a smaller reduction in generated photocurrent during repeating stimuli compared to P3HT or PCE10 alone.Author names: Please confirm if the author names are presented accurately and in the correct sequence (given name, middle name/initial, family name). Author: Given name [Jae Young] Last name [Kim]. Author: Given name [Byung Chul] Last name [Lee].Yes, they are correct.

微电子视网膜植入物可以在受光感受器损伤的视网膜上恢复有用的人工视力。以前商业化的视网膜假体需要经眼连接到外部电源和/或数据传输,这是笨重的,可能会导致不必要的副作用,如感染。最近报道了一种使用刚性硅衬底的无线设备。然而,它有可能与软视网膜组织长期机械不匹配。在这项工作中,我们使用了有机光伏材料,它可以在柔性衬底上制造,并且可以在没有任何物理连接的情况下与外部世界进行操作。本研究首次采用PCE10作为视网膜假体应用的活性层。与之前研究的用于视网膜假体研究的有机光伏材料(如P3HT)相比,我们的PCE10器件具有更高的效率,在该领域具有巨大的优势。当PCE10与其他非富勒烯受体共混形成三元有机光伏层(PCE10:ITIC:Y6共混物)时,在相同辐照频率条件下,其光电流降低幅度较小。本发明的有机光伏器件制作方法简单,厚度易于控制。与单独的P3HT或PCE10相比,制造的装置显示出足够的光电流来刺激视网膜神经元,并且在重复刺激期间产生的光电流减少较少。作者姓名:请确认作者姓名是否准确且顺序正确(名,中间名/首字母,姓)。作者:名[Jae Young]姓[Kim]。作者:名[秉哲]姓[李]。是的,他们是正确的。
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引用次数: 0
Investigation of LIG-based pressure sensors with various silicon-based elastomeric encapsulation layers 不同硅基弹性体封装层的硅基压力传感器研究
IF 3.6 Q1 Engineering Pub Date : 2023-09-27 DOI: 10.1186/s40486-023-00176-9
Yoo-Kyum Shin, Ki-Hoon Kim, Min-Ho Seo

Laser-induced graphene (LIG) has attracted significant interest in the field of pressure sensors owing to the high sensitivity associated with its inherent three-dimensional porous structure. However, the brittleness of fabricated LIG poses a critical challenge in terms of durability. To address this issue, current research on LIG-based pressure sensors has focused on the utilization of Si-elastomer encapsulation layers. Despite the importance of the mechanical properties of Si elastomers for the performance of physical sensors, few studies have been conducted on the characterization of pressure sensors based on the encapsulation layer. In this study, we investigated the electromechanical characteristics of LIG-based pressure sensors encapsulated in various Si-based elastomers. For an unbiased evaluation, we first introduce a simple and reliable fabrication process for LIG-based pressure sensors with different Si-elastomer encapsulation layers. Subsequently, the electromechanical responses of the sensors were characterized using an automated pressure machine, demonstrating that sensors with encapsulation layers with a lower Young’s modulus exhibited increased resistance changes and extended response times. Finally, an in-depth exploration of the environmental stability of the pressure sensors was conducted for various encapsulation materials, ultimately confirming negligible performance variations based on the encapsulation materials.

激光诱导石墨烯(LIG)由于其固有的三维多孔结构具有高灵敏度,在压力传感器领域引起了极大的兴趣。然而,制造LIG的脆性对耐久性提出了严峻的挑战。为了解决这一问题,目前基于li的压力传感器的研究主要集中在硅弹性体封装层的利用上。尽管硅弹性体的力学性能对物理传感器的性能非常重要,但基于封装层的压力传感器的表征研究却很少。在这项研究中,我们研究了封装在各种硅基弹性体中的硅基压力传感器的机电特性。为了进行公正的评估,我们首先介绍了具有不同硅弹性体封装层的基于lige的压力传感器的简单可靠的制造工艺。随后,使用自动化压力机对传感器的机电响应进行了表征,证明具有较低杨氏模量的封装层的传感器具有更大的电阻变化和更长的响应时间。最后,对各种封装材料对压力传感器的环境稳定性进行了深入的探索,最终确定了基于封装材料的性能变化可以忽略不计。
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引用次数: 0
Overcoming delamination in two-photon lithography for improving fabrication of 3D microstructures 克服双光子光刻中分层现象,改善三维微结构的制造
IF 3.6 Q1 Engineering Pub Date : 2023-09-22 DOI: 10.1186/s40486-023-00173-y
Cheol Woo Ha

Two-photon lithography has emerged as a highly effective method for fabricating intricate three-dimensional (3D) microstructures. It enables the rapid fabrication of 3D microstructures, unlike conventional two-dimensional nanopatterning. Researchers have extensively investigated two-photon polymerization (TPP) for the fabrication of diverse 3D micro/nanodevices with high resolution. TPP can be applied in cell cultures, metamaterials, optical materials, electrical devices, and fluidic devices, to name a few. In this study, we investigate the applications and innovative research pertaining to TPP, which is an effective fabrication technique with significant advancement in various fields. In particular, we attempt to determine the reasons that cause the detachment or delamination of 3D microstructures during the development process and propose some solutions. A step-by-step fabrication process for a glass substrate, from photoresist deposition to laser scanning and the dissolution of the uncured photoresist, is presented. Defects such as pattern delamination are discussed, with emphasis on the cell scaffold structure and microlens array. Understanding and addressing these defects are vital to the success of 3D microstructure fabrication via TPP.

双光子光刻技术已经成为一种制造复杂三维微结构的高效方法。它使3D微结构的快速制造成为可能,不像传统的二维纳米图形。研究人员广泛地研究了双光子聚合(TPP)用于制造各种高分辨率的三维微/纳米器件。TPP可以应用于细胞培养、超材料、光学材料、电子设备和流体设备等。在本研究中,我们探讨了与TPP相关的应用和创新研究,这是一种有效的制造技术,在各个领域都有显著的进步。特别是,我们试图确定在开发过程中导致三维微结构脱离或分层的原因,并提出一些解决方案。介绍了从光刻胶沉积到激光扫描和未固化光刻胶溶解的玻璃基板的一步一步制造过程。讨论了诸如图案分层等缺陷,重点讨论了细胞支架结构和微透镜阵列。了解和解决这些缺陷对于通过TPP成功制造3D微结构至关重要。
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引用次数: 0
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