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Charge Plasma Based Si1-xGex Sourced Nanowire Tunnel Field Effect Transistor Oxygen Gas Device with Enhanced Sensitivity 灵敏度更高的基于等离子体的 Si1-xGex 源纳米线隧道场效应晶体管氧气器件
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-30 DOI: 10.1007/s12633-024-03126-1
Navaneet Kumar Singh, Chandan Kumar, Thakur Prasad Mahato, Suraj Kumar, Saquib Azam, Shradhya Singh, Naveen Kumar, Prashant Kumar Singh, Rajib Kar, Durbadal Mandal

In this paper, Charge Plasma Nanowire Tunnel Field Effect Transistor based sensor is proposed for the recognition of Oxygen (O2) gas molecules by means of a Silicon Germanium (Si1-xGex) sourced device abbreviated as SiGe-CP-NW-TFET. The electrical performances of SiGe-CP-NW-TFET have been compared with the conventional Charge Plasma Nanowire Tunnel Field Effect Transistor (CP-NW-TFET). The parameters measured for comparison are ION, IOFF, ION/IOFF, Subthreshold slope (SS), and threshold voltage (Vt). The proposed SiGe-CP-NW-TFET has better electrical performance as compared to Si-CP-NW-TFET. Further, the device characteristics such as electric potential, electric field, charge carriers, and energy band diagram of both the devices have also been compared. The fundamental physics of the proposed sensor is also explored from a comprehensive electrostatic study of the tunnelling junction in the context of gas molecule adsorption. The influence of device constraints of the proposed SiGe-CP-NW-TFET on the electrical performance indicators has also been studied. The device parameters e.g. oxide thickness, extended gate length, silicon film thickness, and molar concentration of SiGe at the source side are considered. The impact of oxide thickness, extended gate length, the radius of NW, and the concentration of SiGe (molar) at the source side have been analysed on the sensitivity of the O2 gas sensor. The presented Oxygen gas sensor has an ION/IOFF ratio of 3.65 × 107 and a subthreshold slope of 58.23 mV/decade.

本文提出了基于电荷等离子体纳米线隧道场效应晶体管的传感器,通过硅锗(Si1-xGex)源器件(缩写为 SiGe-CP-NW-TFET)识别氧气(O2)气体分子。SiGe-CP-NW-TFET 的电气性能与传统的电荷等离子体纳米线隧道场效应晶体管 (CP-NW-TFET) 进行了比较。用于比较的测量参数包括 ION、IOFF、ION/IOFF、次阈值斜率 (SS) 和阈值电压 (Vt)。与 Si-CP-NW-TFET 相比,拟议的 SiGe-CP-NW-TFET 具有更好的电气性能。此外,还比较了两种器件的电动势、电场、电荷载流子和能带图等器件特性。在气体分子吸附的背景下,通过对隧道结的综合静电研究,还探讨了拟议传感器的基本物理原理。此外,还研究了拟议的 SiGe-CP-NW-TFET 器件约束对电气性能指标的影响。研究考虑了器件参数,如氧化物厚度、扩展栅极长度、硅薄膜厚度以及源侧 SiGe 的摩尔浓度。分析了氧化物厚度、扩展栅极长度、氮化硅半径和源侧锡锗(摩尔)浓度对氧气传感器灵敏度的影响。该氧气传感器的离子/离子交换比为 3.65 × 107,阈下斜率为 58.23 mV/decade。
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引用次数: 0
Face Index of Silicon Carbide Structures: An Alternative Approach 碳化硅结构的面指数:另一种方法
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-29 DOI: 10.1007/s12633-024-03119-0
Shriya Negi, Vijay Kumar Bhat

Face index is a critical topological descriptor that provides important information about the structural variations of various materials. Initially introduced as a novel metric, the face index has become essential in characterizing the complexity and properties of molecular structures like silicate networks, carbon sheets, and nanotubes. This analysis focuses on the face index within the Silicon Carbide structure, highlighting its profound significance as a pivotal structural descriptor. By shedding light on its implications for the fundamental properties of three different Silicon Carbide structures: (Si_2C_3)-I[mn], (Si_2C_3)-II[mn] and (Si_2C_3)-III[mn], this study aims to advance our understanding of the structural complexities and potential applications of this unique material system.

面指数是一种重要的拓扑描述符,可提供有关各种材料结构变化的重要信息。面指数最初是作为一种新颖的度量指标引入的,现在已成为表征硅酸盐网络、碳片和纳米管等分子结构的复杂性和特性的重要指标。本文重点分析碳化硅结构中的面指数,突出其作为关键结构描述符的深远意义。通过阐明面指数对三种不同碳化硅结构的基本特性的影响,我们将对碳化硅结构中的面指数进行分析:(Si_2C_3)-I[m,n]、(Si_2C_3)-II[m,n]和(Si_2C_3)-III[m,n],这项研究旨在推进我们对这种独特材料系统的结构复杂性和潜在应用的理解。
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引用次数: 0
Sensitivity Investigation of Underlap Gate Cavity-Based Reconfigurable Silicon Nanowire Schottky Barrier Transistor for Biosensor Application 用于生物传感器应用的基于下隙栅极空腔的可重构硅纳米线肖特基势垒晶体管的灵敏度研究
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-29 DOI: 10.1007/s12633-024-03125-2
Anil Kumar, Vijay Thakur, Suraj Kumar, Sumit Kale, Kaustubh Ranjan Singh

This study investigates the sensitivity of Underlap Gate Cavity-based Reconfigurable Silicon Nanowire Schottky Barrier Transistor (UCG-RSiNW SBT) with an underlap gate-drain region for biosensing application. The featured unique reconfigurable capability enables the device to operate as either p-type or n-type, dependent on the applied bias polarity. The proposed biosensor incorporates a cavity beneath the control gate on the source side, facilitating the placement of both neutral and charged biomolecules with varying dielectric constant (K) values. Upon injection of biomolecules into the cavity, the device changes electrostatic characteristics, including modulation in threshold voltage, potential, electric field, and sub-threshold swing, (I_{ON}), (I_{ON})/( I_{OFF}) ratio. The threshold voltage ((V_{TH})) Sensitivity of n-mode is enhanced by (97.91%), while that of p-mode is raised by (16%) compared to conventional RFET biosensors. The drain current sensitivity and the linearity of proposed biosensor is enhanced upto the values of 2792 and 0.997 respectively in n-mode configuration whereas in p-mode configuration, the drain current sensitivity and the linearity comes out to be 968 and 0.995 respectively. These high sensitivity and linearity values make this biosensor superior to the existing state-of-the-art biosensors. The findings from this study provide valuable insights into the development of highly sensitive biosensors for applications in diverse fields, including healthcare and biotechnology.

本研究调查了基于栅下隙腔的可重构硅纳米线肖特基势垒晶体管(UCG-RSiNW SBT)的灵敏度,该器件具有栅下隙栅漏区,可用于生物传感应用。该器件具有独特的可重构功能,能根据应用的偏置极性以 p 型或 n 型工作。拟议中的生物传感器在源侧控制栅极下方集成了一个空腔,便于放置介电常数(K)值不同的中性和带电生物分子。将生物分子注入空腔后,器件的静电特性会发生变化,包括阈值电压、电势、电场和亚阈值摆幅((I_{ON})、(I_{ON})/( I_{OFF})比)的调制。阈值电压((V_{TH})与传统的 RFET 生物传感器相比,n 模式的灵敏度提高了 97.91%,p 模式的灵敏度提高了 16%。在 n 模式配置下,拟议生物传感器的漏极电流灵敏度和线性度分别提高到 2792 和 0.997,而在 p 模式配置下,漏极电流灵敏度和线性度分别为 968 和 0.995。这些高灵敏度和线性度值使这种生物传感器优于现有的最先进生物传感器。这项研究的结果为开发应用于医疗保健和生物技术等不同领域的高灵敏度生物传感器提供了宝贵的启示。
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引用次数: 0
Statistical Analysis of Increased Immunity to Poly-Si Grain Boundaries in Nanosheet CMOS Logic Inverter Through Sheet Stacking 通过片式堆叠提高纳米片 CMOS 逻辑逆变器多晶硅晶粒边界抗扰度的统计分析
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-27 DOI: 10.1007/s12633-024-03113-6
Min Seok Kim, Sang Ho Lee, Jin Park, So Ra Jeon, Seung Ji Bae, Jeong Woo Hong, Jaewon Jang, Jin-Hyuk Bae, Young Jun Yoon, In Man Kang

Herein, the advantages of sheet stacking in polycrystalline Si (Poly-Si)–based nanosheet MOSFETs and CMOS inverters were statistically analyzed through technology computer-aided design simulations. Poly-Si is used as the channel material to make the high-density three-dimensional structure in a simple process. We studied the transfer characteristics of single-layer nanosheet (SN) MOSFETs and 3-layer multi-bridge nanosheet (MN) MOSFETs depending on the location and the number of grain boundaries (GBs). Further, the DC/switching performance of SN CMOS and MN CMOS inverters was analyzed based on the location and number of GBs. The multilayer stacked structure not only increased the average on state current and switching speed but also reduced the dispersion of characteristics and performance. In addition, multilayer stacked structure increased the yield based on the 3 sigma-level. Therefore, the stacked MN structure is suitable for implementation in MOSFETs and CMOS inverters with high performance and reliability against fluctuations caused by poly-Si GBs.

本文通过技术计算机辅助设计模拟,对基于多晶硅(Poly-Si)的纳米片 MOSFET 和 CMOS 逆变器中片堆叠的优势进行了统计分析。采用多晶硅作为沟道材料,以简单的工艺制造出高密度的三维结构。我们研究了单层纳米片(SN)MOSFET 和三层多桥纳米片(MN)MOSFET 的传输特性,具体取决于晶界(GB)的位置和数量。此外,还根据晶界的位置和数量分析了 SN CMOS 和 MN CMOS 逆变器的直流/开关性能。多层堆叠结构不仅提高了平均导通电流和开关速度,还降低了特性和性能的分散性。此外,多层堆叠结构还提高了基于 3 sigma 级的良品率。因此,堆叠 MN 结构适用于 MOSFET 和 CMOS 逆变器,具有高性能和高可靠性,可抵御多晶硅 GB 引起的波动。
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引用次数: 0
Silica Shield: Harnessing Phytoliths for Sustainable Plant Protection-A Comprehensive Exploration 硅盾:利用植物岩石实现可持续植物保护--全面探索
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-27 DOI: 10.1007/s12633-024-03122-5
R. Saranya, M. Suganthy, K. Ganesan, S. K. Rajkishore, K. Sathiya Bama, P. Janaki, A.C. Priya Varshini

Phytoliths, the microscopic silica structures formed within plant tissues, are an emerging component of many sustainable plant protection attempts. They offer defense in multiple directions, physically strengthening plant tissues and biochemically engaging with the surroundings, and can diminish reliance on chemical pesticides and fertilizers. Physically, phytoliths enhance plant tissue rigidity and toughness, rendering them indigestible and less nutritious to herbivores and pathogens, thereby reducing feeding damage and disease incidence. Biochemically, phytoliths influence plant–microbe and plant–herbivore interactions by decreasing leaf palatability to herbivores, altering rhizosphere microbial communities including silica-specializing, plant-growth-promoting rhizobacteria, and diminishing pathogen proliferation. These effects enhance plant health by reducing pathogen spread and improving overall resilience. Furthermore, phytoliths accomplish crucial biogenic environmental roles such as facilitating biogeochemical silica and participating in essential nutrient cycles that uphold soil pH, fertility, and agricultural sustainability. Their enduring presence in soil enhances its structure, augments water retention, and improves nutrient availability, thereby fostering optimal conditions for plant growth. Additionally, phytoliths play a pivotal role in carbon sequestration and can immobilize heavy metals, mitigating soil contamination and advocating safer agricultural practices. This dual function in bolstering direct plant defense and indirectly enhancing soil health through carbon sequestration underscores the significant potential of phytoliths in sustainable agriculture. In our comprehensive exploration, we delve deeply into the imperative of integrating phytoliths into sustainable agricultural practices to cultivate innovative, eco-friendly, and resilient farming systems. Harnessing the complete potential of phytoliths can lead to advanced strategies for sustainable plant protection, aligning with global initiatives aimed at promoting environmental sustainability and agricultural resilience.

在许多可持续植物保护尝试中,植物硅片--植物组织内形成的微观二氧化硅结构--是一个新兴的组成部分。它们提供多方位的防御,在物理上加强植物组织,在生物化学上与周围环境接触,并能减少对化学农药和化肥的依赖。从物理角度讲,植物鳞片能增强植物组织的硬度和韧性,使其不易被食草动物和病原体消化,降低其营养价值,从而减少食害和病害的发生。在生物化学方面,植物鳞片石通过降低叶片对食草动物的适口性、改变根瘤微生物群落(包括硅专化、促进植物生长的根瘤菌)以及减少病原体增殖,影响植物与微生物以及植物与食草动物之间的相互作用。这些作用通过减少病原体传播和提高整体恢复能力来增强植物健康。此外,植物石还能发挥重要的生物源环境作用,如促进硅的生物地球化学作用,参与维持土壤酸碱度、肥力和农业可持续性的重要养分循环。它们在土壤中的持久存在可增强土壤结构、提高保水性、改善养分供应,从而为植物生长创造最佳条件。此外,植物石还在固碳方面发挥着关键作用,并能固定重金属,减轻土壤污染,倡导更安全的农业生产方式。这种既能直接增强植物防御能力,又能通过碳固存间接增强土壤健康的双重功能,凸显了植物体在可持续农业中的巨大潜力。在我们的全面探索中,我们深入探讨了将植物石融入可持续农业实践的必要性,以培养创新、生态友好和具有弹性的农业系统。利用植物体的全部潜力,可以制定先进的可持续植物保护战略,与旨在促进环境可持续性和农业恢复力的全球倡议保持一致。
{"title":"Silica Shield: Harnessing Phytoliths for Sustainable Plant Protection-A Comprehensive Exploration","authors":"R. Saranya,&nbsp;M. Suganthy,&nbsp;K. Ganesan,&nbsp;S. K. Rajkishore,&nbsp;K. Sathiya Bama,&nbsp;P. Janaki,&nbsp;A.C. Priya Varshini","doi":"10.1007/s12633-024-03122-5","DOIUrl":"10.1007/s12633-024-03122-5","url":null,"abstract":"<div><p>Phytoliths, the microscopic silica structures formed within plant tissues, are an emerging component of many sustainable plant protection attempts. They offer defense in multiple directions, physically strengthening plant tissues and biochemically engaging with the surroundings, and can diminish reliance on chemical pesticides and fertilizers. Physically, phytoliths enhance plant tissue rigidity and toughness, rendering them indigestible and less nutritious to herbivores and pathogens, thereby reducing feeding damage and disease incidence. Biochemically, phytoliths influence plant–microbe and plant–herbivore interactions by decreasing leaf palatability to herbivores, altering rhizosphere microbial communities including silica-specializing, plant-growth-promoting rhizobacteria, and diminishing pathogen proliferation. These effects enhance plant health by reducing pathogen spread and improving overall resilience. Furthermore, phytoliths accomplish crucial biogenic environmental roles such as facilitating biogeochemical silica and participating in essential nutrient cycles that uphold soil pH, fertility, and agricultural sustainability. Their enduring presence in soil enhances its structure, augments water retention, and improves nutrient availability, thereby fostering optimal conditions for plant growth. Additionally, phytoliths play a pivotal role in carbon sequestration and can immobilize heavy metals, mitigating soil contamination and advocating safer agricultural practices. This dual function in bolstering direct plant defense and indirectly enhancing soil health through carbon sequestration underscores the significant potential of phytoliths in sustainable agriculture. In our comprehensive exploration, we delve deeply into the imperative of integrating phytoliths into sustainable agricultural practices to cultivate innovative, eco-friendly, and resilient farming systems. Harnessing the complete potential of phytoliths can lead to advanced strategies for sustainable plant protection, aligning with global initiatives aimed at promoting environmental sustainability and agricultural resilience.</p></div>","PeriodicalId":776,"journal":{"name":"Silicon","volume":"16 16","pages":"5771 - 5789"},"PeriodicalIF":2.8,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morpho-Physio-Biochemical Responses of Sweet Basil Plants to Integrated Application of Silicon and Salicylic Acid under Water Supply Restrictions 甜罗勒植物在供水限制条件下对硅和水杨酸综合施用的形态-生理-生化反应
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-23 DOI: 10.1007/s12633-024-03123-4
Arindam Biswas, Hayat Ullah, Sushil Kumar Himanshu, Pedro García-Caparrós, Daonapa Chungloo, Patchara Praseartkul, Rujira Tisarum, Suriyan Cha-um, Avishek Datta

Drought stress can markedly reduce plant growth and development, leading to considerable yield losses in sweet basil (Ocimum basilicum L.). Individual application of silicon (Si) and salicylic acid (SA) has the potential to mitigate the detrimental effects of drought stress; however, their combined effect is largely unknown. The aim of this study was to evaluate the efficacy of Si and SA, both independently and in concert, in mitigating the deleterious impacts of drought stress on sweet basil plants. A factorial experiment was implemented using a completely randomized design, incorporating soil application of three Si levels (0, 30, and 60 kg ha–1), foliar application of three SA levels (0, 100, and 200 mg L–1), and three soil moisture levels (50, 75, and 100% field capacity ‘FC’). Leaf area, shoot dry matter, leaf yield, irrigation water productivity, net photosynthetic rate, and stomatal conductance were declined by 54–78%, 55–66%, 77–84%, 55–68%, 42–70%, and 73–92%, respectively, at 50% FC in contrast to conditions at 100% FC, while electrolyte leakage, free proline concentration, total phenol concentration, and total flavonoid concentration were increased by 77–130%, 173–330%, 87–148%, and 101–169%, respectively, across Si and SA doses. The treatment of 60 kg Si ha–1 in conjunction with 100 mg SA L–1 emerged as the most efficacious treatment. This combination resulted in a 174% augmentation in leaf area, a 91% enhancement in shoot dry matter, a 98% increase in leaf yield, a 63% increase in irrigation water productivity, a 28% rise in leaf relative water content, and a 112% increase in total phenol concentration at 50% FC, when compared to plants grown under the same soil moisture level without Si and SA supplementation. Additionally, this treatment combination reduced electrolyte leakage by 26% compared to the plants not receiving Si and SA at 50% FC. The performance of plants under this combination at 75% FC was superior to that of the control plants even under optimal conditions at 100% FC for some parameters, underscoring the drought-mitigating potential of Si and SA in sweet basil. The combination of Si (60 kg ha–1) as a soil amendment and SA (100 mg L–1) applied as a foliar spray could be an effective strategy for improving the drought tolerance ability of sweet basil and enhancing its performance under both water-stressed and well-watered conditions.

干旱胁迫会显著降低植物的生长和发育,导致甜罗勒(Ocimum basilicum L.)的产量大幅下降。单独施用硅(Si)和水杨酸(SA)有可能减轻干旱胁迫的不利影响;但是,它们的综合效应在很大程度上还不为人所知。本研究的目的是评估硅和水杨酸单独或联合使用对减轻干旱胁迫对甜罗勒植物的有害影响的功效。采用完全随机设计进行了一项因子试验,包括土壤施用三种浓度的 Si(0、30 和 60 千克/公顷-1)、叶面施用三种浓度的 SA(0、100 和 200 毫克/升-1)以及三种土壤湿度(50、75 和 100%田间持水量 "FC")。与 100% FC 条件相比,50% FC 条件下的叶面积、嫩枝干物质、叶片产量、灌溉水生产力、净光合速率和气孔导度分别下降了 54-78%、55-66%、77-84%、55-68%、42-70% 和 73-92%、而在不同的 Si 和 SA 剂量下,电解质渗漏、游离脯氨酸浓度、总酚浓度和总黄酮浓度分别增加了 77-130%、173-330%、87-148% 和 101-169%。60 kg Si ha-1 与 100 mg SA L-1 的组合是最有效的处理方法。与未补充 Si 和 SA 的相同土壤湿度下生长的植物相比,这一组合使叶面积增加了 174%,嫩枝干物质增加了 91%,叶片产量增加了 98%,灌溉水生产率增加了 63%,叶片相对含水量增加了 28%,50% FC 时的总酚浓度增加了 112%。此外,在 50% FC 条件下,与未补充 Si 和 SA 的植物相比,该处理组合可将电解质渗漏减少 26%。在 75% FC 条件下,即使在 100% FC 的最佳条件下,该组合下的植株在某些参数上的表现也优于对照植株,这突出表明了 Si 和 SA 在甜罗勒中的抗旱潜力。将土壤改良剂 Si(60 千克/公顷-1)和叶面喷施的 SA(100 毫克/升-1)结合使用,可以有效提高甜罗勒的抗旱能力,并提高其在水分胁迫和水分充足条件下的表现。
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引用次数: 0
Investigation of Strontium/Barium Silicate Glasses through MCNPX and Phy-X for X-rays Shielding 通过 MCNPX 和 Phy-X 研究用于 X 射线屏蔽的锶/钡硅酸盐玻璃
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-22 DOI: 10.1007/s12633-024-03109-2
Afreen Alam, Shaukat Ali Khattak, Gul Rooh, Hasan B. Albargi, Arshad Khan, Nadeem Khan, Irfan Ullah, Syed Zulfiqar, Tahirzeb Khan, Gulzar Khan

We study the radiation shielding properties 40X-60SiO2 glasses, where X represents either SrO or BaO, while using MCNPX simulations code and Phy-X software by assessing radiation shielding parameters such as mass and linear attenuation shielding parameters, mean free path, half-value layer, effective atomic number, and tenth value layer in the photon energy ranging from 0.001 to 15 MeV. The result obtained for the mass attenuation coefficient is used to determine the half-value layer (HVL), mean free path (MFP), tenth value layer (TVL), and effective atomic number (Zeff). Both mass attenuation coefficient results obtained for MCNPX and Phy-X demonstrate a high degree of agreement with each other. The half-value layer for 40BaO-60SiO2 is found to be increasing from 0.004 cm to 5.01 cm with the increasing the photon energy from 0.015 to 15 MeV, while for 40SrO-60SiO2 it increases from 0.01 cm to 7.19 cm in the same energy range. Similarly, the mean free path for 40BaO-60SiO2 increases from 0.006 cm to 7.23 cm with increasing energy from 0.015 to 15 MeV while it increases from 0.02 cm to 10.37 cm for 40SrO-60SiO2 in the same energy range. The lower half-value layer and mean free path for 40BaO-60SiO2 than for 40SrO-60SiO2 in the entire energy range is attributed to the higher density of Ba in 40BaO-60SiO2 than that of Sr in the 40SrO-60SiO2. The higher mass- and linear-attenuation coefficients and lower half- and tenth-value layers and mean free path for 40BaO-60SiO2 (with higher density) than for 40SrO-60SiO2 (with lower density) suggest that 40BaO-60SiO2 is more efficient in shielding the X-rays than the 40SrO-60SiO2. Therefore, it is inferred that 40BaO-60SiO2 glass can be used as a potential shielding material for medical applications such as in X-ray rooms and radiation therapy.

我们使用 MCNPX 仿真代码和 Phy-X 软件研究了 40X-60SiO2 玻璃(其中 X 代表 SrO 或 BaO)的辐射屏蔽特性,评估了光子能量范围从 0.001 到 15 MeV 的辐射屏蔽参数,如质量和线性衰减屏蔽参数、平均自由路径、半值层、有效原子序数和十值层。质量衰减系数的结果用于确定半值层(HVL)、平均自由路径(MFP)、十值层(TVL)和有效原子序数(Zeff)。MCNPX 和 Phy-X 的质量衰减系数结果显示出高度的一致性。随着光子能量从 0.015 兆电子伏增加到 15 兆电子伏,40BaO-60SiO2 的半值层从 0.004 厘米增加到 5.01 厘米,而 40SrO-60SiO2 的半值层在相同的能量范围内从 0.01 厘米增加到 7.19 厘米。同样,随着能量从 0.015 到 15 MeV 的增加,40BaO-60SiO2 的平均自由路径从 0.006 厘米增加到 7.23 厘米,而在相同的能量范围内,40SrO-60SiO2 的平均自由路径从 0.02 厘米增加到 10.37 厘米。在整个能量范围内,40BaO-60SiO2 的半值层和平均自由路径低于 40SrO-60SiO2,这是因为 40BaO-60SiO2 中 Ba 的密度高于 40SrO-60SiO2 中 Sr 的密度。与密度较低的 40SrO-60SiO2 相比,40BaO-60SiO2 的质量和线性衰减系数更高,半值和十值层以及平均自由路径更低,这表明 40BaO-60SiO2 比 40SrO-60SiO2 能更有效地屏蔽 X 射线。因此,可以推断 40BaO-60SiO2 玻璃可作为一种潜在的屏蔽材料用于医疗应用,如 X 射线室和放射治疗。
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引用次数: 0
Preparation of a New Single Component Silicone Resin and Its Application in Impregnating Varnish 新型单组分硅树脂的制备及其在浸渍清漆中的应用
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1007/s12633-024-03114-5
Jin-Hui Li, Dan Peng, Qiu-Hong Mou, Feng Wang, Yun-Qiao Ding

In this paper, a new single component silicone resin with D-T structural components was prepared through two condensation processes. The design of the silicone resin structure is based on computational simulation by B3LYP functional method with the 6-31G (d) level. A new class- C insulating solvent-free silicone impregnating varnish based the new single component silicone resin was prepared. The solvent-free varnish can be cured under the influence of heat and platinum catalysis. We tested the viscosity-temperature characteristic of the impregnating varnish. We observed the stability of the impregnating varnish under different temperature. We analyzed the curing characteristics of the impregnating varnish by DSC and Moving Die Rheometer. The curing process of the impregnating varnish is determined as follow: first curing stage for 22 h at 190℃, and then the second curing stage for 2 h at 200℃.

本文通过两种缩合工艺制备了一种具有 D-T 结构成分的新型单组分硅树脂。硅树脂结构的设计基于 6-31G (d) 水平的 B3LYP 函数计算模拟。以新型单组分硅树脂为基础,制备了一种新型 C 级绝缘无溶剂有机硅浸渍漆。该无溶剂浸渍漆可在加热和铂催化作用下固化。我们测试了浸渍漆的粘度-温度特性。我们观察了浸渍漆在不同温度下的稳定性。我们用 DSC 和移动模流变仪分析了浸渍漆的固化特性。浸渍漆的固化过程如下:第一阶段在 190℃下固化 22 小时,然后在 200℃下固化 2 小时。
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引用次数: 0
Ameliorating and Tailoring The Morphological, Structural, and Dielectric Characteristics of SiO2 /NiO Futuristic Nanocomposites Doped PVA-PEG for Nanoelectronic and Energy Storage Applications 改善和调整掺杂 PVA-PEG 的二氧化硅/氧化镍未来纳米复合材料的形态、结构和介电特性,用于纳米电子和储能应用
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-21 DOI: 10.1007/s12633-024-03121-6
Waleed Khalid Kadhim, Majeed Ali Habeeb

The current investigation inquiry involves silicon dioxide (SiO2) and nickel oxide (NiO) nanoparticles to enhance the structural and dielectric properties of a polyvinyl alcohol (PVA) with polyethylene glycol (PEG) combination for use in flexible pressure sensors and nanoelectrical devices. Solution casting was used to fabricate PVA-PEG-SiO2/NiO nanocomposites at various weight percentages of (SiO2/NiO) N.Ps (0, 2, 4, 6 and 8) wt%. The structural properties of PVA-PEG-SiO2/NiO nanocomposites were studied by X-ray diffraction (XRD), and the amorphous state of the mixture consisting of polyvinyl alcohol (PVA) and polyethylene glycol (PEG) was revealed. Furthermore, the characteristic peak of the original polymers was much smaller at higher doping concentrations. According to field emission scanning electron microscopy (FE-SEM), when the weight percentage approaches 8%, the top surface of the (PVA-PEG-SiO2/NiO) N.Cs films exhibits homogenous and cohesive clumps or fragments dispersed randomly. Optical microscopy made it possible to observe that nanoparticles (SiO2/NiO) generate an integrated network inside the matrix of polymers, unlike the pure film of (PVA-PEG). The electrical properties of alternating current illustrate that as the frequency of the applied electrical field increases, the dielectric constant and dielectric loss of nanocomposites decline. Also, on the contrary, these values increase in conjunction with the increase in the concentration of nanoparticles, and the highest value is at a frequency of 100 Hz at a concentration of 8%. The (PVA-PEG) blend’s dielectric constant and A.C. electrical conductivity were improved by almost 300% and 112%, respectively, at the highest addition rate (8 wt.%). The findings obtained revealed that the structural and AC electrical conductivity were enhanced by doping (PVA-PEG) with (SiO2/NiO) NPs. Findings indicated that the (PVA-PEG-SiO2/NiO) nanostructures would be excellent materials for a range of nanoelectronics industries. The results obtained showed an increase in parallel capacity. It reached 400 pf with an increase in applied pressure, as well as an increase in sensitivity to pressure of about 77.2 with the biggest percentage of weight addition of nanoparticles.

目前的研究涉及二氧化硅(SiO2)和氧化镍(NiO)纳米粒子,以增强聚乙烯醇(PVA)与聚乙二醇(PEG)组合的结构和介电特性,用于柔性压力传感器和纳米电气设备。采用溶液浇注法制造了不同重量百分比(SiO2/NiO)N.Ps(0、2、4、6 和 8)的 PVA-PEG-SiO2/NiO 纳米复合材料。通过 X 射线衍射(XRD)研究了 PVA-PEG-SiO2/NiO 纳米复合材料的结构特性,发现聚乙烯醇(PVA)和聚乙二醇(PEG)的混合物呈无定形状态。此外,掺杂浓度越高,原始聚合物的特征峰就越小。场发射扫描电子显微镜(FE-SEM)显示,当重量百分比接近 8%时,(PVA-PEG-SiO2/NiO)N.Cs 薄膜的顶面呈现出均匀且有内聚力的团块或随机分散的碎片。通过光学显微镜可以观察到,纳米颗粒(SiO2/NiO)在聚合物基质中形成了一个完整的网络,这与纯薄膜(PVA-PEG)不同。交流电的电特性表明,随着外加电场频率的增加,纳米复合材料的介电常数和介电损耗都会下降。相反,随着纳米颗粒浓度的增加,这些数值也随之增加,最高值出现在频率为 100 Hz、浓度为 8%的情况下。在最高添加率(8 wt.%)下,(PVA-PEG)混合物的介电常数和 A.C. 导电性分别提高了近 300% 和 112%。研究结果表明,在(PVA-PEG)中掺入(SiO2/NiO)氮氧化物可增强其结构和交流导电性。研究结果表明,(PVA-PEG-SiO2/NiO)纳米结构将成为一系列纳米电子工业的优良材料。研究结果表明,并联容量有所增加。随着施加压力的增加,并联容量达到了 400 pf,并且随着纳米粒子重量百分比的增加,对压力的灵敏度增加了约 77.2。
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引用次数: 0
Composite coatings from polycarbosilane derived SiC and Al/SiC cermet active fillers as protective barriers against steel corrosion 由聚碳硅烷衍生的碳化硅和铝/碳化硅金属陶瓷活性填料制成的复合涂层作为钢材防腐保护层
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-08-20 DOI: 10.1007/s12633-024-03115-4
María F. Valerio-Rodríguez, Luis A. González, José M. Mata-Padilla, Eddie López-Honorato

Stainless steel is used throughout the world as a structural material. However, it undergoes corrosion damage when exposed to extremely corrosive media, such as the marine environment. An alternative to solve this problem lies in the development of coatings that can withstand extreme conditions but also be easily deposited with inherently corrosion-resistant materials such as silicon carbide (SiC). The present study shows a simple method to produce Al/SiC cermet powders by attrition milling. The resulting cermet powders with a metallic matrix and hemispherical morphology, were employed as fillers in polycarbosilane (PCS) solutions that were sprayed on A304 stainless steel substrates. Al/SiC composite coatings were produced after heating the sprayed suspensions at 700 °C for 1 h in Ar atmosphere. The resulting composite coatings exhibited low surface energies (< 35 mN/m), water contact angles of 53°, and adhesion strength of up to 30 MPa. Finally, corrosion tests were performed in a cyclic corrosion test chamber, showing that these coatings effectively reduced the corrosion rate of stainless steel by 87%, reaching corrosion rate values of 0.007 g/cm2 year.

不锈钢在世界各地都被用作结构材料。然而,当不锈钢暴露在海洋环境等腐蚀性极强的介质中时,就会受到腐蚀破坏。解决这一问题的另一种方法是开发既能承受极端条件,又能轻松沉积碳化硅(SiC)等固有耐腐蚀材料的涂层。本研究展示了一种通过自然磨损法生产 Al/SiC 金属陶瓷粉末的简单方法。得到的具有金属基体和半球形态的金属陶瓷粉被用作聚碳硅烷(PCS)溶液的填料,喷涂在 A304 不锈钢基底上。在氩气环境中将喷涂悬浮液在 700 °C 下加热 1 小时后,生成了 Al/SiC 复合涂层。生成的复合涂层具有较低的表面能(35 mN/m),水接触角为 53°,附着强度高达 30 MPa。最后,在循环腐蚀试验箱中进行了腐蚀试验,结果表明这些涂层有效地降低了 87% 的不锈钢腐蚀率,腐蚀率值达到每年 0.007 g/cm2。
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