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Tuning Ag+ and Mn2+ doping in ZnS:Ag,Mn embedded polymers for flexible white light emitting films 调节 ZnS:Ag、Mn 嵌入聚合物中的 Ag+ 和 Mn2+ 掺杂,制造柔性白光发光薄膜
Pub Date : 2024-01-04 DOI: 10.20517/ss.2023.32
Lun Ma, E. Amador, George S. Belev, Chhabindra Gautam, Weidong Zhou, J. P. Liu, R. Sammynaiken, Wei Chen
Flexible Light Emitting Diodes are versatile lighting solutions that offer bendable and adaptable illumination possibilities. A soft, flexible white luminescent film (1 mm) shows promise for foldable electroluminescent devices and applications. This film was fabricated using ZnS:Ag and Mn. Under different excitation wavelengths, the phosphors emit blue light due to Ag+ luminescence centers and red light from the d-d transition of Mn2+. The blue emission is greatly suppressed at high Mn2+ doping levels, requiring reduced Ag+ doping in co-doped ZnS:Ag,Mn compared to solo-doped ZnS:Ag samples. By adjusting Ag+ and Mn2+ concentrations, the ZnS:Ag(1%),Mn(0.2%) phosphors show a proper intensity ratio of blue and red emissions, making them a promising candidate for future white light applications.
柔性发光二极管是一种多功能照明解决方案,可提供可弯曲和适应性强的照明可能性。一种柔软、灵活的白色发光薄膜(1 毫米)显示了可折叠电致发光器件和应用的前景。这种薄膜是用 ZnS:Ag 和 Mn 制成的。在不同的激发波长下,荧光粉因 Ag+ 发光中心而发出蓝光,因 Mn2+ 的 d-d 转变而发出红光。与单独掺杂的 ZnS:Ag 样品相比,在高 Mn2+掺杂水平下,蓝色发射被大大抑制,这就要求减少共掺杂 ZnS:Ag,Mn 中的 Ag+掺杂。通过调整 Ag+ 和 Mn2+ 的浓度,ZnS:Ag(1%),Mn(0.2%) 荧光粉显示出适当的蓝光和红光发射强度比,使其成为未来白光应用的理想候选材料。
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引用次数: 0
Flourishing electronic textiles towards pervasive, personalized and intelligent healthcare 发展电子纺织品,实现无处不在的个性化和智能化医疗保健
Pub Date : 2024-01-04 DOI: 10.20517/ss.2023.35
Feifan Sheng, Cheng Zhao, Bo Zhang, Yingxue Tan, Kai Dong
In the face of pandemic infectious diseases and increasing aging trends, traditional public health systems lack the capacity for real-time monitoring, immediate clinical detection, continuous vital sign monitoring, and the implementation of long-cycle treatment protocols, among other deficiencies. On the basis of the rapid development of wearable electronic devices, the Internet of Things, and artificial intelligence, the future healthcare model will transform from a therapeutic, centralized, passive, and even one-size-fits-all treatment to a new paradigm of proactive, preventive, personalized, customized, and intelligent way. The development of wearable electronics has facilitated the evolution of healthcare from healthcare to biological monitoring, enabling continuous monitoring of critical biomarkers for diagnostic treatment, physiological health monitoring, and assessment. Electronic textiles (e-textiles) are among the rapidly developing wearable electronics in recent years. They have revolutionized the functionality of traditional textiles by incorporating smart attributes, enabling unique and multifunctional applications. Significantly, e-textiles have made notable advancements in the field of personalized healthcare. The article introduces several common e-textiles and their applications in personalized medicines, which also gives a forward-looking outlook on their future growth in infectious diseases, real-time health preventive monitoring, auxiliary therapy, and rehabilitation training.
面对流行性传染病和日益加剧的老龄化趋势,传统的公共卫生系统缺乏实时监测、即时临床检测、连续生命体征监测和实施长周期治疗方案等能力。在可穿戴电子设备、物联网和人工智能快速发展的基础上,未来的医疗模式将从治疗型、集中型、被动型,甚至一刀切的治疗方式转变为主动型、预防型、个性化、定制化、智能化的新模式。可穿戴电子设备的发展促进了医疗保健从医疗保健向生物监测的演变,实现了对诊断治疗、生理健康监测和评估所需的关键生物标志物的连续监测。电子纺织品是近年来发展迅速的可穿戴电子产品之一。它们通过融入智能属性,实现了独特的多功能应用,从而彻底改变了传统纺织品的功能。值得一提的是,电子纺织品在个性化医疗保健领域取得了显著进展。本文介绍了几种常见的电子纺织品及其在个性化医疗中的应用,并对其在传染病、实时健康预防监测、辅助治疗和康复训练等方面的未来发展进行了前瞻性展望。
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引用次数: 0
Emerging epidermal electrodes towards digital health and on-skin digitalization 面向数字健康和皮肤数字化的新兴表皮电极
Pub Date : 2024-01-01 DOI: 10.20517/ss.2023.44
Yan Wang
Epidermal electrodes can be directly attached to the human skin for high-fidelity electrophysiological monitoring owing to their preponderance in thinness, lightweight, conformability, biocompatibility, self-adhesiveness, mechanical flexibility, gas-permeability, etc. These devices have attracted immense attention due to their emerging applications in personalized health care, human/brain-machine interfaces, and soft robotics. This Perspective focuses on the most recent significant progress in this area, especially materials, properties, and applications. Challenges and prospects are summarized to underscore the unexploited areas and future directions toward digital health and on-skin digitalization.
由于表皮电极具有轻薄、顺应性、生物相容性、自粘性、机械柔韧性、气体渗透性等优点,可直接附着在人体皮肤上进行高保真电生理监测。这些设备在个性化医疗保健、人/脑-机接口和软机器人等领域的新兴应用引起了广泛关注。本视角聚焦于该领域的最新重大进展,尤其是材料、特性和应用。此外,还总结了面临的挑战和发展前景,强调了尚未开发的领域以及数字健康和皮肤数字化的未来方向。
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引用次数: 0
Liquid metals nanotransformer for healthcare biosensors 医疗保健生物传感器用液态金属纳米变压器
Pub Date : 2023-11-03 DOI: 10.20517/ss.2023.38
Yunlong Bai, Jie Zhang, Chennan Lu, Wei Rao
Featuring low cost, low melting points, excellent biocompatibility, outstanding electrical conductivity, and mechanical properties, gallium-based liquid metals (LMs) have become a promising class of materials to fabricate flexible healthcare sensors. However, the extremely high surface tension hinders their manipulation and cooperation with substrates. To address this problem, the inspiration of nanomaterials has been adopted to mold LMs into LM nanoparticles (LMNPs) with expanded advantages. The transformability of LMNPs endows them with functionalities for sensors in multiple dimensions, such as intelligent response to specific molecules or strains, various morphologies, integration into high-resolution circuits, and conductive elastomers. This review aims to summarize the superior properties of LMs, transformability of LMNPs, and correlated advantages for sensor performance. Multidimensional functional sensing forms consisting of LMNPs and corresponding applications as healthcare sensors will be presented. In the end, the existing challenges and prospects in the processing and application of LMNPs will also be discussed.
镓基液态金属(LMs)具有低成本、低熔点、优异的生物相容性、优异的导电性和机械性能,已成为制造柔性医疗传感器的有前途的材料。然而,极高的表面张力阻碍了它们与衬底的操纵和合作。为了解决这一问题,采用纳米材料的灵感将LM模塑成具有扩展优势的LM纳米颗粒(LMNPs)。LMNPs的可转换性赋予它们在多个维度上的传感器功能,例如对特定分子或应变的智能响应,各种形态,集成到高分辨率电路和导电弹性体中。本文旨在总结LMs的优越性能、LMNPs的可转换性以及在传感器性能方面的相关优势。将介绍由LMNPs组成的多维功能传感形式及其作为医疗保健传感器的相应应用。最后,讨论了LMNPs在加工和应用中存在的挑战和前景。
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引用次数: 0
Soft devices empowered by mechanoluminescent materials 由机械发光材料驱动的软装置
Pub Date : 2023-11-02 DOI: 10.20517/ss.2023.33
Chunfeng Wang, Hongjie Hu, Dengfeng Peng, Lin Dong, Deliang Zhu
Mechanoluminescence is the phenomenon in which certain materials emit light when subjected to mechanical stimuli, such as bending, stretching, or compression. Soft devices containing embedded mechanoluminescent materials are capable of responding to mechanical deformation by emitting light, which can be utilized for various applications, including sensing, display, communication, and visual feedback. In this Perspective, we discuss recent advancements and emerging applications of mechanoluminescent materials for soft devices, with a focus on the remaining challenges in mechanoluminescent materials, such as performance, mechanism, synthesis, and device fabrication, that need to be addressed for developing advanced soft devices, and propose the potential solutions.
机械发光是指某些材料在受到机械刺激(如弯曲、拉伸或压缩)时发光的现象。包含嵌入式机械发光材料的软器件能够通过发光来响应机械变形,可用于各种应用,包括传感,显示,通信和视觉反馈。在本展望中,我们讨论了软器件机械发光材料的最新进展和新兴应用,重点讨论了开发先进软器件需要解决的机械发光材料的性能、机理、合成和器件制造等挑战,并提出了潜在的解决方案。
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引用次数: 0
Morphing matter: from mechanical principles to robotic applications 变形物质:从机械原理到机器人应用
Pub Date : 2023-11-01 DOI: 10.20517/ss.2023.42
Xudong Yang, Yuan Zhou, Huichan Zhao, Weicheng Huang, Yifan Wang, K. Jimmy Hsia, Mingchao Liu
The adaptability of natural organisms in altering body shapes in response to the environment has inspired the development of artificial morphing matter. These materials encode the ability to transform their geometrical configurations in response to specific stimuli and have diverse applications in soft robotics, wearable electronics, and biomedical devices. However, achieving the morphing of intricate three-dimensional shapes from a two-dimensional flat state is challenging, as it requires manipulations of surface curvature in a controlled manner. In this review, we first summarize the mechanical principles extensively explored for realizing morphing matter, both at the material and structural levels. We then highlight its applications in the soft robotics field. Moreover, we offer insights into the open challenges and opportunities that this rapidly growing field faces. This review aims to inspire researchers to uncover innovative working principles and create multifunctional morphing matter for various engineering fields.
自然生物在改变身体形状以响应环境方面的适应性激发了人工变形物质的发展。这些材料编码的能力,以改变其几何结构,以响应特定的刺激,并有不同的应用在软机器人,可穿戴电子产品和生物医学设备。然而,从二维平面状态实现复杂的三维形状的变形是具有挑战性的,因为它需要以可控的方式操纵表面曲率。在这篇综述中,我们首先总结了在材料和结构水平上广泛探索的实现变形物质的力学原理。然后重点介绍了其在软机器人领域的应用。此外,我们对这个快速发展的领域所面临的公开挑战和机遇提供了见解。本文旨在启发研究人员揭示创新的工作原理,并为各种工程领域创造多功能变形材料。
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引用次数: 0
Recent advancements in liquid metal enabled flexible and wearable biosensors 液态金属的最新进展使柔性和可穿戴生物传感器成为可能
Pub Date : 2023-10-16 DOI: 10.20517/ss.2023.30
Guoqiang Li, Sanhu Liu, Zhiwu Xu, Jinhong Guo, Shi-Yang Tang, Xing Ma
Wearable biosensors have demonstrated enormous potential in revolutionizing healthcare by providing real-time fitness tracking, enabling remote patient monitoring, and facilitating early detection of health issues. To better sense vital life signals, researchers are increasingly favoring wearable biosensors with flexible properties that can be seamlessly integrated with human tissues, achieved through the utilization of soft materials. Gallium (Ga)-based liquid metals (LMs) possess desirable properties, such as fluidity, high conductivity, and negligible toxicity, which make them inherently soft and well-suited for the fabrication of flexible and wearable biosensors. In this article, we present a comprehensive overview of the recent advancements in the nascent realm of flexible and wearable biosensors employing LMs as key components. This paper provides a detailed exposition of the unique characteristics of Ga-based LM materials, which set them apart from traditional materials. Moreover, the state-of-the-art applications of Ga-based LMs in flexible and wearable biosensors that expounded from six aspects are reviewed, including wearable interconnects, pressure sensors, strain sensors, temperature sensors, and implantable bioelectrodes. Furthermore, perspectives on the key challenges and future developing directions of LM-enabled wearable and flexible biosensors are also discussed.
可穿戴生物传感器通过提供实时健身跟踪、远程患者监控和促进健康问题的早期发现,在彻底改变医疗保健方面展示了巨大的潜力。为了更好地感知重要的生命信号,研究人员越来越青睐具有柔性特性的可穿戴生物传感器,这种传感器可以通过使用柔软材料与人体组织无缝集成。镓(Ga)基液态金属(LMs)具有理想的特性,如流动性、高导电性和可忽略不计的毒性,这使得它们天生柔软,非常适合制造柔性和可穿戴的生物传感器。在本文中,我们全面概述了采用LMs作为关键部件的柔性可穿戴生物传感器的最新进展。本文详细阐述了ga基LM材料不同于传统材料的独特特性。此外,从可穿戴互连、压力传感器、应变传感器、温度传感器和植入式生物电极六个方面综述了基于ga的LMs在柔性和可穿戴生物传感器中的最新应用。此外,还讨论了基于lm的可穿戴和柔性生物传感器的主要挑战和未来发展方向。
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引用次数: 0
A highly stretchable and sintering-free liquid metal composite conductor enabled by ferrofluid 一种由铁磁流体实现的高度可拉伸且无烧结的液态金属复合导体
Pub Date : 2023-10-16 DOI: 10.20517/ss.2023.28
Maoyu Peng, Biao Ma, Guoqiang Li, Yong Liu, Yang Zhang, Xing Ma, Sheng Yan
Stretchable and highly conductive elastomers with intrinsically deformable liquid metal (LM) fillers exhibit promising potential in soft electronics, wearables, human-machine interfaces, and soft robotics. However, conventional LM-elastomer (LME) conductors require a high loading ratio of LM and the post-sintering to rupture LM particles to achieve electric conductivity, which results in high LM consumption and process complexity. In this work, we presented a straightforward and post-sintering-free method that utilizes magnetic aggregation to fabricate stretchable LME conductors. This was achieved by dispersing LM ferrofluid into the elastomer precursor, followed by applying the magnetic field to induce the aggregation and interconnection of the LM ferrofluid particles to form conductive pathways. This method not only simplifies the preparation of initially conductive LME but also reduces the LM loading ratio. The resulting conductive LME composites show high stretchability (up to 650% strain), high conductance stability, and magnetic responsiveness. The stretchable LME conductors were demonstrated in various applications, including the creation of flexible microcircuits, a magnetically controlled soft switch, and a soft hydrogel actuator for grasping tasks. We believe the stretchable LME conductors may find wide applications in electronic skins, soft sensors, and soft machines.
具有内在可变形液态金属(LM)填充物的可拉伸和高导电性弹性体在软电子、可穿戴设备、人机界面和软机器人领域具有广阔的应用前景。然而,传统的LM-弹性体(LME)导体需要较高的LM载荷比,并且在烧结后使LM颗粒破裂以实现导电性,这导致了较高的LM消耗和工艺复杂性。在这项工作中,我们提出了一种直接的、无烧结后的方法,利用磁聚集来制造可拉伸的LME导体。这是通过将LM铁磁流体分散到弹性体前体中,然后施加磁场诱导LM铁磁流体颗粒聚集和互连以形成导电途径来实现的。该方法不仅简化了初始导电LME的制备,而且降低了LM加载比。所得到的导电LME复合材料具有高拉伸性(高达650%的应变),高电导稳定性和磁响应性。可拉伸LME导体在各种应用中进行了演示,包括创建柔性微电路,磁控软开关和用于抓取任务的软水凝胶执行器。我们相信可拉伸LME导体在电子皮肤、软传感器和软机器中有广泛的应用。
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引用次数: 0
Vacuum filtration method towards flexible thermoelectric films 柔性热电薄膜的真空过滤方法
Pub Date : 2023-10-09 DOI: 10.20517/ss.2023.25
Chenxi Wang, Qing Liu, Haijun Song, Qinglin Jiang
Thermoelectric (TE) conversion technology can directly exploit the temperature difference of several Kelvin between the human body and the environment to generate electricity, which provides a self-powered solution for wearable electronics. Flexible TE materials are increasingly being developed through various methods, among which the vacuum filtration method stands out for its unique advantages, attracting the favor of researchers. It has been proven to construct flexible TE thin films with excellent performance effectively. This paper presents a comprehensive overview and survey of the advances of the vacuum filtration method in producing flexible TE thin films. The materials covered in this study include conducting polymer-based materials, carbon nanoparticle-based materials, inorganic materials, two-dimensional materials, and ternary composites. Finally, we explore potential research outlooks and the significance of flexible films, which are at the forefront of research in TE materials science.
热电(TE)转换技术可以直接利用人体与环境之间几个开尔文的温差来发电,为可穿戴电子产品提供了自供电的解决方案。柔性TE材料正通过各种方法得到越来越多的开发,其中真空过滤法以其独特的优势脱颖而出,吸引了研究人员的青睐。已被证明可以有效地构建性能优异的柔性TE薄膜。本文对真空过滤法制备柔性TE薄膜的研究进展进行了综述和综述。本研究涉及的材料包括导电聚合物基材料、碳纳米颗粒基材料、无机材料、二维材料和三元复合材料。最后,我们探讨了柔性薄膜的潜在研究前景和意义,这是TE材料科学研究的前沿。
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引用次数: 0
A stretchable all-nanofiber iontronic pressure sensor 一种可拉伸的全纳米纤维离子电子压力传感器
Pub Date : 2023-10-07 DOI: 10.20517/ss.2023.24
Yigen Wu, Shuai Dong, Xiaojuan Li, Liguo Wen, Hongwei Shen, Mengjiao Li, Xin Liu, Yang Zhang, Guolong Zeng, Jianyi Zheng, Dezhi Wu
Flexible pressure sensors with high stretchability, sensitivity, and stability are undoubtedly urgently required for potential applications in intelligent soft robots, human-machine interaction, health monitoring, and other fields. However, most current flexible pressure sensors are unable to endure large deformation and are prone to performance degradation or even failure during frequent operation due to their multilayered structures. Here, we propose a stretchable all-nanofiber iontronic pressure sensor that is composed of ionic nanofiber membranes used as dielectric layers and liquid metal used as electrodes. This sensor exhibits a high sensitivity of 1.08 kPa-1 over a wide range of 0-300 kPa, with a fast response-relaxation time of about 18/22 ms and excellent stability. The high sensitivity comes from the electric double layer formed at the ionic film/electrode interface, while high stretchability and stability are enabled by in-situ encapsulated all-nanofiber structures. As a proof of concept, a prototype sensor array is integrated into a soft pneumatic gripper, demonstrating its capability of pressure perception and object recognition during the grasping process. Thus, the scheme provides another excellent strategy to fabricate stretchable pressure sensors with superb performance in terms of high stretchability, sensitivity, and stability.
具有高拉伸性、高灵敏度、高稳定性的柔性压力传感器在智能软机器人、人机交互、健康监测等领域的潜在应用无疑是迫切需要的。然而,目前大多数柔性压力传感器由于其多层结构,不能承受大的变形,在频繁的操作中容易出现性能下降甚至失效。在这里,我们提出了一种可拉伸的全纳米纤维离子电子压力传感器,该传感器由用作介电层的离子纳米纤维膜和用作电极的液态金属组成。该传感器在0-300 kPa的宽范围内具有1.08 kPa-1的高灵敏度,响应弛缓时间约为18/22 ms,稳定性好。高灵敏度来自于离子膜/电极界面形成的双电层,而高拉伸性和稳定性来自于原位封装的全纳米纤维结构。作为概念验证,将传感器阵列原型集成到软气动夹持器中,展示了其在抓取过程中的压力感知和物体识别能力。因此,该方案为制造具有高拉伸性、灵敏度和稳定性的优异性能的可拉伸压力传感器提供了另一种极好的策略。
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引用次数: 0
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Soft science
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