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Magnetic metal-based MOF composite materials: a multidimensional regulation strategy for microwave absorption properties 磁性金属基 MOF 复合材料:微波吸收特性的多维调节策略
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-08 DOI: 10.1007/s42114-024-00991-7
Zuxiang Mu, Peitao Xie, Anoud Saud Alshammari, Salah M. El-Bahy, Juanna Ren, Gemeng Liang, Mukun He, Zeinhom M. El-Bahy, Peng Zhang, Chunzhao Liu

The rapid development of information and communication technology has led to a considerable increase in electromagnetic pollution, prompting the necessity for designing microwave-absorbing materials as an unavoidable trend. The incorporation of magnetic materials can enhance the magnetic loss capacity of microwave-absorbing materials, thereby improving their absorption performance. However, magnetic materials, especially the high-density metals or oxides, are unsuitable for the lightweight design principle of microwave-absorbing materials. In recent years, metal–organic frameworks (MOFs), particularly magnetic metal-based MOFs, are considered advantageous competitors in designing high-performance microwave-absorbing materials because of their high porosity, adjustable structure, and inherent magnetism. This review summarizes the recent progress in studies of microwave-absorbing materials using magnetic metal-based MOFs and their derivatives, including their synthesis process, microwave absorption mechanisms, and comparisons of absorbing performances for MOFs-derived materials with different compositions and microstructures. Finally, potential challenges and future development prospects that MOF-derived composite materials may face in the field of microwave absorption are put forward. We hope to shed light on the mechanism of microwave absorption for magnetic metal-based MOFs, as well as the effect of subsequent processing on the MOF precursor in this regard.

信息和通信技术的快速发展导致电磁污染大幅增加,因此设计微波吸收材料已成为不可避免的趋势。磁性材料的加入可以增强微波吸收材料的磁损耗能力,从而改善其吸收性能。然而,磁性材料,尤其是高密度金属或氧化物,并不适合微波吸收材料的轻量化设计原则。近年来,金属有机框架(MOFs),尤其是磁性金属基 MOFs 因其高孔隙率、可调结构和固有磁性,被认为是设计高性能微波吸收材料的有利竞争者。本综述总结了利用磁性金属基 MOFs 及其衍生物研究微波吸收材料的最新进展,包括其合成工艺、微波吸收机理,以及不同成分和微结构的 MOFs 衍生材料的吸收性能比较。最后,提出了 MOF 衍生复合材料在微波吸收领域可能面临的挑战和未来的发展前景。我们希望能阐明磁性金属基 MOFs 的微波吸收机理,以及后续加工对 MOF 前体在这方面的影响。
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引用次数: 0
Carbon fiber and carbon fiber composites—creating defects for superior material properties 碳纤维和碳纤维复合材料--制造缺陷,实现优异的材料性能
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-07 DOI: 10.1007/s42114-024-00971-x
Ashis Sutradhar Nitai, Tonny Chowdhury, Md Nafis Inam, Md Saifur Rahman, Md Ibrahim H. Mondal, M. A. H. Johir, Volker Hessel, Islam Md Rizwanul Fattah, Md Abul Kalam, Wafa Ali Suwaileh, John L. Zhou, Masoumeh Zargar, Mohammad Boshir Ahmed

Recent years have seen a rise in the use of carbon fiber (CF) and its composite applications in several high-tech industries, such as the design of biomedical sensor components, 3D virtual process networks in automotive and aerospace parts, and artificial materials or electrodes for energy storage batteries. Since pristine CF have limited properties, their properties are often modified through a range of technologies, such as laser surface treatment, electron-beam irradiation grafting, plasma or chemical treatments, electrophoretic deposition, carbonization, spinning-solution or melt, electrospinning, and sol–gel, to greatly improve their properties and performance. These procedures cause faulty structures to emerge in CF. The characteristics and performances of CF (thermo-electric conductivity, resistivity, stress tolerance, stiffness and elasticity, chemical resistivity, functionality, electrochemical properties, etc.) vary greatly depending on the modification technique used. Thus, the purpose of this review is to demonstrate how the insertion of faults can result in the production of superior CF. The characteristics of CF defects were examined using a variety of analytical techniques, such as defect-forming chemistry, molecular organization, and ground-level chemistries like their crystallinities. Finally, some future work is also included.

Graphical abstract

近年来,碳纤维(CF)及其复合材料在一些高科技产业中的应用日益增多,例如生物医学传感器部件的设计、汽车和航空航天部件中的三维虚拟加工网络,以及储能电池的人造材料或电极。由于原始 CF 的性能有限,通常需要通过一系列技术对其进行改性,如激光表面处理、电子束辐照接枝、等离子体或化学处理、电泳沉积、碳化、纺丝溶液或熔体、电纺丝和溶胶-凝胶等,以大大提高其性能和表现。这些程序会导致 CF 出现错误的结构。CF 的特性和性能(热电导率、电阻率、应力耐受性、硬度和弹性、化学电阻率、功能性、电化学性质等)因所使用的改性技术不同而有很大差异。因此,本综述旨在说明插入缺陷如何能生产出优质的 CF。我们使用了多种分析技术来研究 CF 缺陷的特性,如缺陷形成化学、分子组织和结晶度等底层化学。最后,还包括一些未来的工作。
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引用次数: 0
ZIF-8-enhanced multifunctional, high-performance nanocomposite hydrogel–based wearable strain sensor for healthcare applications 基于 ZIF-8 增强型多功能、高性能纳米复合水凝胶的可穿戴应变传感器在医疗保健领域的应用
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-07 DOI: 10.1007/s42114-024-00987-3
Md Sazzadur Rahman, Muhammad Toyabur Rahman, Hitendra Kumar, Keekyoung Kim, Seonghwan Kim

The rapid growth of strain sensors in cutting-edge applications, including wearable human–machine interfaces, electronic skins, soft robotics, and advanced healthcare, has greatly heightened the demand for high-performance hydrogels. In this report, we demonstrate a multifunctional, highly stretchable, and robust conductive hydrogel composed of polyacrylamide (AM), 2-hydroxyethyl acrylate (HEA), and lithium chloride (LiCl) reinforced by zeolite imidazolate frameworks-8 (ZIF-8) through a one-pot free radical polymerization method. The synergy of electrostatic interactions between the AM-HEA polymer chain and nanoporous ZIF-8 enhances the mechanical properties, while the abundant hydrogen bonds originating from the polarized surface of ZIF-8 also introduce multifunctionality to the nanocomposite hydrogel. Tuning the composition of ZIF-8 within the hydrogel matrix results in the attainment of outstanding properties such as excellent stretchability of 808%, high toughness of 453.5 kJm−3, and minimal hysteresis as low as 2.6%. Notably, the nanocomposite hydrogel displays strong adhesion, self-healing properties, and resilience in freezing temperatures down to − 20 °C. Furthermore, the as-developed strain sensor exhibits relatively high sensitivity with a gauge factor of 2.98 across a wide dynamic range, along with fast response and recovery times of 280 ms and 330 ms, respectively. The multifunctionality and electromechanical properties of ZIF-8 enhanced high-performance hydrogel hold promise for its application as a wearable, flexible, and stretchable strain sensor for detecting human physiological activities and providing vital biomechanical information for health assessment.

应变传感器在可穿戴人机界面、电子皮肤、软机器人和先进医疗保健等尖端应用中的快速发展,大大提高了对高性能水凝胶的需求。在本报告中,我们展示了一种由聚丙烯酰胺(AM)、2-羟乙基丙烯酸酯(HEA)和氯化锂(LiCl)组成的多功能、高拉伸性和坚固的导电水凝胶,该水凝胶由沸石咪唑啉框架-8(ZIF-8)通过一锅自由基聚合法增强。AM-HEA 聚合物链与纳米多孔 ZIF-8 之间的静电相互作用协同作用增强了其机械性能,而 ZIF-8 极化表面产生的大量氢键也为纳米复合水凝胶带来了多功能性。通过调节水凝胶基质中 ZIF-8 的成分,可以获得出色的性能,如 808% 的卓越拉伸性、453.5 kJm-3 的高韧性和低至 2.6% 的最小滞后。值得注意的是,这种纳米复合水凝胶具有很强的粘附性和自愈性,在低至零下 20 ℃ 的冰冻温度下也能保持弹性。此外,所开发的应变传感器在较宽的动态范围内表现出较高的灵敏度(测量系数为 2.98),以及快速的响应和恢复时间(分别为 280 毫秒和 330 毫秒)。ZIF-8 增强型高性能水凝胶的多功能性和机电特性使其有望用作可穿戴、柔性和可拉伸的应变传感器,用于检测人体生理活动,并为健康评估提供重要的生物力学信息。
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引用次数: 0
Augmented neuromuscular transmission: bridging physical and cognitive practices through intrinsic hybrid nanogenerator-integrated confirmation analysis system 增强神经肌肉传导:通过内在混合纳米发电机集成确认分析系统连接身体和认知实践
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-05 DOI: 10.1007/s42114-024-00967-7
Asokan Poorani Sathya Prasanna, Monunith Anithkumar, Nagamalleswara Rao Alluri, Sang-Jae Kim

Computer-assisted smart neurotherapy (CASNuT) is an emerging technology used for psychiatric rehabilitation, neurological rehabilitation, and schizophrenia to improve treatment and clinical decision-making. Combined mental practice (cognitive control) and physical practice (bending fingers) were incorporated into the prepared CASNuT. It is constructed using the network of multifunctional piezo-tribo hybrid (PDMS/BCST) composite film-based intrinsic hybrid nanogenerators (which acts as a mechano-electric sensor for the smart gloves) and computation with the interfacing circuit/display devices. Successful integration of piezoelectric and triboelectric charges enhanced the intrinsic hybrid nanogenerator output (426 V, 1.72 mA/m2, and 368.66 µW/m2 at 100 MΩ) and sensing properties. Next, it demonstrated rehabilitation treatment (via CASNuT) and smart medical assistance using a mechano-electric smart medical glove. Computer-aided or assisted therapy computes for better assistance and treatment.

Graphical abstract

计算机辅助智能神经疗法(CASNuT)是一项新兴技术,用于精神康复、神经康复和精神分裂症的治疗,以改善治疗和临床决策。所制备的 CASNuT 结合了心理练习(认知控制)和身体练习(弯曲手指)。它是利用多功能压电三元混合(PDMS/BCST)复合膜为基础的本征混合纳米发电机网络(作为智能手套的机械电传感器)和计算与接口电路/显示设备构建而成的。压电和三电荷的成功集成增强了本征混合纳米发电机的输出(426 V、1.72 mA/m2 和 368.66 µW/m2 ,100 MΩ)和传感性能。接着,它展示了康复治疗(通过 CASNuT)和使用机电智能医疗手套的智能医疗辅助。计算机辅助或辅助治疗计算可提供更好的帮助和治疗。
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引用次数: 0
High-performance magnetic artificial silk fibers produced by a scalable and eco-friendly production method 采用可扩展的环保型生产方法生产高性能磁性人造丝纤维。
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00962-y
Gabriele Greco, Benjamin Schmuck, Lucia Del Bianco, Federico Spizzo, Luca Fambri, Nicola Maria Pugno, Sabino Veintemillas-Verdaguer, Maria Puerto Morales, Anna Rising

Flexible magnetic materials have great potential for biomedical and soft robotics applications, but they need to be mechanically robust. An extraordinary material from a mechanical point of view is spider silk. Recently, methods for producing artificial spider silk fibers in a scalable and all-aqueous-based process have been developed. If endowed with magnetic properties, such biomimetic artificial spider silk fibers would be excellent candidates for making magnetic actuators. In this study, we introduce magnetic artificial spider silk fibers, comprising magnetite nanoparticles coated with meso-2,3-dimercaptosuccinic acid. The composite fibers can be produced in large quantities, employing an environmentally friendly wet-spinning process. The nanoparticles were found to be uniformly dispersed in the protein matrix even at high concentrations (up to 20% w/w magnetite), and the fibers were superparamagnetic at room temperature. This enabled external magnetic field control of fiber movement, rendering the material suitable for actuation applications. Notably, the fibers exhibited superior mechanical properties and actuation stresses compared to conventional fiber-based magnetic actuators. Moreover, the fibers developed herein could be used to create macroscopic systems with self-recovery shapes, underscoring their potential in soft robotics applications.

柔性磁性材料在生物医学和软机器人应用方面具有巨大潜力,但它们必须具有机械坚固性。从机械角度来看,蜘蛛丝是一种非凡的材料。最近,人们开发出了用可扩展的全水基工艺生产人造蜘蛛丝纤维的方法。如果具有磁性,这种仿生人造蜘蛛丝纤维将成为制造磁性致动器的绝佳候选材料。在这项研究中,我们介绍了磁性人造蜘蛛丝纤维,它由磁铁矿纳米颗粒和介-2,3-二巯基丁二酸组成。这种复合纤维可采用环保的湿法纺丝工艺大量生产。研究发现,即使在高浓度(高达 20% w/w 磁铁矿)的情况下,纳米粒子也能均匀地分散在蛋白质基质中,而且纤维在室温下具有超顺磁性。这使得外部磁场能够控制纤维的运动,从而使这种材料适用于驱动应用。值得注意的是,与传统的纤维磁性致动器相比,这种纤维具有更优异的机械性能和致动应力。此外,本文开发的纤维还可用于创建具有自恢复形状的宏观系统,这凸显了它们在软机器人应用中的潜力:在线版本包含补充材料,可查阅 10.1007/s42114-024-00962-y。
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引用次数: 0
Hybridization and its transformative role in bamboo fiber reinforced polymer composites: a review 竹纤维增强聚合物复合材料中的杂化及其变革作用:综述
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00974-8
Abir Khan, S.M. Sapuan, E.S. Zainudin, M.Y.M. Zuhri

Design and development of environmentally friendly composite materials is underway in response to escalating environmental concerns and the looming scarcity of petroleum-based resources. A key strategy in this endeavor is the application of biologically derived polymers, reinforced with organic fibers. This approach has appeared to be a potent substitute for synthetic fiber-reinforced polymers in the development of composite materials. Among the organic fibers, bamboo has seen a surge in popularity due to its wide availability, cost-effectiveness, biodegradability, and superior mechanical properties. However, bamboo fiber is combined with other natural fibers in order to maximize the performance, address limitations, and broaden the scope of application of bamboo fiber-reinforced hybrid polymer composites. This review covers topics including the anatomy of bamboo and the chemical composition of bamboo fiber. Later on, different aspects of hybrid composites such as configurations of fibers and polymers, orientation of fibers, mechanical properties, thermal properties, biodegradability and applications in aerospace, ballistic protection, automotive, structural, filtration, electrode, electromagnetic wave absorption, sensor technologies, and infrared shielding are discussed. This review also highlights several problems and solutions in the development of bamboo hybrid composites. This article offers valuable perspectives and recommendations for those engaged in the field of green composites, paving the way for the creation of sustainable materials suitable for diverse applications.

Graphical abstract

为应对日益严重的环境问题和石油资源的日益匮乏,环保型复合材料的设计和开发正在进行之中。这方面的一个关键策略是应用生物聚合物,并用有机纤维进行增强。在开发复合材料的过程中,这种方法似乎是合成纤维增强聚合物的有效替代品。在有机纤维中,竹子因其广泛的可获得性、成本效益、生物降解性和优越的机械性能而大受欢迎。然而,为了最大限度地提高竹纤维增强杂化聚合物复合材料的性能、解决其局限性并扩大其应用范围,竹纤维与其他天然纤维进行了结合。本综述涉及的主题包括竹子的解剖结构和竹纤维的化学成分。随后,还讨论了混合复合材料的不同方面,如纤维和聚合物的配置、纤维的取向、机械性能、热性能、生物降解性以及在航空航天、防弹、汽车、结构、过滤、电极、电磁波吸收、传感器技术和红外屏蔽等方面的应用。这篇综述还强调了竹混合复合材料开发过程中的几个问题和解决方案。本文为绿色复合材料领域的从业人员提供了宝贵的观点和建议,为创造适用于各种应用的可持续材料铺平了道路。
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引用次数: 0
Enhanced detection of HER2 using a TiVC MXenes/gold nanocomposite amplified analytical biosensor for precise cancer biomarker monitoring 利用 TiVC MXenes/金纳米复合材料放大分析生物传感器增强对 HER2 的检测,实现对癌症生物标记物的精确监测
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00966-8
Najmeh Zare, Hassan Karimi-Maleh, Zhouxiang Zhang, Yangpin Wen, Nianbing Zhong, Li Fu

Recently, aptamers have been widely used in the detection and measurement of cancer biomarkers. This issue has had a significant impact on the process of diagnosing all types of cancers. This research work explores the development and application of layer-by-layer modified electrochemical apta-sensor for the precise monitoring of HER2, a crucial biomarker associated with breast cancer. The surface of the screen-printed carbon electrode was modified with gold nanoparticle (Au-NP) and TiVC MXene catalyst plus Pb2+ loaded aptamer (SPCE/TiVC-MXene/Au NPs/Pb2+-aptamer), which showed a high selectivity and affinity towards HER2 and offered a sensitive detection platform. The MXene nano-layer was synthesized and characterized by XPS, MAP, EDS, AFM, BET, and TEM methods and used as a substrate to improve electrochemical conductivity and loading of biological recognition element. The square-wave anodic stripping voltammetry (SWASV) method was used as a highly sensitive platform in HER2 detection. The difference of stripping signals of the Pb2+ from the SPCE/TiVC-MXene/Au NPs/Pb2+-aptamer before and after incubation in HER2 solution was selected as analytical response to achieve a reliable and quantitative analysis for HER2 concentrations. The effective factors in monitoring of HER2 such as concentration of Pb2+, incubation time, and buffer type were optimized and results showed that 5 mM of Pb2+ and 90-min incubation time in Tris–HCl created best condition in fabrication of biosensor. The results demonstrate a linear dynamic range of 1.0–1200 pg/mL for monitoring of HER2 with limit of detection of 50 fg/mL. A good affinity of fabricated apta-sensor to HER2 in the presence some other biomarkers such as PR, ER, and CEA confirmed the selectivity of the fabricated biosensor towards HER2 detection.

最近,适配体被广泛应用于癌症生物标志物的检测和测量。这一问题对各种癌症的诊断过程产生了重大影响。这项研究工作探讨了逐层修饰电化学适配体传感器的开发和应用,以精确监测与乳腺癌相关的重要生物标志物 HER2。丝网印刷碳电极表面经金纳米粒子(Au-NP)和 TiVC MXene 催化剂以及 Pb2+ 载体(SPCE/TiVC-MXene/Au NPs/Pb2+-aptamer)修饰,对 HER2 具有高选择性和亲和性,提供了一个灵敏的检测平台。通过 XPS、MAP、EDS、AFM、BET 和 TEM 方法合成并表征了 MXene 纳米层,并将其用作基底以提高电化学传导性和生物识别元素的负载。方波阳极剥离伏安法(SWASV)被用作检测 HER2 的高灵敏平台。该方法以 SPCE/TiVC-MXene/Au NPs/Pb2+-aptamer 在 HER2 溶液中孵育前后 Pb2+ 的剥离信号差作为分析响应,以实现对 HER2 浓度的可靠定量分析。结果表明,5 mM 的 Pb2+和 90 分钟的 Tris-HCl 培养时间为生物传感器的制作创造了最佳条件。结果表明,HER2 监测的线性动态范围为 1.0-1200 pg/mL,检测限为 50 fg/mL。在存在其他生物标志物(如 PR、ER 和 CEA)的情况下,所制造的 apta 传感器对 HER2 具有良好的亲和力,这证实了所制造的生物传感器对 HER2 检测的选择性。
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引用次数: 0
Integration of element codoping and electron-donor functional groups into metal–organic framework to improve photoelectrochemical water oxidation of hematite photoanode 在金属有机框架中整合元素共掺和电子捐献官能团,改善赤铁矿光阳极的光电化学水氧化性能
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00963-x
Xin Wang, Xin Song, Hala M. Abo-Dief, Dalal A. Alshammari, Vignesh Murugadoss, Zhexenbek Toktarbay, Liguo Yang, Zhongyuan Zhou

Hematite (α-Fe2O3) can be a promising photoelectrode to promote the development of photoelectrochemical water splitting (PEC-WS), but the low photogenerated carrier separation efficiency limits the further application. In this work, a nano-heterojunction is constructed by a metal–organic framework (MOF-5) and α-Fe2O3 films to regulate photogenerated carrier transport. The electronic structure regulation (element doping and electron-donor functional groups) is introduced to solve the problems of poor electrical conductivity of MOF-5 and interface defects and band mismatch caused by contacting with α-Fe2O3 film. The α-Fe2O3/NH2:MOF-5(Ni)@Ru photoanode exhibits the optimal photocurrent density of 2.6 mA/cm2 at 1.23 VRHE, which is 2.68 times of the pure α-Fe2O3 photoanode. This can be attributed to that the introduction of MOF catalyst can provide more abundant active sites for PEC water oxidation. The element codoping and synergistic effect of Ni and Ru improve the conductivity and inhibit the recombination rate of photogenerated electron–hole pairs of α-Fe2O3 photoanode. The electron-donor functional group of –NH2 can regulate the electron distribution to prolong the lifetime of photogenerated holes, which further enhances the photogenerated carrier separation and transfer efficiency.

赤铁矿(α-Fe2O3)是一种前景广阔的光电电极,可促进光电化学分水(PEC-WS)技术的发展,但其较低的光生载流子分离效率限制了其进一步应用。本研究利用金属有机框架(MOF-5)和α-Fe2O3 薄膜构建了纳米异质结,以调节光生载流子的传输。引入电子结构调控(元素掺杂和电子捐献官能团)解决了 MOF-5 导电性差以及与 α-Fe2O3 膜接触造成的界面缺陷和带错配问题。α-Fe2O3/NH2:MOF-5(Ni)@Ru 光阳极在 1.23 VRHE 下的最佳光电流密度为 2.6 mA/cm2,是纯α-Fe2O3 光阳极的 2.68 倍。这可能是因为 MOF 催化剂的引入为 PEC 水氧化提供了更丰富的活性位点。Ni 和 Ru 元素的共掺杂和协同效应提高了 α-Fe2O3 光阳极的导电率,并抑制了光生电子-空穴对的重组率。-NH2的电子疏导官能团可以调节电子分布,延长光生空穴的寿命,从而进一步提高光生载流子的分离和转移效率。
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引用次数: 0
Modulating magnetic properties of high entropy soft FeSiB(P)Cu alloys with excellent GFA via α-Fe(Si) grain preferential growth mechanism 通过α-Fe(Si)晶粒优选生长机制调节具有优异 GFA 的高熵软 FeSiB(P)Cu 合金的磁性能
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00952-0
Shujie Kang, Zhe Chen, Qianke Zhu, Kewei Zhang, Mohammed A. Amin, Anoud Saud Alshammari, Hua Qiu, Zhijie Yan, Mukun He, Yong Jiang, Nawal D. Alqarni, Zijian Wu

The harmony between glass-forming ability (GFA) and soft magnetic properties (SMPs) of Fe-based amorphous/nanocrystalline alloys has garnered considerable attention. Herein, a prototypical FeSiBCu amorphous alloy system by microalloying P was investigated regarding the GFA, thermal stability, SMPs, and microstructure. It was found that including P not only raised the degree of amorphous disorder but also facilitated the precipitation of α-Fe(Si) grains and widened the annealing window. Furthermore, adding P changed the optimal crystallographic orientation of the α-Fe(Si) phase and enhanced the growth competition of grains with different orientations, which promoted grain refinement (The average grain size was decreased from 61.36 to 21.24 nm). After optimal annealing processing, the ribbons with 8 at.% P addition displayed a lower coercivity (Hc) of 4.61 A/m. While the 4 at.% P-added ribbons exhibited a higher saturation magnetic flux density (Bs) of 1.75 T. The distinctive mechanism of grain preferential growth in FeSiBPCu alloys provides relevant guidance on the correlation between nanocrystalline structure evolution and the modulation of SMPs.

铁基非晶/纳米晶合金的玻璃化能力(GFA)和软磁特性(SMPs)之间的协调性引起了广泛关注。本文通过微合金化 P,研究了铁硅铜非晶合金体系的玻璃化能力(GFA)、热稳定性、软磁性能和微观结构。研究发现,加入 P 不仅提高了非晶无序度,还促进了 α-Fe(Si)晶粒的析出,并拓宽了退火窗口。此外,添加 P 改变了 α-Fe(Si)相的最佳结晶取向,增强了不同取向晶粒的生长竞争,从而促进了晶粒细化(平均晶粒尺寸从 61.36 nm 减小到 21.24 nm)。经过最佳退火处理后,添加了 8% P 的带材显示出较低的矫顽力(Hc),为 4.61 A/m。FeSiBPCu 合金中晶粒优先生长的独特机制为纳米结晶结构演变与 SMPs 调制之间的关联提供了相关指导。
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引用次数: 0
Field-dependent nonlinear electrical response characteristics in polymer dielectrics with sodium alginate scaffold 带有海藻酸钠支架的聚合物电介质中随场变化的非线性电响应特性
IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-02 DOI: 10.1007/s42114-024-00984-6
Daoming Zhang, Chunhui Bi, Bin Gou, Jiangang Zhou, An Zhong, Baisen Lin, Hangchuan Cai, Congzhen Xie, Huasong Xu, Rui Wang

Polymer-based self-adaptive dielectrics are considered promising materials to meet the growing insulation needs of flexible electronic devices and high-voltage DC cables. However, the temperature-sensitive electrical performance and poor thermal management ability of polymer dielectrics are bottlenecks that limit their further development. Here, we report a novel three-dimensional microstructure, i.e., nonlinear silicon carbide (SiC) micromaterials loaded on sodium alginate (SA) aerogel, exhibiting satisfactory non-linear electric conductivity with ultra-high thermal conductivity (3.86 W m−1 K−1, compared to 0.21 W m−1 K−1 of the pure epoxy resin). The SA aerogel, rich in high-density pores, is conductive to SiC forming a highly interconnected network structure under low loading, which endows polymer composites with the ability to quickly disperse charges under high electric field. In addition, the three-dimensional interconnected SiC network can disperse the Joule heat from local currents generated by nonlinear behavior, preventing thermal breakdown caused by the adverse effect of heat accumulation on the electrical properties of the material. In combining the advantages of nonlinear electrical conductivity characteristics, high thermal management ability, and low load capacity, this strategy expands the application scenarios of electric field self-adaptive polymer materials under high-temperature conditions.

Graphical abstract

We report a novel three-dimensional microstructure dielectric composite with self-assembly SiC on sodium alginate aerogel. Due to the high interconnectivity and porous structure of SA aerogel, efficient construction of conducting paths is achieved at a low filler content (1 vol%), which endows the composite with satisfying nonlinear conductivity and thermal management capacity.

聚合物基自适应电介质被认为是满足柔性电子设备和高压直流电缆日益增长的绝缘需求的有前途的材料。然而,聚合物电介质对温度敏感的电气性能和较差的热管理能力是限制其进一步发展的瓶颈。在此,我们报告了一种新型三维微结构,即在海藻酸钠(SA)气凝胶上负载非线性碳化硅(SiC)微材料,该微结构具有令人满意的非线性电导率和超高导热率(3.86 W m-1 K-1,而纯环氧树脂的导热率为 0.21 W m-1 K-1)。SA 气凝胶富含高密度孔隙,在低负载条件下可与 SiC 形成高度互连的网络结构,从而使聚合物复合材料具有在高电场下快速分散电荷的能力。此外,三维互连的 SiC 网络还能分散非线性行为产生的局部电流焦耳热,防止因热量积累对材料电气性能产生不利影响而导致热击穿。该策略结合了非线性导电特性、高热管理能力和低负载能力等优点,拓展了电场自适应聚合物材料在高温条件下的应用场景。由于海藻酸钠气凝胶具有高互联性和多孔结构,因此可以在较低的填料含量(1 vol%)下高效构建导电路径,从而使复合材料具有令人满意的非线性导电性和热管理能力。
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Advanced Composites and Hybrid Materials
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